WO1999063027A1 - Fluide fonctionnel - Google Patents

Fluide fonctionnel Download PDF

Info

Publication number
WO1999063027A1
WO1999063027A1 PCT/GB1999/001486 GB9901486W WO9963027A1 WO 1999063027 A1 WO1999063027 A1 WO 1999063027A1 GB 9901486 W GB9901486 W GB 9901486W WO 9963027 A1 WO9963027 A1 WO 9963027A1
Authority
WO
WIPO (PCT)
Prior art keywords
functional fluid
acid ester
phosphate acid
alkyl phosphate
fluid
Prior art date
Application number
PCT/GB1999/001486
Other languages
English (en)
Inventor
David Anthony Coates
Original Assignee
Castrol Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9811690.8A external-priority patent/GB9811690D0/en
Application filed by Castrol Limited filed Critical Castrol Limited
Priority to AU41525/99A priority Critical patent/AU4152599A/en
Priority to EP99925133A priority patent/EP1090096A1/fr
Publication of WO1999063027A1 publication Critical patent/WO1999063027A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/30—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/32—Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
    • C10M107/34—Polyoxyalkylenes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/02—Bearings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/042—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/044—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/046—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids

Definitions

  • This invention concerns a functional fluid, preferably a gear oil, that is compatible with water-based functional fluids used in metaiworking operations.
  • Functional fluids are primarily used to prevent metal-to-metal contact between moving metal parts. Functional fluids also act by reducing friction and protecting against corrosion, thereby increasing the working life of the metal parts.
  • Functional fluids such as gear oils are used in, for example, worm gear boxes as transmission fluids in cars and in machine presses that deform metal sheets, such as tin coated steel or aluminium sheets, to produce deformed components such as metal cans.
  • gear oils that are currently used in the deformation of steel or aluminium are based on mineral oils. Although mineral oil fluids are good gear oils, they contaminate water based functional fluids that are also used in the production of the metal cans. Also, residues from the gear oil can remain on the cans, which then need to be removed by, for example, expensive, high energy cleaning processes, before the cans can be finished with, for example, lacquers or paints.
  • the mineral oils can also contaminate the cleaning fluids used in the cleaning processes, which means that the cleaning fluids need to be disposed of by following environmental guidelines and regulations. This can be costly and time-consuming.
  • water based functional fluids are also used in the production of cans.
  • the water based functional fluids can include, for example, deformation fluids that are used primarily to provide lubricity during deformation of the tin coated steel or aluminium
  • the deformation fluid also protects against corrosion and bacterial and fungal infestation
  • the deformation fluid can be used as both a 'prelube' to coat the metal steel prior to deformation and a lubricant and coolant during the deformation process
  • the deformation fluid does not include any mineral
  • a further aim of the present invention is to be able to produce a can in a can-forming process that is sufficiently clean (i e sufficiently free from mineral oil residue) that cleaning processes such as high energy cleaning processes are not required before the can is lacquered or painted
  • a further aim of the present invention is to provide a functional fluid such as a gear oil that is compatible with water based functional fluids that are also used in metal working operations
  • a further aim of the present invention is to provide a functional fluid that does not cause as much contamination as functional fluids based on mineral oils
  • a further aim of the present invention is to provide a functional fluid that exhibits improved corrosion inhibition
  • a further aim of the present invention is to provide a functional fluid that exhibits improved anti-wear properties
  • a further aim of the present invention is to provide a synthetic functional fluid that exhibits improved compatibility with water based functional fluids.
  • a functional fluid comprising a water soluble polyalkylene glycol.
  • the polyalkylene glycol preferably has a molecular weight of less than 2,900, more preferably less than 2,000
  • the functional fluid is preferably a metal working functional fluid, more preferably a gear oil.
  • the functional fluid may also be a machine slideway lubricant or hydraulic fluid.
  • the non-amine neutralised, alkyl phosphate acid ester preferably comprises from 1 to 18, preferably from 5 to 9, more preferably 5 to 7, carbon atoms.
