WO2001025863A1 - Computer method and apparatus for determining state of physical properties in a chemical process - Google Patents
Computer method and apparatus for determining state of physical properties in a chemical process Download PDFInfo
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- WO2001025863A1 WO2001025863A1 PCT/US2000/027243 US0027243W WO0125863A1 WO 2001025863 A1 WO2001025863 A1 WO 2001025863A1 US 0027243 W US0027243 W US 0027243W WO 0125863 A1 WO0125863 A1 WO 0125863A1
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- physical properties
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- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
- G05B17/00—Systems involving the use of models or simulators of said systems
- G05B17/02—Systems involving the use of models or simulators of said systems electric
Definitions
- Chemical processing plants are designed to carry out various complex, often non-linear, chemical processes, such as a polymer process.
- the processing plant design typically involves a series of various pieces of equipment, e.g., stirring tanks, evaporators, reactors, pumps, feed conduits and the like, and a control system for monitoring and maintaining settings of the various pieces of equipment to effect needed operating conditions (e.g., volume, flow rate, stirring rate, temperature, pressure, feed composition, etc.).
- the resulting product is analyzed in a laboratory for quality outcome.
- Product quality is commonly measured in terms of physical properties (or polymer properties), e.g., melt index, density, etc. Thus it is desired that these properties achieve certain values or value ranges, such that the product is termed "on spec".
- Polymer properties are complex, non-linear functions of polymer process plant operating conditions (process variables).
- process variables There are two methods of developing estimates of polymer properties such as melt index (MI) and density typically used for describing polymer product quality.
- the first method is a regression based inferential that uses neural networks, partial least squares (PLS), and other conventional regression methods.
- the second method employs State Estimation Models (SEM) which use an auto-calibrated (self-adjusting), non-linear, online rigorous dynamic model.
- SEM State Estimation Models
- State Estimation Models provide a mass and energy balance model of the entire plant and thus involves heat and mass balance equations, polymer thermodynamics and kinetics.
- the first method being a regression is only valid in the area where polymer property data has been collected in related areas of operation. Its advantage is that it is easy to use by plant engineers and is relatively inexpensive.
- One example implemented as a software tool is Aspen IQTM by Aspen Technology, Inc. of Cambridge, Massachusetts.
- the second method is rigorous which means that it can extend its predictions beyond the range of data available.
- the advantage provided is that when new polymer products are made, for which there is no data, the probability of the model predicting correctly is higher for the rigorous method than for the regressed method.
- the disadvantage with the rigorous method is that it is difficult to implement and maintain with all its mass and energy balance equations, polymer thermodynamics and kinetics.
- the non-linearity of polymer processes arises from several sources. First is the non-linearity introduced by the nature of the kinetic relationships governing polymerization and gas concentrations. Second is the non-linearity introduced by changing residence time caused by changing density of the polymer in the reactor. Third is the non-linearity introduced by changing inventory in the reactor. Finally, the non-linearity introduced by changing production rates is another source of the non-linearity of polymer processes.
- Polymers Plus is a polymer process modeling system manufactured by Aspen Technology, Inc. of Cambridge, Massachusetts, assignee of the present invention. Together with Aspen Plus, Polymers Plus performs steady state polymer process calculations. Used in conjunction with an interface for online modeling (e.g. Aspen OnlineTM by Aspen Technology, Inc.), Polymers Plus enables the calculation of various steady state process performance parameters such as approach to dewpoint, superficial gas velocity, bed density and production rate, among others.
- the combination of Polymers Plus and Aspen Online is a software package called Polymers Plus Online by Aspen Technology, Inc. Polymers Plus Online is completely based on rigorous chemical engineering models.
- Polymers Plus handles the issue of non-linearities around kinetics and compositions. This handles the non-linearities associated with steady state behavior.
