WO2000041672A1 - A combined insect repellent and sunscreen composition - Google Patents
A combined insect repellent and sunscreen composition Download PDFInfo
- Publication number
- WO2000041672A1 WO2000041672A1 PCT/GB2000/000068 GB0000068W WO0041672A1 WO 2000041672 A1 WO2000041672 A1 WO 2000041672A1 GB 0000068 W GB0000068 W GB 0000068W WO 0041672 A1 WO0041672 A1 WO 0041672A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- sunscreen composition
- emulsifiers
- sunscreening
- titanium dioxide
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/02—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings containing insect repellants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
Definitions
- This invention relates to insect repellent and sunscreen compositions and in particular to combined insect repellent and sunscreen compositions that have both effective repellency and sunscreening properties.
- the present invention consists in a sunscreen composition including one or more insect repellents and one or more UV sunscreening agents characterised in that the composition includes 3-9% by weight in total of at least two emulsifiers, based on the total weight of the composition.
- the sunscreen agent in combination with insect repellent give a composition that is stable and effective with respect to SPF.
- One or more inorganic compounds are incorporated in the composition of the invention as a sunscreening agent.
- the preferred inorganic compounds are titanium oxide and zinc oxide.
- the particle size can be selected to scatter light in the UV range whilst transmitting light in the visible range thereby remaining transparent on the skin. This is highly desirable from a cosmetic point of view.
- Micronised particles that is those particles less than 100 nm in size, give optimal performance.
- Micronised titanium dioxide is most preferred for the composition of the invention.
- the concentration of inorganic compound may be in the range of 1-5% by weight based on the total weight of the composition, preferably 2-4% by weight and more preferably 3% by weight.
- One or more insect repellents are included in the composition. The repellents are chosen for repellency of flying or biting insects and for low skin irritancy.
- Suitable repellents include N,N-diethyl-m-toluamide (DEET), dipropyl pyridine-2,5- dicarboxylate, pyrethrins, dimethyl phthalate, 2,3:4,5-bis(2-butylene)tetrahydrofurfural, citronella, geraniol, lemon grass oil, eugenol, p-menthane-3,8-diol, ethylbutyl acetylamino propionate, 1-piperidinecarboxylic acid and 2-(2-hydroxyethyl)- ester 1 -methylpropyl-ester.
- DEET N,N-diethyl-m-toluamide
- DEET dipropyl pyridine-2,5- dicarboxylate
- pyrethrins dimethyl phthalate
- 2,3:4,5-bis(2-butylene)tetrahydrofurfural citronella
- geraniol lemon grass
- the total amount of insect repellent in the composition may be 4-20% by weight based on the total weight of the composition, preferably 4-15% by weight and more preferably 5-10% by weight.
- the composition may include one or more other UV sunscreening agents. These are generally organic compounds which absorb a specific range of UV radiation. Suitable sunscreening agents include octyl methoxycinnamate, oxybenzone, amino benzoic acid, Cinoxate, DEA-methoxycinnamate, Digalloyl, Dioxybenzene, Padimate O, Ethyl dihydroxypropyl p-aminobenzoate, octyl salicylate, glyceryl aminobenzoate, Homosalate, Urocanic acid, isopropylbenzyl salicylate, menthyl anthranilate, octocrylene, Sulisbenzone and its sodium salt and triethanolamine salicylate.
- sunscreening agents include octyl methoxycinnamate, oxybenzone, amino benzoic acid, Cinoxate, DEA-methoxycinnamate, Digalloyl, Dioxybenzene, Padimate O, Ethy
- a combination of octylmethoxycinnamate and oxybenzone is most preferred.
- Each sunscreening agent is preferably incorporated in the composition in an amount of 3-10% by weight based on the total weight of the composition.
