WO2003014407A1 - High-strength, high-ductility nodular iron, and transmission housing produced therefrom - Google Patents

High-strength, high-ductility nodular iron, and transmission housing produced therefrom Download PDF

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Publication number
WO2003014407A1
WO2003014407A1 PCT/AT2002/000234 AT0200234W WO03014407A1 WO 2003014407 A1 WO2003014407 A1 WO 2003014407A1 AT 0200234 W AT0200234 W AT 0200234W WO 03014407 A1 WO03014407 A1 WO 03014407A1
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WO
WIPO (PCT)
Prior art keywords
percent
strength
ductility
silicon
housing
Prior art date
Application number
PCT/AT2002/000234
Other languages
German (de)
French (fr)
Inventor
Oskar Kehrer
Original Assignee
Magna Steyr Powertrain Ag & Co Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Magna Steyr Powertrain Ag & Co Kg filed Critical Magna Steyr Powertrain Ag & Co Kg
Priority to US10/486,154 priority Critical patent/US20040219052A1/en
Priority to KR10-2004-7001871A priority patent/KR20040017853A/en
Priority to DE50205710T priority patent/DE50205710D1/en
Priority to JP2003519535A priority patent/JP2004537652A/en
Priority to CA002456432A priority patent/CA2456432A1/en
Priority to EP02766913A priority patent/EP1415009B1/en
Publication of WO2003014407A1 publication Critical patent/WO2003014407A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/04Cast-iron alloys containing spheroidal graphite

Definitions

  • the invention relates to a nodular cast iron with siliconized silicon, as it is commonly used for heavily used castings, for example the materials according to DIN or SAE [in square brackets]:
  • the first one (a) is still ferritic and therefore tenacious, but its strength is only mediocre. If the strength is to be higher, one resorts to the materials b), c) and d), which in turn are ferritic-perlitic to 0 perlitiscli, with strong declinative toughness and weldability. These materials have from a) to d) increasingly a multiphase (ferritic-pearlitic) Grundfuge locally different composition, which is reinforced by the unavoidable during casting locally different cooling conditions and to 5 problems in the subsequent, in particular machining , Editing leads. Their use is therefore limited to special applications. In vehicle construction, the reduction of weight is a particular concern, which in castings low wall thickness - ie high strength - but also requires toughness and good workability. It is then necessary to use steel, but it is about 10 percent heavier.
  • a nodular cast iron according to the invention contains: 4 to 6 percent silicon and a proportion of carbon corresponding to the carbon equivalent, a maximum of 0.03 percent phosphorus and 0.2 to 0.5 percent nickel.
  • the high content of silicon has a ferrite-stabilizing effect and also increases the strength.
  • the carbon equivalent requires a corresponding reduction of the carbon content. Since phosphorus acts as embrittlement due to the strong solid solution hardening of the compounds it has received, the phosphorus content must be kept as small as possible. Nickel also reduces the brittleness and increases the strength, the required proportions are so small that the resulting additional costs are negligible.
  • the invention also relates to housings, in particular gear housing, which consist of a ductile iron according to one of the preceding claims.
  • gear housing which consist of a ductile iron according to one of the preceding claims.
  • Such a gear housing can be thinner walled and lighter because of the high strength of the fiction, according to improved ductile iron.
  • the machining necessary for the formation of connection flanges and bearing seats is possible without restriction.
  • a gear housing made of the material according to the invention can be welded to a toothed part made of alloyed and / or case-hardened steel.
  • Fig. 1 A comparison of nodular iron according to the prior
  • FIG. 2 shows a section through a transmission housing according to the invention.
  • the housing for example, the housing of a transmission, with 1 and a connected thereto to a component gear designated by 2.
  • the housing 1 here consists of an inventively improved ductile iron.
  • the gear 2 is made of steel and case hardened.
  • the housing 1 has a first axis normal to be welded surface 3, To which a cylindrical collar 4 connects, which forms an outer cylindrical mating surface 5.
  • the housing 1 may be provided at a location greater wall thickness with a parallel to the first surface to be welded to circumferential groove 6, which is rounded in cross-section.
  • the cylindrical mating surface 8 can be withdrawn at the transition to the second surface 7 to be welded, so that an extension 9 forms. This facilitates the production and the sliding of the gear on the collar 4 and, if necessary, improves the penetration of the root.
  • the axis of rotation of the component and 20 of the welding head is designated.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Details Of Gearings (AREA)
  • Gears, Cams (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

