WO2001012761A1 - Crystal formation reduction in lubricating compositions - Google Patents
Crystal formation reduction in lubricating compositions Download PDFInfo
- Publication number
- WO2001012761A1 WO2001012761A1 PCT/EP2000/007814 EP0007814W WO0112761A1 WO 2001012761 A1 WO2001012761 A1 WO 2001012761A1 EP 0007814 W EP0007814 W EP 0007814W WO 0112761 A1 WO0112761 A1 WO 0112761A1
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- Prior art keywords
- mixture
- phosphorus
- anhydride
- sulfur
- wear
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- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
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- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/04—Hydroxy compounds
- C10M129/10—Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
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- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/68—Esters
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- C10M129/86—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of 30 or more atoms
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Definitions
- This invention relates to lubricating oil based on base stocks having a saturates content of 99 wt% or more, preferably essentially 100% saturates and containing sulfur-phosphorus containing anti- wear/extreme pressure additives and hindered phenol antioxidants which combination of anti-wear/extreme pressure agent and hindered phenol antioxidant are prone to crystal formation, wherein the formation of crystals is reduced or eliminated by the use of a crystallization suppressant.
- Lubricating oils containing various antioxidants or esters or fatty acid amides or sulfur-phosphorus additives in combination with phenols are known in the literature.
- U.S. Patent 5,167,844 is directed to a formulation comprising a base oil, at least one sulfur phosphorus containing compound, at least one amine and at least one hindered phenol.
- JP 07034078 is directed to a hydraulic oil comprising mineral oil with an aromatic content of up to 1.5 wt% and a phenolic and aminic anti-oxidant, an alkenyl succinic acid imide rust inhibitor and a phosphoric acid type anti wear agent.
- U.S. Patent 5.580,483 is directed for lubricating a refrigeration system compressor using a break-in lubricating oil which is an ester type oil. Additionally an adipate, phthalate. azelate, sebacate, corrosion inhibitors such as alkali and/or alkaline earth metal sulfonate, antioxidants such as aminic or phenolic antioxidants and metal deactivators such as triazoles.
- WO 97/14776 is directed to hydraulic oils comprising base oils combined with an amine antioxidant, a phenolic antioxidant, a phosphate ester and a fatty acid amide and/or polyhydric alcohol ester.
- U.S. Patent 5,773,393 is directed to a composition comprising at least 70 wt% oil of lubricating viscosity and an amount effective to inhibit metal corrosion of a soluble additive comprising (a) at least one amide compound of a mono- or polycarboxylic acid or reactive derivative thereof and (b) at least 0.5 equivalents of at least one primary or secondary amine per mole of amide provided that when (a) is an amide of a dicarboxylic acid and the amine is an alkanol amine the mixture contains more than 0.5 equivalent of the amine (b) per equivalent of the amide.
- the present invention is directed to a lubricating oil formulation having a reduced potential for the formation of crystals comprising a major amount of a lubricating oil base stock having a saturates content of 99 wt% or more, preferably essentially about 100 wt% and a minor amount of additives comprising a mixture of sulfur- phosphorus containing anti-wear/extreme pressure additive, hindered phenol antioxidant, and a di- or polycarboxylic acid, anhydride or mixture thereof and an ester, and to a method for reducing crystal formation in lubricating oil formulations comprising base oil having saturates content of 99 wt% or more, preferably essentially about 100 wt%, and containing sulfur phosphorus anti-wear/extreme pressure additive and hindered phenolic anti-oxidant wherein the crystals are attributable to the interaction between the sulfur-phosphorus containing anti-wear/extreme pressure agent and the hindered phenol, by adding to said lubricating oil a minor effective amount of
- the lubricating base oil is any oil of lubricating oil viscosity having a saturates content of 99 wt% or more, preferably essentially 100 Wt%.
- Lubricating oils meeting this criterion are any natural mineral or petroleum based lubricating oils derived from crude oil, tar sands, shale oil, etc., such that they have a saturates content in the recited range, or a mixture of natural mineral or petroleum based lubricating oils in combination with poly-alpha olef ⁇ ns, isomerized wax or isomerized Fischer- Tropsch wax, the combination or mixture of such oils being characterized as having a saturates content of 99 wt% or more, preferably essentially 100 wt%.
