WO2002074470A1 - Brique ou bouchon réfractaire pour l'injection de gaz dans du métal en fusion - Google Patents

Brique ou bouchon réfractaire pour l'injection de gaz dans du métal en fusion Download PDF

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Publication number
WO2002074470A1
WO2002074470A1 PCT/BE2002/000039 BE0200039W WO02074470A1 WO 2002074470 A1 WO2002074470 A1 WO 2002074470A1 BE 0200039 W BE0200039 W BE 0200039W WO 02074470 A1 WO02074470 A1 WO 02074470A1
Authority
WO
WIPO (PCT)
Prior art keywords
porous
gas
molten metal
plug
brick
Prior art date
Application number
PCT/BE2002/000039
Other languages
English (en)
Inventor
Craig Willoughby
Cavan Millward
Original Assignee
Vesuvius Crucible Company
Vesuvius Group S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vesuvius Crucible Company, Vesuvius Group S.A. filed Critical Vesuvius Crucible Company
Priority to AT02712669T priority Critical patent/ATE301014T1/de
Priority to BRPI0208100-8A priority patent/BR0208100B1/pt
Priority to JP2002573171A priority patent/JP2004531396A/ja
Priority to CA002440404A priority patent/CA2440404C/fr
Priority to DE60205350T priority patent/DE60205350T2/de
Priority to MXPA03008488A priority patent/MXPA03008488A/es
Priority to HU0303607A priority patent/HU228285B1/hu
Priority to KR1020037012162A priority patent/KR100874397B1/ko
Priority to EP02712669A priority patent/EP1372888B1/fr
Priority to PL364828A priority patent/PL202712B1/pl
Priority to US10/472,642 priority patent/US20040100004A1/en
Publication of WO2002074470A1 publication Critical patent/WO2002074470A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00—Treatment of fused masses in the ladle or the supply runners before casting
    • B22D1/002—Treatment with gases
    • B22D1/005—Injection assemblies therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00—Treatment of fused masses in the ladle or the supply runners before casting