The invention relates to an improved high-strength nodular iron that is yet tenacious and can be easily machined and welded. The inventive iron comprises 4 to 6 % of silicon and a percentage of carbon reduced according to the carbon equivalent, not more than 0.03 % of phosphorus and 0.2 to 0.5 % of nickel. A housing (1) produced from said iron is welded with a toothed element (2) from alloyed and/or case-hardened steel.

Description

SPHAROGUSS MIT HOHER FESTIGKEIT UND DUKTILITAT UND DARAUS HERGESTELLTES GETRIEBEGEHAUSE 5SPHAROGOUS WITH HIGH STRENGTH AND DUCTILITY AND GEARBOX MANUFACTURED THEREOF 5
Die Erfindung betrifft einen Sphäroguss mit einlegiertem Silizium, wie er für stark beanspruchte Gussteile üblicherweise verwendet wird, beispielsweise die Werkstoffe nach DIN beziehungsweise SAE [in eckiger Klam- 0 mer]:The invention relates to a nodular cast iron with siliconized silicon, as it is commonly used for heavily used castings, for example the materials according to DIN or SAE [in square brackets]:
a) EN-GJS-400-16 [D4018], b) EN-GJS-500- 7 [D4512], c) EN-GJS-600- 3 [D5608], 5 d) EN-GJS-700- 2 [D7003].a) EN-GJS-400-16 [D4018], b) EN-GJS-500-7 [D4512], c) EN-GJS-600-3 [D5608], 5d) EN-GJS-700-2 [ D7003].
Von diesen ist der erste (a)) noch ferritisch und daher zähe, aber seine Festigkeit ist nur mittelmäßig. Soll die Festigkeit höher sein, greift man zu den Werkstoffen b), c) und d), die der Reihe nach ferritisch-perlitisch bis 0 rein perlitiscli sind, bei stark abnelimender Zähigkeit und Schweissbarkeit. Diese Werkstoffe weisen in von a) bis zu d) zunehmendem Maße ein mehrphasiges (ferritisch-perlitisches) Grundgefuge örtlich verschiedener Zusammensetzung auf, was durch die beim Giessen unvermeidlichen örtlich verschiedenen Abkühlbedingungen noch verstärkt wird und zu Pro- 5 blemen bei der nachfolgenden, insbesondere zerspanenden, Bearbeitung führt. Deren Einsatz ist daher auf besondere Anwendungen beschränkt. Im Fahrzeugbau ist die Verringerung des Gewichtes ein besonderes Anliegen, was bei Gussteilen geringe Wandstärken - also hohe Festigkeit - aber auch Zähigkeit sowie gute Bearbeitbarkeit erfordert. Man ist dann genötigt, Stahl einzusetzen, der aber um etwa 10 Prozent schwerer ist.Of these, the first one (a) is still ferritic and therefore tenacious, but its strength is only mediocre. If the strength is to be higher, one resorts to the materials b), c) and d), which in turn are ferritic-perlitic to 0 perlitiscli, with strong declinative toughness and weldability. These materials have from a) to d) increasingly a multiphase (ferritic-pearlitic) Grundfuge locally different composition, which is reinforced by the unavoidable during casting locally different cooling conditions and to 5 problems in the subsequent, in particular machining , Editing leads. Their use is therefore limited to special applications. In vehicle construction, the reduction of weight is a particular concern, which in castings low wall thickness - ie high strength - but also requires toughness and good workability. It is then necessary to use steel, but it is about 10 percent heavier.
Zwar ist es bekannt, im Fahrzeugbau für Anwendungen, die eine hohe Hitzebeständigkeit erfordern, Sphäroguss mit hohem Gehalt an Silizium und 0,5 bis 2 Prozent Molybdän einzusetzen. Dieser ist jedoch sehr spröde und überhaupt schwer bearbeitbar.Although it is known in automotive applications for applications that require high heat resistance, to use nodular cast iron with a high content of silicon and 0.5 to 2 percent molybdenum. However, this is very brittle and difficult to work at all.
Es ist somit Aufgabe der Erfindung, Sphäroguss so zu verbessern, dass er trotz hoher Festigkeit zäh, gut bearbeitbar und schweissbar ist.It is therefore an object of the invention to improve nodular cast iron so that it is tough, easy to machine and weld despite high strength.
