WO1999058004A1 - Procede, composition et dispositif permettant de produire un gaz fumigene, procedes de fumigation et systeme de commande - Google Patents
Procede, composition et dispositif permettant de produire un gaz fumigene, procedes de fumigation et systeme de commande Download PDFInfo
- Publication number
- WO1999058004A1 WO1999058004A1 PCT/RU1999/000154 RU9900154W WO9958004A1 WO 1999058004 A1 WO1999058004 A1 WO 1999058004A1 RU 9900154 W RU9900154 W RU 9900154W WO 9958004 A1 WO9958004 A1 WO 9958004A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas
- mixture
- fumigant
- carbon dioxide
- acid
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3409—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M13/00—Fumigators; Apparatus for distributing gases
Definitions
- Iz ⁇ b ⁇ e ⁇ enie ⁇ n ⁇ si ⁇ sya ⁇ ⁇ ischev ⁇ y and sels ⁇ zyays ⁇ venn ⁇ y ⁇ myshlenn ⁇ s ⁇ i and m ⁇ zhe ⁇ by ⁇ is ⁇ lz ⁇ van ⁇ for unich ⁇ zheniya v ⁇ edi ⁇ eley in ⁇ ischevy ⁇ ⁇ du ⁇ a ⁇ , ⁇ eimusches ⁇ venn ⁇ ze ⁇ ne, ⁇ aba ⁇ e and ⁇ a ⁇ zhe on ⁇ a ⁇ an ⁇ inny ⁇ ⁇ be ⁇ a ⁇ , ⁇ a ⁇ e, ⁇ ans ⁇ ny ⁇ s ⁇ eds ⁇ va ⁇ and ⁇ mescheniya ⁇ , ⁇ ednaznachenny ⁇ for ⁇ e ⁇ e ⁇ ab ⁇ i, ⁇ aneniya or dli ⁇ elny ⁇ ⁇ e ⁇ ev ⁇ z ⁇ .
- the known method of emitting a fumigant gas is to emit it in the form of a mixture of phosphine and carbon dioxide.
- the phosphine is obtained through the interaction of the metal phosphide with the water obtained from the melting of the ice, and is mixed with the carbon dioxide obtained from the non-separated carbon dioxide. We recommend that you compensate for heat.
- the device for receiving the gas-fumigant is subject to the risk of failure to comply with the following conditions: To ensure that the process is free, the melting of the ice and the passage of the non-pollutant to the gas begins to freeze.
- ⁇ ed ⁇ s ⁇ a ⁇ ami izves ⁇ ny ⁇ s ⁇ s ⁇ ba and us ⁇ ys ⁇ va for ⁇ lucheniya gas ⁇ umigan ⁇ a and s ⁇ s ⁇ ba ⁇ umigatsii yavlyayu ⁇ sya sl ⁇ zhn ⁇ s ⁇ ⁇ azmescheniya is ⁇ dny ⁇ ⁇ eagen ⁇ v in us ⁇ ys ⁇ ve, nev ⁇ zm ⁇ zhn ⁇ s ⁇ ⁇ susches ⁇ vleniya ⁇ n ⁇ lya for ⁇ ea ⁇ tsiey ⁇ b ⁇ az ⁇ vaniya ⁇ s ⁇ ina and sled ⁇ va ⁇ eln ⁇ gas- ⁇ umigan ⁇ a and ⁇ a ⁇ zhe
- Disadvantages of such devices are as follows. It is designed to be used for one-time use and to use only the sanitary and hygienic air conditioner, i.e. low percentages, or only for the division of technology, i.e. high, interest. Failure to do so may result in severe damage to the unit, resulting in severe damage to the device. Otherwise, in the case of foodstuffs, it is advisable to open the glass capsules without additional precautions.
- Reactors may be executed by a communicating device that is disconnected between them, or is interrupted.
- a pipe connecting the outlet or a flue gas outlet may be disconnected.
- the aforementioned foreign means may be removable. To start the process, it may be performed as a result of changing its position from the vertical to the horizontal.
- the device can be carried out with the possibility of discharging a process with a mixture of a metal phosphide, a substance that is a chemical process or a gas
- the device can be equipped with a device for holding the mixture of acid and water in the chamber with a mixture of metal and chemical products
- the device may be equipped with a mains for the supply of gas-fumigant to the processed plant.