Definitions

  • Refractory plug or brick for injecting gas into molten metal Description.
  • the present invention relates to a refractory plug or brick for injecting gas into molten metal and to the manufacture of a refractory plug or brick for injecting gas into molten metal.
  • Gases are often injected into molten metal in vessels such as ladles, crucibles or tundishes for diverse purposes. For instance, a gas may be introduced into the bottom part of a vessel to clear the relatively cool bottom area of solidification products, e.g. to remove them from the vicinity of a bottom pour outlet where the vessel has such an outlet.
  • the use of slow injection of a fine curtain of gas bubbles in the tundish assists in inclusion removal; the inclusions being attracted to the fine gas bubbles and rising upwards through the melt to the surface where they are conventionally captured by the tundish cover powder or flux.
  • Gas may also be introduced for rinsing or to homogenise the melt thermally or compositionally, or to assist in dispersing alloying additions throughout the melt.
  • an inert gas is used but reactive gases may also be employed, e.g. reducing or oxidising gases, when the melt compositions or components thereof needs modifying.
  • gases such as nitrogen, chlorine, freon, sulphur hexafluoride, argon, and the like into molten metal, for example molten aluminium or aluminium alloys, in order to remove undesirable constituents such as hydrogen gas, non-metallic inclusions and alkali metals.
  • gases such as nitrogen, chlorine, freon, sulphur hexafluoride, argon, and the like
  • the reactive gases added to the molten metal chemically react with the undesired constituents to convert them into a form such as a precipitate, a dross or an insoluble gas compound that can be readily separated from the remainder of the melt.
  • gases might also be used for example with steel, copper, iron, magnesium or alloys thereof.
  • the gas be introduced into the molten metal, preferably from the bottom of the recipient, in the form of a very large number of extremely small bubbles.
  • the number of bubbles per unit volume increases.
  • An increase in the number of bubbles and their surface area per unit volume increases the probability of the injected gas being utilised effectively to perform the expected operation.
  • a solid porous refractory plug or brick in the refractory lining of the vessel, generally on the floor but also in the walls.
  • the plugs or bricks introduce a flow of gas in the form of bubbles.
  • a known technique for introducing gas into molten metal consists of lining a portion of a molten metal-containing vessel (preferably the floor of the vessel) with a porous ceramic body. The gas is introduced into the porous body at a location remote from the metal-contacting surface of the body. During its passage through the body, the gas follows a number of small, tortuous paths such that a large number of bubbles will be issued into the molten metal.
  • a metal casing that acts as a manifold to introduce gas into the body supports the porous ceramic body.
  • the casing is made of mild steel (for use with inert or slightly reactive gas such as argon or nitrogen) or inconel (for use with highly reactive chlorine or freon).
  • the assembled body/ casing is surrounded and supported on all sides except its upper surface by refractory material such as low- cement alumina castable or bricks. When castable is used this can either be cast is situ around the porous body or formed from pre-cast components fixed in place during the hot metal container lining installation. The lining material will "butt" up against the porous body construction.
  • a problem with the foregoing construction is that it is difficult to maintain an effective gas seal between the casing and the body, and between the casing and the support castable/bricks.
  • One difficulty arises in part because the coefficients of thermal expansion of the metal casing and the refractory materials are considerably different; also, the metal casing is subject to attack if chlorine is the gas being used. If a crack should develop (as used herein, the term "crack" refers to any defect in the gas dispersing apparatus that permits undesired gas leakage), gas will leak through the crack, and hereafter frequently will migrate through the next brick and the refractory support to the ambient atmosphere. Gas migration through 50 cm or more or refractory material is possible.
  • the problem is undesirable as the effect of gas leakage upon the flow of gas through the designed gas bubbling surface can be seriously reduced and effectiveness of the bubbling block diminished.
  • gas flow by means of fine gas bubbles will cease and be replaced with uncontrolled direction of gas flow by means of large ineffective gas bubbles.
  • argon is being used the relatively great expense must be considered.
  • the problem is particularly acute in the case of chlorine due to the harmful effects of chlorine upon release into the atmosphere. Regardless of the type of purifying gas being used, it is important that cracks be prevented so that gas leakage will be prevented.
  • a technique would be available for injecting gas into molten metal that would accomplish the objectives of dispersing a large number of exceedingly small bubbles into the molten metal while, at the same time, avoiding cracks in the gas dispersing apparatus that results in gas leakage.
  • any such apparatus it also would be desirable for any such apparatus to be capable of being manufactured easily, at reasonable expense and having smaller dimensions than the existing apparatus. Further, it would be desirable that any such gas injection apparatus be usable with existing equipment such as a tundish, ladle, melting vessel, and the like, with no modification, or with only minor modification, of the existing equipment.
  • the invention relates thus to a solid porous refractory plug or brick for injecting gas into molten metal through a molten metal-contacting surface comprising i) a porous refractory body substantially surrounded by a substantially non-porous body except at the molten-metal contact surface; and ii) gas conducting means for conveying the gas from a gas source to the porous body.
  • a plug or brick for injecting gas can be a plug, brick, block, dam, tile, bar, and the like.
  • the plug or brick of the invention can be used to inject any gas (whether reactive or inert) into any molten metal or alloy thereof.
  • the plug or brick has at least a molten-metal contacting surface through which the gas is injected.
  • the plug or brick comprises a porous refractory body substantially surrounded by (for example encased by or embedded in) a non-porous body except, of course, at the molten-metal contacting surface. It can be included or form part of the lining of the molten metal vessel.
  • the porous body can be made of any porous refractory material. As a matter of fact, the nature of the material used is not essential as far as said material has the required porosity. Generally, it will be considered that a material having an apparent porosity higher than 20 % is porous. Suitable materials typically comprise alumina, alumina spinel, magnesia or magnesia spinel, or combinations of any of the above.
  • the plug or brick also comprises gas conducting means for conveying the gas from a gas source, to the porous body.
