WO1999050075A1 - Process for the decoration of wall-tiles and floor-tiles - Google Patents

Process for the decoration of wall-tiles and floor-tiles Download PDF

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Publication number
WO1999050075A1
WO1999050075A1 PCT/ES1999/000079 ES9900079W WO9950075A1 WO 1999050075 A1 WO1999050075 A1 WO 1999050075A1 ES 9900079 W ES9900079 W ES 9900079W WO 9950075 A1 WO9950075 A1 WO 9950075A1
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WO
WIPO (PCT)
Prior art keywords
tiles
temperature
image
decoration
ceramic
Prior art date
Application number
PCT/ES1999/000079
Other languages
Spanish (es)
French (fr)
Inventor
Roberto Manrique Ramos
Original Assignee
Roberto Manrique Ramos
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roberto Manrique Ramos filed Critical Roberto Manrique Ramos
Priority to BR9909426-6A priority Critical patent/BR9909426A/en
Priority to EP99910382A priority patent/EP1127705A1/en
Priority to AU29356/99A priority patent/AU2935699A/en
Priority to CA002326428A priority patent/CA2326428A1/en
Publication of WO1999050075A1 publication Critical patent/WO1999050075A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0446—Ornamental plaques, e.g. decorative panels, decorative veneers bearing graphical information
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/12—Transfer pictures or the like, e.g. decalcomanias
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/175—Transfer using solvent
    • B44C1/1752—Decalcomanias provided with a particular decorative layer, e.g. being specially adapted to allow the formation of a metallic or dyestuff layer on a substrate unsuitable for direct deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0438—Ornamental plaques, e.g. decorative panels, decorative veneers containing stone elements

Definitions

  • the present invention relates to a new procedure for the ornamentation of tiles and pavements, with which it is feasible to obtain on them any type of motif, and especially motifs or photographic images.
  • the procedure allows obtaining such images in both black and white and color.
  • the current state of the art in the field of application of the invention presents a problem that focuses primarily on a lack of accurate registration and the consequent inability to work with high plot lines to obtain high quality photographic images, in the generation of weft points and uneven point density, and in the use of a step to greater in the process, the screen screen, which loses even more point definition, since it is likely that a photolithic point is find at the intersection of two screen threads, it is impossible to obtain a motif on the screen screen identical to the photolith.
  • the tracing paper is laminated and insolated by means of a four-color photolitho, this lamination and insolation operation must be repeated as many times as colors must participate in the printing, depending on whether it is intended, as previously stated, that said printing be mono or polychromatic
  • a transport solution for common use is applied, allowed to dry and the glazed ceramic support is cleaned, after which it is baked at a maximum temperature of 1,050 ° C, the baking phase that is carried out during the tile itself, so that the image is integrated into the enamel of the latter.
  • the gloss or matte finish is achieved by incorporating less or more flux in the ceramic colors so that they melt less or more easily and, consequently, to obtain less or more brightness.
  • the image to be captured in the ceramic piece in question is digitized and processed. More specifically, the photolithography is shot at 200 lines per inch, which is equivalent to 78.74 points per c 2.
  • the tracing paper is laminated and insolated using a magenta quatricomy photolith.
  • the protective plastic is removed from the decal sheet to apply the magenta ceramic powder and then the test or decal is cleaned with antistatic suede.
  • a common use transport solution is applied, either by brush or by screen printing. It is allowed to dry and the enameled ceramic support is cleaned. The test is then immersed or traced in water to detach the image from the cardboard support and, once detached, is applied to the ceramic piece, removing water and air with a rubber spatula. -6 -
  • the cooking curve should be as follows:

Abstract

The process starts with the digitalization and processing of the images to be reproduced on the ceramic piece, said images having been obtained for example from a photography. The process proceeds with a lamination and photo-exposure phase by means of photolyte and which can be carried out in a single step, for monochromatic decorations, or several times for polychromatic (quadrichromy) decorations, specifically one operation for each color used. Further, a transport solution is applied for example with a serigraphic screen. After implantation of the image on the ceramic piece and drying thereof, the latter is placed in a furnace at high temperature, approximately 1 050 °C.