- a second aspect of the invention consists in a sunscreen composition further including, by weight, based on the total weight of the composition, 7% in total emulsif ⁇ er, up to 5%, preferably 1-5%, more preferably 3% film former, up to 0.25%, preferably 0.05-0.25%, more preferably 0.15% thickener, up to 0.3%, preferably 0.1-0.3%, more preferably 0.15% neutraliser, up to 0.3%, preferably 0.1-0.3%), more preferably 0.2%) chelating agent and up to 2.5%) of at least one of preservative, perfume and moisturiser.
- emulsifier will depend on the insect repellents and sunscreening agents selected. More than two emulsifiers may be included. An emulsion is most accurately defined as a dispersion of liquid droplets in a second immiscible liquid.
- Dispersions may be formed temporarily through agitation of the two immiscible liquids, however, resolution of the emulsion is usually rapid and complete unless a stabilising additive or emulsifier is used.
- Emulsions usually consist of water or an aqueous solution as one immiscible phase and some organic liquid, or "oil", as the other phase.
- oil When the oil is dispersed in the aqueous phase the emulsion is called oil in water (o/w ) or alternatively, if the aqueous phase is dispersed in the oily phase the emulsion is described as water in oil ( w/o ).
- An emulsifying agent is usually required to stabilise the emulsion.
- Such agents are ordinarily large molecules of which the greatest part of the molecule is non-polar (for solubility in the oil phase ) and a smaller part is polar ( for orientation and solubility into the water phase ).
- compositions of the invention are preferably in the form of an oil in water emulsion.
- An example of a suitable emulsifying system includes fatty acid ethoxylates such as glycerol monostearate, fatty alcohol ethoxylates such as ethoxy (20 ) stearyl alcohol, fatty alcohols such as C ⁇ 6 - ⁇ 8 fatty alcohols, and blends of fatty alcohol ethoxylates with alkyl phenol ethoxylates such as a blend of cetostearyl alcohol and PEG stearate. A wide range of other emulsifiers also appear useful for this purpose.
- the composition optionally includes a film former. The preferred film former is
- the composition may include thickeners, chelating agents and pH adjusting agents as required. These are readily known to the person skilled in the art. Suitable thickeners include acidic acrylates such as carboxyl polymethylene, and cellulose based thickeners such as methyl cellulose, guar gum, sodium alginate and sodium carboxymethyl cellulose. A suitable chelating agent is disodium EDTA. Triethanolamine may be used as a neutraliser as if required.
- perfumes may be included to satisfy organoleptic requirements.
- Preservatives may also be used as required. These are readily known to the person skilled in the art.
- the inventors have found that in preparing an emulsion, the order of addition of ingredients affects the SPF of the final composition.
- a third aspect of the invention consists in a method of manufacturing a sunscreen composition including one or more insect repellents and one or more UV sunscreening agents, the composition being in the form of an emulsion having a water phase and an oil phase characterised in that the water phase and oil phase are prepared and combined to form an emulsion prior to the addition of at least one inorganic compound which is used as a sunscreening agent.
- the invention consists in a method of manufacturing a sunscreen composition including the steps of:
- the invention consists in a sunscreening composition manufactured according to the methods described above. The invention will now be further described with reference to a number of examples.
- a water phase is prepared by adding water to a clean, dry mixing vessel and stirring to create a vortex. Carbopol powder is sprinkled into the vortex and the mixture heated to 75-80°C.
- an oil phase is prepared by adding emulsifiers, film former, mosquito and fly repellent i.e. Cithrol GMS A S, Volpo S20, Crodacol CS70, Polawax GP 200, Antaron WP-660, DEET and MGK-326. The mixture is stirred and heated. When all ingredients have melted, oxybenzone is added. Heating is continued to 75- 80°C until the oxybenzone is melted then octyl methoxycinnamate is added. Stirring is maintained until the mixture is homogenous and clear.
- both the water and the oil phases are at a temperature of 75-80°C
- the oil phase is introduced into the water phase with stirring.
- stirring is stopped and the mixture is homogenised for five minutes.
- Stirring is recommenced and the chelating agent and half of the neutraliser are added followed by the addition of the titanium dioxide. The remaining neutraliser is then added.