  • the gas conducting means generally comprises a conduit extending through the side wall of the non-porous body. This conduit can be made from metal or a refractory material for example.
  • the conduit can be fixed into place by means of a conventional refractory sealing material (mortar or cement) or it can be pressed within the non-porous body.
  • Conventional gas conducting means can be utilised. However, since the tightness of the connection is to be particularly monitored, special arrangements such as for example these disclosed in WO-Al-01 /83138 are particularly preferred.
  • the gas conducting means comprises a plenum chamber through which the gas contacts a surface of the porous body at least substantially equivalent to the molten metal contacting surface so that the gas is perfectly homogeneously distributed into the porous body and, consequently, will bubble into the molten metal through substantially the whole molten-metal contacting surface.
  • the plug or brick of the present invention is characterised by the fact that the non-porous body is made of refractory material and that the porous and non-porous bodies have been co-pressed. All the above identified requirements are fulfilled with such a plug or brick.
  • non-porous material is not essential as long as it is a refractory material and has the required porosity. Generally, it will be considered that a material having an apparent porosity lower than 20 % is non-porous.
  • the non-porous body and the porous body are preferably constituted of refractory materials with similar coefficients of thermal expansion. This serves to prevent the formation of cracks upon thermal cycling.
  • the granulometry and permeability of the inner porous body can be carefully and consistently controlled to provide an even fine pore structure so that small evenly distributed gas bubbles flow from the molten metal contacting surface of the body.
  • This permeability can be readily adjusted via formulation granulometry changes and a plug or brick according to the invention can be manufactured to suit specific individual customer requirements.
  • This process route is further advantageous in that high magnesia content refractories can be used for the formulations such as magnesia spinel. Such formulations are more compatible with the composition of steel plant tundihs linings which are usually basic (magnesia) based. Chemical and thermal characteristics are therefore very similar.
  • the porous and non-porous refractory bodies have thus a high magnesia content, more than 50 %, preferably more than 80 % and even more preferably more than 90 % by weight of the composition.
  • similar materials but with different granulometries can be used for the porous and non-porous bodies.
  • the natural low permeability of the non-porous body prevent gas leakage without having to resort to other gas leakage restriction techniques.
  • co-pressing is that a plug or brick for injecting gas with lower overall dimensions, achieving the required degree of gas bubbling can be used. This assists in handling of these plug or brick during transport and installation in the vessel; in particular in the lining.
  • the co-pressing concept is not restricted to oblong, square, round or oval shapes but can also be used to produce any refractory cross section suitable for co- pressing.
  • a ring co-pressed component can be envisaged which would be located to surround the exit ports of a tundish thereby forming a surrounding stream of gentle rising bubbles though which the hot liquid metal would have to pass prior to entry into the continuous casting moulds.
  • the invention concerns a process for the manufacture of a plug or brick for injecting gas into molten metal.
  • this process comprises the steps of: 1) introducing into a mould of appropriate amounts of the refractory materials constituting the porous and non-porous bodies while respecting the desired limits for these bodies;
  • a delimiter for example made from a thin (but rigid) plastic or metal foil is placed into the mould prior to introducing the refractory material.
  • the delimiter can be shaped as a cylinder (with circular or oval base), or a parallelepiped, without upper and lower surfaces.
  • the refractory material which will form the porous body is then introduced in the central portion formed by the delimiter and the refractory material which will form the non-porous body is introduced between the delimiter and the mould wall.
  • the delimiter is then carefully removed and another amount of the material forming the non-porous body is introduced into the mould to form the surface opposite to the molten metal contacting surface.
  • the step of providing the gas conducting means can be carried out before or after the co-pressing step or both before and after.
  • a plenum chamber is formed by introducing a strip of consumable material into the mould at the junction between the base of the porous body forming material and the adjacent surface of the non-porous body forming material.
  • a hole can be drilled or a conduit placed through the non- porous body after or before co-pressing the materials to connect the porous body (whether or not through the plenum chamber) to an external gas source.
  • the co-pressing step can be carried out according to any known pressing method, for example in an hydraulic press.
  • the heat treating step should be carried out at a temperature sufficient to develop a ceramic bond between the porous and non-porous bodies so that the integrity of the plug or brick and its gas tightness are enhanced.
  • the consumable material (if used) placed to generate the plenum chamber will advantageously be removed during the heat treating step. This consumable material can burn (cardboard, paper) or melt (wax, alloy) at the temperature used.
  • the heat treating step consists in firing the co-pressed material for a temperature comprised between 800 and 1800°C for 2 to 12 hours.
  • FIG. 1 and 2 show cross-sectional views of embodiments of the invention.
  • Both figures show a plug or brick (1) for injecting gas into molten metal through a molten metal-contacting surface (11) comprising a porous refractory body (2) substantially surrounded by a substantially non-porous body (9) except at the molten metal-contacting surface (11).
  • the gas conducting means comprised of a metallic or refractory conduit (4) extending through a wall (6) of the plug or brick and connecting to the plenum chamber (3).
  • the conduit (4) is typically fixed into place by means of a conventional sealing cement or mortar (5).
  • a gradual tapered section (7) is created towards the molten metal-contacting surface (4) during the pressing step as depicted on figure 1.
  • the materials used are the following: (% given by weight):
  • the materials After being introduced into the mould, the materials have been mechanically pressed at a rate to ensure the best possible compaction and integration of the co pressed materials .
  • the heat treating step was carried out by slowly heating the co- pressed material at a rate to avoid thermal fractures/ cracking within the pressed body until 1600°C, leaving the plug or brick at this temperature for 4 hours and allowing it to cool gently.
  • the following properties have been measured:
  • the plug or brick has injected fine bubbles reliably and constantly.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)
  • Furnace Charging Or Discharging (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Continuous Casting (AREA)

