WO1999037581A3 - High efficiency glow discharge gaseous processing system for hydrogen peroxide production and other chemical processing of gases - Google Patents

High efficiency glow discharge gaseous processing system for hydrogen peroxide production and other chemical processing of gases Download PDF

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Publication number
WO1999037581A3
WO1999037581A3 PCT/US1999/000911 US9900911W WO9937581A3 WO 1999037581 A3 WO1999037581 A3 WO 1999037581A3 US 9900911 W US9900911 W US 9900911W WO 9937581 A3 WO9937581 A3 WO 9937581A3
Authority
WO
WIPO (PCT)
Prior art keywords
discharge
high efficiency
glow discharge
gases
hydrogen peroxide
Prior art date
Application number
PCT/US1999/000911
Other languages
French (fr)
Other versions
WO1999037581A2 (en
Inventor
William M Moeny
David M Barrett
Robert W Bennett
Original Assignee
William M Moeny
David M Barrett
Robert W Bennett
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by William M Moeny, David M Barrett, Robert W Bennett filed Critical William M Moeny
Priority to AU22309/99A priority Critical patent/AU2230999A/en
Publication of WO1999037581A2 publication Critical patent/WO1999037581A2/en
Publication of WO1999037581A3 publication Critical patent/WO1999037581A3/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122—Incoherent waves
    • B01J19/123—Ultraviolet light
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122—Incoherent waves
    • B01J19/125—X-rays
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/10—Preparation of ozone
    • C01B13/11—Preparation of ozone by electric discharge
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/027—Preparation from water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/0805—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B01J2219/0807—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes
    • B01J2219/0809—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes employing two or more electrodes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/0805—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B01J2219/0807—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes
    • B01J2219/0824—Details relating to the shape of the electrodes
    • B01J2219/0826—Details relating to the shape of the electrodes essentially linear
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/0805—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B01J2219/0807—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes
    • B01J2219/0824—Details relating to the shape of the electrodes
    • B01J2219/0826—Details relating to the shape of the electrodes essentially linear
    • B01J2219/083—Details relating to the shape of the electrodes essentially linear cylindrical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/0805—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B01J2219/0845—Details relating to the type of discharge
    • B01J2219/0847—Glow discharge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0875—Gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00—Preparation of ozone by electrical discharge
    • C01B2201/80—Additional processes occurring alongside the electrical discharges, e.g. catalytic processes
    • C01B2201/82—Treatment with ultraviolet light
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2201/00—Preparation of ozone by electrical discharge
    • C01B2201/80—Additional processes occurring alongside the electrical discharges, e.g. catalytic processes
    • C01B2201/84—Treatment with magnetic fields

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
  • Lasers (AREA)

Abstract

A high efficiency plasma processing system for use in the generation of large quantities of gases, particularly hydrogen peroxide or ozone, for chemical commercial and industrial applications is based upon a homogeneous electrical glow discharge. In addition to the homogenous discharge, the high efficiency of ozone or other chemical production is achieved by exciting the discharge with high voltage pulses which have a voltage rate-of-rise in excess of 500 V/ns and incorporating an internal gas circulation system which maintains the temperature of the process gas to a level where the thermal decomposition of ozone, for example, is significantly reduced. A homogeneous and stable atmospheric glow discharge is developed by preionizing the discharge region with ultra-violet radiation, for example, immediately before the application of the main high voltage pulse across the electrodes of the discharge cell.
PCT/US1999/000911 1998-01-22 1999-01-15 High efficiency glow discharge gaseous processing system for hydrogen peroxide production and other chemical processing of gases WO1999037581A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU22309/99A AU2230999A (en) 1998-01-22 1999-01-15 High efficiency glow discharge gaseous processing system for hydrogen peroxide production and other chemical processing of gases

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US7221198P 1998-01-22 1998-01-22
US60/072,211 1998-01-22
US5737798A 1998-04-08 1998-04-08
US09/057,377 1998-04-08

Publications (2)

Publication Number Publication Date
WO1999037581A2 WO1999037581A2 (en) 1999-07-29
WO1999037581A3 true WO1999037581A3 (en) 1999-10-28