- Saturates content for the purpose of this invention, is a measure of the absence of aromatic species, and was determined using high pressure liquid chromatography (HPLC) according to method IP 368, except where otherwise expressly indicated.
- the lubricating oil base stocks useful in the present invention have the typical lubricating oil viscosity, usually possessing kinematic viscosities in the range of about 1.5 to 500 mm2/s at 100°C, preferably 5 to 120 mm2/s at 100°C.
- Mineral or petroleum based lubricating oil base stocks can be derived from paraffinic, naphthenic and mixed base crudes. Conventional refinery techniques include distillation, solvent and/or catalytic dewaxing, solvent extraction, hydrofinishing, hydrocracking, vis breaking, deasphalting, etc.
- Preferred mineral or petroleum based base stocks include white oils, hydrocracked or hydroisomerised base stocks.
- Synthetic lubricating oils that can be used include esters of di- and tri-basic acids, reacted with linear or branched aliphatic alcohols such as C6-Ci5 alcohols, such as di-2-ethylhexyl sebacate, phthalates, esters of glycols such as C13 oxo acid diester or tetraethylene glycol, or complex esters such as one formed from 1 mole of sebacic acid and 2 moles of tetraethylene glycol and 2 moles of 2-ethylhexanoic acid.
- linear or branched aliphatic alcohols such as C6-Ci5 alcohols, such as di-2-ethylhexyl sebacate, phthalates, esters of glycols such as C13 oxo acid diester or tetraethylene glycol, or complex esters such as one formed from 1 mole of sebacic acid and 2 moles of tetraethylene glycol and 2 moles of 2-ethylhe
- oils that can be used include silicone oils, e.g., methyl polysiloxanes, etc.; poly glycol oils, e.g., those obtained by condensing butyl alcohol with propylene oxide; carbonate esters, e.g., the product of reacting Cg oxo alcohol with ethyl carbonate to form a half ester followed by reaction of the latter with tetraethylene glycol, etc.
- silicone oils e.g., methyl polysiloxanes, etc.
- poly glycol oils e.g., those obtained by condensing butyl alcohol with propylene oxide
- carbonate esters e.g., the product of reacting Cg oxo alcohol with ethyl carbonate to form a half ester followed by reaction of the latter with tetraethylene glycol, etc.
- the only requirement is that such oils be 100% saturated (that is, contain no unsaturation).
- suitable oils are the polyol ester oils made by reacting an aliphatic polyol with carboxylic acid.
- Aliphatic polyols contain from 4 to 15 carbon atoms and has from 2 to 8 esterif ⁇ able hydroxyl groups. Examples of polyols are trimethylolpropane, pentaerythritol, dipentaerythritol, neopentyl glycol, tripentaerythritol and mixtures thereof.
- the carboxylic acid reactant is selected from aliphatic moncarboxylic acid or mixtures of aliphatic mono carboxylic acids or mixtures of aliphatic mono- and di-carboxylic acids.
- the carboxylic acids contain 4 to 12 carbons and include straight and branched chain carboxylic acids.
- Included in the group of synthetic oils are those recovered from tar sands, shale oil, light hydrocarbons produced via, for example, the Fischer-Tropsch process for converting synthesis gas (CO and hydrogen) into hydrocarbons, wax isomerate oils produced by the catalytic hydroisomerization of natural petroleum waxes (i.e., slack wax) or synthetic waxes (i.e., Fischer-Tropsch waxes) or mixtures of such waxes. See USP 5,059,299 and USP 5,158,671 for description of wax isomerization and the oils produced thereby.
- polystyrene resin such as polybutene, polyisobutenes and especially the polyalphaolefins, i.e., fluids formed by the oligomerzation of at least one 1-alkane hydrocarbon having from 6 to 20 carbons, preferable 8 to 16 carbons, more preferably 8 to 12 carbons.
- the lube oil base stock is characterized as having a saturates content of 99 wt% or more, preferably about 99.8 wt% or more.
- Sulfur-phosphorus containing anti wear/extreme pressure additives are well known in the industry, and are materials containing both sulfur and phosphorus in the same materials.
- sulfur-phosphorus containing anti-wear/extreme pressure additives are those which react with hindered phenol antioxidant to produce crystals.