- Stirring is stopped and the mixture is homogenised for five minutes.
- Stirring is recommenced with addition of moisturiser, emollient and preservative.
- a zinc oxide inorganic sunscreen agent is used, a different thickening system would be appropriate.
- a cellulose-based thickener such as methyl cellulose, guar gum, sodium alginate and sodium carboxymethyl cellulose could be used, in which case a neutraliser would not be required.
- Formulae 1 and 3 were tested in two ways: A. Determination of sun protection factor (SPF) and B. Broad spectrum test.
- SPF sun protection factor
- B Broad spectrum test.
- the individual sun protection factor, SPF, of a sunscreen product is determined from the minimum erthemal dose (MED) of the skin that has been protected with the sunscreen product and from the MED of an adjacent area of unprotected skin, under specific conditions by means of the following relationship, where the UV source has constant intensity:
- MED for unprotected skin The sun protection factor of a product is calculated as the arithmetical mean of the individual sun protection factors. MED is defined as the amount of energy from any source required to produce a minimally perceptible redness reaction of the skin.
- the MED is determined more precisely by a set of exposures which span a dose range of approximately 0.6 to 1.5 of the MED.
- these doses are administered the day before the product is tested but they may be administered at the same time.
- the result when read not only provides the denominator for calculating the protection factor but, when multiplied by the expected or likely value of the product's protection factor, provides an estimate for the longer exposure needed to assess the product.
- the product is assessed by exposing a set of small subsite areas adjacent to the untreated areas, after application of the product. Times of exposure are selected to bracket the above estimate, when read 16h to 24h later, the MED for the treated skin is divided by the MED for untreated skin to give the protection factor.
- MED minimal erythermal dose SPF over 30 was demonstrated in each case.
- a spectrophotometer capable of determining percentage transmission from 320 -360nm radiation.
- compositions of formulae 1 and 3 did not transmit more than 10% of UV radiation at any wavelength between 320 nm and 360 nm inclusive.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Cosmetics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0000425A GB2345636A (en) | 1999-01-14 | 2000-01-11 | A combined sunscreen and insect repellent containing two or more emulsifiers |
MXPA01007172A MXPA01007172A (en) | 1999-01-14 | 2000-01-11 | A combined insect repellent and sunscreen composition. |
CA002360494A CA2360494C (en) | 1999-01-14 | 2000-01-11 | A combined insect repellent and sunscreen composition |
EP00900269A EP1146849A1 (en) | 1999-01-14 | 2000-01-11 | A combined insect repellent and sunscreen composition |
JP2000593286A JP2002534453A (en) | 1999-01-14 | 2000-01-11 | Insect repellent and sunscreen combination composition |
BR0007497-7A BR0007497A (en) | 1999-01-14 | 2000-01-11 | Combined composition of insect repellent and sunscreen |
AU19932/00A AU770861B2 (en) | 1999-01-14 | 2000-01-11 | A combined insect repellent and sunscreen composition |
US09/889,031 US20030072782A1 (en) | 1999-01-14 | 2001-01-11 | Combined insec repellent and suncreen composition |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9900663.7 | 1999-01-14 | ||
