WO2002033158A1 - Knitted goods using noble metal wire - Google Patents

Knitted goods using noble metal wire Download PDF

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Publication number
WO2002033158A1
WO2002033158A1 PCT/JP2001/008929 JP0108929W WO0233158A1 WO 2002033158 A1 WO2002033158 A1 WO 2002033158A1 JP 0108929 W JP0108929 W JP 0108929W WO 0233158 A1 WO0233158 A1 WO 0233158A1
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WO
WIPO (PCT)
Prior art keywords
noble metal
metal wire
wire
knitting
metallic fiber
Prior art date
Application number
PCT/JP2001/008929
Other languages
French (fr)
Japanese (ja)
Inventor
Izumi Takemoto
Yoko Kobayashi
Tsumugi Fujita
Kanna Usuda
Original Assignee
Nugget Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nugget Co., Ltd. filed Critical Nugget Co., Ltd.
Publication of WO2002033158A1 publication Critical patent/WO2002033158A1/en

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/20Metallic fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2403/00Details of fabric structure established in the fabric forming process
    • D10B2403/01Surface features
    • D10B2403/011Dissimilar front and back faces
    • D10B2403/0114Dissimilar front and back faces with one or more yarns appearing predominantly on one face, e.g. plated or paralleled yarns

Definitions

  • the present invention relates to a knitted fabric using a noble metal wire, and a method for producing the same. (Background technology)
  • Knitting made of precious metal wires such as gold, silver, and platinum is beautiful and will not lose its radiance, so it is considered to be highly decorative and very valuable. These knitted fabrics can be used alone or processed to produce decorative articles: or used as a net with high corrosion resistance. However, noble metal wires that are thick enough to be used for knitting have very low bow I tension and elongation, and are easily broken. Neither knitting nor hand knitting could be used to knit a knitted fabric using a precious metal wire. '.
  • FIG. 4 shows a schematic front view of the automatic circular knitting machine 1.
  • the automatic circular knitting machine 1 includes a frame 2, a support 4 mounted on the frame 2, a bobbin frame 6 mounted on the support 4, a needle hook mount 8 mounted on an upper part of the support 4, and a needle.
  • Needle hook 10 attached to hook stand 8, Needle hook lid 1 2 provided above needle hook 10 and having needle hook thread guide 14 and thread guide plate 16, and multiple thread guides 20 , A take-off device 22 having a mouth for taking out the finished knitted fabric, and a handle for manually rotating the needle hook 10 and the take-off device 22 (not shown) ), And a driving device (not shown) for rotating the needle hook 10 and the take-off device 22 all at once. Also, the needle hook thread The guide 14 and the yarn guide plate 16 are provided with a plurality of holes (not shown) for guiding the yarn.
  • the structure of the needle hook 10 will be described with reference to FIG.
  • the needle hook 10 has a substantially cylindrical needle hook main body 24, a rotating portion 26 rotatably mounted in the needle hook main body 24, and a vertically movable portion on the circumference of the rotating portion 26. It has a number of spatula needles 28 attached thereto and a sinker 30 movably mounted in a radial direction between each of the spatula needles 28.
  • a bobbin on which a yarn S as a raw material is wound is set in a bobbin frame 6.
  • the thread S is passed through the thread guide 20, the hole provided in the thread guide plate 16, and the hole of the needle hook thread guide 14, and the thread S is passed through the spatula needle 28 in the needle hook 10.
  • the handle (not shown) is manually rotated in this state
  • the rotating portion 26 of the needle hook 10 is rotated.
  • the needle '28 attached to the rotating part moves sequentially up and down, and at the same time, the sinker 30 moves in the radial direction.
  • the yarn S is knitted and the knitting ⁇ is made. Referring to FIG. 6, the principle of the knitting ⁇ being knitted by the movement of the latch needle .28 and the thinning force 30 will be described.
  • the symbol N in Fig. 6 (a) indicates the already knitted stitch.
  • the bevel needle 28 moves downward while holding the thread S.
  • the spatula catches on the stitch and closes.
  • a new stitch is created by passing the needle 28 with the thread S through the already stitched stitch.
  • the sinker 30 arranged between the spatula needles 28 moves inward in the radial direction, and the yarn between the stitches is subjected to a thin force.
  • the driving device (not shown) is temporarily stopped, and the knitting N which has been knitted is picked up by the take-up device 22. .
  • the knitted fabric N in the take-up device 22 After setting the knitted fabric N in the take-up device 22, an appropriate tension is applied to the knitted knitted fabric N, and the completed knitted fabric N accumulates at the lower part of the take-up device 22.
  • the knitting of the precious metal wire to make a knitting N--As a thread S For example: If, a single wire of 50 ⁇ m thick gold is cut on a circular knitting machine 1, the single wire of gold is broken Then, the knitting N cannot be knitted. Even if the circular knitting machine 1 is operated with extremely low tension applied to the yarn to prevent excessive force from being applied to the gold single wire, the gold single wire frequently breaks and the knitting that has a commercial value can be achieved. I could't make it. ',
  • an object of the present invention is to obtain a method for producing a knitted fabric using a noble metal wire.
  • Another object of the present invention is to obtain a knit using a noble metal wire. .
  • the cause of breakage of a single wire of noble metal will be investigated.
  • the point where the solid line breaks is as follows: (1) the point where the single lines contact each other while forming a loop; A loop is formed-the point where the solid line touches the stick needle, as shown at point C in Fig. 6 (c): (.3 There are three possible points of the loop where the single line touches the sinker b Therefore, a tensile test was performed to determine the breaking load when breaking occurs at each of the above points.
  • the precious metal single-wire loop is pulled by another precious metal single-wire loop, flat needle, and thin force. It was set on the clamp of the testing machine.
  • the tensile tester used was a Shimadzu AGS-lkNG tester.
  • An example of the experimental results is shown in (Table 1). In the test, a single wire of 524 gold in diameter was used, the length of each single wire forming the loop was 150111111, and the pulling speed was 150111111/111; 1_11.
  • FIG. 2 shows the results of a tensile test performed under these conditions.
  • a combined yarn of 50 m in diameter and 24 gold solid wire and 75 denier vinylon / synthetic fiber was used in parallel.
  • FIG. 2 shows the relationship between the elongation and the tensile force of the combined yarn when the combined yarn was pulled under various conditions.
  • the solid line in Fig. 2 is when the loop of the combined yarn is pulled as shown in Fig. 1 '(a), and the broken line in Fig. 2 is that the combined yarn is pulled with a flat needle as shown in Fig. 1' (b).
