WO2000069398A1 - Composition pour produit capillaire fixatif a base de siloxane - Google Patents

Composition pour produit capillaire fixatif a base de siloxane Download PDF

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Publication number
WO2000069398A1
WO2000069398A1 PCT/EP1999/003339 EP9903339W WO0069398A1 WO 2000069398 A1 WO2000069398 A1 WO 2000069398A1 EP 9903339 W EP9903339 W EP 9903339W WO 0069398 A1 WO0069398 A1 WO 0069398A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
hairspray composition
composition containing
hairspray
siloxanes
Prior art date
Application number
PCT/EP1999/003339
Other languages
German (de)
English (en)
Inventor
Wilma M. Dausch
Volker Schehlmann
Original Assignee
Basf Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Aktiengesellschaft filed Critical Basf Aktiengesellschaft
Priority to PCT/EP1999/003339 priority Critical patent/WO2000069398A1/fr
Publication of WO2000069398A1 publication Critical patent/WO2000069398A1/fr

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/06Preparations for styling the hair, e.g. by temporary shaping or colouring
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/046Aerosols; Foams
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585Organosilicon compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol

Definitions

  • Synthetic polymers have been used successfully for setting hairstyles for almost 50 years. While vinyl lactam homo- and copolymers were preferred in the early days, later carboxylate-containing polymers became more and more important.
  • the desired property profile such as strong strengthening at high air humidity, elasticity, washability from the hair and compatibility with the other formulation components are achieved by copolymerizing a combination of hydrophobic, elasticizing and carboxyl group-containing monomers (Lit: Robert Y. Lochhead, Vol. 103, December 1988, 24 ff., Rolf-Dieter Reinhardt Cosmetics and Toiletries Manufacture World Wide 1995, 189m ff.).
  • No. 5,599,524 describes hairspray compositions which, in addition to the setting polymer and customary additives, contain certain siloxanes (hexamethyldisiloxane, bisphenylhexamethicone) in an amount of 0.6 to 5% by weight.
  • These hairspray compositions have improved spray characteristics, while other siloxanes such as dimethicones do not contribute to improved spray characteristics (Example 1).
  • siloxanes dimethicones
  • hairspray compositions with a precisely defined, relatively low content of specific siloxanes have particularly advantageous application properties.
  • the invention relates to hairspray composition containing
  • Suitable setting polymers (A) have long been known to the person skilled in the art, in particular those made from copolymers of vinyl acetate / crotonic acid / vinyl neodecanoate; Octylacrylamide / acrylate / butylaminoethyl methacrylate; Vinyl acetate / crotonate; Polyvinylyrrolidone
  • PVP Polyvinyl pyrrolidone / vinyl acetate; PVP / acrylate; Vinyl acetate / crotonic acid / vinyl propionate; Acrylate / acrylamide; Acrylate / octyl acrylamide and alkyl ester of polyvinyl methyl ether / maleic anhydride; Diglycol / cyclohexanedimethanol / isophthalate / sulfoisophthalate; Vinyl acetate / butyl maleate / isobornyl acrylate; Vinyl caprolactam / PVP / dimethylaminoethyl methacrylate; Vinyl acetate / alkyl maleate half esters / N-substituted acrylamide terpolymers; Vinyl caprolactam / vinyl pyrrolidone / methacrylamidopropyl trimethyl ammonium chloride terpolymer, - methacrylate / acrylate cop
  • the carboxylate groups of the polymers are advantageously partially or completely neutralized. This neutralization can take place in the preparation of the polymers or in the final formulation of the hairspray composition.
  • Particularly suitable polymers (A) are vinyl pyrrolidone copolymers, as for example sold under the trademark LUVISKOL ® from BASF Aktiengesellschaft and acrylate copolymers such as are for example sold under the trade name Luvimer ® and Ultrahold ® from BASF Aktiengesellschaft.
  • the hair fixatives according to the invention contain the polymers (A) in an amount of 0.5-15, preferably 2-10% by weight.
  • the siloxanes (B) are known and commercially available. Hexamethyldisiloxane is sold, for example, by the Rhone-Poulenc company under the brand name MIRASIL HMS ® .
  • Dimethicone Copolyol is available, for example, from Dow Chemicals Inc. under the brand name DOW CORNING 190-, or from Union Carbide under the brand names SILWET COPOLYMER L-7500 ® , L-7087 ® , L-7602 ® , L-7622 ® or SILSOFT 900 ® expelled.
  • Laurylmethicone Copolyol is sold, for example, by Dow Chemicals Inc. under the brand name DOW CORNING 5200 ® .
  • the siloxanes (B) are used in an amount of 0.01-0.5% by weight, preferably 0.03-0.25% by weight.
  • the amount of 15 refers to the formulated hairspray composition.
  • the siloxanes can be used both as individual compounds and as a mixture.
  • additives (C) customary additives such as light stabilizers, perfume oils, dyes, antistatic agents, preservatives, thickeners can be added in an amount of up to 10% by weight.
  • blowing agent (D) hydrocarbons such as propane, butane, isobutane or mixtures thereof can usually be used alone or in combination with compressed gases such as nitrogen, air or carbon dioxide. (D) is usually used in amounts of 10 to 60% by weight.
  • organic solvents can be used alone or together with water.
  • Volatile alcohols such as methanol, ethanol, propanol, isopropanol, butanol, ketones such as acetone, ethers such as dimethoxymethane and dimethyl ether and methylene chloride are preferred,
  • Preferred (E) ethanol or ethanol / water mixtures in particular 80:20, are used.
  • Component (E) is usually used in amounts of 25 to 40 90% by weight.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une composition pour produit capillaire fixatif contenant : (A) entre 0,1 et 15 % en poids de polymères à pouvoir fixant ; (B) entre 0,01 et 0,5 % en poids d'un ou de plusieurs siloxanes du groupe comprenant l'hexaméthyldisiloxane, le diméthicone copolyol et le laurylméthicone copolyol ; (F) entre 0 et 10 % en poids d'additifs habituels ; (G) des agents propulseurs ; (H) des solvants organiques et éventuellement de l'eau, la somme constituants (A) à (E) s'élevant au total à 100 % en poids.
PCT/EP1999/003339 1999-05-12 1999-05-12 Composition pour produit capillaire fixatif a base de siloxane WO2000069398A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/EP1999/003339 WO2000069398A1 (fr) 1999-05-12 1999-05-12 Composition pour produit capillaire fixatif a base de siloxane

