WO2001041728A1 - Fragrance or flavor formulation - Google Patents
Fragrance or flavor formulation Download PDFInfo
- Publication number
- WO2001041728A1 WO2001041728A1 PCT/EP2000/012239 EP0012239W WO0141728A1 WO 2001041728 A1 WO2001041728 A1 WO 2001041728A1 EP 0012239 W EP0012239 W EP 0012239W WO 0141728 A1 WO0141728 A1 WO 0141728A1
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- WO
- WIPO (PCT)
- Prior art keywords
- fragrance
- flavor
- formulation according
- composition
- flavor formulation
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
Definitions
- the inventions concerns a stable, aqueous, ethanol-free fragrance or flavor formulation, a vessel equipped with a valve for spraying said formulation, and a method of producing said formulation and vessel.
- Said formulation and vessel are used for the manufacture of a perfume, deodorant, cosmetic, aromatherapeutic, spagyric essence, wound, water or room disinfectant, insecticide, insect or marten repellent, food seasoning and the like.
- fragrance and flavor formulations are known and widely used in the art of cosmetics, deodorants, room aromatizing, aromatherapy, insect or marten repellents, or food flavoring or seasoning, and the like.
- These formulations contain lipophilic compounds, such as essential oils or other lipophilic, water insoluble fragrant or flavor ingredients.
- Fragrance or perfume compositions in deodorants, disinfectants, insect or marten repellents, in room sprays, mouth and nose sprays, in aroma-therapy, and spagyric compositions are wellknown in the art.
- Representative publications include "The Illustrated Encyclopedia of Essential Oils, The Complete Guide to the Use of Oils in Aromatherapy and Herbalism", by Julia Lawless, Klement Hooks, Shaftesbury, Dorset, GB 1995 (German issue “Die illustrêt Enzyklopadie der Aromaole", Scherz Verlag, Bern etc.
- solubilisers or emulsifiers are added.
- surfactants water soluble solvents and/or surface active compounds
- Most commoi. as solvent or solubiliser is a high percentage of a lower alcohol, in particular ethanol, or also isopropanol or glycerine, which are usually used in combination with a surfactant.
- Some room deodorising or disinfecting formulations contain enzymes which help to oxidise and/or split bad smelling compounds. Such enzymes are expensive and quite often not very stable.
- Single phase, homogeneous aqueous formulations in particular need an alcohol, in particular ethanol, or another solubiliser, e.g. acetone, in order to maintain a clear solution or at least a homogeneous emulsion of the lipophilic fragrance or flavor composition comprised by the formulation.
- Alcohol or acetone containing fragrance formulations impose considerable risks during their production, storage, transportation and use as they are easily inflammable, in particular if sprayed in form of an aerosol and if in contact with a hot material, e. g. a hot cocking-plate, a hot engine, e. g. a hot automobile motor, smoulder cigarette or burning candle.
- fragrance and flavor compositions such as essential oils, have a high vapour pressure and are by themselves inflammable.
- a disadvantage of the most commonly used ethanol in fragrance formulations for animal or human use is that it may irritate sensitive skin and cause a painful reaction.
- the use of ethanol in the aerosol furthermore has the other disadvantage in that it may anaesthetise the olfactory nerves.
- the loss of fragrance intensity may only be counteracted by a higher concentration of the fragrant ingredients. This comprises economic consequences.
- Alcohol also increases the addictive potential, which is to be avoided in particular in hospitals, schools, kindergartens and in food flavoring.
- addition of one or more surfactants is common in the art.
- surfactants are mainly selected from those also used and acceptable in pharmaceutical and cosmetical formulations and include for example those of the polyethyleneglykol type.
- An alcohol-free aerosol formulation is described in US 5,508,023.
- the formulation comprises less than 5% by weight of micronized drug, less than 5 % by weight of at least one polar surfactant, and 90 % by weight of 1,1,1,2-tetrafluoroethane or 1,1,1,2,3,3,3- heptafluoropropane.
- the fluoroethane or -propane is used as solvent and propellant.
- This formulation is quite expensive, ecologically unsatisfactory and does not contain water.
- WO 94/07461 are disclosed non-sticky, non-ethanolic fragrance formulations containing conventional odoriferous material at a level of about 2%, preferably 5% to about 30%, which is solubilised by a combination of (a) a solubiliser and (b) a cosolubiliser in water.