  • the dashed line in FIG. 2 represents the time when the combined yarn is pulled with a thin force as shown in FIG. 1 (c).
  • the single line of the combined yarn breaks at a point of a tensile load of about 350 mN and an elongation of about 2.2%. You can see that it was done. Furthermore, the dashed line in FIG. 2 shows that when the combined yarn was pulled by the sinker, the single line broke at a point of a tensile load of about 19 ° mN and an elongation of about 0.7%.
  • the non-metallic fiber exists along the gold single line, the curvature at which the gold single line is bent at the contact points between the gold single lines and the points of contact with the lancing needle and the sinker increases, and the gold single line The effect of relaxation of tensile and compressive stress generated by bending can be expected.
  • the presence of non-metallic fibers may reduce friction at the point of contact between gold single wires and at points of contact with lint needles and sinkers.
  • the inventor of the present invention succeeded in producing a knitted fabric using a noble metal wire by the following method for the first time in the world.
  • the present invention provides a step of preparing a noble metal wire and a non-metal fiber
  • a method for producing a knitted fabric using a noble metal wire is provided.
  • the noble metal wire may be a single wire of gold, silver, platinum, iridium, or palladium, or a wire along the same.
  • the step of removing the non-metallic fiber by treating the non-metallic fiber with a water-soluble fiber and treating a knitted knit obtained by knitting the precious metal wire and the non-metallic fiber along with water add more.
  • the water-soluble fiber is removed from the knitted fabric knitted with the noble metal wire and the water-soluble fiber, and a knitted fabric composed only of the noble metal wire can be obtained.
  • the present invention also relates to a knitted fabric using a noble metal wire obtained by knitting a single noble metal wire or a plurality of noble metal single wires.
  • the present invention also relates to a knitted fabric using a noble metal wire woven by knitting one or more single wires of a noble metal and nonmetal fibers.
  • a single wire of the noble metal a single wire of gold, silver, platinum, iridium,... Or palladium can be used, and a water-soluble fiber can be used as the nonmetallic fiber.
  • FIG. 1 is a schematic diagram showing a method of a tensile test of a noble metal wire. ⁇
  • FIG. 2 is a graph showing the results of a tensile test of a combined yarn obtained by combining a precious metal wire and a non-metallic fiber.
  • FIG. 3 is a schematic front view of a circular knitting machine for producing a knitted fabric using a noble metal wire according to an embodiment of the present invention.
  • FIG. 4 is a schematic front view of a conventional automatic circular knitting machine. .
  • FIG. 5 is a plan view showing a structure of a needle hook of a conventional automatic circular knitting machine. .
  • FIG. 6 is a schematic view showing the principle of a conventional automatic circular knitting machine for forming stitches. [Best mode for carrying out the invention]
  • FIG. 3 is a schematic front view of a TN-6F type circular knitting machine 1 manufactured by Koike Machinery used in the production method of the present invention.
  • the circular knitting machine 1 has 16 gauges, and the reference numbers, functions and operations of the respective parts are the same as those in FIG.
  • the bobbin around which the noble metal wire M is wound and the bobbin around which the non-metallic fiber S is wound are set on the bobbin frame 6.
  • the non-metallic fiber S is passed through the thread guide 20 and the thread guide plate 1 It is guided into needle hook 10 through hole 6 and needle hook thread guide 14.
  • the precious metal wire M is passed through a thread guide 20 different from the one passed through the non-metallic fiber S, and then passed through the same hole as the hole passed through the non-metallic fiber S of the thread guide plate 16, Finally, the noble metal wire M is guided into the needle hook 10 through the same hole of the needle hook thread guide 14 as the hole through which the non-metallic fiber S passes.
  • the bobbin around which the precious metal wire M is wound is generally heavy, so that the precious metal wire M is smoothly fed out.
  • the precious metal wire M and non-metallic fiber S to be used for the knitting machine and knitting machine to be used change the way of threading the precious metal wire M and the non-metallic fiber S as appropriate.
  • the phrase "make the precious metal wire and the non-metallic fiber extend" means that the precious metal wire and the non-metallic fiber are parallel to each other, and It means both a state in which metal fibers are twisted with each other. Therefore, in order to make the precious metal wire and the non-metallic fiber follow, if the precious metal wire and the non-metallic fiber are wound on separate bobbins, set on a knitting machine, and knitted while aligning them, the precious metal wire and the non-metallic When metal fibers are aligned and wound on one bobbin, the bobbin is set on a knitting machine and knitting is performed, a precious metal wire and non-metal fibers are twisted with a twisting machine to make a twisted yarn of precious metal wires and non-metal fibers, When setting the twisted yarn on a knitting machine and knitting, and when precious metal wire and non-metallic fiber And twisting a single bobbin into a twisting machine to create a twisted yarn of precious metal wire and non-metall
  • the noble metal wire M is, for example, a single gold wire of 50 ⁇ 111 in diameter
  • the non-metallic fiber S is a water-soluble synthetic fiber, for example, Nichibi Co., Ltd., Soluble (registered trademark) 75 denier was used.
  • the noble metal wire M a noble metal wire that cannot be knitted alone, such as a single wire having a diameter of approximately 20 / m to 100 m, or a noble metal wire obtained by arranging several wires thereof can be used.
  • the noble metal 14 gold, .18 gold, '24 gold, silver, platinum, iridium, palladium and the like can be used.
  • the nonmetallic fiber S not only water-soluble fiber but also any suitable fiber that can be knitted alone such as wool, cotton, silk, hemp, and chemical fiber can be used. +
  • the precious metal wire M and the non-metallic fiber S ' are wound on separate bobbins and set on the circular knitting machine.
  • the precious metal wire M and the non-metallic fiber S You may wind it around a bobbin and knit the yarn with a circular knitting machine. ...
  • a method for producing a knitted fabric using a noble metal wire can be obtained. Also, according to the present invention, a knitted fabric using a noble metal wire can be obtained.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Knitting Of Fabric (AREA)
  • Knitting Machines (AREA)

Abstract

A method for producing knitted goods using a noble metal wire (M), characterized in that it comprises a step of providing a noble metal wire (M) and a non-metallic fiber (S), a step of bringing the noble metal wire (M) into line with the non-metallic fiber (S), and a step of knitting the resultant combination of the noble metal wire (M) and the non-metallic fiber (S) being brought into line with each other.