  • the non-amine neutralised, alkyl phosphate acid ester preferably comprises a high proportion, preferably greater than 70%, of linear chains of carbon atoms
  • the non-amine neutralised, alkyl phosphate acid ester can also be:
  • the non-amine neutralised, alkyl phosphate acid ester is preferably a pentyl, hexyl. heptyl, octyl or nonyl phosphate acid ester or a mixture thereof.
  • the alkyl phosphate acid ester predominantly contains pentyl or heptyl phosphate acid esters or a mixture thereof.
  • the residues can be easily removed using a reduced energy cleaning process such as a hot or cold water wash, which is cheap and convenient to use when compared to high energy alkali cleaning processes.
  • the non-amine neutralised, alkyl phosphate acid ester is available from, for example, Elf Atochem, Albright and Wilson and Bayer.
  • the polyalkylene glycol will usually have a viscosity at 40°C within the range of 20 to 10,000 centistokes and a viscosity at 100°C within the range of 3 to 2,000 centistokes
  • the polyalkylene glycol may be based on the reaction product of a 1 ,2-ox ⁇ de (vicinal epoxide) with water, alcohol or aliphatic polyhyd ⁇ c alcohol containing from 2 to 6 hydroxyl groups and from 2 to 8 carbon atoms per molecule
  • the polyalkylene glycol is available from Inspec ('BREOX') and Dow Chemicals ('SYNALOX')
  • the functional fluid may also comprise the following usual additives- extreme pressure agents; anti-foaming additives; anti-wear additives, corrosion inhibitor additives; anti-oxidants; metal passivators; and vapour phase corrosion inhibitors
  • Functional fluids comprising water soluble polyalkylene glycols exhibit surface active properties. This presents the formulator with a challenge to provide the same level of corrosion inhibition, anti-wear and extreme pressure properties as obtained with mineral, ester and polyalphaolefin based lubricants.
  • the functional fluid of the present invention preferably comprises: from 0 10 to 99.00%, more preferably 70 to 99%, of polyalkylene glycol, from 0 01 to 5.00%, more preferably 0 10 to 1 00%, of phenolic antioxidant, from 0.01 to 5.00%, more preferably 0.10 to 1.00%, of aminic antioxidant; from 0.01 to 1.00% of benzot ⁇ azole; from 0.005 to 1.00%, more preferably 0.005 to 0.5% of antifoam; from 0.00 to 5.00%, more preferably 0.1 to 1.0%, of polysulphide;and from 0.01 to 5.0%, more preferably 0.15 to 1.0%, of alkyl phosphate acid ester
  • the functional fluid exhibits compatibility with aqueous based metalworking fluids without affecting their function
  • the functional fluid should contain no mineral oil
  • the functional fluid may contain insignificant amounts of mineral oil. Therefore, contamination of metal working fluids with mineral oil, or significant amounts of mineral oil, is avoided, and expensive and time-consuming cleaning processes are not required
  • the polyalkylene glycol based fluid was placed into a blending vessel and the benzotriazole, antioxidant, polysulphide, antifoam and alkyl phosphate were added.
  • the mixture was heated, while mixing, to between 45°C and 50°C to dissolve the benzotriazole and butylated hydroxy toluene (BHT).
  • BHT butylated hydroxy toluene
  • the functional fluid prepared above may be prepared with, for example, the following viscosity grades: 150cSt, 220cSt, 320cSt and 460cSt.
  • the functional fluid prepared in the above example had a viscosity grade of 150cSt.
  • the steel pin corrosion test was carried out in accordance with ASTM D-665B (10% synthetic sea water at 60°C for 24 hours). Examples 1 and 2 gave no rust at 0.35% of alkyl phosphate acid ester. This level of corrosion protection is usually difficult to achieve with polyalkylene glycol based fluid due to surface activity and competition for the metal surface with corrosion inhibitors and antiwear additives.
  • the steel pin corrosion test was carried out in accordance with the ASTM D-665 method with the 10% deionised water or synthetic sea water being replaced with 10% of a 5% solution of a metalworking fluid.
  • the metalworking fluid was CASTROL SYNTILO GX, which is available from Castrol Limited. Further examples were carried out using lloform PS 300 and PS 301 , which are also available from Castrol Limited. Examples 1 and 2 gave no rust when contaminated with these synthetic non-mineral oil-containing, water based metalworking fluids.
  • lloform PS 300 or lloform PS 301 The advantage of using lloform PS 300 or lloform PS 301 is that the metalworking fluid uses the same type of basefluid as in the gear oil. Contamination of the gear oil by the llofrom PS 300 or PS 301 maximises fluid function and minimises stability problems because:
  • Timken OK load test was carried out in accordance with ASTM D-2782.
  • Example 1 gave a load carrying OK load of >90 pounds and when contaminated with 5% lloform PS 300 the OK load was 60 pounds.
  • Example 2 gave an OK load of 45 pounds and, when contaminated with 0.5% lloform PS 300, the OK load was not affected.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Lubricants (AREA)