- USP 5,736,505 discloses the use of glycereth-7-triacetate for the production of a non- alcoholic transparent fragrant composition comprising a hydrophobic perfume base, a non- ionic surfactant and water.
- WO 96/07395 discloses a clear, thickened, fragrant topical skin care composition utilising a polymeric gelling agent.
- WO 96/03963 discloses an aqueous, perfumed cosmetic composition which is essentially free of short-chain, mono-hydric alcohol comprising (a) a first non-ionic surfactant of the formula R 1 -(OCH(CH 3 )CH2) m - (OCH 2 CH 2 ) n -OH, wherein Ri is an alkyl group of from about 10 to about 22 carbon atoms and m and n represent weight-averages in the range from about 2 to about 80., and (b) an auxiliary nonionic surfactant comprising one or more polyethoxylated nonionic surfactants of hydrophile-lipophile balance from about 10 to about 16.
- fragrance formulations have not yet found a simple solution for avoiding alcohol in stable aqueous formulations. In contrast, there exists still the conviction that alcohol can only be avoided in combination with more than one other ingredient. Ethanol- free deodorants are known which are not stable but need to be shaken before use. Stable, aqueous, ethanol-free, non-sticky, easily sprayable fragrance or flavor formulations, such as aerosol formulations, comprising lipophilic fragrance or flavor combinations in form of homogeneous solutions or emulsions and free of alcohol have not become known. Objective of the Invention
- the new fragrance formulation should be alcohol-free, in particular ethanol-free, enzyme-free, physically and chemically stable, i. e. homogeneous and not separating into two or more layers under normal, higher or lower temperatures. It should be easily sprayable.
- the aerosol produced by this formulation upon spraying should not be inflammable, should be non-toxic, non-sticky and cosmetically and pharmaceutically acceptable to the skin and sensitive organs, should not have addictive properties and should need a lower amount of the expensive fragrant or flavor ingredients.
- the flavor formulation should be orally acceptable for being used in food flavoring.
- the invention concerns a stable aqueous fragrance or flavor formulation, characterised in that it comprises a fragrance or flavor composition, water and a surfactant, said formulation being alcohol-free.
- fragrance and flavor overlap in certain respects.
- Some ingredients of fragrance formulations are also present in flavor formulations.
- the essential oils of fruits such as lemons, oranges, or of spices, such as rosemary, marjoram, and the like, widely used in food flavoring, are also present or used in natural or synthetic fragrances. Their water and alcohol solubilities are about similar and for the purpose of this invention comparable.
- the fragrance or flavor composition comprised by the present formulation is any fragrance or flavor composition new or known in the art, such as a fragrant perfume, an aroma- therapeutic, an air hygienic agent, an insect or marten repellent, a food flavoring agent and the like.
- Such compositions are composed in particular of natural or also of synthetic fragrant or flavor compounds. They are usually of lipophilic nature.
- the term comprises essential oils, fragrant or aromatic smelling alcohols, esters, ethers, aldehydes, and/or acetals common in the art of perfume or food flavoring compositions or spagyric compositions.
- the fragrant ingredient may be a naturally occurring essential oil, such as rose oil, bergamot oil, jasmine oil, peppermint oil, rosemary, camomile, lavender, marjoram, and the like oil.
- An animal fragrant is for example musk, castoreum, amber or zibet.
- Spagyric essences are also known in the art. They are made by fermenting certain herbs, which were collected while they were flowering, in the presence of water and yeast, steam distilling off the active ingredients, and concentrating the distillate to the spagyric basic essence. The remaining mash is calcinated, and the basic essence and the calcinated mash are combined to give the final spagyric essence.
- Synthetic fragrant ingredients are for example synthetic essential oils, such as composed of single compounds, such as linalol, cineol, terpineol, nerol, citronelal, benzaldehyde, cinnamon aldehyde, vanillin, methylacetophenone, and the like. Comprised are also mixtures of such ingredients.
- the fragrance or flavor formulation may have, in addition to the desired pleasant smell, disinfectant activities, such as desirable in room sprays for hospitals, kitchens and toilettes, in water or also in mouth or nose sprays.
- the disinfectant effect may be directed against any microorganisms, such as virus, bacteria or yeasts.
