WO2002050188A1 - Procede pour ameliorer la resistance aux agressions chimiques d'un enrobe bitumineux. - Google Patents
Procede pour ameliorer la resistance aux agressions chimiques d'un enrobe bitumineux. Download PDFInfo
- Publication number
- WO2002050188A1 WO2002050188A1 PCT/FR2001/004082 FR0104082W WO0250188A1 WO 2002050188 A1 WO2002050188 A1 WO 2002050188A1 FR 0104082 W FR0104082 W FR 0104082W WO 0250188 A1 WO0250188 A1 WO 0250188A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- bituminous
- mix
- weight
- bituminous mix
- aggregates
- Prior art date
Links
Classifications
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/18—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders
- E01C7/26—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre
- E01C7/265—Coherent pavings made in situ made of road-metal and binders of road-metal and bituminous binders mixed with other materials, e.g. cement, rubber, leather, fibre with rubber or synthetic resin, e.g. with rubber aggregate, with synthetic resin binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
Definitions
- the invention relates to a method for improving the resistance to chemical attack by a bituminous mix intended for producing the various layers of a roadway, in particular the wearing course, in particular aeronautical roadways or any other roadway subject to chemical attack. .
- a bituminous mix intended for producing the various layers of a roadway, in particular the wearing course, in particular aeronautical roadways or any other roadway subject to chemical attack.
- the surface and the body of the pavements are liable to deteriorate.
- environmental conditions other than traffic and weather conditions can also adversely affect the condition of the roadway. These include environmental conditions linked to pollution.
- leaks, or even spills of petroleum liquids on the pavement can degrade the pavement by dissolving the bitumen.
- Chemicals of the fluxing or petrochemical solvent type are known to be particularly aggressive with respect to this type of material.
- the present invention therefore relates to a process for improving the resistance to chemical attack by bituminous mixes for the manufacture of roadways and which overcomes the drawbacks of the prior art.
- the subject of the present invention is a process for increasing the resistance to chemical aggressions of bituminous mixes, in particular those linked to leaks or spills of petroleum liquids, and which leads to mixes which are neither toxic nor susceptible to contain carcinogens.
- bituminous mixes in particular those linked to leaks or spills of petroleum liquids, and which leads to mixes which are neither toxic nor susceptible to contain carcinogens.
- polymer type additives for improving the mechanical properties of bituminous binders or bituminous mixes.
- French patent application FR-2753210 describes a bituminous mix for road surfacing based on bitumen modified by polymers and in which polyethylene has been added. Thanks to such a coating, it was possible to improve the water and frost resistance, the resistance to punching and rutting, the rigidity and the resistance to fatigue.
- European patent EP-0605377 describes asphaltic compositions for the preparation of draining mixes, comprising a first modifier chosen from styrene-butadiene or styrene-isoprene copolymers, their blends and recycled tires, and a second modifier chosen from polyolefins, polyethylene terephthalate and their mixtures. These additives make it possible to increase the resistance to fatigue, the resistance to permanent deformation, as well as the hesitant and cohesive properties.
- bitumens can be modified by terpolymers, such as for example the compound of an ethylenic chain with functional groups of butyl acrylate and methyl glycidyl acrylate which ensures good stability to the bitumen / polymer mixture , as well as elastomers and plastomers allowing a significant improvement in resistance to cracking and rutting.
- terpolymers such as for example the compound of an ethylenic chain with functional groups of butyl acrylate and methyl glycidyl acrylate which ensures good stability to the bitumen / polymer mixture , as well as elastomers and plastomers allowing a significant improvement in resistance to cracking and rutting.
- bitumens with polyvinyl chloride (PVC), other copolymers based on styrene and butadiene, or ethylene and vinyl acetate (EVA).
- PVC polyvinyl chloride
- EVA ethylene and vinyl acetate
- the object of the invention therefore relates to a method for improving the resistance to chemical attack of a bituminous mix for road surfaces comprising a bituminous binder and aggregates, characterized in that it consists in adding to the bituminous mix 1 to 5 % by weight of at least one polyolefin and preferably 1 to 2% by weight relative to the weight of the aggregates, to obtain a modified bituminous mix having a compactness ratio greater than or equal to 97%.
- chemicals of the fluxing type or petrochemical solvent are particularly aggressive with respect to bituminous mixes.
- the ability of the mix to resist these attacks is called anti-kerosene or anti-K.
- the anti-K character will be more or less marked depending on the composition of the mix.
- bitumen of the composition according to the invention is a bitumen modified by polymers, the bitumens modified by polymers being defined within the meaning of the document "Technical Guide: use of modified binders, special bitumens and bitumens with additives in techniques "previously mentioned.
- the polymers are advantageously chosen from styrene-butadiene or styrene-isoprene copolymers and their mixtures or terpolymers.