Ein erfindungsgemäßer Sphäroguss enthält: 4 bis 6 Prozent Silizium und einen entsprechend dem Kohlenstoffäquivalent verringerten Anteil an Kohlenstoff, maximal 0,03 Prozent Phosphor und 0,2 bis 0,5 Prozent Nickel. Der hohe Gehalt an Silizium wirkt Ferrit - stabilisierend und erhöht auch die Festigkeit. Das Kohlenstoffäquivalent erfordert eine entsprechende Absenkung des Kohlenstoffgehaltes. Da Phosphor aufgrund der starken Mischkristallverfestigung der mit von ihm eingegangenen Verbindungen versprödend wirkt, ist der Phosphorgehalt möglichst klein zu halten. Auch Nickel verringert die Sprödigkeit und vergrößert die Festigkeit, wobei die erforderlichen Anteile so gering sind, dass die dadurch entstehenden Mehrkosten vemachlässigbar sind.A nodular cast iron according to the invention contains: 4 to 6 percent silicon and a proportion of carbon corresponding to the carbon equivalent, a maximum of 0.03 percent phosphorus and 0.2 to 0.5 percent nickel. The high content of silicon has a ferrite-stabilizing effect and also increases the strength. The carbon equivalent requires a corresponding reduction of the carbon content. Since phosphorus acts as embrittlement due to the strong solid solution hardening of the compounds it has received, the phosphorus content must be kept as small as possible. Nickel also reduces the brittleness and increases the strength, the required proportions are so small that the resulting additional costs are negligible.
Die Festigkeit wird hier nicht, wie bei Sphäroguss nach dem Stand der Technik, über einen höheren Gehalt an Perlit erhalten, sondern durch Mischkristallverfestigung. Im Zusammenwirken dieser Maßnahmen wird eine deutliche Festigkeitssteigerung bei guter Duktilität und Schweissbarkeit erreicht.The strength is not obtained here, as in nodular cast iron according to the prior art, via a higher content of perlite, but by solid solution hardening. The interaction of these measures will achieved a significant increase in strength with good ductility and weldability.
Die Mengenverhältnisse, bei denen besonders gute Werte erzielt wurden sind gemäß Ansprüchen 2 und 3 Silizium bei 4,1 bis 4,5 Prozent und Nickel bei 0,25 bis 0,35 Prozent. Die Begrenzung des Gehaltes an Kupfer unter das übliche Maß verstärkt die Wirkung der erfindungsgemäßen Maßnahmen, da Kupfer ein Perlitbildner ist.The proportions at which particularly good values have been achieved according to claims 2 and 3 silicon at 4.1 to 4.5 percent and nickel at 0.25 to 0.35 percent. The limitation of the content of copper below the usual level enhances the effect of the measures according to the invention, since copper is a perlite former.
Schließlich betrifft die Erfindung auch Gehäuse, insbesondere Getriebe- gehäuse, die aus einem Sphäroguss nach einem der vorhergehenden Ansprüche bestehen. Ein solches Getriebegehäuse kann wegen der hohen Festigkeit des erfindungs gemäß verbesserten Sphäroguss dünnwandiger und leichter sein. Die für die Bildung von Anschlussflanschen und Lager- sitzen nötige spanabhebende Bearbeitung ist uneingeschränkt möglich.Finally, the invention also relates to housings, in particular gear housing, which consist of a ductile iron according to one of the preceding claims. Such a gear housing can be thinner walled and lighter because of the high strength of the fiction, according to improved ductile iron. The machining necessary for the formation of connection flanges and bearing seats is possible without restriction.
Weiters kann ein Getriebegehäuse aus dem erfindungsgemäßen Werkstoff mit einem Verzahnungsteil aus legiertem und/oder einsatzgehärtetem Stahl verschweisst sein.Furthermore, a gear housing made of the material according to the invention can be welded to a toothed part made of alloyed and / or case-hardened steel.
Im folgenden wird die Erfindung anhand von Tafeln beziehungsweise Abbildungen erläutert. Es stellen dar:In the following the invention will be explained with reference to panels or figures. They show:
Fig. 1 : Eine Gegenüberstellung von Sphäroguss nach dem Stand derFig. 1: A comparison of nodular iron according to the prior