Abstract

La présente invention concerne un bouchon ou une brique (1) pour l'injection de gaz dans du métal en fusion au travers d'une surface de contact avec le métal en fusion (11), comprenant (i) un corps réfractaire poreux (2) sensiblement entouré d'un corps sensiblement non poreux (9) à l'exception de la surface de contact avec le métal en fusion (11); et (ii) des organes conduisant les gaz (3, 5) servant à amener le gaz d'une source de gaz au corps poreux (2). Le bouchon ou la brique sont caractérisés en ce que le corps non poreux (11) est fait d'un matériau réfractaire, et que les corps poreux et non poreux (2, 11) ont été comprimés ensemble. Ce bouchon ou cette brique conviennent particulièrement pour l'injection puissante et fiable de petites bulles dans le bain de métal en fusion.
PCT/BE2002/000039 2001-03-19 2002-03-19 Brique ou bouchon réfractaire pour l'injection de gaz dans du métal en fusion WO2002074470A1 (fr)

Priority Applications (11)

Application Number Priority Date Filing Date Title
AT02712669T ATE301014T1 (de) 2001-03-19 2002-03-19 Feuerfester baukörper oder stein zum einblasen von gas in geschmolzene metalle
BRPI0208100-8A BR0208100B1 (pt) 2001-03-19 2002-03-19 processo para a fabricação de um plugue ou tijolo refratário sólido poroso para revestimento de recipiente para injetar gás em metal em fusão, e, plugue ou tijolo refratário sólido poroso obtido pelo processo.
JP2002573171A JP2004531396A (ja) 2001-03-19 2002-03-19 溶融金属にガスを注入するための耐火性プラグもしくはレンガ
CA002440404A CA2440404C (fr) 2001-03-19 2002-03-19 Brique ou bouchon refractaire pour l'injection de gaz dans du metal en fusion
DE60205350T DE60205350T2 (de) 2001-03-19 2002-03-19 Feuerfester baukörper oder stein zum einblasen von gas in geschmolzene metalle
MXPA03008488A MXPA03008488A (es) 2001-03-19 2002-03-19 Bloque o ladrillo refractorio para inyectar gas en un metal fundido.
HU0303607A HU228285B1 (hu) 2001-03-19 2002-03-19 Tûzálló dugó vagy tégla gáz injektálásához olvadt fémbe, valamint eljárás annak elõállítására
KR1020037012162A KR100874397B1 (ko) 2001-03-19 2002-03-19 용융된 금속 내에 가스를 주입하는 내화 플러그
EP02712669A EP1372888B1 (fr) 2001-03-19 2002-03-19 Brique ou bouchon refractaire pour l'injection de gaz dans du m tal en fusion
PL364828A PL202712B1 (pl) 2001-03-19 2002-03-19 Lista porowata ogniotrwała zatyczka albo cegła do wyłożenia zbiornika, do wdmuchiwania gazu do roztopionego metalu, oraz sposób jej wytwarzania
US10/472,642 US20040100004A1 (en) 2001-03-19 2002-03-19 Refractory plug or brick for injecting gas into molten metal