- bituminous mix comprises 3 to 1 1, preferably 5 to 1 1% by weight of bituminous binder relative to the weight of the aggregates.
- the granulometry of the aggregates is chosen from the range 0 / Dmax, Dmax being the maximum diameter of the aggregate as defined according to standard XP P 1 8-540, and going from 4 to 25 mm.
- the polyolefin is advantageously a polyethylene, a polypropylene or a mixture of the two.
- the polyolefin may be virgin, that is to say coming directly from industrial production, or from recovery, that is to say obtained by recycling used objects or manufacturing waste comprising polyolefins.
- the polyolefin, the bituminous binder and the aggregates are kneaded to form the modified bituminous mix.
- the kneading takes place at a temperature of 140 to 190 ° C, and preferably from 160 to 190 ° C.
- bituminous mixes obtained according to the present invention have a Rchydrocarburei ⁇ 'c / Rcair-i sc ratio greater than or equal to 0.70, where Rchydrocarburei 8 ° c is the compressive strength at 1 8 ° C after immersion for one week in a hydrocarbon bath at 18 ° C and Rcair 18 ° c the compressive strength at 18 ° C in air.
- the compactness ratio of bituminous mixes according to the invention, or else modified bituminous mixes, measured according to standard NF P 98 250-6 is greater than or equal to 97%.
- Bituminous mix manufactured using the process according to the invention, can be used on pavements with a high potential for receiving an accidental oil spill, road pavements, aeronautical pavements, tank tracks and military roads. , as well as on industrial platforms and roads and also on bus tracks and tram tracks on tires.
- bitumen 50/70 or - bitumen 70/100, or
- Coal tar mix binders (prior art binder)
- Polyolefin low density polyethylene, presented in the form of 0/4 mm lenses
- the compressive strength after immersion in the Exxsol D80 oil bath at 18 ° C is also determined by carrying out compression tests according to standard NF P 98-251-1. For this determination, the DU RI EZ test pieces are prior to the mechanical characterization test, completely immersed for one week in an oil bath at a temperature of 18 ° C.
- the ratio Rckérosène18 ° C / Rcairi8 ° c is calculated in order to estimate the degree of conservation of the compression resistance of a bituminous mix after complete immersion in an aggressive agent such as petroleum Exxsol D80.
- the ratio Rchydrocarbure ⁇ a ° c / Rcair 18 ° c is representative of the anti-K character of the bituminous mix. The closer the value of this ratio is to 1, the more marked the anti-K character of the mix, or the higher the resistance to chemical aggression caused by petroleum. compactness
- the compactness is measured according to standard NF P 98 250-6. It is a measurement of the apparent density of a test piece by hydrostatic weighing.
- a first bituminous mix was prepared according to the invention (EB 1), by mixing, with 100 parts of aggregates, 6 parts of a 70/100 bitumen for 4 minutes at 180 ° C. Then, 1.5 parts of a polyethylene are added to the mix obtained and kneaded for 8 minutes to homogenize well.
- a second bituminous mix was prepared according to the invention (EB2), by mixing, with 100 parts of aggregates, 6 parts of a 180/220 bitumen for 4 minutes at 150 ° C. Then, 1 to 2 parts of a polyethylene are added to the mix obtained and the whole is kneaded for 8 minutes to homogenize well.
- EB2 bituminous mix
- a third bituminous mix according to the invention was prepared (EB3), by mixing, with 100 parts of aggregates, 6 parts of a 50/70 modified bitumen based on polymers or terpolymers, and 1.5 parts of a wax-shaped polyethylene, and the whole is kneaded for 4 minutes at 180 ° C. to homogenize well.
- bituminous mixes T1 and T2 containing neither polyethylene nor polymers: - bituminous mix T1 was obtained, by adding 6 parts by weight of a bitumen 50/70 to 100 parts by weight of aggregates, then kneading everything for 4 minutes at 150 ° C.,
- bituminous mix T2 was obtained, by adding 7.5 parts of STAVOJET® coal tar to 100 parts of aggregates, then mixing everything for 4 minutes at 150 ° C.
- bituminous mixes manufactured using the process according to the invention (EB 1, EB2 and EB3) and having undergone chemical attack, are better than those of the T1 mix containing neither polyethylene nor polymers.
- bituminous mixes EB1, EB2 and EB3 retain more than 75% of their mechanical resistance in compression after a full immersion of one week in an oil bath (Exxsol D80®), while the bituminous mix T1 does not canned only 18%.
- the hydrocarbon content of the asphalt mixes EB1 to EB3 are lower than those of the asphalt mix T2, for which the binder is a coal tar but of the same order of magnitude as the control T1.