- Disinfectant fragrance and flavor formulation comprise in particular a synergistic mixture of disinfectant essential oils, in particular of natural sources, such as of eucalyptus
- the fragrance formulation may have a therapeutic effect as known in aromatherapy.
- Well known are stimulating, antidepressive or narcotic effects of certain fragrance compositions.
- it comprises one or more essential oils, in particular of natural origin and having the desired therapeutic effect.
- a therapeutic effect may also be provided by spagyric essences, which are mostly also of fragrant nature.
- Such fragrance formulations may be applied in form of room, mouth or nose sprays.
- the fragrance formulation may also have an insect or marten repellent effect or be useful in plant protection.
- the flavor formulation of the invention is orally acceptable, easily sprayable and can be dosed simply. It can be used for flavoring any food.
- food flavors are extracts of herbs, such as thyme, oregano, marjoram, salvia, sage, rosemary, garlic, lovage, horseradish, coffee or tea aroma, or any fruit aroma, such as lemon, orange or grapefruit oil, apple, pear or raspberry aroma, and the like.
- the flavor may be destroyed, whereupon the present flavor formulation is applied for refreshing or improving the taste.
- the food e.g. a cooked, broiled, baked, fried or grilled food, also salads or after dinner dishes, may be sprayed shortly before serving.
- the fragrant or flavor composition is present in amounts of less than about 20%, preferably of less than about 15% by weight or volume. In general, a sufficient or even excellent fragrant or flavor smell is surprisingly obtained with a relatively low amount, e. g. about 0.01 to about 3% of the fragrant or flavor composition. This amount is lower than in common fragrance or flavor formulations, however provides a similar or even stronger fragrance or flavor intensity.
- the surfactant used in the present fragrance formulation is one known in the art and is cosmetically and/or pharmaceutically acceptable. Preferably it is selected from the group consisting of one or more polyoxyethylene sorbitan fatty acid esters, mono- polyoxyethylene alkyl ethers and mono-polyoxyethylene alkanoic acid esters.
- Polyoxyethylene sorbitan fatty acid esters are for example selected from the group of water-soluble or -dispersible Tweens, such as polyoxyethylene sorbitan mono-laurate (Tween 20), polyoxyethylene sorbitan mono-stearate (Tween 60) or polyoxyethylene sorbitan mono-oblate (Tween 80).
- Tween 20 polyoxyethylene sorbitan mono-laurate
- Tween 60 polyoxyethylene sorbitan mono-stearate
- Tween 80 polyoxyethylene sorbitan mono-oblate
- a preferred group of surfactants is represented by the general formula
- R is an alkyl group of the partial formula CH (CH 2 ) m - or an acyl group of the partial formula CH 3 (CH 2 ) m- ⁇ -CO-, wherein m is of from 9 to 19 and n is from 1 to 99.
- R is an alkyl group n is preferably 1 to 24. If R is an acyl group n is preferably 29 to 99.
- the index m is preferably 9, 11, 13, 15, 17, or 19.
- the index n is preferably 1, 3, 9, 17, 19, 21, 29, 39, 39, 49 or 99. Higher values of n may be only proximate or average values.
- Preferred are commercially available ethers of the formula I, e. g. known under the proprietary names AKYPOROXTM RLM 22, RLM 40, RLM 80, CO 400, BrijTM 30, 35, 52,
- CETOMACROGOLTM 1000 CETOMACROGOLTM 1000
- EMULGINTM 700 or 1000 esters of the formula I, e. g. MYRJ 45, 49, 51, 52, 52 C, 53, or 59.
- Particularly preferred surfactants of the formula I are tetrapolyoxyethylene monododecyl (lauryl) ether, tetrapolyoxyethylene monotetradecyl (myristyl) ether and mixtures thereof, such as present in the ether from tetrapolyoxyethylene and coconut alcohol, e. g. AKYPOROXTM RLM 40.
- the surfactant is present in the fragrance or flavor formulation in an amount sufficient to provide a stable, homogeneous, monophasic aqueous solution or emulsion.
- the amount depends mainly on the amount and lipophilic nature of the fragrance or flavor composition in the formulation.
- the ratio of fragrance or flavor composition to surfactant is from about 1:0.01 to about 1:5 either by weight or by volume. Whenever in the present description ratios or percentages are given they are either by weight or by volume if not specifically defined.