Technik mit einem erfindungsgemäß verbesserten, Fig. 2: einen Schnitt durch ein erfindungsgemäßes Getriebegehäuse.2 shows a section through a transmission housing according to the invention.
In Fig. 1 sind die Eigenschaften der Werkstoffe nach dem Stand der Technik gemäß a) bis d) weiter oben in den ersten vier Spalten denen des erfindungsgemäß verbesserten in der fünften Spalte gegenübergestellt. Die Zahlen und Angaben sprechen für sich und untermauern das in der Be- schreibungseinleitung gesagte.In Fig. 1, the properties of the prior art materials according to a) to d) above in the first four columns are compared with those of the invention improved in the fifth column. The Numbers and data speak for themselves and substantiate what has been said in the description introduction.
Als Beispiel folgt eine Analyse des Werkstoffes in der fünften Spalte der Fig. 1. Die angegebenen Prozentaiiteile sind die Mittelwerte aus mehreren Gussstücken einer Charge:As an example, an analysis of the material in the fifth column of FIG. 1 follows. The percentages given are the mean values of several castings of a batch:
C Si Mn P S Cr Mo NiC Si Mn P S Cr Mo Ni
AIAI
% % % % % % % % % X 3,142 -4,314 0,1922 0,0240 0,0074 0,0252 0,0024 0,3028%%%%%%%%% X 3,142 -4,314 0.1922 0.0240 0.0074 0.0252 0.0024 0.3028
0,00350.0035
Co Cu Nb TI V W Pb SnCo Cu Nb TI V W Pb Sn
Mg - % % % % % % % % %Mg -%%%%%%%%%
X 0,0032 0,2276 0,0015 0,0093 0,0027 <0,0050 0,0017 0,0059 0,0293X 0.0032 0.2276 0.0015 0.0093 0.0027 <0.0050 0.0017 0.0059 0.0293
As Zr Bi Ca Ca Sb Se Te B - % % % % % % % % %As Zr Bi Ca Ca Sb Se Te B -%%%%%%%%%
X 0,0049 0,0078 <0,0010 0,0040 0,0049 0,0028 <0,0010 0,0078X 0.0049 0.0078 <0.0010 0.0040 0.0049 0.0028 <0.0010 0.0078
<0,0001<0.0001
La N Fe - % % %La N Fe -%%%
X 0,0025 >0,0240 <91,6X 0.0025> 0.0240 <91.6
In Fig. 2 ist das Gehäuse, beispielsweise das Gehäuse eines Getriebes, mit 1 und ein mit diesem zu einem Bauteil verbundenes Zahnrad mit 2 bezeichnet. Das Gehäuse 1 besteht hier aus einem erfindungsgemäß verbesserten Sphäroguß. Das Zahnrad 2 ist aus Stahl und einsatzgehärtet. Das Gehäuse 1 weist eine erste achsnormale zu verschweißende Fläche 3 auf, an die ein zylindrischer Kragen 4 anschließt, der eine äussere zylindrische Paßfläche 5 bildet. Das Gehäuse 1 kann an einer Stelle größerer Wandstärke mit einer parallel zur ersten zu verschweißenden Fläche verlaufenden Umfangsnut 6 versehen sein, die im Querschnitt gerundet ist. Am Zahnrad 2 ist eine in einer Ebene normal zur Achse liegende zweite zu verschweißende Fläche 7 und eine zylindrische Paßfläche 8 vorgesehen, die auf der zylindrischen Paßfläche 5 sitzt.In Fig. 2, the housing, for example, the housing of a transmission, with 1 and a connected thereto to a component gear designated by 2. The housing 1 here consists of an inventively improved ductile iron. The gear 2 is made of steel and case hardened. The housing 1 has a first axis normal to be welded surface 3, To which a cylindrical collar 4 connects, which forms an outer cylindrical mating surface 5. The housing 1 may be provided at a location greater wall thickness with a parallel to the first surface to be welded to circumferential groove 6, which is rounded in cross-section. On the gear 2 a lying in a plane normal to the axis second to be welded surface 7 and a cylindrical mating surface 8 is provided, which sits on the cylindrical mating surface 5.
Die zylindrische Paßfläche 8 kann am Übergang zur zweiten zu verschweißenden Fläche 7 zurückgenommen sein, sodaß sich eine Erwei- terung 9 bildet. Diese erleichtert die Fertigung und das Aufschieben des Zahnrades auf den Kragen 4 und verbessert erforderlichenfalls die Durch- schweißung der Wurzel. Mit 18 ist die Drehachse des Bauteiles und mit 20 der Schweißkopf bezeichnet. The cylindrical mating surface 8 can be withdrawn at the transition to the second surface 7 to be welded, so that an extension 9 forms. This facilitates the production and the sliding of the gear on the collar 4 and, if necessary, improves the penetration of the root. With 18, the axis of rotation of the component and 20 of the welding head is designated.