Abstract

La présente invention concerne un fluide fonctionnel compatible avec les fluides fonctionnels à base d'eau utilisés dans les opérations de travail des métaux. Le fluide fonctionnel de l'invention comprend un polyalkèneglycol hydrosoluble et, de préférence, un ester d'acide alkyl-phosphate. L'ester d'acide alkyl-phosphate est de préférence neutralisé par une non amine.
PCT/GB1999/001486 1998-06-01 1999-05-28 Fluide fonctionnel WO1999063027A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU41525/99A AU4152599A (en) 1998-06-01 1999-05-28 A functional fluid
EP99925133A EP1090096A1 (fr) 1998-06-01 1999-05-28 Fluide fonctionnel

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB9811690.8 1998-06-01
GBGB9811690.8A GB9811690D0 (en) 1998-06-01 1998-06-01 A functional fluid
GBGB9828115.7A GB9828115D0 (en) 1998-06-01 1998-12-21 A functional fluid
GB9828115.7 1998-12-21

Publications (1)

Publication Number Publication Date
WO1999063027A1 true WO1999063027A1 (fr) 1999-12-09

Family

ID=26313770

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1999/001486 WO1999063027A1 (fr) 1998-06-01 1999-05-28 Fluide fonctionnel

Country Status (4)

Country Link
EP (1) EP1090096A1 (fr)
AU (1) AU4152599A (fr)
GB (1) GB9912650D0 (fr)
WO (1) WO1999063027A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000044859A1 (fr) * 1999-01-26 2000-08-03 Imperial Chemical Industries Plc Composition de nettoyage
WO2007084207A1 (fr) * 2006-01-17 2007-07-26 Exxonmobil Chemical Patents Inc. Système d'additifs pour fluides de lubrification
WO2007084208A1 (fr) * 2006-01-17 2007-07-26 Exxonmobil Chemical Patents Inc. Fluides de lubrification
US7790660B2 (en) 2004-02-13 2010-09-07 Exxonmobil Research And Engineering Company High efficiency polyalkylene glycol lubricants for use in worm gears
WO2012150105A1 (fr) * 2011-04-08 2012-11-08 Micronic Mydata AB Composition de pâte à souder contenant des corps solides
US9975206B2 (en) 2011-04-08 2018-05-22 Micronic Mydata AB Composition of solid-containing paste