- the amount of fragrance or flavor composition is about 1%, the amount of surfactant is about 0.5%. In general, less than from about 3% to about 10% of surfactant is sufficient to provide a homogeneous stable formulation.
- the water in the aerosol formulation may be normal tap water, or distilled or deionised water, preferably with a pH of about 7. It may be necessary to adjust the entire aerosol formulation to a pH around 7.
- Such fragrance or flavor formulation comprises e. g. 3% of fragrant or flavor composition, 3% of surfactant and 94% of water, or 1% of fragrant or flavor composition, 0.5% of surfactant and 98.5% of water. It may also comprise, e. g. about 3%, of an emulsifying mixture, consisting of about 75% of castor oil, about 12.5% of glycerin, 12.5% of propylene glycol.
- the present fragrance or flavor formulations lack any large amounts of easily inflammable ingredients, such as ethyl alcohol, isopropanol, acetone, ethers, lower carbon hydrogens and the like, which are usually present in common aerosol sprays.
- fragrance or flavor compositions in particular the essential oils
- the fragrance or flavor compositions are easily inflammable by themselves, they are surprisingly not inflammable in the present aqueous formulations. This may be so in view of the low concentration and the presence of comparative large amounts of water.
- the present fragrance formulation is enzyme-free, thus limiting the risk of allergic reactions and enzymatic destruction of the organic ingredients in the formulation.
- the invention concerns further a fragrance or flavor formulation, as described hereinbefore inserted together with a propellant in a spray vessel equipped with a valve.
- the present fragrance formulation is preferably sprayable by forcing through a tiny outlet under applying sufficient pressure.
- the formulation devices able to perform this task are well known in the art and comprise closed vessels which can be set under pressure by a propellant and to which a valve with a fine outlet is attached which upon operating releases a pre-selectable amount of the composition in form of an aerosol.
- the invention concerns further a vessel equipped with a dosage valve, characterised in that it comprises a stable aqueous fragrance or flavor formulation as described hereinbefore and a propellant.
- the valve is not metered or preferably a metered dose provider, standardised to eject by each push a specific amount, e.g. from 0.1 to 0.5 cm of the fragrance formulation.
- the vessel is equipped with a valve, which is standardised to eject in a pre-selected time a standardised amount of aerosol.
- the propellant is not inflammable and is selected from one common in the art, e. g. from the group consisting of a fluorinated hydrocarbon, such as 1,1,1,2,3,3,3-heptafluoropropane
- the vessel is made of a non-corrosive metal, such as tin, a metal being protected against corrosion by a hard and insoluble organic polymer, or is made of glass or a hard and insoluble polymer.
- the invention concerns further a method for producing a fragrance or flavor formulation according to the invention, characterised in homogeneously mixing the fragrant or flavor composition, the surfactant and the water. Homogeneously mixing is achieved by vigorously shaking, stirring, vibrating or sonicating the mixture with a common mixing device at a temperature of between about between 10° C and 50° C, e.g. at room temperature.
- the mixing time depends mainly on the amount of the ingredients. Small amounts, e. g. to provide about 10 to about 500 ml of fragrance formulation, are homogeneously mixed within about one minute or less.
- the fragrance and flavor composition and the surfactant are at first homogeneously mixed to give a more or less sticky fluid, whereupon the water is added, e. g. slowly or by drops.
- the invention is further directed to the use of the stable, aqueous, alcohol free fragrance or flavor formulation for the manufacture of a perfume, a deodorant, such as a room deodorant, an arm spray (deos), a cosmetic preparation, an aromatherapeutic, a spagyric essence, a wound, water or room disinfectant, insecticide, insect or marten repellent, and the like.
- a deodorant such as a room deodorant, an arm spray (deos)
- a cosmetic preparation such as a a cosmetic preparation
- an aromatherapeutic such as a room deodorant, an arm spray (deos)
- a cosmetic preparation such as a wound, water or room disinfectant, insecticide, insect or marten repellent, and the like.
- the aqueous ethanol free fragrance formulations of the invention can further be used to aromatise paper, such as news papers, printing papers, or other natural or synthetic carriers, such as fleeces, fiber glass, clothing, shoes, and the like.