Description

明 細 書 貴金属線を用いた編み物及びその製造方法  Knitting using precious metal wire and method for producing the same
〔技術分野〕 〔Technical field〕
本発明は、 '貴金属線を用いて編んだ編み物、 及び、 その製造方法に関する。 〔背景技術〕  The present invention relates to a knitted fabric using a noble metal wire, and a method for producing the same. (Background technology)
金、 銀、 プラチナ等の貴金属線を用いて編んだ編み物は、 美しく、 その輝きを 失うことがないため、 装飾性が高く、 非常に価値の高いものになると考えられる。 これらの編み物は、 単独で、 又は加工を施して装飾品を製造した:り、 或いは、 耐 蝕性が高い網としての用途等に用いることができる。 しかしながら、 編み物に使 用することができる程度の太さの貴金属線は、 弓 I張り強度や伸び率が非常に小さ く、 また、 折れやすい性質があるため、 動力を用いた編み機、 手動による編み機、 及び手編みの何れの方法によっても、 貴金属線を用いて編み物を編むこ 'とはでき なかった。 '.  Knitting made of precious metal wires such as gold, silver, and platinum is beautiful and will not lose its radiance, so it is considered to be highly decorative and very valuable. These knitted fabrics can be used alone or processed to produce decorative articles: or used as a net with high corrosion resistance. However, noble metal wires that are thick enough to be used for knitting have very low bow I tension and elongation, and are easily broken. Neither knitting nor hand knitting could be used to knit a knitted fabric using a precious metal wire. '.
従来技術による編み物の製造方法を、 自動丸編み機を例に説明する。'図 4に、 自動丸編み機 1の概略正面図を示す。 自動丸編み機 1は、 フレーム 2と、 フレ一 ム 2に取付けられた支柱 4と、 支柱 4に取付けられたボビン用フレーム 6と、 支 柱 4の上部に取付けられた針釜架台 8と、 針釜架台 8に取付けられた針釜 1 0と、 針釜 1 0の上部に設けられ、 針釜糸ガイド 1 4及び糸ガイド板 1 6を有する針釜 蓋 1 2と、 複数の糸ガイド 2 0を有する副支柱 1 8と、 出来上がった編み物を引 き取るための口一ラーを有する引取装置 2 2と、 針釜 1 0及び引取装置 2 2を手 動で回転させるためのハンドル (図示せず) と、 針釜 1 0及び引取装置 2 2をモ 一夕で回転駆動するための駆動装置 (図示せず) と、 を有する。 また、 針釜糸ガ ィド 1 4及び糸ガイド板 1 6には、 糸を案内するための複数の孔 (図示せず) が 設けられている。 A knitting method according to the prior art will be described using an automatic circular knitting machine as an example. Figure 4 shows a schematic front view of the automatic circular knitting machine 1. The automatic circular knitting machine 1 includes a frame 2, a support 4 mounted on the frame 2, a bobbin frame 6 mounted on the support 4, a needle hook mount 8 mounted on an upper part of the support 4, and a needle. Needle hook 10 attached to hook stand 8, Needle hook lid 1 2 provided above needle hook 10 and having needle hook thread guide 14 and thread guide plate 16, and multiple thread guides 20 , A take-off device 22 having a mouth for taking out the finished knitted fabric, and a handle for manually rotating the needle hook 10 and the take-off device 22 (not shown) ), And a driving device (not shown) for rotating the needle hook 10 and the take-off device 22 all at once. Also, the needle hook thread The guide 14 and the yarn guide plate 16 are provided with a plurality of holes (not shown) for guiding the yarn.
図 5を参照して、 針釜 1 0の構造を説明する。針釜 1 0は、 概略円筒形の針釜 本体 2 4と、 針釜本体 2 4の中に回転可能に取付けられた回転部 2 6と、 回転部 2 6の円周上に上下動可能に取付けられた多数のベら針 2 8と、 各ベら針 2 8の 間に半径方向に移動可能に取付けられたシンカー 3 0と、 を有する。  The structure of the needle hook 10 will be described with reference to FIG. The needle hook 10 has a substantially cylindrical needle hook main body 24, a rotating portion 26 rotatably mounted in the needle hook main body 24, and a vertically movable portion on the circumference of the rotating portion 26. It has a number of spatula needles 28 attached thereto and a sinker 30 movably mounted in a radial direction between each of the spatula needles 28.
編み物を編むには、 原料となる糸 Sを卷いたボビンをボビン用フレーム 6にセ ヅトする。 次に、 糸 Sを糸ガイド 2 0、 糸ガイド板 1 6に設けられた孔、 及び針 釜糸ガイド 1 4の孔に通し、 糸 Sを針釜 1 0の中のベら針 2 8に掛ける。 この状 態でハンドル (図示せず) .を手動で回転させると、 針釜 1 0の回転部 2 6が回転 する。 回転部 2 6:が回転すると、 回転部に取付けられたべら'針: 2 8が順次上下に 移動し、 また同時にシンカー ·3 0が半径方向に移動する。 この動きによって糸 S が編まれて編み物 Νが作られる。. - . 図 6を参照して、 ベら針.2 8とシン力一 3 0の動きによ.つて、 編み物 Νが編ま れる原理を説明する。 .図 6 ( a ) の記号 Nは既に編み上がった編み物の編み目を ·To knit a knit, a bobbin on which a yarn S as a raw material is wound is set in a bobbin frame 6. Next, the thread S is passed through the thread guide 20, the hole provided in the thread guide plate 16, and the hole of the needle hook thread guide 14, and the thread S is passed through the spatula needle 28 in the needle hook 10. Multiply. When the handle (not shown) is manually rotated in this state, the rotating portion 26 of the needle hook 10 is rotated. When the rotating part 26 : rotates, the needle '28 attached to the rotating part moves sequentially up and down, and at the same time, the sinker 30 moves in the radial direction. By this movement, the yarn S is knitted and the knitting Ν is made. Referring to FIG. 6, the principle of the knitting Ν being knitted by the movement of the latch needle .28 and the thinning force 30 will be described. The symbol N in Fig. 6 (a) indicates the already knitted stitch.
'表し、 記号 Sは新たに供給された糸を表す。 図 6 ( a ) に示すように、 .ベら針 2'Represents the symbol S represents the newly supplied yarn. As shown in Fig. 6 (a),
8は、'既に編まれた編み物 Nの編み目に通された状態で上方べ移動し、 新たに供' 給された糸 Sを針の先のカギに引っかける。 次に、 図 6 ( b ) に示すように、 ベ ら針 2 8は糸 Sをくわえたまま下方に移動する。ベら針 2 8の上部が上方から下 方へ編み目を通り抜ける際に、 編み目にベらが引つかかり、 ベらが閉じる。 糸 S をくわえたベら針 2 8が既に編まれていた編み目を通り抜けることによって新た な編み目が作られる。 ここで、 図 6 ( c ) に示すように、 ベら針 2 8の間に配置 されたシンカー 3 0が半径方向内方に移動し、 編み目と編み目の間の糸をシン力8 moves upward while passing through the stitches of the already knitted knit N, and hooks the newly supplied thread S to the key at the tip of the needle. Next, as shown in FIG. 6 (b), the bevel needle 28 moves downward while holding the thread S. As the upper part of the spatula needle 28 passes through the stitch from top to bottom, the spatula catches on the stitch and closes. A new stitch is created by passing the needle 28 with the thread S through the already stitched stitch. Here, as shown in FIG. 6 (c), the sinker 30 arranged between the spatula needles 28 moves inward in the radial direction, and the yarn between the stitches is subjected to a thin force.