GB9900663 | 1999-01-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000041672A1 true WO2000041672A1 (en) | 2000-07-20 |
Family
ID=10845892
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2000/000068 WO2000041672A1 (en) | 1999-01-14 | 2000-01-11 | A combined insect repellent and sunscreen composition |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP1146849A1 (en) |
JP (1) | JP2002534453A (en) |
CN (1) | CN1172655C (en) |
AR (1) | AR022280A1 (en) |
AU (1) | AU770861B2 (en) |
BR (1) | BR0007497A (en) |
CA (1) | CA2360494C (en) |
GB (1) | GB2345636A (en) |
MX (1) | MXPA01007172A (en) |
WO (1) | WO2000041672A1 (en) |
ZA (1) | ZA200106589B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6436377B1 (en) | 2001-02-26 | 2002-08-20 | Societe L'oreal S.A. | Enhanced SPF sunscreen (sprayable) formulations comprising interpolymers of PVP/dimethiconylacrylate/polycarbamyl/polyglycol ester |
US6436376B1 (en) | 2001-02-26 | 2002-08-20 | Societe L'oreal S.A. | Enhanced SPF UV-sunscreen/tricontanyl PVP photoprotecting (sprayable) formulations |
WO2007093298A1 (en) * | 2006-02-16 | 2007-08-23 | Saltigo Gmbh | Gel formulations for arthropod and plathelminth control |
CN102860960A (en) * | 2012-09-22 | 2013-01-09 | 南京正亮医药科技有限公司 | Insect repelling emulsifiable paste |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MXPA05008479A (en) | 2003-02-12 | 2006-03-10 | Connetics Australia Pty Ltd | Film foaming hydroalcoholic foam. |
US8512721B2 (en) * | 2004-11-19 | 2013-08-20 | Illinois Tool Works Inc. | Water resistant sunscreen and insect repellant towel |
CN101215782B (en) * | 2008-01-08 | 2010-06-09 | 上海大学 | Light ageing resisting finishing method for aromatic polyamide fabric |
US8580861B2 (en) | 2008-08-15 | 2013-11-12 | Pibed Limited | Chemical composition for skin care formulations |
US8362077B2 (en) * | 2008-08-15 | 2013-01-29 | Pibed Limited | Chemical compositions for skin care emulsions and heavy duty hand cleansers |
BRPI0914444B1 (en) * | 2008-10-22 | 2017-03-28 | Dow Global Technologies Llc | sunscreen composition comprising methyl cellulose and method for increasing the fps of a sunscreen composition |
CN101779627A (en) * | 2009-01-16 | 2010-07-21 | 岑绍辉 | Invisible mosquito-prevention mosquito-repellent combination |
CN103356410A (en) * | 2012-03-29 | 2013-10-23 | 威玛精密化学科技股份有限公司 | Catalpa extract component with anti-mosquito and sun-protection effects |
BR112015001664A2 (en) * | 2012-07-26 | 2017-07-04 | Riemann Trading Aps | improved sunscreen composition |
CN105708863A (en) * | 2016-03-21 | 2016-06-29 | 江南大学 | Composition capable of achieving sun protection and preventing infection of mosquito-borne viruses such as Zika virus |
MY199207A (en) * | 2016-07-15 | 2023-10-19 | Lec Kk | Pest repellent composition, and method for repelling pests |
CN109769538A (en) * | 2019-03-08 | 2019-05-21 | 珠海市润农科技有限公司 | Utilize the method for photosynthetic film prevention and control balsam pear drosophila high in fat |
CN110638675A (en) * | 2019-09-17 | 2020-01-03 | 江西农业大学 | Terpenoid repellent R2 microemulsion and preparation method thereof |
CN110934780B (en) * | 2019-12-31 | 2021-07-27 | 威莱(广州)日用品有限公司 | Health care bath foam for pet dogs and preparation method thereof |
CN112618434A (en) * | 2020-12-29 | 2021-04-09 | 广东岭南职业技术学院 | Mosquito-repelling sunscreen cream and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0859447A (en) * | 1994-08-12 | 1996-03-05 | Kanebo Ltd | Skin protective agent |
WO1997049380A1 (en) * | 1996-06-26 | 1997-12-31 | S.C. Johnson & Son, Inc. | Insect repellent sunscreen |