- any sulfur-phosphorus containing anti-wear/extreme pressure agent which is found to react with hindered phenol antioxidant to produce crystals in the subject base oil is within the invention and formulations containing such agent(s) and phenolic antioxidant will be beneficially affected as evidenced by reduction or elimination of crystal formation by the addition of the high molecular weight di- or polycarboxylic acid, anhydride or mixtures thereof and ester, as shown below, provided such carboxylic acid, anhydride or mixture thereof is used in an amount of at least about 0.0013 wt% for each 1 ppm phosphorus attributable to the sulfur-phosphorus containing anti -wear/extreme pressure agent, about 0.033 wt% or more ester is used for each 1 ppm phosphorus and the high molecular weight di- or poly carboxylic acid, anhydride or mixture thereof and the ester is employed in an ester to acid ratio of 25: 1 by weight or higher.
- Sulfur-phosphorus anti wear/extreme pressure additives are exemplified by, but not limited to, materials of the type: R ⁇ X — P— (X)R 3 (X)-R 2
- R ⁇ , R2 and R3 are independently hydrogen or hydrocarbyl provided at least one is hydrocarbyl so as to render the material oil soluble and X is sulfur.
- the hydrocarbyl groups preferably contain form 1 to 40 carbons and are aromatic and/or aliphatic groups and include aryl, alkyl and alkaryl and aralkyl and heteroatom substituted aromatic and aliphatic group, the hetero atom substitutents being sulfur, nitrogen or oxygen substituted as such into the hydrocarbon selection or as sulfur, oxygen or nitrogen containing moiety, e.g., — ORy, — SH, — SO2H, — N(Ry)2, C R ⁇ ORy,
- R x is C1-C20 hydrocarbyl or hydrocarbylene group and Ry is hydrogen or a C1 -C20 hydrocarbyl or hydrocarbylene group.
- Such sulfur-organo phosphorus containing anti wear/extreme pressure agent is typically used at a concentration of from about 2 ppm to 320 ppm phosphorus, preferably about 40 ppm to 200 ppm phosphorus, most preferably about 80 ppm to 130 ppm phosphorus.
- sulfur phosphorus anti-wear/extreme pressure additive which has been found to react with hindered phenols to form crystals
- a material is 2-ethylhexyl 10-ethyl-4-[[2-[(2 ethylhexyl)- oxyl]-2-oxoethyl] thio]-7-oxo-8-oxa-3,5-dithia-4-phospha tetradecanoate, CAS # 83547-95-9. Based on the name and the CAS number, it is believed this material has the following structure:
- metal dihydrocarbyl dithio phosphates metal DDP
- ashless DDP do not fall within the scope of the above definition of sulfur-phosphorus containing anti-wear/extreme pressure agents because it has been found that they do not form crystals when combined with hindered henols in base oils.
- Hindered phenolic antioxidants are also well known in the industry. Such materials include by way of example and not limitation 2,6-di-t-butyl phenol, 2,6-di-t-butyl alkylated phenol where the alkyl substituent is hydrocarbyl and contains between 1 and 20 carbon atoms, such as 2,6-di-t-butyl-4-methyl phenol, 2,6-di-t-butyl-4-ethyl phenol, etc., or 2,6-di-t-butyl-4-alkoxy phenol where the alkoxy substituent contains between 1 and 20 carbons such as 2,6-di-t-butyl-4-methoxyphenol; materials of the formula
- Rg and RQ are the same or different and are Cj-C20 hydrocarbyl which may contain oxygen or sulfur or be substituted with oxygen or sulfur containing groups; and materials of the formula
- R1 Q is a C ⁇ to C20 hydrocarbyl which may contain oxygen, sulfur or nitrogen or be substituted with oxygen, sulfur or nitrogen containing groups, such as 2,6 di tert butyl dimethyl amino p- cresol,
- K ⁇ ⁇ is CgCi 7 (CAS # 125643-61-0), and mixtures of such phenolic type antioxidants.
- the phenolic antioxidant contains an ester group, such as in formula IV above.
- Phenolic type antioxidants are typically used at a concentration of from about 0.01 to 2.0 wt%, preferably 0.1 to 1.0 wt%, most preferably 0.3 to 0.5 wt%, based on active ingredient.