- aromatise paper such as news papers, printing papers, or other natural or synthetic carriers, such as fleeces, fiber glass, clothing, shoes, and the like.
- the aqueous ethanol free flavor formulation can be used to aromatise and improve the smell of kitchens, restaurants, and food stuff.
- the fragrance or flavor composition and the surfactant are homogeneously mixed by shaking or stirring. About 1 to 2% of the water is added and again stirred to give a homogeneous sticky fluid. The rest of the water is added and stirring continued until a homogeneous solution or emulsion is obtained.
- the solution or emulsion may be filled into a bottle with a normal or safety stopper cap.
- the bottle may be equipped with a standardized metered valve allowing aerosol release of 0.1 cm 3 upon one push.
- the propellant is for example air.
- the solution or emulsion may also be filled into a pressure bottle equipped with a valve which may be standardized and metered.
- the propellant one common in the art, usually 1,1,1,2,-tetrafluoroethane, is added and the bottle sealed.
- the valve may be metered in that it allows an aerosol release of 0.086 cm 3 upon each push.
- the bottles may have a capacity of about 5 to 500 cm 3 .
- Example 2 A fragrance formulation for a room deodorant
- a mixture of 3 ml of a fragrance composition consisting of the following essential oils
- the emulsion is filled into a pressure bottle equipped with a standardized valve allowing aerosol release of 0.086 cm upon one push.
- the emulsion is stable within a temperature range of at least -5° C to 50° C over a time of at least 12 months.
- Example 3 A fragrance formulation for a room deodorant
- the emulsion is filled into a pressure can equipped with a standardised valve allowing aerosol release of 0.086 cm upon one push.
- the emulsion is stable within a temperature range of at least -5° C to 50° C over a time of at least 12 months.
- fragrance or flavor composition 50 ml of AKYPOROX TM RLM40
- the solution or emulsion may be filled into a bottle with a normal or safety stopper cap.
- the bottle may be equipped with a standardised metered valve allowing aerosol release of 0.1 cm upon one push.
- the propellant is for example air.
- the solution or emulsion may also be filled into a pressure bottle equipped with a valve which may be standardised and metered.
- the propellant one common in the art, usually 1,1,1,2,-tetrafluoroethane, is added and the bottle sealed.
- the valve may be metered in that it allows an aerosol release of 0.086 cm upon each push.
- the bottles may have a capacity of about 5 to 500 cm .
- Example 5 A fragrance formulation with synergistic disinfectant properties
- the disinfecting fragrance composition is composed of
- the emulsion is produced according to the general procedure of Example 4. It may be filled into a pressure can equipped with a standardised valve allowing aerosol release of
- The- emulsion is stable within a temperature range of at least -5° C to 50° C over a time of at least 12 months.
- Example 6 A fragrance formulation with synergistic disinfectant properties
- the disinfecting fragrance composition is composed of 25 ml of eucalyptus oil (Eucalyptus globulus), 25 ml of peppermint oil (Mentha piperita), 30 ml of pine needle oil (Picca excelsa),
- This mixture (90 ml) is admixed to 10 ml of a mixture consisting of
- Example 4 50 ml of bay leave oil (Laurus nobilis) and 50 ml of Ho-leaf oil (Cinnamomum camphora hosch) to give the fragrance formulation with synergistic disinfectant properties, wherefrom the emulsion is produced according to the general procedure of Example 4. It may be filled into a pressure can equipped with a standardised valve allowing aerosol release of 0.086 cm 3 upon one push.
- Example 7 A fragrance formulation with synergistic disinfectant properties
- the fragrance composition is produced as follows:
- compositions composed of 50 ml of litsea oil (Litsea cubeba) 10 ml of citronella oil (Cymbopogon nardus), 10 ml of elemi oil (Canarium luzonicum), 10 ml of lemon oil (Citrus limonum), and 20 ml of grapefruit (citrus paradisi),
- compositions (b) composed of 40 ml of lemon oil (Citrus limonum), 40 ml of fir tree oil (Abies alba pectinata), 10 ml of pine needle oil (Picca excelsa), and 10 ml of lavender oil (Lavandula officinalis),
- composition (c) composed of 60 ml of lemon oil (Citrus limonum), 30 ml of peppermint oil ( Mentha piperita),
- the emulsion may be produced according to the general procedure of Example 4.