- the device may have a process performed in the form of a few blocks.
- the device may have been manufactured in such a way that the outlet for the gas-fumigant is by-pass to the by-product.
- the device can be equipped with a source of gas-converter and a material for its delivery to the processed plant, with each process being communicated.
- the device may be operated from a separate camera with the option of discharging and or charging in the area of the fumigation.
- the device may be portable.
- composition for the production of a fumigant gas in the form of a mixture of phosphine and carbon dioxide, which contains a metal phosphide and water, which are additionally injected with an oxidizing agent;
- ⁇ d ⁇ ug ⁇ m va ⁇ ian ⁇ e s ⁇ s ⁇ ba ⁇ umigatsii ⁇ be ⁇ a an array ⁇ du ⁇ a, che ⁇ ez ⁇ y ⁇ di ⁇ es ⁇ es ⁇ venny ⁇ nve ⁇ ivny v ⁇ zdushny ⁇ , zamy ⁇ ayuschiysya is array ⁇ du ⁇ a, ⁇ dachu gas ⁇ umigan ⁇ a ⁇ izv ⁇ dya ⁇ on account s ⁇ zdavaem ⁇ g ⁇ ⁇ i ⁇ e ⁇ anii ⁇ imiches ⁇ i ⁇ ⁇ ea ⁇ tsy izby ⁇ chn ⁇ g ⁇ pressure sve ⁇ u or bottom array ⁇ du ⁇ a in zavisim ⁇ s ⁇ i ⁇ na ⁇ avleniya v ⁇ zdushn ⁇ g ⁇ ⁇ a in The flow of time is sufficient to fill the entire product array with a gas-fumigant.
- va ⁇ ian ⁇ e s ⁇ s ⁇ ba ⁇ umigatsii ⁇ be ⁇ a an array ⁇ du ⁇ a, che ⁇ ez ⁇ y ⁇ di ⁇ es ⁇ es ⁇ venny ⁇ nve ⁇ ivny v ⁇ zdushny ⁇ ⁇ e ⁇ emenn ⁇ g ⁇ na ⁇ avleniya, zamy ⁇ ayuschiysya is array ⁇ du ⁇ a, ⁇ dachu gas ⁇ umigan ⁇ a ⁇ izv ⁇ dya ⁇ on account izby ⁇ chn ⁇ g ⁇ pressure s ⁇ zdavaem ⁇ g ⁇ in us ⁇ ys ⁇ ve ⁇ i ⁇ luchenii ⁇ s ⁇ ina and ugle ⁇ isl ⁇ g ⁇ gas sve ⁇ u and bottom of the array product.
- va ⁇ ian ⁇ e s ⁇ s ⁇ ba ⁇ umigatsii ⁇ be ⁇ a an array ⁇ du ⁇ a, che ⁇ ez ⁇ y not ⁇ di ⁇ es ⁇ es ⁇ venny ⁇ nve ⁇ ivny v ⁇ zdushny ⁇ or ⁇ isu ⁇ s ⁇ vuyu ⁇ zam ⁇ nu ⁇ ye vnu ⁇ i array ⁇ du ⁇ a es ⁇ es ⁇ vennye ⁇ nve ⁇ ivnye v ⁇ zdushnye ⁇ i, ⁇ dachu gas- ⁇ umigan ⁇ a ⁇ izv ⁇ dya ⁇ in ve ⁇ nyuyu Part ⁇ be ⁇ a.
- a gas-fumigant When implementing any variant of the fumigation method, a gas-fumigant is used, while the gas and carbon dioxide are in the case of gas inlet 1: (1.5-20.0) -translation.
