WO2000007945A1 - Procede de traitement d'eaux mineralisees - Google Patents
Procede de traitement d'eaux mineralisees Download PDFInfo
- Publication number
- WO2000007945A1 WO2000007945A1 PCT/RU1999/000178 RU9900178W WO0007945A1 WO 2000007945 A1 WO2000007945 A1 WO 2000007945A1 RU 9900178 W RU9900178 W RU 9900178W WO 0007945 A1 WO0007945 A1 WO 0007945A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water
- ratio
- concentration
- processing
- crystallisation
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/12—Halogens or halogen-containing compounds
Definitions
- the original source is softened with the allocation of the vehicle ⁇ altsiya, ⁇ s ⁇ a ⁇ chny ⁇ as ⁇ v ⁇ ⁇ ntsen ⁇ i ⁇ uyu ⁇ vy ⁇ a ⁇ ivaniem with allocation sul ⁇ a ⁇ a na ⁇ iya, ⁇ s ⁇ a ⁇ chny ⁇ as ⁇ v ⁇ ⁇ sle vy ⁇ a ⁇ ivaniya zasalivayu ⁇ d ⁇ s ⁇ n ⁇ sheniya sul ⁇ a ⁇ v ⁇ l ⁇ id ⁇ v and 1: 3 and ⁇ ntsen ⁇ atsii ⁇ l ⁇ ida na ⁇ iya 18- 21% ⁇ is ⁇ allizuyu ⁇ de ⁇ agid ⁇ a ⁇ sul ⁇ a ⁇ a na ⁇ iya ⁇ lazhdeniem, vy ⁇ a ⁇ ivayu ⁇ ma ⁇ chny ⁇ as ⁇ v ⁇ d ⁇ su ⁇ g ⁇ ⁇
- This method for all stages allows the separation of salts from high concentration products with a total of 200-240 g / l.
- a good concentration of a solid sulfate product can be achieved only with the use of embedding, which is implemented in this way.
- the concentration of sodium hydroxide is allocated to the stages of maximum total salvage, when the percentage of saline is in the range of 3–6%. This is due to the fact that the resulting health care results in a significant number of hardships and requires a subsequent payment. Otherwise, when the percentage of chlorides and sulphides is less than 1: 6, the entire resulting acid chloride will result in salting of the required system.
- the implementation of the process of installation at lower interest rates and incentives of accidents and sulphides is not more than 1: 20.
- the business phase may include the removal of heavy metals, as well as the removal of calcium.
- caustic is added to the flocculant with poliakrilamide, and, in addition, it is a matter of between 9 and 9
- the proposed method may include the removal of magnesium hardness. It does not delete from the rest of the products after the installation and centralization of the direct conversion to the cycle of processing. For this, add the soda ash and flocculant type polylactamide to the product, open until 13-14. The concentration of magnesium ions in the economy after the stage of installation and centralization is reached at its maximum value. Therefore, the release of magnesium hydroxide is the most advantageous at this point, t. ⁇ . It allows you to save time for its precipitation, especially when the concentration of magnesium ions in the source is small.
- the indicated range of values of the general bodyguard allows you to use the method of concentrating the concentrate for the purpose of concentrating. Whereas this process is applied and the working pressure is from 1.5 to 4.0% and the specified law of affection means that the increase in the rate of sulphide is reduced by at least 2.5, This is explained by the fact that, in the case of working in the case of refrigerant - ions, which occurred in the past, we had much better luck. For mildly disproportionate water with a difference of less than 1: 6 in terms of health and other conditions, there is little evidence of It eliminates the cost of accrual of accruals due to installation due to installation in the process of processing. The indicated reduction of the concentra- tions in the residual output is much higher than in the original water.
- ⁇ ig. 1 shows the reason for the processing of mineralized water according to the invention.
- the original part is delivered to the unit 1, but it may also include the stage of removal of the heavy metals 1 and the calcium ⁇ yazhelye me ⁇ ally (zhelez ⁇ , ma ⁇ ganets, ⁇ m and d ⁇ .) Udalyayu ⁇ of ⁇ as ⁇ v ⁇ a ⁇ sazhdenie ⁇ m, d ⁇ bavlyaya ⁇ aus ⁇ iches ⁇ uyu s ⁇ du and ⁇ l ⁇ ulyan ⁇ . The resulting suspension is freed with the release of iron-containing pigment in the quality of the commercial product.
- the lightened solution is reactivated by softening 1c, where the calcium hardness is removed add ⁇ m of the best soda and flocculant type poliakrilamida.
- the resulting product is illuminated, the suspension is depleted with the receipt of a calcium deposit in the bulk of the product.
- a clarified solution with a residual iron content of no more than 0.02 mg / l was mixed with a quick recovery from the crystallization stage.