— 3 0のカギに引っかける。 次に、 図 6 ( d ) に示すように、 ベら針 2 8が再び 上方に移動する。ベら針 2 8の上部が編み目を下方から上方へ通り抜ける際にべ ら針 2 8のべらが開く。 既に編まれた編み物 Nはシンカー 3 0に引つかかってい るので、 ベら針 2 8が上方に移動する際に、 編み物 Nがベら針 2 8と一緒に上方 に移動することはない。 — Hook on the 30 key. Next, as shown in FIG. 6 (d), the latch needle 28 moves upward again. As the upper part of the lever needle 28 passes through the stitch from below to above, The needle of the needle 28 opens. Since the already knitted fabric N is hooked on the sinker 30, the knitted fabric N does not move upward together with the spatula needle 28 when the flat needle 28 moves upward.
針釜 1 0の回転部 2 6が針釜本体 2 4の中で回転すると、 回転部 2 6の円周上 に交互に配置された多数のベら針 2 8及びシンカー 3 0が、 上記の動きを順次繰 り返す。針 2 8及びシンカー 3 0のこの動きによって、 編み物 Nが編まれる。 ハンドル (図示せず) を手動で回転させることによって、 針釜 1ひの回転部 2 6を回転させ、 編み物 Nを数段編む。 編み物 Nが安定して編まれるようになった ならば、 駆動装置 (図示せず) を起動させる。 その後は、 駆動装置 (図示せず) の駆動ガによって、 自動的に編み物 Nが編まれてい.ぐ。 編み物 Nが編み進められ 十分な長さにな.づたならば、 駆動装置 (図示せず) を一旦停止 て、:編み上がつ た編み物 Nを引取'り装置 2 2の口 ラーに挟む。 編み物 Nを引取り装置 2 2にセ ットした後は、 編み上がった編み物 Nに適度な張力が加えられ、 完成した編み物 Nは引取り装置 2 2の.下部に溜まる。  When the rotating portion 26 of the needle hook 10 rotates in the needle hook main body 24, a large number of spatula needles 28 and sinkers 30 alternately arranged on the circumference of the rotating portion 26 are formed as described above. Repeat the movement sequentially. With this movement of the needle 28 and the sinker 30 the knit N is knitted. By manually rotating the handle (not shown), the rotating part 26 of the needle hook 1 is rotated to knit the knitting N several steps. When the knitting N has been stably knitted, the drive (not shown) is activated. After that, the knitting N is automatically knitted by the driving gear of the driving device (not shown). When the knitting N has been advanced to a sufficient length, the driving device (not shown) is temporarily stopped, and the knitting N which has been knitted is picked up by the take-up device 22. . After setting the knitted fabric N in the take-up device 22, an appropriate tension is applied to the knitted knitted fabric N, and the completed knitted fabric N accumulates at the lower part of the take-up device 22.
,しかしながら、 貴金属線で編んだ編み物 Nを作るベぐ、 - '糸 Sとして、:例え:ば、 ·· 太さ 5 0〃mの金の単線を丸編み機 1にかけても、 金の単線が破断して.しまい編 み物 Nを編むことができない。 金の単線に無理な力がかからないように、 糸にか かる張力を極端に弱くして丸編み機 1を作動させたとしても、.金の単線の破断が 頻繁に起り、 商品価値のある編み物を作ることは出来なかった。 ' ,  However, the knitting of the precious metal wire to make a knitting N--As a thread S: For example: If, a single wire of 50〃m thick gold is cut on a circular knitting machine 1, the single wire of gold is broken Then, the knitting N cannot be knitted. Even if the circular knitting machine 1 is operated with extremely low tension applied to the yarn to prevent excessive force from being applied to the gold single wire, the gold single wire frequently breaks and the knitting that has a commercial value can be achieved. I couldn't make it. ',
同様に、 金の単線を横編み機や縦編み機にかけた場合にも、 金の単線の破断が 頻繁に起り、 編み物を編むことはできなかった。 更に、 金の単線を手編みで編む ことを試みたが、 金の単線は切れやすく取扱いが難しいので、 編み物を編むこと は非常に困難であり、 金の単線を手編みで編むことも実質的に不可能であると言 約 3 0 m乃至約 1 0 0〃mの貴金属の単線、 及びそれらを数本組み合わせた もので編み物を編むことも試みたが、 何れの場合にも貴金属の単線の破断が頻繁 に起り、 商品として使用できる程度の品質の編み物を製造することは不可能であ つた。 Similarly, when a single gold wire was placed on a flat knitting machine or a vertical knitting machine, the single gold wire was frequently broken, and the knitting could not be performed. Furthermore, we tried to knit a single gold wire by hand, but it is very difficult to knit a single wire of gold because it is easy to cut and difficult to handle, and it is virtually impossible to knit a single wire of gold by hand. Noble metal single wire of about 30 m to about 100 〃m and a combination of several of them Attempts were also made to knit knitted fabrics, but in each case, the single wires of precious metal were frequently broken, and it was impossible to produce knitted fabrics of sufficient quality for commercial use.
従って、 本発明の目的は、 貴金属線を用いた編み物の製造方法を得ることにあ る。  Therefore, an object of the present invention is to obtain a method for producing a knitted fabric using a noble metal wire.
本発明の他の目的ば、 貴金属線を用いた編み物を得ることにある。.  Another object of the present invention is to obtain a knit using a noble metal wire. .
〔発明の開示〕 ' ·  [Disclosure of the Invention] '
. 前記課題を解決するために、 貴金属の単線が破断する原因を調べることにする。 単線が破断する箇所としては、 図 6 (b)の点 Aのように、 (1)単線どうしが ル—プを形成した状態で接触する点、 同図点 Bのよう.に、 (2)ループをな.した- 単線がベら針に接触する点、.図 6 (c)の点 Cのように、: (.3 ループをなしたぺ 単線がシンカーに接触する点の 3つが考えられる b そこで、 前記の各点で破断が 起る際の破断荷重を求めるために引張り試験を行った。 In order to solve the above-mentioned problem, the cause of breakage of a single wire of noble metal will be investigated. As shown in point A in Fig. 6 (b), the point where the solid line breaks is as follows: (1) the point where the single lines contact each other while forming a loop; A loop is formed-the point where the solid line touches the stick needle, as shown at point C in Fig. 6 (c): (.3 There are three possible points of the loop where the single line touches the sinker b Therefore, a tensile test was performed to determine the breaking load when breaking occurs at each of the above points.
. 引張り試験では、 図 1 (a)乃至 (c) に示すように、 貴金属の単線のループ を、 もう 1·.つの貴金属の単線のループ、 ベら針、 シン力 で夫々引張るように、 引張試験機のクランプ 32.にセットした。 なお、 引張試験機には、 島津製作所製 ォ トグラフ AGS— lkNG試験機を使用した。実験結果の一例を (表 1) に . 示す。 試験には、 直径 5 24金の単線を用い、ル一プを形成する各単線 の長さを 150111111、 引張り速度を150111111/111;1_ 11とした。  In the tensile test, as shown in Fig. 1 (a) to (c), the precious metal single-wire loop is pulled by another precious metal single-wire loop, flat needle, and thin force. It was set on the clamp of the testing machine. The tensile tester used was a Shimadzu AGS-lkNG tester. An example of the experimental results is shown in (Table 1). In the test, a single wire of 524 gold in diameter was used, the length of each single wire forming the loop was 150111111, and the pulling speed was 150111111/111; 1_11.
