WO2000037576A1 - Composicion de pintura curable por radiacion ultravioleta y proceso para su aplicacion en substratos de vidrio - Google Patents
Composicion de pintura curable por radiacion ultravioleta y proceso para su aplicacion en substratos de vidrio Download PDFInfo
- Publication number
- WO2000037576A1 WO2000037576A1 PCT/MX1999/000038 MX9900038W WO0037576A1 WO 2000037576 A1 WO2000037576 A1 WO 2000037576A1 MX 9900038 W MX9900038 W MX 9900038W WO 0037576 A1 WO0037576 A1 WO 0037576A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- paint composition
- composition
- paint
- ultraviolet radiation
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/34—Printing on other surfaces than ordinary paper on glass or ceramic surfaces
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
Definitions
- the present invention relates to an organic paint composition for glass substrates and a process for its application and, more specifically, to an organic paint composition of the type that is curable by ultraviolet radiation, for printing labels, designs, or any Other decoration in glass bottles.
- paint compositions such as copper, silver, cadmium, chromium, manganese, etc.
- paint compositions are described in United States of America Patents No. 3,957,694; 3,968,056 and 3,989,644 all of Bolón and others, mainly suitable for screen printing on printed circuits.
- organic compositions pigmented or not, which are applied and cured by ultraviolet infrared radiation, for the most diverse purposes such as providing privacy, solar radiation control, abrasion resistance, etc., examples of such organic compositions are described in the patents of
- U.S. Patent No. 5,731,359 to Kamen et al. Discloses a pigmented paint composition that includes a radiation curable component and a pyrrolopyrrole or isoindoline pigment.
- an ultraviolet radiation curable organic paint composition comprising 80% to 95% by weight of a paint based on an epoxy polyurethane; 0.5% to 8% by weight of an additive that includes a mixture of polyethylene waxes and waxes
- polytetrafluoroethylene 1% to 7% by weight of an additive that improves water resistance, prepared from a low and intermediate molecular weight polyamide, which is recommended to be added just before applying the prepared paint composition, because this composition, once ready, lasts at most 8 hours; and an adhesion promoter that can be added to the paint formula or used as a sizing to be applied to the substrate
- glass before decoration which includes a silane in a concentration of 0.15% to 3% by weight, which, among others: is specifically suitable for glass substrates; it has a desired resistance to washing, before and after the filling process, as well as an appropriate resistance to abrasion and rough handling which the non-retainable glass bottles are subjected; can be burned in an oven when glass bottles
- Decorated with this composition they are redone as "cullet” in a molten glass mass, without affecting the properties of the glass mass, because it does not contain toxic metals such as lead, cadmium, hexavalent chromium, etc .; it is environmentally appropriate because it does not generate harmful flue gases or hot household gases; it reduces the consumption of paint because it has a specific gravity that is approximately four times less heavy than the vitrifiable ceramic paints that have been commonly used for decorating glass bottles; it provides greater performance per unit of weight and saves energy and space because it does not need large furnaces to heat the paint; provides more intense and bright colors and a wider range of colors than ceramic paints;
- a process for the preparation and application of the ultraviolet radiation curable organic paint composition comprising: a) preparing an ultraviolet radiation curable paint composition, mixing 80% to 95% by weight of an epoxy-polyurethane-based paint composition; and 0.5% to 8% by weight of an additive prepared from a
- an ultraviolet radiation curable organic paint composition of the nature discussed above, that reduces paint consumption because it has a specific gravity that is approximately four times less heavy than vitrifiable ceramic paints that have been commonly used for decorating glass bottles, providing
- UV curable paint comprising: a UV curable paint composition, which includes 80 to 95% by weight of an epoxy-polyurethane-based paint; and 0.5 to 8% by weight of an additive that includes a mixture of polyethylene waxes and polytetrafluoroethylene waxes; 1% to 7% by weight of an additive that improves water resistance,
- this comprises: a) prepare a radiation curable paint composition
- ultraviolet which includes mixing 80% to 95% by weight of a paint based on
- composition once prepared, lasts at most 8 hours; c) add an adhesion promoter sizing composition, which
- a lubricating agent that includes an oleic acid-based product, such as a gas or vapor, and spraying an aqueous emulsion of an ethoxylated polyethylene derivative, onto a portion of the glass substrate that includes the
- the adhesion promoter sizing composition it is convenient to separately prepare the adhesion promoter sizing composition, adding 70% to 97% by weight of demineralized water and 0% to 19.4% by weight of ethyl alcohol and 0.15% to 3% of a silane, by stirring, and apply it as
- Said epoxy-polyurethane-based paint can be selected in different colors, when the color red is desired, it is selected from the
- Graftol 210 brand Network 2000 CD-JC-2455; Red Rubine CD-155; Intensive Red CD-141; Heat-Red CD-180, all from Sericol, Inc.