JPH10182344A (en) * | 1996-12-26 | 1998-07-07 | Kose Corp | Oil-in-water type skin lotion |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5518712A (en) * | 1992-06-25 | 1996-05-21 | Stewart; Ernest | Water resistant sunscreen protection and insect repellent compound |
US5916541A (en) * | 1992-06-25 | 1999-06-29 | Stewart; Ernest G. | Water resistant sunscreen and insect repellent composition |
GB2279007B (en) * | 1993-06-11 | 1997-04-02 | Tioxide Specialties Ltd | Compositions containing sunscreens |
JPH08183720A (en) * | 1994-12-28 | 1996-07-16 | Kose Corp | Skin external medicine |
DE69632255T3 (en) * | 1995-06-08 | 2010-05-20 | Johnson & Johnson Consumer Companies, Inc. | SUNSCREEN |
-
2000
- 2000-01-11 WO PCT/GB2000/000068 patent/WO2000041672A1/en active IP Right Grant
- 2000-01-11 MX MXPA01007172A patent/MXPA01007172A/en unknown
- 2000-01-11 BR BR0007497-7A patent/BR0007497A/en not_active IP Right Cessation
- 2000-01-11 JP JP2000593286A patent/JP2002534453A/en active Pending
- 2000-01-11 EP EP00900269A patent/EP1146849A1/en not_active Withdrawn
- 2000-01-11 CN CNB008027765A patent/CN1172655C/en not_active Expired - Fee Related
- 2000-01-11 CA CA002360494A patent/CA2360494C/en not_active Expired - Fee Related
- 2000-01-11 AU AU19932/00A patent/AU770861B2/en not_active Ceased
- 2000-01-11 GB GB0000425A patent/GB2345636A/en not_active Withdrawn
- 2000-01-13 AR ARP000100151 patent/AR022280A1/en unknown
-
2001
- 2001-08-10 ZA ZA200106589A patent/ZA200106589B/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0859447A (en) * | 1994-08-12 | 1996-03-05 | Kanebo Ltd | Skin protective agent |
WO1997049380A1 (en) * | 1996-06-26 | 1997-12-31 | S.C. Johnson & Son, Inc. | Insect repellent sunscreen |
JPH10182344A (en) * | 1996-12-26 | 1998-07-07 | Kose Corp | Oil-in-water type skin lotion |
Non-Patent Citations (2)
Title |
---|
CHEMICAL ABSTRACTS, vol. 125, no. 2, 8 July 1996, Columbus, Ohio, US; abstract no. 18703, KURODA, AKIHIRO ET AL: "Topical agents containing silicones and UV protectors and/or insect repellents for skin protection" XP002132250 * |
DATABASE CHEMABS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; INAKAWA, TAKASHI: "Oil-in-water skin cosmetics containing insect repellents and UV scattering agents", XP002132251, retrieved from STN Database accession no. 129:85847 CA * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6436377B1 (en) | 2001-02-26 | 2002-08-20 | Societe L'oreal S.A. | Enhanced SPF sunscreen (sprayable) formulations comprising interpolymers of PVP/dimethiconylacrylate/polycarbamyl/polyglycol ester |
US6436376B1 (en) | 2001-02-26 | 2002-08-20 | Societe L'oreal S.A. | Enhanced SPF UV-sunscreen/tricontanyl PVP photoprotecting (sprayable) formulations |
WO2007093298A1 (en) * | 2006-02-16 | 2007-08-23 | Saltigo Gmbh | Gel formulations for arthropod and plathelminth control |
CN102860960A (en) * | 2012-09-22 | 2013-01-09 | 南京正亮医药科技有限公司 | Insect repelling emulsifiable paste |
Also Published As
Publication number | Publication date |
---|---|
AU770861B2 (en) | 2004-03-04 |
BR0007497A (en) | 2001-10-23 |
AR022280A1 (en) | 2002-09-04 |
GB0000425D0 (en) | 2000-03-01 |
CA2360494A1 (en) | 2000-07-20 |
ZA200106589B (en) | 2002-08-12 |
CN1172655C (en) | 2004-10-27 |
JP2002534453A (en) | 2002-10-15 |
CN1336816A (en) | 2002-02-20 |
MXPA01007172A (en) | 2002-07-30 |
EP1146849A1 (en) | 2001-10-24 |
AU1993200A (en) | 2000-08-01 |
CA2360494C (en) | 2007-10-23 |
GB2345636A (en) | 2000-07-19 |
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