Description

PROCEDIMIE-S-TO PARA LA ORNAMENTACIÓN DE AZULEJOS PROCEDIMIE-S-TO FOR ORNAMENTATION OF TILES
Y PAVIMENTOSAND PAVEMENTS
D E S C R I P C I Ó ND E S C R I P C I Ó N
OBJETO DE LA INVENCIÓNOBJECT OF THE INVENTION
La presente invención se refiere a un nuevo procedimiento para la ornamentación de azulejos y pavimentos, con el que resulta factible la obtención sobre los mismos de cualquier tipo de motivo, y en especial de motivos o imágenes fotográficas.The present invention relates to a new procedure for the ornamentation of tiles and pavements, with which it is feasible to obtain on them any type of motif, and especially motifs or photographic images.
El procedimiento permite la obtención de tales imágenes tanto en blanco y negro como en color.The procedure allows obtaining such images in both black and white and color.
ANTECEDENTES DE LA INVENCIÓNBACKGROUND OF THE INVENTION
En la actualidad y para la ornamentación de superficies cerámicas, se vienen utilizando, a grandes rasgos, los siguientes procesos:At present and for the ornamentation of ceramic surfaces, the following processes have been used in broad strokes:
Monococción: Todo el producto se cuece al horno de una sola vez, de manera que el bizcocho o elemento base, sin cocer, recibe el esmalte a campana y a continuación la decoración, por pantalla serigráfica, utilizándose entre pantalla y pantalla una especie de fijador.Monococción: All the product is baked in one go, so that the sponge cake or base element, uncooked, receives the enamel to bell and then the decoration, by screen printing, using a kind of fixative between screen and screen.
- Bicocción: En primer lugar se cuece la base o bizcocho, y seguidamente se aplican las siguientes capas, citadas en el caso anterior, volviéndose a hornear. -2 -- Bicocción: In the first place the base or sponge cake is cooked, and then the following layers are applied, mentioned in the previous case, returning to bake. -two -
Tercer fuego: Con esta solución en primer lugar se cuece el bizcocho, como en el caso anterior, y seguidamente y tras aplicar en su caso el engobe, también como en las dos soluciones anteriores, se procede al esmaltado y a una nueva fase de cocción, aplicándose finalmente la decoración por pantalla o bien a mano (a pincel) , procediéndose finalmente a una tercera cocción, que es la que da el nombre de "tercer fuego" al procedimiento. La decoración en este sistema de "tercer fuego" también se suele realizar pegando calcas predecoradas anteriormente mediante pantalla serigráfico sobre el soporte cerámico esmaltado.Third fire: With this solution, the cake is cooked in the first place, as in the previous case, and then and after applying the engobe, as well as in the two previous solutions, the enamelling and a new cooking phase are carried out, finally applying the decoration by screen or by hand (by brush), finally proceeding to a third firing, which is what gives the procedure a "third fire" name. The decoration in this "third fire" system is also usually done by gluing previously predefined decals by means of a serigraphic screen on the glazed ceramic support.
Recientemente ha aparecido un dispositivo que realiza todo el proceso de engobe, esmaltado y decoración mediante rodillos de caucho o similar sin utilizar campanas de esmaltado ni pantallas serigráficas .Recently a device has appeared that performs the entire process of engobe, enamelling and decoration using rubber rollers or similar without using enamelling bells or screenprints.
En cualquier caso estas soluciones traen consigo una problemática que se centra fundamentalmente en los siguientes aspectos:In any case, these solutions bring a problem that focuses primarily on the following aspects:
La lineatura de trama de las pantallas serigráficas es muy limitada, ya que físicamente los agujeros por donde pasa la pasta (color cerámico + vehículo líquido) han de ser de un diámetro lo bastante grande para permitir el paso de dicha pasta con el consiguiente peligro de que se obturen rápidamente los orificios. Para mitigar este problema se deben utilizar lineaturas de trama con pocos hilos, con lo cual la definición de la imagen final es notablemente inferior.The plot line of the screen-printing screens is very limited, since physically the holes through which the paste passes (ceramic color + liquid vehicle) must be of a diameter large enough to allow the passage of said paste with the consequent danger of the holes are quickly obtained. To mitigate this problem, weft lines with few threads should be used, so that the definition of the final image is noticeably inferior.
- La angulación de cada pantalla serigráfica es - 3 -- The angulation of each screen screen is - 3 -
muy crítica ya que al trabajar con pasta líquida después de haber traspasado el orificio de la pantalla tiende a expandirse en mayor o menor medida dependiendo del diámetro de los puntos de trama, la densidad de la pasta y presión y velocidad de la espátula, a parte de sufrir otros inconvenientes o defectos .very critical since working with liquid paste after having pierced the screen hole tends to expand to a greater or lesser extent depending on the diameter of the plot points, the density of the paste and pressure and speed of the spatula, apart of suffering other inconveniences or defects.