- the resulting product in the amount of 3.19 m7 hours with a total of 4.8 g / l and a combination of acids and sulphides no more than 1: 37 resulted in a stage of removal of calcium.
- the best is 1, 3 kg of calcium powder for 1 m 3 of source water with a mass content of contaminants of less than 5% by weight.
- the concentrate was launched for installation.
- the process was cooled and cooled to a temperature of 0..1 ° C.
- the resulting suspension was settled, after which the condensed stock was sold to the center where standby was allocated at a rate of 92 kg for 1 percent of the supply.
- the number of maladies in dry glauer salt was not more than 0.1%.
- the mixture was mixed with the old appliance after the installation and was supplied to the original water, after the installation of heavy metals, the appliance was not used.
- the proposed method is suitable for the disposal of mineralized water, which is a processed product in the city, coal, energy, chemical. non-gaseous industry, and Food Wastewater and food products.
- the case is affected by a sulphate - a poor class with a relatively low salinity and a ratio of less than 1: 6.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Removal Of Specific Substances (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Abstract
Cette invention concerne un procédé de traitement d'eaux minéralisées à base de sulfates et de chlorures dans lesquelles le rapport entre les concentrations de chlorures et de sulfates est inférieur à 1:6. Ce procédé comprend des étapes de préparation de l'eau, de concentration, de cristallisation et de centrifugation. La cristallisation se fait pour un contenu total en sels de 50 à 100 g/l, tandis que la concentration se fait selon un procédé d'osmose inverse à une pression de travail qui varie de 1,5 à 4,0 Mpa. Le rapport entre les concentrations de sulfates et de chlorures lors du processus de concentration augmente d'au moins 2,5 fois. Grâce au renvoi dans le cycle de traitement des solutions restantes qui sont obtenues après la cristallisation et la centrifugation, il est possible d'accroître encore le rapport entre les concentrations de sulfates et de chlorures avant l'étape de concentration. Le mélange des solutions restantes à l'eau de départ permet d'accroître ledit rapport entre les concentrations d'au moins 18 %. Le mélange des solutions restantes à l'eau de départ ainsi qu'à l'eau après chaque étape de préparation de l'eau permet d'accroître ce même rapport d'au moins 3 % dans l'eau de départ, et d'au moins 17 % dans l'eau devant être concentrée. L'étape de préparation de l'eau décrite dans ce procédé peut par exemple comprendre l'élimination des métaux lourds et des solides à base de calcium et de magnésium.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU42972/99A AU4297299A (en) | 1998-08-06 | 1999-05-28 | Method for processing mineralised water |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU98114359 | 1998-08-06 | ||
RU98114359A RU2129995C1 (ru) | 1998-08-06 | 1998-08-06 | Способ переработки минерализованных вод |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000007945A1 true WO2000007945A1 (fr) | 2000-02-17 |
Family
ID=20208937
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/RU1999/000178 WO2000007945A1 (fr) | 1998-08-06 | 1999-05-28 | Procede de traitement d'eaux mineralisees |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU4297299A (fr) |
RU (1) | RU2129995C1 (fr) |
WO (1) | WO2000007945A1 (fr) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2172411A1 (es) * | 2000-07-14 | 2002-09-16 | Faus Jose Andres Sanchis | Metodo fisico para reciclado de cloruros |
US6792174B1 (en) | 1999-11-02 | 2004-09-14 | Nortel Networks Limited | Method and apparatus for signaling between an optical cross-connect switch and attached network equipment |
ES2375002A1 (es) * | 2008-07-30 | 2012-02-24 | Desalacion Integral Systems, S.L. | Perfeccionamientos en el objeto de la patente n. p200600257 por: planta desaladora-depuradora de aguas salobres y residuos industriales con descarga líquida cero. |
CN104445677A (zh) * | 2014-11-04 | 2015-03-25 | 山西潞安环保能源开发股份有限公司 | 一种井下可移动式模块化矿井水处理*** |