Claims

Patentansprüche claims
1. Sphäroguss mit einlegiertem Silizium, dadurch gekennzeichnet, dass er enthält: a) 4 bis 6 Prozent Silizium und einen entsprechend dem Kohlenstoffäquivalent verringerten Anteil an Kohlenstoff, b) maximal 0,03 Prozent Phosphor und c) 0,2 bis 0,5 Prozent Nickel.1. Spheroidal cast iron with siliconized silicon, characterized in that it contains: a) 4 to 6 percent silicon and a proportion of carbon reduced corresponding to the carbon equivalent, b) a maximum of 0.03 percent phosphorus and c) 0.2 to 0.5 percent Nickel.
2. Sphäroguss nach Anspruch 1, dadurch gekennzeichnet, dass das Gehalt an Silizium bei 4,1 bis 4,5 Prozent liegt.2. nodular cast iron according to claim 1, characterized in that the content of silicon is 4.1 to 4.5 percent.
3. Sphäroguss nach Anspruch 1 , dadurch gekennzeichnet, dass Gehalt an Nickel bei 0,25 bis 0,35 Prozent liegt.3. ductile iron according to claim 1, characterized in that the content of nickel is 0.25 to 0.35 percent.
4. Sphäroguss nach Anspruch 1, dadurch gekennzeichnet, dass das Gehalt an Kupfer unter 0,3 Prozent gehalten wird.4. ductile iron according to claim 1, characterized in that the content of copper is kept below 0.3 percent.
5. Gehäuse, dadurch gekennzeichnet, dass es (1) aus einem Sphäroguss nach einem der vorhergehenden Ansprüche besteht.5. housing, characterized in that it (1) consists of a ductile iron according to one of the preceding claims.
6. Gehäuse nach Anspruch 5, dadurch gekennzeichnet, dass es (1) mit einem Verzalmungsteil (2) aus legiertem und/oder einsatzgehärtetem Stahl verschweisst ist. 6. Housing according to claim 5, characterized in that it (1) with a Verzalmungsteil (2) made of alloyed and / or case-hardened steel is welded.
PCT/AT2002/000234 2001-08-07 2002-08-02 High-strength, high-ductility nodular iron, and transmission housing produced therefrom WO2003014407A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US10/486,154 US20040219052A1 (en) 2001-08-07 2002-08-02 High-strength, high-ductility noudlar iron, and transmission housing produced therefrom
KR10-2004-7001871A KR20040017853A (en) 2001-08-07 2002-08-02 Nodular cast iron with a high strength and ductilitym, and transmission casing produce therefrom
DE50205710T DE50205710D1 (en) 2001-08-07 2002-08-02 SPHAROGUSS WITH HIGH STRENGTH AND DUCTILITY AND GEARBOX MANUFACTURED THEREOF
JP2003519535A JP2004537652A (en) 2001-08-07 2002-08-02 Spheroidal graphite cast iron with high strength and ductility and transmission case produced therefrom
CA002456432A CA2456432A1 (en) 2001-08-07 2002-08-02 High-strength, high-ductility nodular iron, and transmission housing produced therefrom
EP02766913A EP1415009B1 (en) 2001-08-07 2002-08-02 High-strength, high-ductility nodular iron, and transmission housing produced therefrom