- the emulsion may be used as such or in form of a room spray and be filled into a pressure can equipped with a standardised valve allowing aerosol release of 0.086 cm 3 upon one push.
- Example 8 A clear, ethanol-free flavor formulation containing 12 % of a perfume composition
- the emulsifying mixture consists of 5 ml of AKYPOROX TM RLM40, 5 ml of castor oil,
- the coco-nut oil is warmed up until it is fluid, the other ingredients are added and thoroughly mixed.
- fragrance or flavor composition e. g. of any of the previous Examples or “Lenny Jose” of Givaudan AG, ; and 2 parts of the above emulsifying mixture are mixed. Seven parts of water are added and the mixture is shaken to give a clear and ethanol-free perfume composition Example 9.
- the fragrance composition consists of 50 ml of litsea oil ( Litsea cubeba),
- the essential oils are admixed and may be used us such for disinfecting toilets and lavatories.
- Bactericidal Test Results In the laboratory two 10 x 10 cm disinfected glass plates are sprayed with cultures of bacteries predominantly present in public toilets (general appearing germs, coliform germs, E. coli). On one of the plates is sprayed with a spray dose of Example 9 fom a distance of 20 cm an aerosol stream for about 0.5 seconds. After 5 minutes the assembling by swap test was performed. One plate not treated with the spray was used as a reference in the bacteriological test.
- test conditions were as follows:
- Example 9 has a bactericidal activity which is not caused by bactericidal, fungicidal or other synthetic preserving compounds.
- the bactericidal activity is based on the natural essential oils.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Fats And Perfumes (AREA)
- Cosmetics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU23627/01A AU2362701A (en) | 1999-12-06 | 2000-12-04 | Fragrance or flavor formulation |
EP00987352A EP1237533A1 (en) | 1999-12-06 | 2000-12-04 | Fragrance or flavor formulation |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP99811117A EP1106171A1 (en) | 1999-12-06 | 1999-12-06 | Fragant formulations |
EP99811117.3 | 1999-12-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001041728A1 true WO2001041728A1 (en) | 2001-06-14 |
Family
ID=8243174
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2000/012239 WO2001041728A1 (en) | 1999-12-06 | 2000-12-04 | Fragrance or flavor formulation |
Country Status (3)
Country | Link |
---|---|
EP (2) | EP1106171A1 (en) |
AU (1) | AU2362701A (en) |
WO (1) | WO2001041728A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20030021699A (en) * | 2001-09-07 | 2003-03-15 | 주식회사 카이아로마테라피 | A composite of aroma therapy made of Peppermint and Camomile roman |
US7344707B2 (en) | 2002-05-15 | 2008-03-18 | The Procter & Gamble Company | Low combustion aerosol products in plastic packages having a reduced fire hazard classification that subsequently reduces storage costs |
DE202011104143U1 (en) | 2011-08-06 | 2011-12-08 | Constanze Winkler | Natural stanchion device against marten |
WO2013069890A1 (en) * | 2011-11-09 | 2013-05-16 | Woongjin Coway Co., Ltd | Natural antimicrobials and article comprising the same |
AT522393A1 (en) * | 2019-04-01 | 2020-10-15 | Hannes Scherer | Composition for scaring off wildlife |
CN114225086A (en) * | 2021-12-29 | 2022-03-25 | 安徽全民环保科技有限公司 | Natural plant type deodorizing and insect expelling preparation and preparation method thereof |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6783027B2 (en) * | 2002-05-15 | 2004-08-31 | The Procter & Gamble Company | Metered-dose underarm product and package |
FR2927006A1 (en) * | 2008-02-04 | 2009-08-07 | Osmooze Sa | LIQUID SUPPLY METHOD OF A NEBULIZATION DEVICE |
PL238164B1 (en) * | 2018-06-27 | 2021-07-12 | Finea Spolka Z Ograniczona Odpowiedzialnoscia | Alcohol-free perfume and method of producing alcohol-free perfume |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3968905A (en) * | 1975-08-07 | 1976-07-13 | Continental Can Company, Inc. | Time release aerosol dispenser |