Defectos de registro de cruces de cada pantalla sobre la anterior, debido al mismo proceso de fabricación, es decir inherente al propio proceso.Defects of registration of crosses of each screen on the previous one, due to the same manufacturing process, that is, inherent to the process itself.
Así pues, el estado actual de la técnica en el ámbito de aplicación de la invención presenta una problemática que se centra fundamentalmente en una falta de registro exacto y la consecuente imposibilidad para trabajar con lineaturas de trama elevadas para obtener imágenes fotográficas de alta calidad, en la generación de puntos de trama y densidad de punto desigual, y en la utilización de un paso a mayores en el proceso, la pantalla serigráfica, con lo que se pierde aún más definición de punto, ya que es probable que un punto de fotolito se encuentre en la intersección de dos hilos de la pantalla, siendo imposible obtener un motivo en la pantalla serigráfica idéntico al fotolito.Thus, the current state of the art in the field of application of the invention presents a problem that focuses primarily on a lack of accurate registration and the consequent inability to work with high plot lines to obtain high quality photographic images, in the generation of weft points and uneven point density, and in the use of a step to greater in the process, the screen screen, which loses even more point definition, since it is likely that a photolithic point is find at the intersection of two screen threads, it is impossible to obtain a motif on the screen screen identical to the photolith.
DESCRIPCIÓN DE LA INVENCIÓNDESCRIPTION OF THE INVENTION
El procedimiento para la ornamentación de azulejos y pavimentos que la invención propone resuelve de forma plenamente satisfactoria la problemática anteriormente expuesta, asegurando un perfecto grabado de las imágenes seleccionadas , tanto en blanco y negro como en color, tanto con un acabado en brillo como en mate, y con una máxima durabilidad y resistencia . -4 -The procedure for the ornamentation of tiles and pavements that the invention proposes solves in a fully satisfactory way the problem previously exposed, ensuring a perfect engraving of the selected images, both in black and white and in color, both with a gloss and matt finish. , and with maximum durability and resistance. -4 -
Para ello y de forma más concreta en una primera fase operativa se procede, tras la selección de la correspondiente imagen, a la digitalización y procesado de la misma para su filmación en fotolito.To do this and more specifically in a first operational phase, after the selection of the corresponding image, the digitization and processing of the same is carried out for photolithography.
Seguidamente se lamina el papel de calco y se insola mediante fotolito cuatricomía, debiendo repetirse esta operación de laminación e insolación tantas veces como colores deban participan en la impresión, en función de que se pretenda, como anteriormente se ha dicho, que dicha impresión sea mono o policromática.Then the tracing paper is laminated and insolated by means of a four-color photolitho, this lamination and insolation operation must be repeated as many times as colors must participate in the printing, depending on whether it is intended, as previously stated, that said printing be mono or polychromatic
A continuación y en una tercera fase operativa, se aplica una solución de transporte de uso común, se deja secar y se limpia el soporte cerámico esmaltado, tras lo que se hornea a una temperatura máxima de 1.050°C, fase de horneado que se realiza durante la propia cocción del azulejo, de manera que dicha imagen quede integrada en el esmalte de este último.Then, in a third operational phase, a transport solution for common use is applied, allowed to dry and the glazed ceramic support is cleaned, after which it is baked at a maximum temperature of 1,050 ° C, the baking phase that is carried out during the tile itself, so that the image is integrated into the enamel of the latter.
De acuerdo con otra de las características de la invención, se ha previsto que la curva de cocción evolucione de la siguiente manera:According to another of the features of the invention, it is anticipated that the cooking curve will evolve as follows:
Durante la primera hora la temperatura asciende de la ambienta a 350°C. En 2 h. 45 min. se alcanza la temperatura de 700°C. En 30 min. complementarios se alcanza la temperatura de 1.050°C, manteniéndose la temperatura durante 10 min. , para bajar posteriormente a la temperatura ambiente durante un tiempo de 2 h. 30 min.During the first hour the temperature rises from the environment to 350 ° C. In 2 h. 45 min. 700 ° C temperature is reached. In 30 min. Complementary temperature of 1,050 ° C is reached, maintaining the temperature for 10 min. , to subsequently lower to room temperature for a time of 2 h. 30 min.
