WO2000031229A1 - Composition detergente - Google Patents

Composition detergente Download PDF

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Publication number
WO2000031229A1
WO2000031229A1 PCT/JP1999/006335 JP9906335W WO0031229A1 WO 2000031229 A1 WO2000031229 A1 WO 2000031229A1 JP 9906335 W JP9906335 W JP 9906335W WO 0031229 A1 WO0031229 A1 WO 0031229A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
composition
component
parts
bleacher
Prior art date
Application number
PCT/JP1999/006335
Other languages
English (en)
Inventor
Nobuyuki Ogura
Yumi Kubono
Akira Suzuki
Original Assignee
Kao Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=18274759&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2000031229(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Kao Corporation filed Critical Kao Corporation
Publication of WO2000031229A1 publication Critical patent/WO2000031229A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2048—Dihydric alcohols branched
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents

Definitions

  • the present invention relates to a detergent composition and a bleacher composition having an excellent generation of a sweet smell.
  • a perfume composition is compounded with a detergent composition or a bleacher composition in view of a liking therefor (refer, for example, to JP-A 3-115399 and JP-A 60-23498).
  • Water-insoluble solvents or fixatives such as benzyl benzoate and diethyl phthalate are used in the perfume composition for the purpose of adjusting the sustaining property of perfume components .
  • An object of the present invention is to provide a detergent composition and a bleacher composition having an improved generation of a sweet smell.
  • the present invention provides a surfactant composition, such as detergent composition, comprising 0.1 to 60% by weight of a surfactant, a perfume component (a) having a vapor pressure
  • the present invention further provides to an another surfactant composition, such as bleacher composition, comprising 0.1 to 80% by weight of a bleacher, 0.1 to 60% by weight of a surfactant, a perfume component (a) having a vapor pressure
  • an another surfactant composition such as bleacher composition, comprising 0.1 to 80% by weight of a bleacher, 0.1 to 60% by weight of a surfactant, a perfume component (a) having a vapor pressure
  • the amount of the components (a), (b) and (c) is preferably 0.001 to 10% by weight and more preferably 0.005 to 5% by weight.
  • composition of the present invention is suitable for the use such as laundry of clothing, washing of tableware, washing of the surface of architectures or house materials such as bathtub, floor, furniture and wall and bleacher of clothing-product .
  • perfume components which have been known are those mentioned at line 4 from the bottom of page 42 to line 24 of page 45 in "Collection of Well-known Prior Arts (Powdered Detergent for Clothing) " (published as “Patent Office Gazette 10 (1998) - 25 [7159] on March 26th, 1998” in Patent Office in Japan) and those mentioned in “Industrial Chemistry Series - Chemistry of Perfumes” (written by Ryoichi Akaboshi, edited by the Chemical Society of Japan, published by Dainippon Tosho KK on September 16th, 1983) , while the perfume component of the present invention comprises a perfume component (a) having a vapor pressure of 6.67 Pa or more,
  • the ratio by weight of the component (a) to the component (b) is 0 to 6 , preferably 0 to 2 and particularly preferably 0.001 to 6 or 0.001 to 1.
  • component (a) may be cited orange pera, o- tert-butylcyclohexyl acetate, d-limonene, linalool, tetrahydrolinalool , tetrahydrogeraniol , terpineol, iso- bornyl acetate and tetrahydromuguol .
  • the component (b) may be mentioned citronellol, geraniol, methylionone, phenylethyl alcohol, p- tert-butylcyclohexyl acetate, allylcyclohexane propionate, tricyclodecenyl propionate, tricyclodecenyl acetate and hexylcinnamic aldehyde.
  • the total amount of the components (a) and (b) may depend upon the use, shape, etc. of the composition but the amount in the composition is preferably 0.01 to 5% by weight and particularly preferably 0.01 to 2% by weight.