- the dynamic non-linearities are governed by the process geometry. Once that characteristic is identified it does not change but is merely scaled by changing residence time. Most polymer processes will exhibit some kind of low order transfer function behavior plus time delay. As the residence time changes, the time constant and delay change. Since all the factors that affect residence time are calculated by Polymers Plus Online, this scaling factor is able to be calculated at all times.
- the preferred embodiment of the present invention expands on Polymers Plus Online to compute inferential estimates of polymer properties such as melt index and density. It provides a first principles inferential quality estimator that is based on the general purpose, proven, rigorous, easy to configure steady state polymer process simulator Polymers Plus.
- the steady state Polymers Plus model estimates the properties of the instantaneous polymers generated at any given time.
- Aspen IQ provides the filter that integrates the changes in melt index, density and other properties for the accumulated polymers over time.
- the integrator time constant is updated each time based on the calculation of instantaneous residence time by Polymers Plus.
- the estimates of the polymer properties, such as melt index and density then become a dynamic calculation based on a rigorous steady state model.
- the present invention provides a method and apparatus for determining physical properties of a physical (chemical/polymer) process which addresses the problems of the prior art.
- the present invention provides computer apparatus for determining state of chemical/polymer properties of a chemical/polymer process.
- the apparatus includes steady state modeling means for rigorously modeling the chemical/polymer process at steady state. Included in the rigorous steady state model are values for physical (e.g., polymer) properties of the chemical/polymer process at steady state.
- the inferential model means receives the values of the physical (polymer) properties at steady state from the steady state modeling means and therefrom determines state of the physical properties over a period of time.
- the physical (polymer) properties include melt index, density, tacticity, molecular weight distribution, xylene solubles, co-polymer composition and production weight.
- the steady state modeling means computes values of the physical (polymer) properties at steady state in terms of molecular weight distribution, and the inferential model means correlates melt index, density and other physical properties with molecular weight distribution.
- the steady state modeling means further calculates an instantaneous residence time of a reactor.
- the inferential model means calculates cumulative values for the physical properties by mixing the values for the physical properties at steady state with previously calculated cumulative values of the physical properties over the residence time as last calculated by the steady state modeling means.
- the inferential modeling means utilizes a first order dynamics of mixing analysis, with most recent values of the physical (polymer) properties at steady state provided by the steady state modeling means, to calculate cumulative values of the physical (polymer) properties.
- the inferential model means may receive as input off line (laboratory) measured values of the physical (polymer) properties and adjust the determined state of the physical (polymer) properties based on the received off line measured values.
- the computer apparatus may be coupled to a process control subsystem.
- the inferential model means calculates and outputs values of parameters of the subject process, for maintaining the physical (polymer) properties at a user specified state (e.g., on spec).
- the process control subsystem receives from the inferential model means the output parameter values and controls the subject process according to the parameter values.
- the process control subsystem may include sensors for measuring physical conditions of the subject process, such as temperature, pressure, volume, feed composition and the like.
- the inferential model means in the preferred embodiment updates the sensor measurements.
- Fig. 1 is a schematic of a computer implementation of the present invention.
- Fig. 2 is a block diagram of the preferred embodiment.
- FIG. 1 Illustrated in Fig. 1 is an overview of the present invention method and apparatus as implemented in a digital processor 13.
- the illustrated apparatus (and method) 11 for determining physical properties of a chemical/polymer process is basically formed of a steady state modeling member 15 and an inferential modeler 21.
- the steady state modeling member 15 provides a rigorous model of the entire chemical/ polymer process and calculates the instantaneous or steady state properties of the chemical/polymer process products (e.g., polymers) at a given set of plant operating conditions.
- the inferential modeler 21 estimates or predicts cumulative product properties over time given a set of steady state product property values, and hence is also termed an estimator or predictor. Inferential modeler 21 receives the instantaneous product properties calculated by the steady state modeling member 15 and therefrom determines the product properties over a period of time.
- the invention apparatus and method 11 receives indications of a subject plant operating conditions, as source data 17, from a database, another digital processor, a computer program/routine or similar source.
