WO2002032570A3 - Hydrodemetallation catalyst and method for making same - Google Patents

Hydrodemetallation catalyst and method for making same Download PDF

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Publication number
WO2002032570A3
WO2002032570A3 PCT/US2001/032432 US0132432W WO0232570A3 WO 2002032570 A3 WO2002032570 A3 WO 2002032570A3 US 0132432 W US0132432 W US 0132432W WO 0232570 A3 WO0232570 A3 WO 0232570A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
pores
making same
particles
total volume
Prior art date
Application number
PCT/US2001/032432
Other languages
French (fr)
Other versions
WO2002032570A2 (en
Inventor
Opinder Kishan Bhan
Original Assignee
Shell Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Oil Co filed Critical Shell Oil Co
Priority to AU2002215374A priority Critical patent/AU2002215374A1/en
Publication of WO2002032570A2 publication Critical patent/WO2002032570A2/en
Publication of WO2002032570A3 publication Critical patent/WO2002032570A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

A catalyst for hydrodemetallation of a heavy hydrocarbon stream comprising particles of alumina support having a bimodal pore size distribution and catalytically active amounts of metal from Group VIB distributed uniformly throughout and on the surface of the particles, wherein at least 20 % of the total volume of pores contained in said catalyst is in pores having a pore diameter of at least 1000 Å and wherein at least 50 % of the total volume of pores contained in said catalyst is in pores having a pore diameter of no greater than 350 Å. A method of making such catalyst and a process for removing metals from a heavy hydrocarbon stream using said catalyst.
PCT/US2001/032432 2000-10-19 2001-10-16 Hydrodemetallation catalyst and method for making same WO2002032570A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002215374A AU2002215374A1 (en) 2000-10-19 2001-10-16 Hydrodemetallation catalyst and method for making same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US69272600A 2000-10-19 2000-10-19
US09/692,726 2000-10-19

Publications (2)

Publication Number Publication Date
WO2002032570A2 WO2002032570A2 (en) 2002-04-25
WO2002032570A3 true WO2002032570A3 (en) 2002-08-29

Family

ID=24781759

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/032432 WO2002032570A2 (en) 2000-10-19 2001-10-16 Hydrodemetallation catalyst and method for making same

Country Status (3)

Country Link
AR (1) AR030905A1 (en)
AU (1) AU2002215374A1 (en)
WO (1) WO2002032570A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8764972B2 (en) 2003-12-19 2014-07-01 Shell Oil Company Systems, methods, and catalysts for producing a crude product

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6589908B1 (en) * 2000-11-28 2003-07-08 Shell Oil Company Method of making alumina having bimodal pore structure, and catalysts made therefrom
US7820036B2 (en) 2006-08-03 2010-10-26 Shell Oil Company Highly stable heavy hydrocarbon hydrodesulfurization catalyst and methods of making and use thereof
WO2008016971A2 (en) 2006-08-03 2008-02-07 Shell Oil Company A catalyst containing molybdenum and a group viii metal and its use for hydrodesulfrization hydrogen distillate
US7977274B2 (en) 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
MX2007009504A (en) * 2007-08-07 2009-02-06 Mexicano Inst Petrol Catalyst for the first stage of hydro demetallization in a hydro processing system with multiple reactors for the improvement of heavy and extra-heavy crudes.
US8114806B2 (en) 2008-04-10 2012-02-14 Shell Oil Company Catalysts having selected pore size distributions, method of making such catalysts, methods of producing a crude product, products obtained from such methods, and uses of products obtained
US8734634B2 (en) 2008-04-10 2014-05-27 Shell Oil Company Method for producing a crude product, method for preparing a diluted hydrocarbon composition, crude products, diluents and uses of such crude products and diluents
CA2736576C (en) 2008-09-10 2017-05-23 Haldor Topsoe A/S Hydroconversion process and catalyst
US10603656B2 (en) 2013-10-17 2020-03-31 Shell Oil Company Ultra-stable heavy hydrocarbon hydroprocessing catalyst and methods of making and use thereof
CN104549329B (en) * 2013-10-22 2016-08-17 中国石油化工股份有限公司 The preparation method of Hydrodemetalation catalyst
CN110773188A (en) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 Heavy oil hydrogenation deasphaltened catalyst and preparation and application thereof
CN110773209A (en) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 Heavy oil hydrogenation deasphaltened catalyst and preparation and application thereof
CN110773179A (en) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 Alumina carrier and preparation method thereof
CN110773183A (en) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 Heavy oil hydrogenation deasphaltened catalyst and preparation and application thereof
CN110773187A (en) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 Heavy oil hydrogenation deasphaltened catalyst and preparation and application thereof
CN110773190A (en) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 Heavy oil hydrogenation deasphaltened catalyst and preparation and application thereof
CN112547079A (en) * 2019-09-25 2021-03-26 中国石油化工股份有限公司 Heavy oil hydrotreating catalyst and application thereof
CN116020498A (en) * 2021-10-27 2023-04-28 中国石油化工股份有限公司 Preparation method of hydrogenation catalyst, catalyst prepared by method and application

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4294685A (en) * 1979-03-13 1981-10-13 Electric Power Research Institute, Inc. Process for coal liquefaction and catalyst
US4526675A (en) * 1983-05-26 1985-07-02 Standard Oil Company (Indiana) Hydrocarbon conversion method
US4846961A (en) * 1986-12-05 1989-07-11 Union Oil Company Of California Hydroprocessing catalyst with a Ni-P-Mo
US4880525A (en) * 1987-09-24 1989-11-14 Shell Oil Company Process for hydrotreating hydrocarbon feeds
EP0583837A1 (en) * 1992-08-18 1994-02-23 Shell Internationale Researchmaatschappij B.V. Process for the preparation of a catalyst for a catalyst precursor

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4294685A (en) * 1979-03-13 1981-10-13 Electric Power Research Institute, Inc. Process for coal liquefaction and catalyst
US4526675A (en) * 1983-05-26 1985-07-02 Standard Oil Company (Indiana) Hydrocarbon conversion method
US4846961A (en) * 1986-12-05 1989-07-11 Union Oil Company Of California Hydroprocessing catalyst with a Ni-P-Mo
US4880525A (en) * 1987-09-24 1989-11-14 Shell Oil Company Process for hydrotreating hydrocarbon feeds
EP0583837A1 (en) * 1992-08-18 1994-02-23 Shell Internationale Researchmaatschappij B.V. Process for the preparation of a catalyst for a catalyst precursor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8764972B2 (en) 2003-12-19 2014-07-01 Shell Oil Company Systems, methods, and catalysts for producing a crude product

Also Published As

Publication number Publication date
AR030905A1 (en) 2003-09-03
WO2002032570A2 (en) 2002-04-25
AU2002215374A1 (en) 2002-04-29

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