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP1999/003339 WO2000069398A1 (fr) 1999-05-12 1999-05-12 Composition pour produit capillaire fixatif a base de siloxane

Publications (1)

Publication Number Publication Date
WO2000069398A1 true WO2000069398A1 (fr) 2000-11-23

Family

ID=8167292

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1999/003339 WO2000069398A1 (fr) 1999-05-12 1999-05-12 Composition pour produit capillaire fixatif a base de siloxane

Country Status (1)

Country Link
WO (1) WO2000069398A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1566165A1 (fr) * 2004-02-12 2005-08-24 L'oreal Procédé de mise en forme des fibres kératiniques par application d'une composition cosmétique comprenant un polymère fixant anionique et un composé non-ionique et application d'un moyen chauffant
EP1593367A1 (fr) * 2004-05-07 2005-11-09 L'oreal Composition conditionnée dans un dispositif aérosol, comprenant un polymère fixant anionique, une silicone oxyalkylénée en position Alpha et Omega de la chaíne siliconée, et un agent propulseur
FR2989881A1 (fr) * 2012-04-26 2013-11-01 Oreal Composition cosmetique comprenant un silane a chaine grasse et un polymere fixant particulier
FR2989882A1 (fr) * 2012-04-26 2013-11-01 Oreal Composition cosmetique comprenant un silane a chaine grasse et un polymere fixant particulier
WO2013160442A3 (fr) * 2012-04-26 2014-12-04 L'oreal Composition cosmétique comprenant un silane à chaîne grasse et un polymère de fixation spécifique
US8968707B2 (en) 2004-05-07 2015-03-03 L'oreal Composition packaged in an aerosol device, comprising at least one anionic fixing polymer, at least one silicone oxyalkylenated in the alpha and omega positions of the silicone chain, and at least one propellant

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0557087A1 (fr) * 1992-02-21 1993-08-25 Revlon Consumer Products Corporation Laques capillaires sous forme d'aérosol aqueux à faible teneur en produits organiques volatils
EP0635257A1 (fr) * 1993-07-21 1995-01-25 National Starch and Chemical Investment Holding Corporation Aerosol capillaire à faible teneur en produits organiques volatils avec performance améliorée
EP0705595A2 (fr) * 1994-10-03 1996-04-10 Rohm And Haas Company Composition pour la mise en forme des cheveux

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0557087A1 (fr) * 1992-02-21 1993-08-25 Revlon Consumer Products Corporation Laques capillaires sous forme d'aérosol aqueux à faible teneur en produits organiques volatils
EP0635257A1 (fr) * 1993-07-21 1995-01-25 National Starch and Chemical Investment Holding Corporation Aerosol capillaire à faible teneur en produits organiques volatils avec performance améliorée
EP0705595A2 (fr) * 1994-10-03 1996-04-10 Rohm And Haas Company Composition pour la mise en forme des cheveux
JPH08301735A (ja) * 1994-10-03 1996-11-19 Rohm & Haas Co 水性ヘアースタイリング組成物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 1999, no. 06 31 March 1999 (1999-03-31) *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1566165A1 (fr) * 2004-02-12 2005-08-24 L'oreal Procédé de mise en forme des fibres kératiniques par application d'une composition cosmétique comprenant un polymère fixant anionique et un composé non-ionique et application d'un moyen chauffant
EP1593367A1 (fr) * 2004-05-07 2005-11-09 L'oreal Composition conditionnée dans un dispositif aérosol, comprenant un polymère fixant anionique, une silicone oxyalkylénée en position Alpha et Omega de la chaíne siliconée, et un agent propulseur
FR2869798A1 (fr) * 2004-05-07 2005-11-11 Oreal Composition conditionnee dans un dispositif aerosol, comprenant un polymere fixant anionique, une silicone oxyalkylenee en positions alpha et omega de la chaine
KR100827735B1 (ko) * 2004-05-07 2008-05-07 로레알 음이온성 고정 폴리머, 실리콘 사슬의 α 및 ω위치가옥시알킬렌화된 실리콘 및 스프레이용 고압가스를포함하는, 에어로졸 장치에 패키지화된 조성물
US8968707B2 (en) 2004-05-07 2015-03-03 L'oreal Composition packaged in an aerosol device, comprising at least one anionic fixing polymer, at least one silicone oxyalkylenated in the alpha and omega positions of the silicone chain, and at least one propellant
FR2989881A1 (fr) * 2012-04-26 2013-11-01 Oreal Composition cosmetique comprenant un silane a chaine grasse et un polymere fixant particulier
FR2989882A1 (fr) * 2012-04-26 2013-11-01 Oreal Composition cosmetique comprenant un silane a chaine grasse et un polymere fixant particulier
WO2013160442A3 (fr) * 2012-04-26 2014-12-04 L'oreal Composition cosmétique comprenant un silane à chaîne grasse et un polymère de fixation spécifique

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