El acabado en brillo o en mate se consigue mediante incorporación de menos o más fundente en los colores cerámicos para que fundan con menos o más facilidad y, en consecuencia, para obtener menos o más brillo. REALIZACIÓN PREFERENTE DE LA INVENCIÓNThe gloss or matte finish is achieved by incorporating less or more flux in the ceramic colors so that they melt less or more easily and, consequently, to obtain less or more brightness. PREFERRED EMBODIMENT OF THE INVENTION
De acuerdo con un ejemplo preferente de realización práctica de la invención y cuando se pretende la ornamentación de azulejos y pavimentos con imágenes en color, se digitaliza la imagen a plasmar en la pieza cerámica de que se trate y se procesa. Más concretamente se realiza la filmación en fotolito a 200 líneas por pulgada, lo que equivale a 78,74 puntos por c 2.According to a preferred example of practical embodiment of the invention and when the ornamentation of tiles and pavements with color images is intended, the image to be captured in the ceramic piece in question is digitized and processed. More specifically, the photolithography is shot at 200 lines per inch, which is equivalent to 78.74 points per c 2.
Se lamina el papel de calco y se insola mediante fotolito de cuatricomía magenta. Se quita el plástico protector de la hoja de calca para aplicar el color cerámico magenta en polvo y seguidamente se limpia la prueba o calca con gamuza antiestática.The tracing paper is laminated and insolated using a magenta quatricomy photolith. The protective plastic is removed from the decal sheet to apply the magenta ceramic powder and then the test or decal is cleaned with antistatic suede.
Se repite seguidamente esta operación, es decir se realiza una segunda laminación e insolación, siguiendo el mismo proceso, con fotolito color cian, una tercera con amarillo y una última con negro.This operation is repeated again, that is to say a second lamination and insolation is carried out, following the same process, with cyan color, a third with yellow and a last with black.
Posteriormente se aplica una solución de transporte de uso común, bien a pincel o bien por pantalla serigráfica. Se deja secar y se limpia el soporte cerámico esmaltado. A continuación se sumerge la prueba o calca en agua para despegar la imagen del soporte de cartón y, una vez despegada, se aplica sobre la pieza cerámica, eliminado el agua y el aire con una espátula de goma. -6 -Subsequently, a common use transport solution is applied, either by brush or by screen printing. It is allowed to dry and the enameled ceramic support is cleaned. The test is then immersed or traced in water to detach the image from the cardboard support and, once detached, is applied to the ceramic piece, removing water and air with a rubber spatula. -6 -
Se deja secar nuevamente y se hornea a alta temperatura, concretamente a 1.050°C, para cocer el color de la imagen junto con el azulejo y que se integre aquella con el esmalte de este último, incorporando más fundente en los colores cerámicos cuanto mayor sea el nivel de brillo deseado..It is allowed to dry again and it is baked at high temperature, specifically at 1,050 ° C, to cook the color of the image together with the tile and that it is integrated with the enamel of the latter, incorporating more flux in the ceramic colors the larger it is the desired brightness level ..
Cuando se trata de obtener imágenes en blanco y negro o sepia, el procedimiento es exactamente igual al descrito, pero con la particularidad de que sólo se efectúa una fase de laminación e insolación, concretamente en negro o en sepia.When it comes to obtaining black and white or sepia images, the procedure is exactly the same as described, but with the particularity that only a lamination and insolation phase is carried out, specifically in black or sepia.
Tanto para la obtención de imágenes en blanco y negro o sepia como para la obtención de imágenes en color, la curva de cocción debe ser la siguiente:Both for obtaining black and white or sepia images and for obtaining color images, the cooking curve should be as follows:
a) 350°C de subida en 1 hora. b) 700°C de subida en 2 h. 45 min. c) 1.050°C en 30 min. más. d) Permanencia a 1 . 050°C durante 10 min . e) Baj ada en 2 horas 30 minutos a temperatura ambiente .a) 350 ° C rise in 1 hour. b) 700 ° C rise in 2 h. 45 min. c) 1,050 ° C in 30 min. plus. d) Permanence at 1. 050 ° C for 10 min. e) Lower in 2 hours 30 minutes at room temperature.
Como se deduce de lo anteriormente expuesto es necesaria la utilización de colores capaces de soportar las altas temperaturas citadas, en orden a conseguir una mayor durabilidad y resistencia en el acabado.As can be deduced from the above, it is necessary to use colors capable of withstanding the high temperatures mentioned, in order to achieve greater durability and resistance in the finish.
No se considera necesario hacer más extensa esta descripción para que cualquier experto en la materia comprenda el alcance de la invención y las ventajas que de la misma se derivan. It is not considered necessary to make this description more extensive so that any person skilled in the art understands the scope of the invention and the advantages derived therefrom.