- the gas-fumigant When the gas-fumigant is supplied to the unit in the form of an array of product, it can be mixed with gas, which is used for this purpose and is used in P ⁇ i ⁇ ealizatsii lyub ⁇ g ⁇ va ⁇ ian ⁇ a s ⁇ s ⁇ ba ⁇ umigatsii in ⁇ echenie ⁇ tsessa ⁇ susches ⁇ vlyayu ⁇ ⁇ n ⁇ l ⁇ ntsen ⁇ atsii gaz ⁇ v ⁇ s ⁇ eds ⁇ v ⁇ m us ⁇ ys ⁇ va, vy ⁇ lnenn ⁇ g ⁇ as s ⁇ s ⁇ yascheg ⁇ of dvu ⁇ chas ⁇ ey ⁇ azlichn ⁇ g ⁇ diame ⁇ a ball ⁇
- Z ⁇ YAU IJ LIS ⁇ P ⁇ IL ⁇ 26 7 small gas concentrations can be equipped with a mechanism for pumping through a larger gas volume, while the gas separator, which is less than a white, is less.
- Z ⁇ YAU IJ LIS ⁇ P ⁇ IL ⁇ 26 8 USE ONE AND THE SAME CAPACITY OF THE GAS-FUMIGANT WHEN IT IS PERMITTED TO BE POSITION IS AVAILABLE AT HIGHER.
- Fig. 4-6 the methods of fumigation of the products in the form of arrays of products that require the deep penetration of gas-humidifier are illustrated.
- Figs. 7a-7b embodiments of a device for determining gas concentration are described.
- the device for the production of gas-fumigant contains a response (1), which is less than one unit of the two common cameras (2) and (3).
- the starting reagents are placed (the type of the metal, the substance, the process and the carbon dioxide, and the binder), and in the mixture (3).
- the output was completed (4).
- the chambers are communicated between themselves through a failure (5), performed in the general partition, or through a channel (7).
- the failure is overridden (6).
- the chambers and the outlet are protected by shreds.
- a spare element is used, made in the form of a flexible tube (8), one end of the circuit is connected to the channel (7) or the handset is disconnected
- the cameras (2) and (3) can be connected to each other with the help of the plug-in connection (9), but the connection can be made in the form of a channel for the communication of the camera (ig).
- the device may be performed with a node that implements the remote control (1 1).
- ⁇ a ⁇ ig. A variant of the device has been disclosed when the chamber for the reactive mixture (2) is placed inside the chamber for the mixture of acid and water (3). This product is shown to be free of charge, and it is expressly agreed that the battery is free of charge. ⁇ If the device is inaccessible, the mains (12) is connected to supply the gas-fumigant deep into the bulk of the finished product or a busy product.
- the fumigant has a large area of equipment (13), which are connected ⁇ case ⁇ gda ⁇ ebue ⁇ sya glub ⁇ e ⁇ ni ⁇ n ⁇ venie gas ⁇ umigan ⁇ a in ⁇ b ⁇ aba ⁇ yvaemy ⁇ du ⁇ and ⁇ nve ⁇ ivnye v ⁇ zdushnye ⁇ i ⁇ su ⁇ s ⁇ vuyu ⁇ , us ⁇ ys ⁇ v ⁇ vy ⁇ lnen ⁇ with uzl ⁇ m, s ⁇ de ⁇ zhaschim is ⁇ chni ⁇ gas ⁇ e ⁇ en ⁇ schi ⁇ a (14) imeyuscheg ⁇ ⁇ l ⁇ n ⁇ s ⁇ higher than ⁇ l ⁇ n ⁇ s ⁇ v ⁇ zdu ⁇ a and magis ⁇ al (15) for ⁇ mi ⁇ vaniya ⁇ a gas conversion with gas fumigant (fig.4b).
- the appliance turns on the appliance by removing access to the mixture of acid and water from the camera (3) in the camera (2). Turning off the easy-to-use camcorder from the vertical drive to the horizontal. If there is a need to install a large number of portable processors for larger areas of operation, it will be possible to run the remote control (11). For temporary storage of the mixture of acid and water from the chamber (3) in the chamber (2) with a mixture of metal phosphide, a binder and a substance emitting direct gas and oxygen. The time delay ensures the inclusion with a predetermined interval that is necessary and sufficient for the performance of the final fumigation process, the output is processed
- the gas-fumigant is supplied to the processed product due to the excess pressure resulting from the reaction with the formation of gas and carbon dioxide.
- the supply of gas-fumigant to the processed product which is a significant significant volume, filled up with bulk product (also called the “product mass”), is the property
- gas is selected with a higher gas content than air, and gas density is the density.