WO1994007461A1 (en) * | 1992-09-29 | 1994-04-14 | Givaudan-Roure (International) S.A. | Perfume compositions |
WO1996003963A1 (en) * | 1994-07-30 | 1996-02-15 | The Procter & Gamble Company | Aqueous compositions |
WO1996007395A1 (en) * | 1994-09-07 | 1996-03-14 | The Procter & Gamble Company | Clear, thickened topical skin care composition with water-insoluble perfume |
WO1996008425A2 (en) * | 1994-09-12 | 1996-03-21 | The Dial Corp | Air treatment device and method of using same |
WO1996028980A1 (en) * | 1995-03-20 | 1996-09-26 | The Procter & Gamble Company | Flavored cooking oil having reduced room aroma |
WO1997029790A1 (en) * | 1996-02-19 | 1997-08-21 | Marcel Jean | Air freshener aerosol can using a liquefied propellant |
US5736505A (en) * | 1996-08-30 | 1998-04-07 | Dragoco, Inc. | Non-alcoholic perfume or cologne |
WO1999027793A2 (en) * | 1997-11-28 | 1999-06-10 | Barrier Biotech Limited | An antimicrobial composition |
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1999
- 1999-12-06 EP EP99811117A patent/EP1106171A1/en not_active Withdrawn
-
2000
- 2000-12-04 WO PCT/EP2000/012239 patent/WO2001041728A1/en not_active Application Discontinuation
- 2000-12-04 EP EP00987352A patent/EP1237533A1/en not_active Withdrawn
- 2000-12-04 AU AU23627/01A patent/AU2362701A/en not_active Abandoned
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3968905A (en) * | 1975-08-07 | 1976-07-13 | Continental Can Company, Inc. | Time release aerosol dispenser |
WO1994007461A1 (en) * | 1992-09-29 | 1994-04-14 | Givaudan-Roure (International) S.A. | Perfume compositions |
WO1996003963A1 (en) * | 1994-07-30 | 1996-02-15 | The Procter & Gamble Company | Aqueous compositions |
WO1996007395A1 (en) * | 1994-09-07 | 1996-03-14 | The Procter & Gamble Company | Clear, thickened topical skin care composition with water-insoluble perfume |
WO1996008425A2 (en) * | 1994-09-12 | 1996-03-21 | The Dial Corp | Air treatment device and method of using same |
WO1996028980A1 (en) * | 1995-03-20 | 1996-09-26 | The Procter & Gamble Company | Flavored cooking oil having reduced room aroma |
WO1997029790A1 (en) * | 1996-02-19 | 1997-08-21 | Marcel Jean | Air freshener aerosol can using a liquefied propellant |
US5736505A (en) * | 1996-08-30 | 1998-04-07 | Dragoco, Inc. | Non-alcoholic perfume or cologne |
WO1999027793A2 (en) * | 1997-11-28 | 1999-06-10 | Barrier Biotech Limited | An antimicrobial composition |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20030021699A (en) * | 2001-09-07 | 2003-03-15 | 주식회사 카이아로마테라피 | A composite of aroma therapy made of Peppermint and Camomile roman |
US7344707B2 (en) | 2002-05-15 | 2008-03-18 | The Procter & Gamble Company | Low combustion aerosol products in plastic packages having a reduced fire hazard classification that subsequently reduces storage costs |
DE202011104143U1 (en) | 2011-08-06 | 2011-12-08 | Constanze Winkler | Natural stanchion device against marten |
WO2013069890A1 (en) * | 2011-11-09 | 2013-05-16 | Woongjin Coway Co., Ltd | Natural antimicrobials and article comprising the same |
US9968100B2 (en) | 2011-11-09 | 2018-05-15 | Coway Co., Ltd | Natural antimicrobials and article comprising the same |
AT522393A1 (en) * | 2019-04-01 | 2020-10-15 | Hannes Scherer | Composition for scaring off wildlife |
CN114225086A (en) * | 2021-12-29 | 2022-03-25 | 安徽全民环保科技有限公司 | Natural plant type deodorizing and insect expelling preparation and preparation method thereof |
CN114225086B (en) * | 2021-12-29 | 2024-02-02 | 安徽全民环保科技有限公司 | Natural plant type deodorizing and insect-repellent preparation and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
EP1106171A1 (en) | 2001-06-13 |
EP1237533A1 (en) | 2002-09-11 |
AU2362701A (en) | 2001-06-18 |
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