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP01870054.2 2001-03-19
EP01870054A EP1243361A1 (fr) 2001-03-19 2001-03-19 Dispositif pour introduire un gaz dans un métal liquide

Publications (1)

Publication Number Publication Date
WO2002074470A1 true WO2002074470A1 (fr) 2002-09-26

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ID=8184940

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/BE2002/000039 WO2002074470A1 (fr) 2001-03-19 2002-03-19 Brique ou bouchon réfractaire pour l'injection de gaz dans du métal en fusion

Country Status (18)

Country Link
US (1) US20040100004A1 (fr)
EP (2) EP1243361A1 (fr)
JP (1) JP2004531396A (fr)
KR (1) KR100874397B1 (fr)
CN (1) CN1296157C (fr)
AR (1) AR032983A1 (fr)
AT (1) ATE301014T1 (fr)
BR (1) BR0208100B1 (fr)
CA (1) CA2440404C (fr)
DE (1) DE60205350T2 (fr)
ES (1) ES2243701T3 (fr)
HU (1) HU228285B1 (fr)
MX (1) MXPA03008488A (fr)
PL (1) PL202712B1 (fr)
RU (1) RU2277591C2 (fr)
TW (1) TW584615B (fr)
WO (1) WO2002074470A1 (fr)
ZA (1) ZA200306069B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1750075A1 (fr) 2005-08-05 2007-02-07 Vesuvius Becker & Piscantor Grossalmeroder Schmelztiegelwerke GmbH & Co. KG Creuset pour le traitement de métal liquide et et son procédé de fabrication

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BRPI0617924A2 (pt) * 2005-10-27 2016-08-23 Teijin Pharma Ltd processo de produção, e, composto
DE102005060432A1 (de) * 2005-12-15 2007-06-21 Pa-Ha-Ge Feuerfeste Erzeugnisse Gmbh & Co. Kg Spülkegel
KR200451645Y1 (ko) * 2008-06-27 2011-05-23 김봉려 가열수단이 구비된 보온팩
DE202009014246U1 (de) 2009-10-22 2009-12-24 Knöllinger Keramische Verschleißteile GmbH Gasspülstein
RU2666197C2 (ru) * 2015-08-12 2018-09-06 федеральное государственное бюджетное образовательное учреждение высшего образования "Нижегородский государственный технический университет им. Р.Е. Алексеева" (НГТУ) Способ получения дисперсно-упроченного алюминиевого сплава
US20190113282A1 (en) * 2017-10-12 2019-04-18 Porvair Plc Permeable Bottom Crucible
US11964873B2 (en) * 2019-08-28 2024-04-23 Plassein Technologies Ltd Llc Methods for producing hollow ceramic spheres
US20230313340A1 (en) * 2022-04-05 2023-10-05 Doggone Investment Co. LLC Apparatus and method for production of high purity copper-based alloys