- the gas-fume carrier is supplied with such a gas by-product. This will ensure the supply of fumigant gas to the deeper layers of the product without such additional processing, as the transfer.
- the ratio of the phosphine and carbon dioxide in the fumigant gas is 1: (1.5-20.0) volumetric parts.
- P ⁇ i ⁇ umigatsii ⁇ be ⁇ a an array ⁇ du ⁇ a, che ⁇ ez ⁇ y ⁇ di ⁇ ⁇ nve ⁇ ivny v ⁇ zdushny ⁇ , zam ⁇ nu ⁇ y array is ⁇ du ⁇ a gas- ⁇ umigan ⁇ ⁇ dayu ⁇ in zavisim ⁇ s ⁇ i ⁇ na ⁇ avleniya v ⁇ zdushn ⁇ g ⁇ ⁇ nve ⁇ ivn ⁇ g ⁇ ⁇ a bottom or sve ⁇ u ⁇ b ⁇ aba ⁇ yvaem ⁇ g ⁇ array ⁇ echenie v ⁇ emeni, ne ⁇ b ⁇ dim ⁇ g ⁇ for za ⁇ lneniya vseg ⁇ ⁇ bema ⁇ b ⁇ aba ⁇ yvaem ⁇ g ⁇ ⁇ du ⁇ a.
- the gas-fumigant is introduced into the body from above and below (Fig. 5c).
- Devices for the determination of gas concentration are made up of a cylinder (16) made of two parts of a different diameter: ⁇ - smaller and ⁇ - larger.
- the ballot was made from a third-party material (plastic).
- the indicator is placed on the display (19).
- a preferred variant of the indicator is that it is impaired on a foreign medium.
- the limiter (17) placed in part of the cylinder for a smaller diameter is more preferable to be painted in white. This makes it easier to find a faster access to the changing indicator of the adjacent indicator.
- removable sealing elements (20) and (21) are installed for both parts of the tank.
- a sealing element (20) a smaller cylinder may be used, for example, a larger one, and a larger seal (21) is larger.
- Each of the parts of the ballon has its own scale - (22) and (23). For this reason, scales can be placed on a ballon, as well as on a separate carrier, for example, on a device for transporting the device.
- the gas concentration with the help of the devices is determined by the following method.
- the sealing element (21) may be moved to the maximum possible length, i.e. the length corresponding to the length of the scale corresponding to this part of the cylinder. They take into account the length of the beautiful area on the scale, which is partly lower than the size of the ball (22), and the volume of air on the scale, which is 23% higher.
- the gas concentration is determined by the formula:
- C ⁇ (L: V), where C is the concentration of gas in the gas supply, g / m 3 ;
- B the length of the beautiful part of the indi- vidual feed at a scale that is related to the part of the ballot of a smaller diameter, m;
- V the volume of the pumped-in air, calculated at a scale that is related to a part of the ballon for a larger diameter, m.
- the sealing element (21) of the larger cylinder can be moved to a smaller diameter;
- the concentration of gas can be divided directly at a scale that is part of the larger diameter and calibrated for gas.
- reading the information is carried out by placing the scale in accordance with the ballot box.
- Measurement of small, weekly-acceptable, and concentra- tions is carried out as follows. Acting as a sealing element (21), a part of a larger cylinder is available as an empty pump; When this is taken into account, the air inlet to the cylinder is excluded from the analyzed volume, and the discharge from the return air to the inlet is not suitable for the inlet. In this case, the total gas volume is taken into account for the determination of gas concentration.