- sulfrir-phosphorus containing anti-wear/extreme pressure agent is one which interacts with hindered phenol to produce crystals
- a minor, crystal preventing effective amount of a high molecular weight carboxylic acid, anhydride or mixture thereof is added to the lubricating oil formulation, in combination with an ester.
- carboxylic acid anhydride or mixture thereof can be any high molecular weight acid di-, or polycarboxylic acid anhydride or mixture thereof of molecular weight of about 300 to 5000.
- Such acids, anhydrides or mixtures thereof include polyhydrocarbylene substituted di- or polycarboxylic acids wherein the poly hydrocarbylene group has a molecular weight in the range 300 to 5000, preferably 750 to 2000, most preferably 900 to 1000 (e.g., polyisobutylene) and wherein the carboxylic group is preferably succinic or maleic acid, anhydride or mixture thereof.
- Poly hydrocarbylenes are homopolymer or interpolymers of polymerizable olefin group containing monomers having from 2 to 16 carbons. Interpolymers are those made using two or more different olefinic groups containing monomer including monomer such as styrenes. Polyhydrocarbylene homo and interpolymers are well known in the literature and to those skilled in the art and need not be further described herein.
- carboxylic acid anhydride or mixture thereof used is polyalkylene succinic or maleic acid, anhydride, or mixture thereof, most preferably polyisobutylene (PIB) succinic acid, anhydride or mixtures thereof wherein the PIB group has a molecular weight of about 900 to 1000.
- PIB polyisobutylene
- Such high molecular weight carboxylic acids, anhydrides or mixtures thereof are employed in an amount in the range of about 0.0026 to 0.8 wt%, preferably about 0.08 to 0.4 wt%, most preferably about 0.12 to 0.24 wt%, based on active ingredients. In general, from at least 0.0013 wt% of high molecule weight carboxylic acid, anhydride or mixture thereof is used for each 1 ppm from the sulfur-organo phosphorus anti wear/extreme pressure agent.
- the ester can be any of the ester materials previously described as suitable synthetic oils. Esters such as phthalates and trimellitates can also be used.
- the crystal suppressing combination of high molecular weight acid and/or anhydride and ester is employed in an ester to acid ratio of 25: 1 or higher, preferably 32:1 or higher.
- the 99 wt% or more saturates content oil is itself a mixture of mineral oil or synthetic hydrocarbon oil, and ester, it may be enough merely to add a sufficient amount of high molecular weight acid/anhydride to the formulation to meet the aforesaid acid to sulfur-phosphorus anti-wear/extreme pressure additive ratio provided in doing so the ester/acid ratio also satisfies the 25: 1 or more relationship. If insufficient ester is present an amount of ester sufficient to satisfy or reach the 25: 1 or more ratio can be added to the formulation in order to achieve crystal formation suppression.
- Sulfur phosphorus extreme pressure agent CAS # 83547-95-9 which is 60%
- sulfur-phosphorus component active ingredient also contained C4-Cg diphenyl amine as balance of additive
- the fully formulated lubricant has a phosphorus content of 120ppm by weight, measured according to standard test ASTM D5185-97, attributable to the sulphur-phosphorus extreme pressure agent (which is the sole phosphorus containing component contained in the formulation)
- PIBSA is polyisobutylene succinic anhydride having a polyisobutylene molecular weight of about 950.
- esters tested were di iso nonyl phthalate at 0.05 to 4 wt%; di iso tridecyl adipate at 0.1 to 0.5 wt%; C6-C13 phthalate at 0.5 wt%. None were effective alone at eliminating crystal formation during the three month test period.