- the white color is selected from the titanium dioxide family, specifically that sold under the Opaque White CD-311 specifications, also from Sericol, Inc.
- the additive that includes the mixture of polyethylene waxes and polytetraphlorethylene waxes known as "PTFE" are selected from those sold as Polifluo XF-523 from the company Micropowders, Corp., Series
- the waterproof agent produced from low polyamide and intermediate molecular weight, is selected from the sold as Kaeropox, and "Water Resist Agent” from Sericol, Inc.
- the adhesion promoter size is selected from those sold as Z-6011, Z-6032, both from Dow Corning, 1100 from Witco, or the like, or a mixture thereof.
- the lubricating agent that includes a product based on
- oleic acid is selected from the sold as AP-5 of US-CAN.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
- Surface Treatment Of Glass (AREA)
- Polyurethanes Or Polyureas (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE69935808T DE69935808T2 (de) | 1998-12-22 | 1999-12-14 | Uv-polymerisierbare anstrichzusammensetzung und verfahren zu ihrer anwendung auf glasssubstraten |
MXNL01000018 MX246886B (en) | 1998-12-22 | 1999-12-14 | Ultraviolet radiation curable ink composition and a process for its application on glass substrates |
EP99961494A EP1153994B1 (en) | 1998-12-22 | 1999-12-14 | Uv-curable paint composition and process for its application to glass substrates |
CA002353983A CA2353983C (en) | 1998-12-22 | 1999-12-14 | An ultra-violet radiation curable ink composition and a process for its application on glass substrates |
HK02103261.4A HK1043380B (zh) | 1998-12-22 | 2002-04-30 | 紫外線固化的油漆組合物及其在玻璃底物中用的方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US21887898A | 1998-12-22 | 1998-12-22 | |
US09/218,878 | 1998-12-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000037576A1 true WO2000037576A1 (es) | 2000-06-29 |
Family
ID=22816863
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/MX1999/000038 WO2000037576A1 (es) | 1998-12-22 | 1999-12-14 | Composicion de pintura curable por radiacion ultravioleta y proceso para su aplicacion en substratos de vidrio |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP1153994B1 (es) |
AT (1) | ATE359335T1 (es) |
CA (1) | CA2353983C (es) |
CR (1) | CR6140A (es) |
DE (1) | DE69935808T2 (es) |
ES (1) | ES2285868T3 (es) |
GT (1) | GT199900234A (es) |
HK (1) | HK1043380B (es) |
MX (1) | MX246886B (es) |
PE (1) | PE20001572A1 (es) |
PT (1) | PT1153994E (es) |
WO (1) | WO2000037576A1 (es) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003054094A1 (es) * | 2001-08-09 | 2003-07-03 | Vitro Europa, Ltd. | Composicion de pintura curable por radiacion ultravioleta y proceso para su aplicacion en substratos de vidrio |
CN112063284A (zh) * | 2020-08-24 | 2020-12-11 | 安徽未来表面技术有限公司 | 一种水性聚氨酯复合涂料及其制备方法 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105542556A (zh) * | 2016-01-29 | 2016-05-04 | 佛山市聚成生化技术研发有限公司 | 一种光固化网孔版油墨及其制备方法 |
ES2705088B2 (es) | 2017-09-20 | 2020-03-30 | Liderkit S L | Nuevo gel-coat aditivado con particulas de dioxido de titanio y alumina |
FR3084663B1 (fr) * | 2018-07-31 | 2020-07-17 | Saint-Gobain Glass France | Procede et installation de primage de vitrage par tampographie mettant en oeuvre un solvant a base d'eau. |