CN105254099A (zh) * | 2015-10-22 | 2016-01-20 | 东华工程科技股份有限公司 | 一种煤化工浓盐废水高纯度结晶提盐工艺 |
CN106395947A (zh) * | 2016-11-03 | 2017-02-15 | 南京格洛特环境工程股份有限公司 | 双介质蒸发结晶装置及工艺 |
CN108821493A (zh) * | 2018-06-28 | 2018-11-16 | 上海力脉环保设备有限公司 | 一种环保低能耗焦油精制含酚硫酸钠废水处理方法 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10427964B2 (en) | 2016-07-28 | 2019-10-01 | Veolia Water Technologies, Inc. | Enhanced process for selective salt recovery from wastewater, waste salts, and brines |
CN109592815A (zh) * | 2018-12-16 | 2019-04-09 | 金科环境股份有限公司 | 具有高永久性硬度的反渗透浓水的处理*** |
CN111072205A (zh) * | 2019-12-11 | 2020-04-28 | 陕西航天机电环境工程设计院有限责任公司 | 一种高盐高cod废水零排放回收硫酸钠的工艺及*** |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU889633A1 (ru) * | 1979-11-01 | 1981-12-15 | Донецкий Филиал Всесоюзного Научно-Исследовательского И Проектного Института По Очистке Технологических Газов,Сточных Вод И Использованию Вторичных Энергоресурсов Предприятий Черной Металлургии Ссср | Способ обработки сточных вод котельных |
SU1068399A1 (ru) * | 1980-01-28 | 1984-01-23 | Донецкий Филиал Всесоюзного Научно-Исследовательского И Проектного Института По Очистке Технологических Газов,Сточный Вод И Использованию Вторичных Энергоресурсов Предприятий Черной Металлургии | Способ обработки воды |
DE3543661A1 (de) * | 1985-12-11 | 1987-06-19 | Kraftanlagen Ag | Verfahren zur aufbereitung von wasser vor einer umkehr-osmoseanlage |
EP0394607A1 (fr) * | 1989-04-24 | 1990-10-31 | SEKA Gesellschaft für Schutzraumtechnik mbH | Procédé et dispositif pour le traitement de saumures et de sels minéraux et leurs mélanges pollués |
RU2060973C1 (ru) * | 1990-05-28 | 1996-05-27 | Свердловский научно-исследовательский институт химического машиностроения | Способ переработки хлоридно-сульфатных сточных или природных вод |
-
1998
- 1998-08-06 RU RU98114359A patent/RU2129995C1/ru active
-
1999
- 1999-05-28 WO PCT/RU1999/000178 patent/WO2000007945A1/fr active Application Filing
- 1999-05-28 AU AU42972/99A patent/AU4297299A/en not_active Abandoned
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU889633A1 (ru) * | 1979-11-01 | 1981-12-15 | Донецкий Филиал Всесоюзного Научно-Исследовательского И Проектного Института По Очистке Технологических Газов,Сточных Вод И Использованию Вторичных Энергоресурсов Предприятий Черной Металлургии Ссср | Способ обработки сточных вод котельных |
SU1068399A1 (ru) * | 1980-01-28 | 1984-01-23 | Донецкий Филиал Всесоюзного Научно-Исследовательского И Проектного Института По Очистке Технологических Газов,Сточный Вод И Использованию Вторичных Энергоресурсов Предприятий Черной Металлургии | Способ обработки воды |
DE3543661A1 (de) * | 1985-12-11 | 1987-06-19 | Kraftanlagen Ag | Verfahren zur aufbereitung von wasser vor einer umkehr-osmoseanlage |
EP0394607A1 (fr) * | 1989-04-24 | 1990-10-31 | SEKA Gesellschaft für Schutzraumtechnik mbH | Procédé et dispositif pour le traitement de saumures et de sels minéraux et leurs mélanges pollués |
RU2060973C1 (ru) * | 1990-05-28 | 1996-05-27 | Свердловский научно-исследовательский институт химического машиностроения | Способ переработки хлоридно-сульфатных сточных или природных вод |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6792174B1 (en) | 1999-11-02 | 2004-09-14 | Nortel Networks Limited | Method and apparatus for signaling between an optical cross-connect switch and attached network equipment |
ES2172411A1 (es) * | 2000-07-14 | 2002-09-16 | Faus Jose Andres Sanchis | Metodo fisico para reciclado de cloruros |
ES2375002A1 (es) * | 2008-07-30 | 2012-02-24 | Desalacion Integral Systems, S.L. | Perfeccionamientos en el objeto de la patente n. p200600257 por: planta desaladora-depuradora de aguas salobres y residuos industriales con descarga líquida cero. |
CN104445677A (zh) * | 2014-11-04 | 2015-03-25 | 山西潞安环保能源开发股份有限公司 | 一种井下可移动式模块化矿井水处理*** |
CN105254099A (zh) * | 2015-10-22 | 2016-01-20 | 东华工程科技股份有限公司 | 一种煤化工浓盐废水高纯度结晶提盐工艺 |
CN106395947A (zh) * | 2016-11-03 | 2017-02-15 | 南京格洛特环境工程股份有限公司 | 双介质蒸发结晶装置及工艺 |
CN108821493A (zh) * | 2018-06-28 | 2018-11-16 | 上海力脉环保设备有限公司 | 一种环保低能耗焦油精制含酚硫酸钠废水处理方法 |
Also Published As
Publication number | Publication date |
---|---|
AU4297299A (en) | 2000-02-28 |
RU2129995C1 (ru) | 1999-05-10 |
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