  • the component (c) may be at least one compound selected from 2 -methyl -2 , 4 -dihydroxybutane, 2 -methyl -2 , 4 - dihydroxypentane, 2,4-dihydroxybutane, dipropylene glycol and tripropylene glycol and, when these compounds are used as a fixative, the sustaining property of the perfume components, particularly the middle note and generation of sweet smell derived from the component (b) , is improved.
  • dipropylene glycol is particularly preferred.
  • the component (c) is used in such an amount that the ratio by weight of the component (c) to the total amount of the components (a) and (b) is 0.01 to 2, preferably 0.1 to 1, and particularly preferably 0.1 to 0.5.
  • the present invention is applicable to a composition which is used for various treatments such as washing and bleaching wherein the perfumes greatly contribute to the liking of the product.
  • ⁇ Detergent Composition a composition which is used for various treatments such as washing and bleaching wherein the perfumes greatly contribute to the liking of the product.
  • the detergent composition of the present invention may refer to "Dictionary of Detergents and Washing" (edited by Haruhiko Okuyama and Motoi Minakawa, published by Asakura Shoten) and may be applied to detergent compositions for clothing where the perfume greatly contributes to the liking of the product.
  • the detergent composition of the present invention comprises 0.1 to 60% by weight and preferably 1 to 50% by weight of surfactant.
  • Anionic, nonionic, cationic and amphoteric surfactants may be used as the surfactant.
  • anionic surfactant may be mentioned higher alcohol sulfate salts, ethoxylated higher alcohol sulfate salts, alkylbenzene sulfonates, paraffin sulfonates, fatty acid salts, Ot, -olefinsulfonates , 0: - sulfofatty acid salts and ⁇ - sulfofatty acid alkyl ester salts.
  • Linear alkylbenzene sulfonates having C ⁇ . ⁇ alkyl chain and sulfate
  • the compounding amount of the anionic surfactant is preferably
  • nonionic surfactant may be cited adducts of alcohol having 10 to 16 carbon atoms with alkylene oxide, fatty acid alkanolamides and alkyl polyglycosides .
  • Polyoxyalkylene alkyl ethers having alkyl chain are particularly preferred in view of detergency to sebum dirt and resistance to hard water.
  • An average number of moles of ethylene oxide added thereto is preferably 5 to 15.
  • the compounding amount of the nonionic surfactant is preferably 1 to 50% by weight and particularly preferably 1 to 40% by weight.
  • the content ratio of the anionic surfactant to the nonionic surfactant is preferably from 100/0 to 40/60 (ratio by weight), more preferably from 95/5 to 50/50 and particularly preferably from 95/5 to 60/40, in view of the solubility and detergency.
  • the detergent composition of the present invention may further comprise 5 to 60% by weight and preferably 20 to 60% by weight of a builder.
  • a builder such as crystalline aluminosilicate, amorphous aluminosilicate, crystalline silicate, and carbonate and an organic builder such as nitrilotriacetate, ethylenediaminetetraacetate, tartrate, citrate and acrylic acid (co)polymer
  • an organic builder such as nitrilotriacetate, ethylenediaminetetraacetate, tartrate, citrate and acrylic acid (co)polymer
  • antidesperitioning agent such as carboxymethyl cellulose
  • enzyme reductant such as sulfite
  • fluorescent whitening agent fluorescent whitening agent
  • anti-foaming agent such as silicone.
  • Preferred builders are crystalline silicate and carbonate.
  • the builder composition comprises preferably in an amount of 40 to 94.9% by weight of water.
  • the bleacher composition of the present invention comprises 0.1 to 80% by weight, preferably 10 to 70% by weight and more preferably 30 to 70% by weight of a bleacher.
  • a bleacher may be cited percarbonate, perborate, persulfate, organic peracid and hydrogen peroxide as well as hypochlorite which is a chlorine type.
  • sodium percarbonate, sodium perborate and hydrogen peroxide are preferred for clothing, for example.
  • a bleaching activator is used together with the bleacher, more excellent bleaching effect can be obtained .
  • the bleaching activator may be cited a bleaching agent of a metal type and a bleaching agent which generates an organic peracid and which includes carboxylate or amide.
  • the bleacher composition it is appropriate to select, for example, a perfume component having no unsaturated bond.