- the values of Rchydrocarbure ⁇ 8 ° c / Rcair 1 8 ° c show that the bituminous mixes EB 1, EB2 and EB3 have an anti-K character relatively close to that of the mix asphalt T2, with a very significant improvement in the resistance to 50 ° C in the air.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Architecture (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Road Paving Structures (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01994916A EP1358271A1 (fr) | 2000-12-19 | 2001-12-19 | Procede pour ameliorer la resistance aux agressions chimiques d'un enrobe bitumineux. |
HU0302470A HUP0302470A3 (en) | 2000-12-19 | 2001-12-19 | Method for enhancing resistance of a bituminous mix to chemical attacks |
AU2002225113A AU2002225113A1 (en) | 2000-12-19 | 2001-12-19 | Method for enhancing resistance of a bituminous mix to chemical attacks |
PL01362066A PL195252B1 (pl) | 2000-12-19 | 2001-12-19 | Sposób polepszenia odporności na agresywne chemicznie działanie materiału pokrytego bitumem |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR00/16604 | 2000-12-19 | ||
FR0016604A FR2818273B1 (fr) | 2000-12-19 | 2000-12-19 | Procede pour ameliorer la resistance aux agressions chimiques d'une enrobe bitumineux |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002050188A1 true WO2002050188A1 (fr) | 2002-06-27 |
Family
ID=8857886
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2001/004082 WO2002050188A1 (fr) | 2000-12-19 | 2001-12-19 | Procede pour ameliorer la resistance aux agressions chimiques d'un enrobe bitumineux. |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP1358271A1 (fr) |
AU (1) | AU2002225113A1 (fr) |
CZ (1) | CZ20031690A3 (fr) |
FR (1) | FR2818273B1 (fr) |
HU (1) | HUP0302470A3 (fr) |
PL (1) | PL195252B1 (fr) |
WO (1) | WO2002050188A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7517934B2 (en) | 2003-07-31 | 2009-04-14 | Basf Corporation | Modified anionically polymerized polymers |
CN117361940A (zh) * | 2023-11-20 | 2024-01-09 | 北京建筑大学 | 基于离子干扰的抗盐侵蚀型沥青混合料及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0605377A2 (fr) * | 1992-11-12 | 1994-07-06 | Fina Research S.A. | Composition pour enrobés drainants |
FR2753210A1 (fr) * | 1996-09-12 | 1998-03-13 | Colas Sa | Enrobe bitumineux contenant des polymeres et du polyethylene |
FR2774090A1 (fr) * | 1998-01-29 | 1999-07-30 | Smac Acieroid | Asphalte naturellement rugueux en surface et applications notamment aux revetements de circulation |
-
2000
- 2000-12-19 FR FR0016604A patent/FR2818273B1/fr not_active Expired - Fee Related
-
2001
- 2001-12-19 WO PCT/FR2001/004082 patent/WO2002050188A1/fr not_active Application Discontinuation
- 2001-12-19 CZ CZ20031690A patent/CZ20031690A3/cs unknown
- 2001-12-19 AU AU2002225113A patent/AU2002225113A1/en not_active Abandoned
- 2001-12-19 EP EP01994916A patent/EP1358271A1/fr not_active Withdrawn
- 2001-12-19 HU HU0302470A patent/HUP0302470A3/hu unknown
- 2001-12-19 PL PL01362066A patent/PL195252B1/pl not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0605377A2 (fr) * | 1992-11-12 | 1994-07-06 | Fina Research S.A. | Composition pour enrobés drainants |
FR2753210A1 (fr) * | 1996-09-12 | 1998-03-13 | Colas Sa | Enrobe bitumineux contenant des polymeres et du polyethylene |
EP0837185A1 (fr) * | 1996-09-12 | 1998-04-22 | Colas | Enrobé bitumineux contenant des polymères et du polyéthylène |
FR2774090A1 (fr) * | 1998-01-29 | 1999-07-30 | Smac Acieroid | Asphalte naturellement rugueux en surface et applications notamment aux revetements de circulation |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7517934B2 (en) | 2003-07-31 | 2009-04-14 | Basf Corporation | Modified anionically polymerized polymers |
CN117361940A (zh) * | 2023-11-20 | 2024-01-09 | 北京建筑大学 | 基于离子干扰的抗盐侵蚀型沥青混合料及其制备方法 |
CN117361940B (zh) * | 2023-11-20 | 2024-05-17 | 北京建筑大学 | 基于离子干扰的抗盐侵蚀型沥青混合料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
PL195252B1 (pl) | 2007-08-31 |
FR2818273A1 (fr) | 2002-06-21 |
FR2818273B1 (fr) | 2008-08-29 |
CZ20031690A3 (cs) | 2004-04-14 |
HUP0302470A3 (en) | 2008-05-28 |
PL362066A1 (en) | 2004-10-18 |
EP1358271A1 (fr) | 2003-11-05 |
HUP0302470A2 (hu) | 2003-11-28 |
AU2002225113A1 (en) | 2002-07-01 |
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