- steady state modeling member 15 calculates the instantaneous (steady state) product properties at the certain time of the operating conditions as indicated by the source data 17, where the subject chemical/polymer process is rigorously modeled by steady state modeling member 15.
- the inferential modeler 21 uses the instantaneous product property values as calculated by the steady state modeling member 15, determines state of the product properties over time, and outputs 19 quantitative indications of the determined state (product property values over time).
- the present invention method and apparatus 11 dynamically calculates estimations of product (physical) properties based on a rigorous steady state model of the subject chemical/polymer process.
- Output 19 may be to a display subsystem (e.g., screen views on a monitor, hard copy via printer, etc.), a controller system, another digital processor or program/routine, and the like.
- the output quantitative indications 19 include parameter values for maintaining the product property values at a user specified state.
- the control subsystem in response to the parameter values 19, accordingly sets plant operating conditions (temperature, pressure, composition, etc.) via volume, flow rate, heater and other settings.
- steady state modeling member 15 is a software program, computer tool or other similar digital processing means for simulating a desired physical (i.e., chemical or polymer) process.
- One example is Polymers Plus by Aspen Technology, Inc.
- Polymers Plus includes polymer component characterization (including molecular weight distribution), calculation of physical properties and phase equilibria, polymerization kinetics and calculation of polymer product properties.
- Polymers Plus uses a segment approach to characterize polymers as described in U.S. Patent No. 5,687,090 herein incorporated by reference. The polymer is described as composed of a number of structural units called segments. This approach provides a flexible and consistent framework for tracking structural properties via segments in conjunction with other molecular structure attributes.
- a methodology is available for predicting molecular weight distribution for polymers produced via a chain growth kinetics model.
- Polymers Plus calculates physical properties and phase equilibria of polymer-monomer mixtures. This includes:
- Polymers Plus provides a comprehensive set of kinetic schemes for the major polymerization chemistries.
- the kinetics are decoupled from the reactors. This makes it possible to apply a single reaction scheme to multiple reactors or to apply combinations of reaction schemes to any reactor.
- Polymers Plus calculates and tracks polymer product properties such as density, melt index and intrinsic viscosity. User correlations are able to be incorporated to track end-use properties throughout a process simulation.
- Polymers Plus enables a wide range of industrial polymerization processes to be modeled from step-growth polymerization, to free- radical polymerization, ionic polymerization and others.
- step-growth polymerization model various polycondensation and specialty plastic processes are able to be described/simulated.
- This model accounts for any combination of mono- functional and bi-functional linear monomers, generates all possible reactions from the species functional group definition and provides the flexibility for incorporating user reactions for cyclic and multi-functional monomers.
- Applications include polyethelene terephthalate (PET), polybutylene terephthalate (PBT), polycarbonates (PC) and polyamides.
- the free-radical polymerization model provides a comprehensive kinetic scheme for the bulk or solution free radical homo- and co-polymerization of one or more monomers.
- Applications include polystyrene (PS), Styrene-Acrylonitrile (SAN), Polymethylmethacrylate (PMMA), and low density polyethylene (LDPE).
- a free-radical emulsion polymerization model in Polymers Plus is applicable to processes where nucleation occurs by micellar and homogeneous nucleation mechanisms.
- the underlying kinetics are similar to those in the free-radical model discussed above.
- Applications include Styrene butadiene rubber (SBR), polyvinylacetate, and polyacrylates.
- An addition polymerization with Ziegler-Natta and metallocene catalysts model enables modeling of a variety of stereospecific multi-site and single-site catalyzed addition polymerization systems.
- Such systems include the traditional Ziegler-Natta catalyzed systems, chromium-based catalyzed systems and the more recent metallocene- based catalyzed systems.
- Applications include high density polyethylene (HDPE), linear low-density polyethylene (LLDPE), polypropylene (PP), and Ethylenepropylenediene monomer polymer (EPDM).