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ATGM623/01 2001-08-07
AT0062301U AT5381U1 (en) 2001-08-07 2001-08-07 SPHERICAL CASTING OF HIGH STRENGTH AND DUCTILITY AND TRANSMISSION CASE MADE THEREOF

Publications (1)

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WO2003014407A1 true WO2003014407A1 (en) 2003-02-20

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PCT/AT2002/000234 WO2003014407A1 (en) 2001-08-07 2002-08-02 High-strength, high-ductility nodular iron, and transmission housing produced therefrom

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US (1) US20040219052A1 (en)
EP (1) EP1415009B1 (en)
JP (1) JP2004537652A (en)
KR (1) KR20040017853A (en)
AT (2) AT5381U1 (en)
CA (1) CA2456432A1 (en)
WO (1) WO2003014407A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006038670A1 (en) * 2006-08-17 2008-02-21 Federal-Mogul Burscheid Gmbh High silicon steel material for the production of piston rings and cylinder liners

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2546938C1 (en) * 2014-02-25 2015-04-10 Юлия Алексеевна Щепочкина Cast iron

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GB1506947A (en) * 1974-11-30 1978-04-12 Goetzewerke Sealing strip for rotary piston engines
US4435226A (en) * 1981-12-01 1984-03-06 Goetze Ag Wear resistant cast iron alloy with spheroidal graphite separation and manufacturing method therefor
US4450019A (en) * 1982-04-01 1984-05-22 Toyo Kogyo Co., Ltd. Ductile cast iron
US4475956A (en) * 1983-01-24 1984-10-09 Ford Motor Company Method of making high strength ferritic ductile iron parts
US4484953A (en) * 1983-01-24 1984-11-27 Ford Motor Company Method of making ductile cast iron with improved strength
DE19636808C1 (en) * 1996-09-11 1997-09-25 Harzer Grauguswerke Gmbh Spheroidal graphite alloy cast@ iron

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US3749463A (en) * 1970-10-13 1973-07-31 J Krapf Bearing mounting method and apparatus

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1506947A (en) * 1974-11-30 1978-04-12 Goetzewerke Sealing strip for rotary piston engines
US4435226A (en) * 1981-12-01 1984-03-06 Goetze Ag Wear resistant cast iron alloy with spheroidal graphite separation and manufacturing method therefor
US4450019A (en) * 1982-04-01 1984-05-22 Toyo Kogyo Co., Ltd. Ductile cast iron
US4475956A (en) * 1983-01-24 1984-10-09 Ford Motor Company Method of making high strength ferritic ductile iron parts
US4484953A (en) * 1983-01-24 1984-11-27 Ford Motor Company Method of making ductile cast iron with improved strength
DE19636808C1 (en) * 1996-09-11 1997-09-25 Harzer Grauguswerke Gmbh Spheroidal graphite alloy cast@ iron

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006038670A1 (en) * 2006-08-17 2008-02-21 Federal-Mogul Burscheid Gmbh High silicon steel material for the production of piston rings and cylinder liners
DE102006038670B4 (en) * 2006-08-17 2010-12-09 Federal-Mogul Burscheid Gmbh High silicon steel material for the production of piston rings and cylinder liners

Also Published As

Publication number Publication date
CA2456432A1 (en) 2003-02-20
EP1415009A1 (en) 2004-05-06
US20040219052A1 (en) 2004-11-04
KR20040017853A (en) 2004-02-27
EP1415009B1 (en) 2006-01-25
AT5381U1 (en) 2002-06-25
ATE316586T1 (en) 2006-02-15
JP2004537652A (en) 2004-12-16

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