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1055642A (en) * 1963-05-13 1967-01-18 Castrol Ltd Improvements in or relating to hydraulic fluids
US4007123A (en) * 1972-02-28 1977-02-08 Mcdonnell Douglas Corporation Fire resistant functional fluid compositions
JPS52127484A (en) * 1976-04-19 1977-10-26 Kao Corp Functional fluid composition
US4670168A (en) * 1986-05-01 1987-06-02 Aluminum Company Of America Aqueous metal removal fluid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1055642A (en) * 1963-05-13 1967-01-18 Castrol Ltd Improvements in or relating to hydraulic fluids
US4007123A (en) * 1972-02-28 1977-02-08 Mcdonnell Douglas Corporation Fire resistant functional fluid compositions
JPS52127484A (en) * 1976-04-19 1977-10-26 Kao Corp Functional fluid composition
US4670168A (en) * 1986-05-01 1987-06-02 Aluminum Company Of America Aqueous metal removal fluid

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE CAPLUS Accession no. 128:310174; INSPC UK LTD.; "Polyalkylene glycols - versatile water-soluble polymers", XP002900627 *
PATENT ABSTRACTS OF JAPAN vol. 002, no. 031 (C - 004) 27 February 1978 (1978-02-27) *
SPEC. CHEM., vol. 18, no. 3, 1998, pages 100 - 101 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000044859A1 (fr) * 1999-01-26 2000-08-03 Imperial Chemical Industries Plc Composition de nettoyage
US7790660B2 (en) 2004-02-13 2010-09-07 Exxonmobil Research And Engineering Company High efficiency polyalkylene glycol lubricants for use in worm gears
WO2007084207A1 (fr) * 2006-01-17 2007-07-26 Exxonmobil Chemical Patents Inc. Système d'additifs pour fluides de lubrification
WO2007084208A1 (fr) * 2006-01-17 2007-07-26 Exxonmobil Chemical Patents Inc. Fluides de lubrification
WO2012150105A1 (fr) * 2011-04-08 2012-11-08 Micronic Mydata AB Composition de pâte à souder contenant des corps solides
US9975206B2 (en) 2011-04-08 2018-05-22 Micronic Mydata AB Composition of solid-containing paste

Also Published As

Publication number Publication date
AU4152599A (en) 1999-12-20
EP1090096A1 (fr) 2001-04-11
GB9912650D0 (en) 1999-07-28

Similar Documents

Publication Publication Date Title
US9057038B2 (en) Corrosion inhibiting polyalkylene glycol-based lubricant compositions
JP5613678B2 (ja) 潤滑グリース組成物
US6984340B1 (en) Corrosion inhibiting formulations
JP4822685B2 (ja) 潤滑剤組成物
CN105001956A (zh) 链条清洗剂组合物及其制备方法
CN101331216B (zh) 用于高温合成润滑剂的添加剂包
EP1090096A1 (fr) Fluide fonctionnel
JP4116445B2 (ja) 改善された腐食防止を有する圧媒液
CN113913230A (zh) 一种手动变速箱磨合油及其制备方法
CN112239695A (zh) 普碳钢冷轧轧制油组合物及其用途
JP4467024B2 (ja) 高潤滑防錆油組成物
AU665148B2 (en) Method for lubricating metal-metal contact systems in metalworking operations with cyclohexyl esters
EP1000130A1 (fr) Composition lubrifiante pour des operations de travail des metaux
WO2020131603A1 (fr) Composition lubrifiante comprenant un additif acide carboxylique ou ester contenant du soufre
CA3031368C (fr) Utilisation de lubrifiants a base de polyglycols hydrosolubles a haute viscosite
EP4365268A1 (fr) Lubrifiant comprenant du polytetrahydrofurane alcoxyle, un epaississant et une huile de base minerale
CN113845962A (zh) 链条润滑剂组合物及其制备方法
EP4244317A1 (fr) Fluide hydraulique à base d'eau-glycol
WO2023202913A1 (fr) Alcools alcoxylés destinés à augmenter la tension de claquage d'un lubrifiant

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG US UZ VN YU ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW SD SL SZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 1999925133

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 09722422

Country of ref document: US

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWP Wipo information: published in national office

Ref document number: 1999925133

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 1999925133

Country of ref document: EP