- An ionic polymerization model in Polymers Plus is applicable to anionic, cationic and group transfer polymerization schemes. Applications include polystyrene (PS), polyethylene oxide (PEO), polypropylene oxide (PPO), styrene butadiene rubber (SBR).
- PS polystyrene
- PEO polyethylene oxide
- PPO polypropylene oxide
- SBR styrene butadiene rubber
- the preferred inferential modeler 21 is a software program/ routine, computer tool or similar model-based digital processor means for making estimates or predictions about product quality in a manufacturing process.
- Aspen IQ by Aspen Technology, Inc. of Cambridge, Massachusetts (assignee of the present invention).
- a base line version of Aspen IQ includes three modules called the IQ model, IQ predict and IQ update.
- the IQ model provides the user with the means to develop linear partial least squares (PLS), nonlinear- fuzzy PLS and hybrid neural network models.
- PLS linear partial least squares
- a host of data analysis and conditioning tools allow the user to import data and then generate steady state or dynamic empirical models.
- the inferential model development techniques are further described in U.S. Patent Nos. 5,666,297 and 6,041,263 and Application No. 09/160,128, herein incorporated by reference.
- Data alignment and process dynamics determination of IQ model are able to use either a genetic algorithmic or single input/output approach. Variable selection is performed by the use of genetic algorithms.
- Sensor validation models may also be produced such as that described in U.S. Patent Application Nos. 09/179,343 and 09/474,630, herein incorporated by reference.
- an inferential sensor value itself is performed in the IQ predictor module.
- Inferentials based on linear combinations, polynomial, linearized rigorous modeling, as well as user-specified models (with no practical limit to the number of terms) are supported. Input may be dynamically compensated before the inferential prediction is performed.
- One common approach is to build an "analyzer predictor".
- the analyzer predictor uses dynamic models and generates steady state and dynamic predictions of the analyzer. Linear PLS models generated from IQ model and linearized rigorous models generated elsewhere may be executed by IQ predict.
- IQ predict is designed specifically to validate the raw analyzer signals to determine if it is suitable for use in an inferential sensor or control strategy. After the analyzer signal is validated, it may be used to update the inferential sensor.
- the steady state detector is to quantify how close the unit is to steady state. The user may specify a number of major process variables and the steady- state percentage is calculated for each variable. These inputs are combined to produce an overall unit steady state percentage.
- IQ update monitors and validates the laboratory values and if necessary applies an update to the result generated in IQ predict. Before a laboratory value can be used to update an inferential, it must first be validated. The lab value is screened for outliers (values outside of predetermined thresholds) and checked against minimum and maximum values. The steady state detector percentage at the time the sample was taken may also be used to validate the lab value.
- a bias update is calculated as the offset between the inferential sensor prediction and the laboratory value. This offset, or bias, is applied to the current inferential value to ensure that the inferential sensor tracks the laboratory.
- Three bias update schemes are supported by IQ update including a CUSUM, a scoring and a traditional approach. The amount of the calculated bias that is actually applied and the speed at which it is filtered to the online system are some of the end-user tunable parameters.
- the validated signal from IQ predict may be used, instead of the laboratory value, to update the bias.
- the laboratory value is monitored and an analyzer drift is calculated. If the drift exceeds its operator-entered limit, then a message is generated and the bias update source is automatically switched from analyzer to laboratory values.
- time stamps are available for the laboratory data used in the data gathering. If these time stamps are not accurate, then the processed data will not be properly synchronized to the laboratory value. This can lead to the development of poor fitting models and inappropriate laboratory updates.
- IQ update is designed to ensure that the time stamps are as accurate as possible.
- Fig. 2 is a block diagram of the preferred embodiment.
- the preferred embodiment makes use of existing Aspen Technology, Inc. (of Cambridge, Massachusetts) software products as the building blocks. These products include Aspen Plus® and Polymers Plus 27, Aspen Online 25 and Aspen IQ 29.