Family

ID=26736412

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1999/000911 WO1999037581A2 (en) 1998-01-22 1999-01-15 High efficiency glow discharge gaseous processing system for hydrogen peroxide production and other chemical processing of gases

Country Status (2)

Country Link
AU (1) AU2230999A (en)
WO (1) WO1999037581A2 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1052220A3 (en) * 1999-05-13 2003-02-05 21 Century Environment Co. Ltd. Equipment for generating ionized gas using high-voltage discharge
CN100460315C (en) * 2003-11-28 2009-02-11 大连理工大学 Method and device for directly synthesizing hydrogen peroxide at room temperature
PL377451A1 (en) * 2005-10-05 2007-04-16 Instytut Wysokich Ciśnień PAN Methods of reaction leading, chemical reactor
FR2905370B1 (en) * 2006-08-31 2009-02-20 Arkema France PROCESS FOR PRODUCING HYDROGEN PEROXIDE
JP2011006284A (en) * 2009-06-25 2011-01-13 Toyota Motor Corp Ozonizer
ITVR20120123A1 (en) * 2012-06-13 2013-12-14 Renato Consolati DEVICE FOR THE ENERGETIC STRESS OF A SUBSTANCE.
CN104619106B (en) * 2015-01-15 2018-04-20 合肥工业大学 A kind of device for realizing uniform glow discharge in atmosphere air
KR101709644B1 (en) * 2015-12-21 2017-02-23 에스케이건설 주식회사 Water Treating Apparatus for generating hydrogen peroxide
GB2583897A (en) * 2019-04-05 2020-11-18 Servomex Group Ltd Glow plasma stabilisation
US11459883B2 (en) 2020-08-28 2022-10-04 Halliburton Energy Services, Inc. Plasma chemistry derived formation rock evaluation for pulse power drilling
US11585743B2 (en) 2020-08-28 2023-02-21 Halliburton Energy Services, Inc. Determining formation porosity and permeability
US11536136B2 (en) 2020-08-28 2022-12-27 Halliburton Energy Services, Inc. Plasma chemistry based analysis and operations for pulse power drilling
US11499421B2 (en) 2020-08-28 2022-11-15 Halliburton Energy Services, Inc. Plasma chemistry based analysis and operations for pulse power drilling
US11619129B2 (en) 2020-08-28 2023-04-04 Halliburton Energy Services, Inc. Estimating formation isotopic concentration with pulsed power drilling
CN111992161A (en) * 2020-09-04 2020-11-27 江西科技学院 Photocatalytic degradation device for copper slag pollutants and use method thereof
CN112320765B (en) * 2020-09-29 2023-02-14 欧奏沛尔(江苏)环保技术有限公司 Composite high-voltage electrode and double-electrode cooling ozone generator

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4507266A (en) * 1982-03-10 1985-03-26 Tokyo Shibaura Denki Kabushiki Kaisha Glow discharge generating apparatus
US5138627A (en) * 1988-04-22 1992-08-11 Siemens Aktiengesellschaft Preionizationd device, in particular for x-ray preionization in discharge-pumped gas lasers, in particular excimer lasers

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4507266A (en) * 1982-03-10 1985-03-26 Tokyo Shibaura Denki Kabushiki Kaisha Glow discharge generating apparatus
US5138627A (en) * 1988-04-22 1992-08-11 Siemens Aktiengesellschaft Preionizationd device, in particular for x-ray preionization in discharge-pumped gas lasers, in particular excimer lasers

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
SAJIKI KAZUAKI, NISIZAKA TOSHIHIRO, NAKAJIMA SHIN, WATANABE SHUNTARO: "UV Pre-Ionized Wide-Aperture XeCl Laser Using Magnetic Pulse Compression", IEEE JOURNAL OF QUANTUM ELECTRONICS, vol. 31, no. 12, 1995, pages 2183 - 2189, XP000541559 *
SMILANSKI I, BYRON S R, BURKES T R: "Electrical excitation of an XeCl laser using magnetic pulse compression", APPL.PHYS.LETT., vol. 40, no. 7, 1 April 1982 (1982-04-01), pages 547 - 548, XP000706415 *

Also Published As

Publication number Publication date
AU2230999A (en) 1999-08-09
WO1999037581A2 (en) 1999-07-29

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