  • the bleacher composition of the present invention may comprise the above-mentioned surfactant in the above-mentioned amount, the above-mentioned builder and also publicly known bleacher component .
  • compositions examples include powder, granule, liquid, briquette, tablet, sheet and rod.
  • a container where easy use, stability, etc. are taken into consideration is used and it is particularly preferred to select a container which has little influence by light to the component (a) and/or the component (b) .
  • the slurry was spray-dried in a counter-flow spray drier (volatile content of 6%).
  • the spray-dried product thereof in an amount of 80.5 parts by weight was firstly mixed with 2 parts by weight of crystalline aluminosilicate (zeolite A having 4 A pore- diameter , average particle size of 2.7 ⁇ ) and then poured into a high-speed mixer
  • composition B A powdered detergent composition (Composition B)
  • Powdered detergent compositions as shown in Table 2 were prepared. Then 50 ml of each of the compositions filled in a 100-cc screw tube made of glass, which was then tightly closed and allowed to stand at 20°C for 1 hour, the cover was opened and, after 30 seconds, the generation of sweet smell was evaluated by trained panelists. The results were that Invention Products 1, 3 and 5 had good generation of the sweet smell as compared with Comparative Product 1. A particularly excellent generation of sweet smell was noted in Invention Product 1. Invention Products 2 and 4 of the present invention showed a good generation of the sweet smell as compared with Comparative Product 2.
  • Liquid detergent compositions C to H comprising the components shown in Tables 3 and 4 were prepared.
  • the figures 1 and 2 after the alphabets in the tables stand for the product of the present invention and the comparative product, respectively.
  • Nonionic surfactant A Adduct of primary alcohol having 10 to 14 carbon atoms with 5 moles of EO, 2 moles of propylene oxide and 3 moles of EO (a block adduct)
  • Nonionic surfactant B Adduct of secondary alcohol having 10 to 14 carbon atoms with 7 moles of EO
  • Nonionic surfactant C Adduct of primary alcohol having 12 carbon atoms with 8 moles of EO
  • Nonionic surfactant D Adduct of primary alcohol having 12 carbon atoms with 11.5 moles of EO
  • Nonionic surfactant E Alkyl (having 12 carbon atoms) polyglucoside (average polymerization degree: 1.5)
  • AM/isoBT copolymer Copolymer of maleic acid with diisobutylene (50/50) (average molecular weight of 10, 000)
  • composition I A powdered bleacher composition comprising 60% by weight of sodium percarbonate, 30% by weight of sodium carbonate (dense ash) and 10% by weight of granulated bleaching activator was prepared.
  • the granulated bleaching activator was prepared as follows.
  • the mixture was granulated by extruding it from a punching metal screen of pore diameter of 0.8 mm using an extruding granulator (Pelletter Double EDX-100, manufactured by F ji Powder) .
  • the obtained extruded product was cooled by a shaking cooler (Vibro/Flow Drier VDF/6000; manufactured by Fuji Powder) and disintegrated by an arranging granulator (Knife Cutter FL- 200, manufactured by Fukae Kogo K.K) .
  • the obtained granules were classified whereupon granules of average particle size of 900 ⁇ m were prepared.
  • Composition I was compounded with the perfume C of Table 1 and dipropylene glycol so as to make their amounts 0.1% by weight and 0.05% by weight, respectively to obtain a bleacher composition (Invention Product I) .
  • a bleacher composition Comparative Product I compounded with the perfume C and diethyl phthalate so as to make their amount
  • a liquid bleacher composition (Composition J) was obtained using 5% by weight of hydrogen peroxide, 5% by weight of nonionic surfactant (an adduct of higher alcohol comprising 98% or more of lauryl alcohol with 10 moles of EO) , 1% by weight of dodecyltrimethylammonium methylsulfate, 1% by weight of sodium lauroyloxybenzenesulfonate, 0.5% by weight of a chelating agent (Diquest 2010 manufactured by Monsanto) and water as balance.
  • nonionic surfactant an adduct of higher alcohol comprising 98% or more of lauryl alcohol with 10 moles of EO
  • dodecyltrimethylammonium methylsulfate 1% by weight of sodium lauroyloxybenzenesulfonate
  • a chelating agent Disiquest 2010 manufactured by Monsanto
  • Composition J was compounded with the perfume D of Table