(表 1)
Figure imgf000006_0001
(table 1)
Figure imgf000006_0001
弓 I張り試験では、 単線は何れの場合にも、 単線と単線、 単線とベら針、 単線と シンカーの接触点において破断した。 このことは、 単線が、 単純な引張りではな く、 接触点における剪断、 又は接触点において単線が折り曲げられることによつ て発生する引張、 圧縮応力によって破断していることを示している。 また、 (表In the bow I tension test, in each case, the single wire broke at the contact point between the single wire and the single wire, the single wire and the spatula needle, and the single wire and the sinker. This means that a single wire is not a simple pull It indicates that the wire was broken due to the shear at the contact point or the tensile or compressive stress generated by bending the single wire at the contact point. Also, (Table
1 ) の破断荷重を比較すると、 単線の破断は、 単線どうしの接触点で最も起りや すいということがわかる。 Comparing the breaking loads in 1), it can be seen that a single wire break is most likely to occur at the point of contact between the single wires.
本願発明の発明者は、 単線の破断荷重を増大させるために、 適当な引張り強度、 伸び率を有する非金属繊維を、 単線に沿わせることを試みた。 図 2に、 このよう な条件で行った引張り試験の結果を示す。 なお、 弓 I張り試験には、 直径 5 0 m の 2 4金の単線及び 7 5デニールのビニロン.合成繊維を平行に沿わせた組合せ糸 を使用した。 図 2は、 前記の組合せ糸を種々の条件で引張ったときの組合せ糸の 伸び率と引張り力との関係を表している。 図 2の実線は図 1' ( a) のように組合 せ糸どうしのル一プを引張った場合、 図 2の破線は図 1 '( b ) のように組合せ糸 をベら針で引張つた場合、 '図 2の一点鎖線は図 1 ( c ) のように組合せ糸をシン 力一で引張った場合のデ一夕を表す。 ■ '  The inventor of the present invention attempted to make nonmetallic fibers having appropriate tensile strength and elongation along a single wire in order to increase the breaking load of the single wire. Figure 2 shows the results of a tensile test performed under these conditions. For the bow I tension test, a combined yarn of 50 m in diameter and 24 gold solid wire and 75 denier vinylon / synthetic fiber was used in parallel. FIG. 2 shows the relationship between the elongation and the tensile force of the combined yarn when the combined yarn was pulled under various conditions. The solid line in Fig. 2 is when the loop of the combined yarn is pulled as shown in Fig. 1 '(a), and the broken line in Fig. 2 is that the combined yarn is pulled with a flat needle as shown in Fig. 1' (b). In this case, the dashed line in FIG. 2 represents the time when the combined yarn is pulled with a thin force as shown in FIG. 1 (c). ■ '
まず、 図 2の実線を見ると、 弓漲り力を増大させると共に各組合せ糸は伸び、 引張り'荷重約 2 0 0 0 mN、 伸び約 1 . 2 %のところで一時的に引張力が減少し て ることがわか.る。 これは、 組合せ糸の 2つのループうちの、 '一方のループの 単線が破断したことを示している。 引張り力を更に増加させる'と組合せ糸は更に 伸び、 引張り.荷重約 2 5.0 0 mN、 伸び約 2 . 8 %のところで再び引張り力が一 時的に減少する。 これは、 まだ破断していない方の単線が、 この点で破断したこ とを示している。 同様に、 図 2の破線を見ると、 組合せ糸をベら針で引張った場 合には、 引張り荷重約 3 5 0 0 mN、 伸び約 2 . 2 %の点で組合せ糸の単線が破 断したことがわかる。 さらに、 図 2の一点鎖線を見ると、 組合せ糸をシンカーで 引張った場合には、 引張り荷重約 1 9◦ 0 mN、 伸び約 0 . 7 %の点で単線が破 断したことがわかる。  First, looking at the solid line in Fig. 2, as the bow-pulling force increases, each combination yarn elongates, and the tensile force temporarily decreases at a tensile load of about 200 mN and an elongation of about 1.2%. I understand. This indicates that one of the two loops of the combination yarn was broken. When the tensile force is further increased, the combined yarn is further elongated, and the tensile force temporarily decreases again at a tensile load of about 25.0 mN and an elongation of about 2.8%. This indicates that the single line that has not yet broken has broken at this point. Similarly, looking at the dashed line in Fig. 2, when the combined yarn is pulled with a flat needle, the single line of the combined yarn breaks at a point of a tensile load of about 350 mN and an elongation of about 2.2%. You can see that it was done. Furthermore, the dashed line in FIG. 2 shows that when the combined yarn was pulled by the sinker, the single line broke at a point of a tensile load of about 19 ° mN and an elongation of about 0.7%.
この結果から、 何れの引張り条件の場合にも、 金の単線に非金属繊維を沿わせ ることによって、 金の単線が破断する際の破断荷重が 3倍乃至 5倍に増大するこ とがわかる。 これは、 金の単線に非金属繊維を組合せることによって、 組合せ糸 に荷重がかかったとき、 荷重の一部を非金属繊維が負担して、 金の単線に作用す る荷重が減少するためと考えられる。 また、 金の単線に沿って非金属繊維が存在 するために、 金の単線どうしの接触点や、 ベら針、 シンカーとの接触点において 金の単線が折り曲げられる曲率が大きくなり、 金の単線の曲げによって発生する '引張、 圧縮応力が緩和される効果も期待できる。更に、 非金属繊維の存在により、 金の単線どうしの接触点や、 ベら針、 シンカーとの接触点における摩擦が減少す るとも考えられる。 From these results, it was found that the non-metallic fiber was placed along the solid gold wire under any tensile conditions. This shows that the breaking load when a single gold wire breaks increases by 3 to 5 times. This is because the non-metallic fiber is combined with the solid gold wire, and when a load is applied to the combined yarn, a part of the load is borne by the non-metallic fiber and the load acting on the single gold wire is reduced. it is conceivable that. In addition, since the non-metallic fiber exists along the gold single line, the curvature at which the gold single line is bent at the contact points between the gold single lines and the points of contact with the lancing needle and the sinker increases, and the gold single line The effect of relaxation of tensile and compressive stress generated by bending can be expected. In addition, the presence of non-metallic fibers may reduce friction at the point of contact between gold single wires and at points of contact with lint needles and sinkers.
' .·このように貴金属線の破断荷重を増大させることに'より、 貴金属線を用いて編 み物:を編むことが可能になった。 かくして、 本願発明の発明者は、 世界で初めて' 次の方法により貴金属線を用いた編み物を製造することに成功した。  By increasing the breaking load of the noble metal wire in this way, it became possible to knit a knitted article using a noble metal wire. Thus, the inventor of the present invention succeeded in producing a knitted fabric using a noble metal wire by the following method for the first time in the world.
即ち、 本発明は、 貴金属線と、 非金属繊維とを準備する段階と、'  That is, the present invention provides a step of preparing a noble metal wire and a non-metal fiber,
前記貴金属線と前記非金属繊維とを沿わせる段階と、  Bringing the noble metal wire and the non-metallic fiber along,