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- Chemical & Material Sciences (AREA)
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- Organic Chemistry (AREA)
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Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00962304A EP1206511A1 (en) | 1999-08-17 | 2000-08-11 | Crystal formation reduction in lubricating compositions |
CA002381982A CA2381982A1 (en) | 1999-08-17 | 2000-08-11 | Crystal formation reduction in lubricating compositions |
US10/049,973 US6689726B1 (en) | 1999-08-17 | 2000-08-11 | Crystal formation reduction in lubricating compositions |
JP2001517648A JP2003507528A (en) | 1999-08-17 | 2000-08-11 | Stabilized lubricating compositions and methods |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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GB9919488.8 | 1999-08-17 | ||
GB9919488A GB2353290A (en) | 1999-08-17 | 1999-08-17 | Stabilized lubricating formulation and method |
Publications (1)
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WO2001012761A1 true WO2001012761A1 (en) | 2001-02-22 |
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PCT/EP2000/007814 WO2001012761A1 (en) | 1999-08-17 | 2000-08-11 | Crystal formation reduction in lubricating compositions |
Country Status (6)
Country | Link |
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US (1) | US6689726B1 (en) |
EP (1) | EP1206511A1 (en) |
JP (1) | JP2003507528A (en) |
CA (1) | CA2381982A1 (en) |
GB (1) | GB2353290A (en) |
WO (1) | WO2001012761A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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GB2353291A (en) * | 1999-08-17 | 2001-02-21 | Exxon Research Engineering Co | Stabilized lubricating formulation and method |
US8569216B2 (en) | 2011-06-16 | 2013-10-29 | Exxonmobil Research And Engineering Company | Lubricant formulation with high oxidation performance |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2766207A (en) * | 1952-12-31 | 1956-10-09 | Exxon Research Engineering Co | Hydrocarbon oil products |
US3458495A (en) * | 1965-09-16 | 1969-07-29 | Exxon Research Engineering Co | Reaction product of a phosphosulfurized hydrocarbon and an alkylene amino phenol and method for preparing |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1471934A (en) * | 1974-05-17 | 1977-04-27 | Exxon Research Engineering Co | Lubricating oil compositions |
JPS5943725B2 (en) * | 1975-05-05 | 1984-10-24 | ポラロイド、コ−ポレ−シヨン | camera exposure control device |
CA1159437A (en) * | 1980-09-02 | 1983-12-27 | William H. Stadtmiller | Lubricating oil with improved thermal stability |
US4592851A (en) * | 1980-09-02 | 1986-06-03 | Exxon Research And Engineering Co. | Lubricating oil composition and method for providing improved thermal stability |
CA1248516A (en) * | 1985-07-15 | 1989-01-10 | Stephen C. Cohen | Lubricating oil compositions containing novel combination of stabilizers |
GB2272000B (en) * | 1992-10-30 | 1997-03-26 | Castrol Ltd | A method of inhibiting corrosion |
US6048825A (en) * | 1994-04-26 | 2000-04-11 | Castrol Limited | Lubricant composition |
GB9511266D0 (en) * | 1995-06-05 | 1995-08-02 | Exxon Chemical Patents Inc | Ester-free synthetic lubricating oils |
EP0903399B1 (en) * | 1997-09-18 | 2007-02-14 | Ciba SC Holding AG | Lubricant compositions containing thiophosphoric and dithiophosphoric acid esters |
JP4691233B2 (en) * | 2000-06-05 | 2011-06-01 | 東燃ゼネラル石油株式会社 | Lubricating oil composition for continuously variable transmission |
-
1999
- 1999-08-17 GB GB9919488A patent/GB2353290A/en not_active Withdrawn
-
2000
- 2000-08-11 WO PCT/EP2000/007814 patent/WO2001012761A1/en not_active Application Discontinuation
- 2000-08-11 CA CA002381982A patent/CA2381982A1/en not_active Abandoned
- 2000-08-11 EP EP00962304A patent/EP1206511A1/en not_active Withdrawn
- 2000-08-11 US US10/049,973 patent/US6689726B1/en not_active Expired - Lifetime
- 2000-08-11 JP JP2001517648A patent/JP2003507528A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2766207A (en) * | 1952-12-31 | 1956-10-09 | Exxon Research Engineering Co | Hydrocarbon oil products |
US3458495A (en) * | 1965-09-16 | 1969-07-29 | Exxon Research Engineering Co | Reaction product of a phosphosulfurized hydrocarbon and an alkylene amino phenol and method for preparing |
Also Published As
Publication number | Publication date |
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JP2003507528A (en) | 2003-02-25 |
CA2381982A1 (en) | 2001-02-22 |
US6689726B1 (en) | 2004-02-10 |
EP1206511A1 (en) | 2002-05-22 |
GB9919488D0 (en) | 1999-10-20 |
GB2353290A (en) | 2001-02-21 |
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