- the use of Aspen Plus, Aspen Online and Polymers Plus form the commercially known Polymers Plus Online.
- Polymers Plus Online 25, 27 computes instantaneous polymer properties in terms of molecular weight distribution.
- Aspen IQ 29 is used to correlate the polymer properties of melt index and density with molecular weight distribution and also provides the laboratory analyzer, an update facility, as previously described.
- Aspen IQ 29 also provides the filter which is required to integrate the changes in melt index, density and other properties based on the Polymers Plus Online 25, 27 calculation.
- the integrator time constant is updated each time based on the calculation of instantaneous residence time by Polymers Plus 27.
- the estimates of the properties such as melt index and density then become dynamic calculations based on a rigorous steady state model.
- the preferred embodiment utilizes Aspen Online 25 to connect the Aspen Plus/Polymers Plus 27 steady state model of a subject chemical/polymer process to Aspen IQ 29 via a plant information (database) system 23.
- the plant information database system is a plant-wide operations information, data monitoring and analysis system with a relational database that stores each variable of the subject processing plant.
- the illustrated database system 23 is, for example, InfoPlus .21 by Aspen Technology, Inc. of Cambridge, Massachusetts.
- Aspen Online 25 is an interface for online modeling and as such establishes communications and controls the flow of information between plant data sources and process models. Aspen Online 25 also enables the analyzing and validating of plant data and model results. Accordingly, Aspen Online 25 connects the Aspen Plus/Polymers Plus 27 steady state model online and schedules Aspen
- Plant operating conditions (such as gas composition, temperature, pressure, etc.) are stored on the plant information database system 23 of the manufacturing plant and are passed down to the Aspen Plus/Polymer Plus 27 model through Aspen Online 25.
- Gas composition measurements being so critical to the application are validated by Aspen IQ 29 and then stored in database system 23 for subsequent use by modelers 27.
- Aspen Plus/Polymers Plus 27 performs a steady state run calculating the instantaneous polymer properties, especially melt index (MI,), and density (p,) and the reactor residence time ( ⁇ ). These steady state values of melt index, density and residence time are stored in the plant information database system 23.
- Aspen IQ 29 reads these values from the database 23 and performs the calculation of the cumulative properties using an analytical expression of the first order dynamics of mixing.
- the expressions take the form (Equations I):
- MI C (t), p c (t) are the cumulative properties of melt index and density, respectively, at the current time, t.
- the instantaneous properties at the previous simulation time are used because the latest instantaneous properties do not impact the cumulative properties.
- the preferred embodiment 35 is implemented using the Aspen Plus/Polymers Plus/Aspen Online 25, 27 approach, the instantaneous properties correspond to conditions immediately before the model was run. These can be five minutes old and thus the present invention uses the latest instantaneous properties.
- Equations II Equations II
- Aspen IQ 29 also reads laboratory measurements 31 for melt index and density and calculates the model prediction error in the form of a bias term (MI c b ⁇ as , p c b,as ) using established Aspen IQ 29 techniques.
- This bias term is used to correct the predicted melt index and density (MI C P , p c p ) according to the relationship
- MI C MI C + MI c b ⁇ as bias
- Aspen IQ 29 is also used to validate the gas composition. This feature detects any unusual or missing gas composition measurements and substitutes an appropriate value.
- the Aspen Plus/Polymers Plus 27 model takes several minutes to run. Gas composition measurements are available every few minutes. Temperature measurements are available continuously. Thus, the preferred embodiment 35 schedules Aspen IQ 29 and the model to run every five minutes such that the effect of temperature on instantaneous properties is captured between gas composition measurements.