' 前記貴金属線:と前記非金属繊維とを沿わせたものを編む段階と、 '' Knitting the precious metal wire: and the non-metallic fiber along,
を有すること.を特徴とする、 貴金属線を用いた編み物の製造方法である。  A method for producing a knitted fabric using a noble metal wire.
こ'の方法により.、 機械編みによる横編み、 縦編み、 或いはく '手編みで貴金属線 を用 V、た編み物を製造することができるようになつた。.  With this method, it became possible to manufacture precious metal wires using flat knitting, warp knitting, or even hand knitting. .
:.また、 前記貴金属線には、 金、 銀、 プラチナ、 イリジウム、 又はパラジウムの 単線、 或いは、 それらを沿わせたものを使用することができる。  : Further, the noble metal wire may be a single wire of gold, silver, platinum, iridium, or palladium, or a wire along the same.
また、 所望により、 前記非金属繊維を水溶性繊維とし、 前記貴金属線と前記非 金属繊維とを沿わせたものを編んだ編み物を水で処理することにより、 前記非金 属繊維を除去する段階を更に加える。  Further, if desired, the step of removing the non-metallic fiber by treating the non-metallic fiber with a water-soluble fiber and treating a knitted knit obtained by knitting the precious metal wire and the non-metallic fiber along with water. Add more.
この方法により、 貴金属線及び水溶性繊維によって編まれた編み物から水溶性 繊維を除去して、 貴金属線のみで構成された編み物を得ることができる。 本発明は又、 貴金属の単線、 又は複数の貴金属の単線を沿わせた糸を編んだ貴 金属線を用いた編み物である。 By this method, the water-soluble fiber is removed from the knitted fabric knitted with the noble metal wire and the water-soluble fiber, and a knitted fabric composed only of the noble metal wire can be obtained. The present invention also relates to a knitted fabric using a noble metal wire obtained by knitting a single noble metal wire or a plurality of noble metal single wires.
本発明により、 今まで得ることができなかつた貴金属線のみで製造された編み 物を得ることができるようになつた。  According to the present invention, it has become possible to obtain a knitted fabric which has not been obtained until now and which is manufactured only with a noble metal wire.
本発明は又、 1又は複数の貴金属の単線と非金属繊維とを沿わせて編んだ貴金 属線を用'いた編み物である。 - また、 前記貴金属の単線として、 金、 銀、 プラチナ、 イリジウム、..又はパラジ ゥムの単線を用いることができ、 前記非金属繊維とじて、 水溶性繊維を用いるこ とができる。  The present invention also relates to a knitted fabric using a noble metal wire woven by knitting one or more single wires of a noble metal and nonmetal fibers. Further, as the single wire of the noble metal, a single wire of gold, silver, platinum, iridium,... Or palladium can be used, and a water-soluble fiber can be used as the nonmetallic fiber.
〔図面の簡単な説明〕 ·  [Brief description of drawings]
図 1は、 貴金属線の引張り試験の方法を示す概略図である。■  FIG. 1 is a schematic diagram showing a method of a tensile test of a noble metal wire. ■
図 2.は、 '貴金属線と非金属繊維とを組合せた組合せ糸の引張り試験デ一夕を示 すグラフである。 : - . 図 3は、 本発明の実施形態による貴金属線を用いた編み物を製造するための丸 編み機の概略正面図である。  Figure 2 is a graph showing the results of a tensile test of a combined yarn obtained by combining a precious metal wire and a non-metallic fiber. FIG. 3 is a schematic front view of a circular knitting machine for producing a knitted fabric using a noble metal wire according to an embodiment of the present invention.
図' 4は、 従来技術の自動丸編み機の概略正面図である。 .  FIG. 4 is a schematic front view of a conventional automatic circular knitting machine. .
'図 5は、 従来技術の自動丸編み機の針釜の構造を表す平面図である。.  FIG. 5 is a plan view showing a structure of a needle hook of a conventional automatic circular knitting machine. .
図 6は、 従来技術の自動丸編み機が編み目を作る原理を表す模式図である。 〔発明を実施するための最良の形態〕  FIG. 6 is a schematic view showing the principle of a conventional automatic circular knitting machine for forming stitches. [Best mode for carrying out the invention]
図 3を参照して、 本発明による貴金属線を用いた編み物の製造方法の実施形態 を説明する。 図 3は、 本発明の製造方法に使用した、 小池機械製 T N—6 F型丸 編み機 1の概略正面図である。 この丸編み機 1は 1 6ゲージであり、 また、 各部 の参照番号、 機能及び作動は、 図 4と同じであるので説明を省略する。  With reference to FIG. 3, an embodiment of a method for producing a knitted fabric using a noble metal wire according to the present invention will be described. FIG. 3 is a schematic front view of a TN-6F type circular knitting machine 1 manufactured by Koike Machinery used in the production method of the present invention. The circular knitting machine 1 has 16 gauges, and the reference numbers, functions and operations of the respective parts are the same as those in FIG.
まず、 ボビン用フレーム 6に、 貴金属線 Mを巻いたボビンと、 非金属繊維 Sを 巻いたボビンをセッ卜する。 次に、 非金属繊維 Sを糸ガイド 2 0、 糸ガイド板 1 6の孔、 針釜糸ガイド 1 4の孔を通して針釜 1 0の中に導く。 次に、 貴金属線 M を、 非金属繊維 Sを通したものとは異なる糸ガイド 2 0に通し、 続いて、 糸ガイ ド板 1 6の非金属繊維 Sを通した孔と同じ孔に通し、 最後に、 非金属繊維 Sを通 した孔と同じ針釜糸ガイド 1 4の孔に通して、 貴金属線 Mを針釜 1 0の中に導く。 この貴金属線 Mを針釜 1 0の中に導く径路において、 貴金属線 Mに過大な張力が かからないように注意する。特に、 貴金属線 Mを巻いたボビンは一般に重いので、 貴金属線 Mがスムーズに繰り出されるようにする。使用する編み機、 編み機にか. ける貴金属線 M、 非金属繊維 Sに応じて、 貴金属線 M及び非金属繊維 Sの糸のか け方を適宜変更する。 First, the bobbin around which the noble metal wire M is wound and the bobbin around which the non-metallic fiber S is wound are set on the bobbin frame 6. Next, the non-metallic fiber S is passed through the thread guide 20 and the thread guide plate 1 It is guided into needle hook 10 through hole 6 and needle hook thread guide 14. Next, the precious metal wire M is passed through a thread guide 20 different from the one passed through the non-metallic fiber S, and then passed through the same hole as the hole passed through the non-metallic fiber S of the thread guide plate 16, Finally, the noble metal wire M is guided into the needle hook 10 through the same hole of the needle hook thread guide 14 as the hole through which the non-metallic fiber S passes. Care should be taken not to apply excessive tension to the noble metal wire M in the path leading the noble metal wire M into the needle hook 10. In particular, the bobbin around which the precious metal wire M is wound is generally heavy, so that the precious metal wire M is smoothly fed out. Depending on the precious metal wire M and non-metallic fiber S to be used for the knitting machine and knitting machine to be used, change the way of threading the precious metal wire M and the non-metallic fiber S as appropriate.