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GB2096290A (en) * 1981-03-17 1982-10-13 Didier Werke Ag Device for introducing gases into metallurgical vessels
US4791978A (en) * 1987-11-25 1988-12-20 Vesuvius Crucible Company Gas permeable stopper rod
US4836508A (en) * 1988-05-03 1989-06-06 Vesuvius Crucible Company Ladle shroud with co-pressed gas permeable ring
JPH03128165A (ja) * 1989-10-11 1991-05-31 Harima Ceramic Co Ltd ポーラスプラグの製造方法
JPH07308759A (ja) * 1994-05-16 1995-11-28 Tokyo Yogyo Co Ltd スライドゲート用プレートれんが

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DE3833502A1 (de) * 1988-10-01 1990-04-05 Didier Werke Ag Gasspuelstein
DE4014509A1 (de) * 1990-05-07 1991-11-14 Didier Werke Ag Gasspueler
FR2675064B1 (fr) * 1991-04-09 1995-06-02 Vesuvius France Sa Quenouille comportant une manchette resistant a l'erosion.
GB9212953D0 (en) * 1992-06-18 1992-07-29 Foseco Int Purifying molten metal
CA2073219C (fr) * 1992-07-06 1995-12-19 Keizo Aramaki Refractaire pour soufflante de cuve d'affinage de metal en fusion
JPH07198267A (ja) * 1993-12-29 1995-08-01 Kawasaki Refract Co Ltd ガス吹込み用ポ−ラスプラグの製造方法
IN191421B (fr) * 1994-06-15 2003-11-29 Vesuvius Frnance Sa
JPH08143356A (ja) * 1994-11-17 1996-06-04 Kyushu Refract Co Ltd マグネシア質不焼成れんが
JP2001040413A (ja) * 1999-07-29 2001-02-13 Kurosaki Harima Corp ポーラスプラグ

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Publication number Priority date Publication date Assignee Title
GB2096290A (en) * 1981-03-17 1982-10-13 Didier Werke Ag Device for introducing gases into metallurgical vessels
US4791978A (en) * 1987-11-25 1988-12-20 Vesuvius Crucible Company Gas permeable stopper rod
US4836508A (en) * 1988-05-03 1989-06-06 Vesuvius Crucible Company Ladle shroud with co-pressed gas permeable ring
JPH03128165A (ja) * 1989-10-11 1991-05-31 Harima Ceramic Co Ltd ポーラスプラグの製造方法
JPH07308759A (ja) * 1994-05-16 1995-11-28 Tokyo Yogyo Co Ltd スライドゲート用プレートれんが

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PATENT ABSTRACTS OF JAPAN vol. 1996, no. 03 29 March 1996 (1996-03-29) *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1750075A1 (fr) 2005-08-05 2007-02-07 Vesuvius Becker & Piscantor Grossalmeroder Schmelztiegelwerke GmbH & Co. KG Creuset pour le traitement de métal liquide et et son procédé de fabrication

Also Published As

Publication number Publication date
EP1372888B1 (fr) 2005-08-03
RU2277591C2 (ru) 2006-06-10
KR20030081527A (ko) 2003-10-17
ATE301014T1 (de) 2005-08-15
EP1243361A1 (fr) 2002-09-25
BR0208100B1 (pt) 2011-09-06
HUP0303607A3 (en) 2005-05-30
JP2004531396A (ja) 2004-10-14
CA2440404C (fr) 2009-06-09
AR032983A1 (es) 2003-12-03
ES2243701T3 (es) 2005-12-01
DE60205350D1 (de) 2005-09-08
TW584615B (en) 2004-04-21
HU228285B1 (hu) 2013-02-28
ZA200306069B (en) 2004-08-06
CA2440404A1 (fr) 2002-09-26
MXPA03008488A (es) 2003-12-08
BR0208100A (pt) 2004-03-02
US20040100004A1 (en) 2004-05-27
EP1372888A1 (fr) 2004-01-02
PL202712B1 (pl) 2009-07-31
PL364828A1 (en) 2004-12-27
RU2003127675A (ru) 2005-04-10
DE60205350T2 (de) 2006-06-01
CN1296157C (zh) 2007-01-24
HUP0303607A2 (hu) 2004-03-01
KR100874397B1 (ko) 2008-12-17
CN1496292A (zh) 2004-05-12

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