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Abstract
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU39630/99A AU3963099A (en) | 1998-05-14 | 1999-05-13 | Method, composition and device for producing a fumigant gas, fumigation methods and control system |
DE19983232T DE19983232T1 (de) | 1998-05-14 | 1999-05-13 | Verfahren, Zusammensetzung und Vorrichtung für die Erzeugung von Vergasungsmitteln, Begasungsmethoden und Kontrollmittel |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU98108921A RU2145784C1 (ru) | 1998-05-14 | 1998-05-14 | Способ выработки газа-фумиганта, устройство и композиция для его осуществления, способ фумигации, способ фумигации объекта в виде массива продукта (варианты) |
RU98108921 | 1998-05-14 | ||
RU99107391 | 1999-04-19 | ||
RU99107391/04A RU2146365C1 (ru) | 1999-04-19 | 1999-04-19 | Устройство для определения концентрации газа |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999058004A1 true WO1999058004A1 (fr) | 1999-11-18 |
Family
ID=26653957
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/RU1999/000154 WO1999058004A1 (fr) | 1998-05-14 | 1999-05-13 | Procede, composition et dispositif permettant de produire un gaz fumigene, procedes de fumigation et systeme de commande |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU3963099A (fr) |
DE (1) | DE19983232T1 (fr) |
WO (1) | WO1999058004A1 (fr) |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3047373A1 (de) * | 1979-12-18 | 1982-07-15 | Dr. Werner Freyberg Chemische Fabrik Delitia Nachf., 6941 Laudenbach | Phosphorwasserstoff freisetzende zusammensetzung und verfahren zu ihrer herstellung |
SU1054780A1 (ru) * | 1982-07-26 | 1983-11-15 | Войсковая часть 27177 | Индикатор дл обнаружени и измерени концентрации газа |
DE3517324C1 (de) * | 1985-05-14 | 1986-09-25 | Drägerwerk AG, 2400 Lübeck | Pruefroehrchen |
DE3618297A1 (de) * | 1986-05-30 | 1987-12-03 | Deutsche Ges Schaedlingsbek | Verfahren und vorrichtung zur herstellung eines entwesungsfluids |
US4756117A (en) * | 1982-07-26 | 1988-07-12 | Dr. Werner Freyberg Chemische Fabrik Delitia Nachf. | Process and apparatus for treating bulk commodities |
RU2087415C1 (ru) * | 1990-06-21 | 1997-08-20 | Коммонвелт Сайентифик Энд Индастриал Рисерч Организейшн | Способ получения фосфина, устройство для его осуществления и система безопасности для производства фосфина |
RU2088097C1 (ru) * | 1989-06-27 | 1997-08-27 | Коммонвелт Сайентифик Энд Индастриал Рисерч Организейшн | Способ фумигации продуктов фосфином и устройство для его осуществления |
-
1999
- 1999-05-13 WO PCT/RU1999/000154 patent/WO1999058004A1/fr active Application Filing
- 1999-05-13 AU AU39630/99A patent/AU3963099A/en not_active Abandoned
- 1999-05-13 DE DE19983232T patent/DE19983232T1/de not_active Withdrawn
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3047373A1 (de) * | 1979-12-18 | 1982-07-15 | Dr. Werner Freyberg Chemische Fabrik Delitia Nachf., 6941 Laudenbach | Phosphorwasserstoff freisetzende zusammensetzung und verfahren zu ihrer herstellung |
SU1054780A1 (ru) * | 1982-07-26 | 1983-11-15 | Войсковая часть 27177 | Индикатор дл обнаружени и измерени концентрации газа |
US4756117A (en) * | 1982-07-26 | 1988-07-12 | Dr. Werner Freyberg Chemische Fabrik Delitia Nachf. | Process and apparatus for treating bulk commodities |
DE3517324C1 (de) * | 1985-05-14 | 1986-09-25 | Drägerwerk AG, 2400 Lübeck | Pruefroehrchen |
DE3618297A1 (de) * | 1986-05-30 | 1987-12-03 | Deutsche Ges Schaedlingsbek | Verfahren und vorrichtung zur herstellung eines entwesungsfluids |
RU2088097C1 (ru) * | 1989-06-27 | 1997-08-27 | Коммонвелт Сайентифик Энд Индастриал Рисерч Организейшн | Способ фумигации продуктов фосфином и устройство для его осуществления |
RU2087415C1 (ru) * | 1990-06-21 | 1997-08-20 | Коммонвелт Сайентифик Энд Индастриал Рисерч Организейшн | Способ получения фосфина, устройство для его осуществления и система безопасности для производства фосфина |
Also Published As
Publication number | Publication date |
---|---|
AU3963099A (en) | 1999-11-29 |
DE19983232T1 (de) | 2001-07-12 |
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