針釜 1 0の中に導かれた貴金属線 M及び非金属繊維 Sを沿わせて、 針釜 1 0の' 中のベら針 2 8に掛ける。 この状態で丸編み機 1のハンドル (図示せず) を回転 させると針釜 1ひが回転し、 貴金属線 Mと非金属繊維 S'とを組合せた糸による編 み物 Nが編まれる。 ハンドル (図示せず) を回転させて、 編み物 Nを数段編んだ ならば、 駆動装置 (図示せず) を起動してモー夕の動力により編み物 Nを製造す る。編み上がった編み物 Nが十分な長さになったならば、 .編み物 Nを引取り装置 . 2, 2のローラ一に挟み、 出来上がつた編み物 Nに適度な張力が作用するようにす 'る。 : '+ ' ■' ' ' . · : ' . .  Along the noble metal wire M and the non-metallic fiber S guided into the needle hook 10, hang the lever 28 in the needle hook 10 ′. When the handle (not shown) of the circular knitting machine 1 is rotated in this state, the needle hook 1 is rotated, and the knitted fabric N made of a combination of the noble metal wire M and the non-metallic fiber S 'is knitted. When the handle (not shown) is rotated and the knitting N is knitted in several steps, the driving device (not shown) is activated to produce the knitting N by the power of the motor. When the knitted knit N is long enough, take the knit N into the take-off device. 2 and 2 between the rollers so that the finished knit N has a suitable tension. You. : '+' ■ '' '.
- ..なお、..本明細書において、 「貴金属線と非金属繊維とを沿わせる」.とは、 貴金 属線と非金属繊維とを平行に沿わせた状態、 及び貴金属線と非金属繊維とを互い に撚り合せた状態の両方を意味する。 従って、 「貴金属線と非金属繊維とを沿わ せる」 には、 貴金属線と非金属繊維とを別々のボビンに卷いて編み機にセットし、 それらを引き揃えながら編み物を編む場合、 貴金属線と非金属繊維とを引き揃え て 1つのボビンに巻き、 そのボビンを編み機にセットして編み物を編む場合、 貴 金属線と非金属繊維とを撚糸機にかけて貴金属線と非金属繊維との撚糸を作り、 その撚糸を編み機にセットして編み物を編む場合、 及び貴金属線と非金属繊維と を引き揃えて 1つのボビンに巻いたものを撚糸機にかけて貴金属線と非金属繊維 との撚糸を作り、 その撚糸を編み機にセットして編み物を編む場合等が含まれる。 本発明の実施形態では、 貴金属線 Mとして、 例えば、 直径5 0〃111の2 4金の 単線、 非金属繊維 Sとして水溶性合成繊維、 例えば、 株式会社二チビ製、 ソルブ ロン (登録商標) 7 5デニールを使用した。 しかしながら、 貴金属線 Mとして、 直径約 2 0 /m乃至 1 0 0 mの単線、 又はそれらを数本沿わせた貴金属線等、 単独では編むことができない貴金属線を使用することができる。 更に、 貴金属と して、 1 4金、 .1 8金、' 2 4金、 銀、 プラチナ、 イリジウム、 パラジウム等を用 いることができる。 また、 非金属繊維 Sとしては、 水溶性繊維ばかりでなく、 毛、 綿、 絹、 麻、'化学繊維等、 単独でも編み物を編むことができる任意適当な繊維を 使用することができる。 + -In this specification, the phrase "make the precious metal wire and the non-metallic fiber extend" means that the precious metal wire and the non-metallic fiber are parallel to each other, and It means both a state in which metal fibers are twisted with each other. Therefore, in order to make the precious metal wire and the non-metallic fiber follow, if the precious metal wire and the non-metallic fiber are wound on separate bobbins, set on a knitting machine, and knitted while aligning them, the precious metal wire and the non-metallic When metal fibers are aligned and wound on one bobbin, the bobbin is set on a knitting machine and knitting is performed, a precious metal wire and non-metal fibers are twisted with a twisting machine to make a twisted yarn of precious metal wires and non-metal fibers, When setting the twisted yarn on a knitting machine and knitting, and when precious metal wire and non-metallic fiber And twisting a single bobbin into a twisting machine to create a twisted yarn of precious metal wire and non-metallic fiber, setting the twisted yarn in a knitting machine and knitting a knitted fabric. In the embodiment of the present invention, the noble metal wire M is, for example, a single gold wire of 50〃111 in diameter, and the non-metallic fiber S is a water-soluble synthetic fiber, for example, Nichibi Co., Ltd., Soluble (registered trademark) 75 denier was used. However, as the noble metal wire M, a noble metal wire that cannot be knitted alone, such as a single wire having a diameter of approximately 20 / m to 100 m, or a noble metal wire obtained by arranging several wires thereof can be used. Further, as the noble metal, 14 gold, .18 gold, '24 gold, silver, platinum, iridium, palladium and the like can be used. In addition, as the nonmetallic fiber S, not only water-soluble fiber but also any suitable fiber that can be knitted alone such as wool, cotton, silk, hemp, and chemical fiber can be used. +
'· また、 本実施形態では、 貴金属線 Mと非金属繊維 S 'とを別々のボビンに巻いて' 丸編み機にセヅトしたが、 貴金属線 Mと非金属繊維 Sとを予め沿わせて一つのボ ビンに巻いておき、 その糸を丸編み機で編んでも良い。 . . .  Further, in the present embodiment, the precious metal wire M and the non-metallic fiber S 'are wound on separate bobbins and set on the circular knitting machine. However, the precious metal wire M and the non-metallic fiber S You may wind it around a bobbin and knit the yarn with a circular knitting machine. ...
:次に.、.;貴金属線 Mと非金属繊維 Sである水溶性繊維どを用'いて編み上がった編 ·. み-物を、 '約 7 0 ° Cの湯に約 2 0分浸し、 水溶性繊維を溶解、. 除去する。 これに より、 貴金属線 Mのみで構成された編み物 Nを得ることができる。 湯の温度、 溶 解処理時間は使用した水溶性繊維に応じて適宜変更する。.勿論、 貴金属線 Mと水 溶性繊維以外の非金属繊維 Sを用いて編まれた最終製品を製造する場合には、 こ の工程は省略する。 .  : Next, immerse the knitted fabric using the precious metal wire M and the water-soluble fiber that is the non-metallic fiber S in '70 ° C hot water for about 20 minutes. Dissolves and removes water-soluble fibers. Thereby, a knitted fabric N composed of only the noble metal wire M can be obtained. The temperature of the hot water and the dissolution treatment time are appropriately changed depending on the water-soluble fibers used. Of course, when manufacturing a final product woven using the precious metal wire M and the non-metallic fiber S other than the water-soluble fiber, this step is omitted. .
以上、 本発明の実施形態を説明したが、 本発明の範囲又は精神から逸脱するこ となく、 特許請求の範囲に記載された技術的事項の範囲内において、 開示した実 施形態に種々の変更を加えることができる。  While the embodiments of the present invention have been described above, various changes may be made to the disclosed embodiments without departing from the scope or spirit of the present invention and within the scope of the technical matters described in the claims. Can be added.
〔産業上の利用可能性〕  [Industrial applicability]
本発明により、 貴金属線を用いた編み物の製造方法を得ることができる。 また、 本発明により、 貴金属線を用いた編み物を得ることができる。 According to the present invention, a method for producing a knitted fabric using a noble metal wire can be obtained. Also, According to the present invention, a knitted fabric using a noble metal wire can be obtained.