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne une composition détergente et une composition de blanchiment dans lesquelles la production d'odeur agréable se trouve améliorée. La composition détergente comprend un tensioactif, un composant de parfum (a) présentant une pression de vapeur de 6,67 Pa ou plus à 25 °C, un composant de parfum (b) présentant une pression de vapeur comprise entre 0,67 Pa et moins de 6,67 Pa à 25 °C et au moins un composé (c) choisi dans le groupe constitué de 2-méthyl-2, 4-dihydroxybutane, 2-méthyl-2,4-dihydroxypentane, 2,4-dihydroxybutane, dipropylène-glycol and tripropylène-glycol dans une proportion en poids spécifique.
PCT/JP1999/006335 1998-11-25 1999-11-12 Composition detergente WO2000031229A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP10/334208 1998-11-25
JP10334208A JP3128545B2 (ja) 1998-11-25 1998-11-25 洗浄剤組成物

Publications (1)

Publication Number Publication Date
WO2000031229A1 true WO2000031229A1 (fr) 2000-06-02

Family

ID=18274759

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1999/006335 WO2000031229A1 (fr) 1998-11-25 1999-11-12 Composition detergente

Country Status (2)

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JP (1) JP3128545B2 (fr)
WO (1) WO2000031229A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4101585B2 (ja) * 2002-08-14 2008-06-18 花王株式会社 洗濯前処理用組成物
JP5946720B2 (ja) * 2012-08-20 2016-07-06 花王株式会社 繊維製品用液体洗浄剤組成物

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4663068A (en) * 1983-12-22 1987-05-05 Lever Brothers Company Bleach-stable deodorant perfumes in detergent powders
JPS63101496A (ja) * 1986-10-17 1988-05-06 花王株式会社 高密度粒状濃縮洗剤組成物
EP0572080A1 (fr) * 1992-05-29 1993-12-01 Quest International B.V. Microémulsions aqueuses de parfums
WO1995015186A1 (fr) * 1993-11-30 1995-06-08 Quest International B.V. Compositions et parfums antifumee
US5952292A (en) * 1997-12-08 1999-09-14 Firmenich S.A. Utilization of 3-methyl-2-oxo-ethyl-pentanoate as a perfuming ingredient
US5955093A (en) * 1997-06-09 1999-09-21 The Procter & Gamble Company Uncomplexed cyclodextrin compositions for odor control

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4663068A (en) * 1983-12-22 1987-05-05 Lever Brothers Company Bleach-stable deodorant perfumes in detergent powders
JPS63101496A (ja) * 1986-10-17 1988-05-06 花王株式会社 高密度粒状濃縮洗剤組成物
EP0572080A1 (fr) * 1992-05-29 1993-12-01 Quest International B.V. Microémulsions aqueuses de parfums
WO1995015186A1 (fr) * 1993-11-30 1995-06-08 Quest International B.V. Compositions et parfums antifumee
US5955093A (en) * 1997-06-09 1999-09-21 The Procter & Gamble Company Uncomplexed cyclodextrin compositions for odor control
US5952292A (en) * 1997-12-08 1999-09-14 Firmenich S.A. Utilization of 3-methyl-2-oxo-ethyl-pentanoate as a perfuming ingredient

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Derwent World Patents Index; AN 1988-266477, XP002127990 *

Also Published As

Publication number Publication date
JP2000160193A (ja) 2000-06-13
JP3128545B2 (ja) 2001-01-29

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