Claims

-7- -7-
R E I V I N D I C A C I O N E SR E I V I N D I C A C I O N E S
Ia.- Procedimiento para la ornamentación de azulejos y pavimentos, que teniendo por finalidad permitir la traslación a dichos azulejos y pavimentos de cualquier tipo de imágenes, especialmente imágenes fotográficas, se caracteriza porque en el mismo se establecen las siguientes fases operativas:I a .- Procedure for the ornamentation of tiles and pavements, which with the purpose of allowing the transfer to said tiles and pavements of any type of images, especially photographic images, is characterized in that the following operational phases are established therein:
- Se procede a la digitalización de la imagen elegida y al procesamiento de la misma realizándose una filmación en fotolito.- The chosen image is digitalized and processed using a photolithic film.
Se lamina el papel de calco y se insola mediante fotolito de cuatricomía, eliminando el plástico protector de la prueba u hoja de calca para aplicar el color cerámico elegido en polvo, limpiándose seguidamente la prueba con una gamuza antiestética.The tracing paper is laminated and insolated by means of a quatricomy photolith, removing the protective plastic from the test or decal sheet to apply the chosen ceramic color in powder, then cleaning the test with an unsightly suede.
- Se aplica una solución de transporte de uso común, se deja secar y se limpia el soporte cerámico esmaltado, sumergiendo la calca en agua para despegar la imagen del soporte previamente a su aplicación sobre la pieza cerámica, eliminando el agua y el aire con una espátula de goma.- A transport solution for common use is applied, allowed to dry and the enameled ceramic support is cleaned, submerging the decal in water to detach the image of the support prior to its application on the ceramic piece, eliminating water and air with a rubber spatula
- Se deja secar nuevamente y se hornea a alta temperatura, de manera que el color de la imagen queda integrado en el esmalte del azulejo durante la cocción de este último.- Allow to dry again and bake at high temperature, so that the color of the image is integrated in the glaze of the tile during the cooking of the latter.
2 a.- Procedimiento para la ornamentación de azulejos y pavimentos, según reivindicación Ia, caracterizado porque cuando se trata de obtener imágenes -8-2 .- A method for the decoration of tiles and pavement, according to claim I, characterized in that when it comes to image -8-
Los términos en que se ha redactado esta memoria deberán ser tomados siempre en sentido amplio y no limitativo. The terms in which this report has been written must always be taken in a broad and non-limiting sense.
-9 --9 -
policromáticas la fase de laminación e insolación se repite tantas veces como colores o fotolitos participan en la misma.The polychromatic phase of lamination and insolation is repeated as many times as colors or photoliths participate in it.
3 a.- Procedimiento para la ornamentación de azulejos y pavimentos, según reivindicaciones anteriores, caracterizado porque la temperatura de horneado es del orden de 1.050°C.3 .- A method for the decoration of tiles and pavement, according to previous claims, characterized in that the baking temperature is order 1050 ° C.
4a.- Procedimiento para la ornamentación de azulejos y pavimentos, según reivindicaciones Ia, 2a y 3a, caracterizado porque la curva de cocción durante la fase de horneado es tal que se alcanzan 350°C de temperatura en la primera hora, 700°C de temperatura en 2 h. 45. min., 1.050°C en los 30 minutos siguientes, se mantiene esta temperatura durante 10 min. , y finalmente se retorna a la temperatura ambiente durante un tiempo de 2 horas 30 minutos.4 a .- Procedure for the ornamentation of tiles and pavements, according to claims I a , 2 a and 3 a , characterized in that the cooking curve during the baking phase is such that a temperature of 350 ° C is reached in the first hour, 700 ° C temperature in 2 h. 45. min., 1.050 ° C in the next 30 minutes, this temperature is maintained for 10 min. , and finally it returns to room temperature for a time of 2 hours 30 minutes.
5a.- Procedimiento para la ornamentación de azulejos y pavimentos, según reivindicaciones anteriores, caracterizado porque el nivel de brillo resultante se obtiene en función de la cantidad de fundente añadido a los colores cerámicos . 5 .- A method for the decoration of tiles and pavement, according to previous claims, characterized in that the resulting level of brightness is obtained depending on the amount of flux added to the ceramic color.
PCT/ES1999/000079 1998-03-31 1999-03-26 Process for the decoration of wall-tiles and floor-tiles WO1999050075A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BR9909426-6A BR9909426A (en) 1998-03-31 1999-03-26 Procedure for ornamentation of tiles and floors
EP99910382A EP1127705A1 (en) 1998-03-31 1999-03-26 Process for the decoration of wall-tiles and floor-tiles
AU29356/99A AU2935699A (en) 1998-03-31 1999-03-26 Process for the decoration of wall-tiles and floor-tiles
CA002326428A CA2326428A1 (en) 1998-03-31 1999-03-26 Process for the decoration of wall-tiles and floor-tiles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ES9800677A ES2150846B1 (en) 1998-03-31 1998-03-31 PROCEDURE FOR THE ORNAMENTATION OF TILES AND PAVEMENTS.
ESP9800677 1998-03-31