US10752538B1 (en) | 2019-03-06 | 2020-08-25 | Owens-Brockway Glass Container Inc. | Three-dimensional printing on glass containers |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0604815A2 (en) * | 1992-12-30 | 1994-07-06 | Cerdec Aktiengesellschaft Keramische Farben | Thermoplastic/thermoset coatings or inks for glass, ceramic and other hard surfaces |
JPH0848923A (ja) * | 1994-08-08 | 1996-02-20 | Sakura Color Prod Corp | 紫外線硬化型インキ組成物およびこれを用いる無機材料の印刷方法 |
WO1998052700A1 (en) * | 1997-05-23 | 1998-11-26 | Revlon Consumer Products Corporation | Method and compositions for decorating glass |
-
1999
- 1999-12-14 CA CA002353983A patent/CA2353983C/en not_active Expired - Lifetime
- 1999-12-14 EP EP99961494A patent/EP1153994B1/en not_active Expired - Lifetime
- 1999-12-14 MX MXNL01000018 patent/MX246886B/es active IP Right Grant
- 1999-12-14 ES ES99961494T patent/ES2285868T3/es not_active Expired - Lifetime
- 1999-12-14 PT PT99961494T patent/PT1153994E/pt unknown
- 1999-12-14 WO PCT/MX1999/000038 patent/WO2000037576A1/es active IP Right Grant
- 1999-12-14 DE DE69935808T patent/DE69935808T2/de not_active Expired - Lifetime
- 1999-12-14 AT AT99961494T patent/ATE359335T1/de active
- 1999-12-21 PE PE1999001303A patent/PE20001572A1/es not_active IP Right Cessation
- 1999-12-22 GT GT199900234A patent/GT199900234A/es unknown
- 1999-12-22 CR CR6140A patent/CR6140A/xx not_active Application Discontinuation
-
2002
- 2002-04-30 HK HK02103261.4A patent/HK1043380B/zh not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0604815A2 (en) * | 1992-12-30 | 1994-07-06 | Cerdec Aktiengesellschaft Keramische Farben | Thermoplastic/thermoset coatings or inks for glass, ceramic and other hard surfaces |
JPH0848923A (ja) * | 1994-08-08 | 1996-02-20 | Sakura Color Prod Corp | 紫外線硬化型インキ組成物およびこれを用いる無機材料の印刷方法 |
WO1998052700A1 (en) * | 1997-05-23 | 1998-11-26 | Revlon Consumer Products Corporation | Method and compositions for decorating glass |
Non-Patent Citations (1)
Title |
---|
DATABASE HCAPLUS EN STN. [online] 20 February 1996 (1996-02-20), SAKURA COLOR PROD. CORP, XP002946787, Database accession no. 1996:321209 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003054094A1 (es) * | 2001-08-09 | 2003-07-03 | Vitro Europa, Ltd. | Composicion de pintura curable por radiacion ultravioleta y proceso para su aplicacion en substratos de vidrio |
JP2005525435A (ja) * | 2001-08-09 | 2005-08-25 | ヴィトロ ヨーロッパ リミテッド | 紫外線硬化可能なインク組成物及びガラス基材上への前記組成物を施用する方法 |
JP4903364B2 (ja) * | 2001-08-09 | 2012-03-28 | ヴィトロ ヨーロッパ リミテッド | 紫外線硬化可能なインク組成物及びガラス基材上への前記組成物を施用する方法 |
CN112063284A (zh) * | 2020-08-24 | 2020-12-11 | 安徽未来表面技术有限公司 | 一种水性聚氨酯复合涂料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
ATE359335T1 (de) | 2007-05-15 |
CA2353983A1 (en) | 2000-06-29 |
PE20001572A1 (es) | 2001-01-24 |
HK1043380A1 (en) | 2002-09-13 |
DE69935808D1 (de) | 2007-05-24 |
PT1153994E (pt) | 2007-06-01 |
GT199900234A (es) | 2006-10-25 |
HK1043380B (zh) | 2007-11-30 |
EP1153994B1 (en) | 2007-04-11 |
MXNL01000018A (es) | 2002-08-09 |
ES2285868T3 (es) | 2007-11-16 |
CA2353983C (en) | 2009-03-17 |
MX246886B (en) | 2007-06-12 |
CR6140A (es) | 2008-04-28 |
EP1153994A1 (en) | 2001-11-14 |
DE69935808T2 (de) | 2007-12-06 |
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