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Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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EP00968615A EP1234219A1 (en) | 1999-10-05 | 2000-10-03 | Computer method and apparatus for determining state of physical properties in a chemical process |
AU78499/00A AU7849900A (en) | 1999-10-05 | 2000-10-03 | Computer method and apparatus for determining state of physical properties in a chemical process |
CA002386538A CA2386538A1 (en) | 1999-10-05 | 2000-10-03 | Computer method and apparatus for determining state of physical properties in a chemical process |
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US15778399P | 1999-10-05 | 1999-10-05 | |
US60/157,783 | 1999-10-05 |
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EP (1) | EP1234219A1 (en) |
AU (1) | AU7849900A (en) |
CA (1) | CA2386538A1 (en) |
TW (1) | TW487834B (en) |
WO (1) | WO2001025863A1 (en) |
Cited By (4)
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WO2003044607A1 (en) * | 2001-11-20 | 2003-05-30 | Basf Corporation | Method and apparatus for predicting polymer latex properties in an emulsion polymerization process to improve the quality and productivity of the polymer latex |
EP1560087A2 (en) | 2004-01-29 | 2005-08-03 | Invensys Systems, Inc. | Method and apparatus for translation of process models to facilitate usage by plural simulation applications |
US7389186B2 (en) | 2006-08-11 | 2008-06-17 | Exxonmobil Research And Engineering Company | Prediction of stream composition and properties in near real time |
WO2021165406A1 (en) * | 2020-02-20 | 2021-08-26 | Evonik Operations Gmbh | Method and system for process control |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102736570B (en) * | 2011-04-13 | 2014-07-16 | 北京化工大学 | Gas phase polyethylene device quality index and operational constraint on-line estimation system and method thereof |
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US5687090A (en) * | 1994-09-01 | 1997-11-11 | Aspen Technology, Inc. | Polymer component characterization method and process simulation apparatus |
WO1999014642A1 (en) * | 1997-09-12 | 1999-03-25 | Cambridge Consultants Limited | Machine controller calibration process |
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2000
- 2000-10-03 WO PCT/US2000/027243 patent/WO2001025863A1/en not_active Application Discontinuation
- 2000-10-03 EP EP00968615A patent/EP1234219A1/en not_active Withdrawn
- 2000-10-03 AU AU78499/00A patent/AU7849900A/en not_active Abandoned
- 2000-10-03 CA CA002386538A patent/CA2386538A1/en not_active Abandoned
- 2000-10-05 TW TW89120730A patent/TW487834B/en active
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US5687090A (en) * | 1994-09-01 | 1997-11-11 | Aspen Technology, Inc. | Polymer component characterization method and process simulation apparatus |
US5933345A (en) * | 1996-05-06 | 1999-08-03 | Pavilion Technologies, Inc. | Method and apparatus for dynamic and steady state modeling over a desired path between two end points |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003044607A1 (en) * | 2001-11-20 | 2003-05-30 | Basf Corporation | Method and apparatus for predicting polymer latex properties in an emulsion polymerization process to improve the quality and productivity of the polymer latex |
US6657019B2 (en) | 2001-11-20 | 2003-12-02 | Basf Corporation | Method and apparatus for predicting polymer latex properties in an emulsion polymerization process to improve the quality and productivity of the polymer latex |
EP1560087A2 (en) | 2004-01-29 | 2005-08-03 | Invensys Systems, Inc. | Method and apparatus for translation of process models to facilitate usage by plural simulation applications |
EP1560087A3 (en) * | 2004-01-29 | 2006-02-22 | Invensys Systems, Inc. | Method and apparatus for translation of process models to facilitate usage by plural simulation applications |
US7389186B2 (en) | 2006-08-11 | 2008-06-17 | Exxonmobil Research And Engineering Company | Prediction of stream composition and properties in near real time |
WO2021165406A1 (en) * | 2020-02-20 | 2021-08-26 | Evonik Operations Gmbh | Method and system for process control |
Also Published As
Publication number | Publication date |
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TW487834B (en) | 2002-05-21 |
EP1234219A1 (en) | 2002-08-28 |
CA2386538A1 (en) | 2001-04-12 |
AU7849900A (en) | 2001-05-10 |
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