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WO1999050075A1 true WO1999050075A1 (en) 1999-10-07

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AU (1) AU2935699A (en)
CA (1) CA2326428A1 (en)
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ES2213453B2 (en) * 2002-05-18 2005-06-16 Maria Rosario Delgado Poblete MONOCOLOR REPRODUCTION PROCEDURE OF PHOTOGRAPHS IN GRES PORCELANICO.
ES2300186B1 (en) * 2006-05-19 2009-03-16 Francisco Javie Ramon Lima LAPIDA CERAMIC DESIGN.
ES2321265B1 (en) * 2007-09-18 2010-02-08 Jose Castañ Centelles PROCEDURE FOR OBTAINING PRINTED EYES AND LIPS AS OBTAINED.
ES2357211B9 (en) * 2008-05-12 2013-06-19 Fco. Javier Ramon Lima FIRST CERTIFICATE OF ADDITION TO THE PATENT N. 200.601.306: LAPIDA CERAMICA DE DESIGN
CN102275455B (en) * 2011-06-20 2012-09-12 景德镇陶瓷学院 Method for designing ceramic decorative patterns

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GB1455585A (en) * 1973-03-07 1976-11-17 Alexander Boston Holdings Ltd Method of producing a reproduction of a pattern or representation on a ceramic article
WO1996033446A1 (en) * 1995-04-16 1996-10-24 Indigo N.V. Process for forming an image on ceramic substrates

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BE739282A (en) * 1968-09-23 1970-03-02
ES409619A1 (en) * 1972-12-14 1976-03-16 Levoni New procedure of serigraphy in quadricomy on tiles and analogs. (Machine-translation by Google Translate, not legally binding)
GB1455585A (en) * 1973-03-07 1976-11-17 Alexander Boston Holdings Ltd Method of producing a reproduction of a pattern or representation on a ceramic article
WO1996033446A1 (en) * 1995-04-16 1996-10-24 Indigo N.V. Process for forming an image on ceramic substrates

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CA2326428A1 (en) 1999-10-07
EP1127705A1 (en) 2001-08-29
ES2150846B1 (en) 2001-06-16
ES2150846A1 (en) 2000-12-01
AU2935699A (en) 1999-10-18

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