Claims

請 求 の 範 囲 The scope of the claims
1 . 貴金属線と、 非金属繊維とを準備する段階と、 1. Preparing precious metal wires and non-metallic fibers;
前記貴金属線と前記非金属繊維とを沿わせる段階と、  Bringing the noble metal wire and the non-metallic fiber along,
前記貴金属線と前記非金属繊維とを沿わせたものを編む段階と、  Knitting the precious metal wire and the non-metallic fiber along,
を有することを特徴とする、 貴金属線を用いた編み物の製造方法。  A method for producing a knitted fabric using a noble metal wire, comprising:
2 . 前記貴金属線が、 金、 銀、 プラチナ、 イリジウム、 又はパラジウムの単線、 或いは、 それらを沿わせたものであることを特徴とする、 請求項 1.に記載の貴金 属線を用いた編み物の製造方法。 2. The noble metal wire according to claim 1, wherein the noble metal wire is a single wire of gold, silver, platinum, iridium, or palladium, or a combination thereof. Manufacturing method of knitting.
3 . 前記非金属繊維が水溶性繊維であり、 前記貴金属線と前記非金属繊維とを 沿わせたものを編んだ編み物を水で処理することにより、 前記非金属繊維を除去. する段階を更に含むことを特徴とする、 請求項 1又は請求項 2に記載の貴金属線 を用いた編み物の製造方法。 3. The non-metallic fiber is a water-soluble fiber, and the step of removing the non-metallic fiber by treating a knitted fabric obtained by knitting the precious metal wire and the non-metallic fiber along with water is further performed. A method for producing a knitted fabric using the noble metal wire according to claim 1 or 2, characterized by comprising:
4 . 貴金属の単線、 又は複数の貴金属の単線を沿わせた糸を編んだ貴金属線を: 用いた編み物。 4. Knitting using a noble metal wire or a noble metal wire made by knitting a thread along a single wire of noble metal or multiple noble metal wires.
5 . 1又は複数の貴金属の単線と非金属繊維とを沿わせて編んだ貴金属線を用 いた編み物。 5. Knitting using a noble metal wire woven with one or more single wires of noble metal and non-metallic fibers.
6 . 前記貴金属の単線が、 金、 銀、 プラチナ、 イリジウム、 又はパラジウムの 単線であることを特徴とする、 請求項 4又は請求項 5に記載の貴金属線を用いた 編み物。 6. The noble metal wire according to claim 4 or 5, wherein the single wire of the noble metal is a single wire of gold, silver, platinum, iridium, or palladium. knitting.
7 . 前記非金属繊維が水溶性繊維であることを特徴とする、 請求項 5に記載の 貴金属線を用いた編み物。 7. The knitted fabric using a noble metal wire according to claim 5, wherein the non-metallic fiber is a water-soluble fiber.
PCT/JP2001/008929 2000-10-13 2001-10-11 Knitted goods using noble metal wire WO2002033158A1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT201800005463A1 (en) * 2018-05-17 2019-11-17 PROCEDURE FOR MAKING PRECIOUS KNITTED FABRIC

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JP6211763B2 (en) * 2012-12-21 2017-10-11 株式会社ベスト Metal net manufacturing method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4985344A (en) * 1972-12-21 1974-08-15
JPH02216247A (en) * 1988-10-12 1990-08-29 Johnson Matthey Plc Metal fabric
JPH10259550A (en) * 1997-03-19 1998-09-29 Yoshihito Horio Production of knitted fabric using metallic wire

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4985344A (en) * 1972-12-21 1974-08-15
JPH02216247A (en) * 1988-10-12 1990-08-29 Johnson Matthey Plc Metal fabric
JPH10259550A (en) * 1997-03-19 1998-09-29 Yoshihito Horio Production of knitted fabric using metallic wire

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT201800005463A1 (en) * 2018-05-17 2019-11-17 PROCEDURE FOR MAKING PRECIOUS KNITTED FABRIC

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