WO1999017932A2 - Methods for controlling bacteria, mold, mildew and odors in conjunction with construction of buildings and related articles therefor - Google Patents

Methods for controlling bacteria, mold, mildew and odors in conjunction with construction of buildings and related articles therefor Download PDF

Info

Publication number
WO1999017932A2
WO1999017932A2 PCT/US1998/020509 US9820509W WO9917932A2 WO 1999017932 A2 WO1999017932 A2 WO 1999017932A2 US 9820509 W US9820509 W US 9820509W WO 9917932 A2 WO9917932 A2 WO 9917932A2
Authority
WO
WIPO (PCT)
Prior art keywords
organisms
micro
controlling
growth
woven fabric
Prior art date
Application number
PCT/US1998/020509
Other languages
French (fr)
Other versions
WO1999017932A3 (en
Inventor
Frank L. Hollowell, Jr.
Paul C. Weber
Gregory J. Lacasse
Original Assignee
Synthetic Industries, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Synthetic Industries, Inc. filed Critical Synthetic Industries, Inc.
Priority to AU96746/98A priority Critical patent/AU9674698A/en
Publication of WO1999017932A2 publication Critical patent/WO1999017932A2/en
Publication of WO1999017932A3 publication Critical patent/WO1999017932A3/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282Addition polymers
    • D04H1/4291Olefin series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D04H1/43825Composite fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0005Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
    • D06N7/0039Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by the physical or chemical aspects of the layers
    • D06N7/0044Sealing or barrier layers, e.g. against solvents, asphalt, plasticisers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0063Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
    • D06N7/0089Underlays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00Floor coverings
    • B32B2471/02Carpets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels
    • B32B2607/02Wall papers, wall coverings

Definitions

  • the present invention relates to a method for controlling bacteria, mold, mildew and related odors which frequently occur in areas where dampness and moisture are present as well as where bacteria can flourish.
  • Typical examples of such environments include floors and wall surfaces of hospitals, nursing homes, hotels, commercial kitchens, exercise facilities and the like.
  • the method of the present invention involves the usage of a non-woven antimicrobial material, located between a floor covering, such as carpet, and the flooring and surrounding areas.
  • the present invention also provides non-woven fabrics having antimicrobial properties.
  • antimicrobial carpets are known which are topically treated with minimal doses of antimicrobial agents. While these applications meet Government Standards for commercial carpets, namely Method GS-20, as the test for effectiveness, this test has inherent deficiencies. For one, by the nature of the test, minimal additions of antimicrobial agent have proven effective in the test; for another, the way the test is administered, topically treating the face fibers or the backing will pass the test and finally, the low dosage levels historically used in the industry have not translated in proven product performance to the end consumer and therefore, these have not been viewed as effective or as offering value added benefits.
  • Another disadvantage with topical treatments other than the minimal amount of agent that is employed is that the agent is readily removed, particularly by cleaning operations. The latter often effect a trade-off, however, because the cleaning operation can employ antimicrobial agents whose residue is left on and in the carpet for subsequent duty in killing the bacteria that is present. This too, can lead to erroneous evaluations of the initial treatment.
  • the antimicrobial agent migrates to the surface of the binder and onto the fibers, continuously until the supply is exhausted.
  • Such non-woven fabrics are useful in the manufacture of washing and wiping cloths, hospital gowns, sheets, pillow cases, and curtains, and as backing agents for garments, bed spreads and the like.
  • U.S. Pat. No. 4,769,268 relates to the stabilization of antimicrobial agents, thermoplastic compositions containing the same, and a method of melt processing such thermoplastic compositions.
  • the patent discloses that it is known to form fibers from the thermoplastic compositions and to utilize the fibers to form articles such as carpets.
  • U.S. Pat. No. 4,343,853 discloses two-face fabrics containing antimicrobial agents and a method for imparting antimicrobial characteristics to two-face fabrics.
  • the construction of the latter involves the formation of a face fabric, having no antimicrobial additives, and a backing fabric, having an antimicrobial additive incorporated therein.
  • the patent discloses and claims such fabrics and a method of imparting antibacterial characteristics to untreated yarns in a two-face fabric. Typical examples include the construction of athletic sweatshirts and of carpets.
  • the two fabrics are tied together in a conventional manner and one of the objects achieved is migration of the antimicrobial agent into the untreated, face fabric.
  • the patent states that growth of mildew and other odor forming bacteria is significantly decreased by the invention, as compared to other known approaches, where one face fabric is treated to protect against antimicrobial growth on the other.
  • an object of the present invention to provide a method for controlling biological attack from micro-organisms which come into contact with floors, floor coverings and wall surfaces.
  • the present invention provides a method for controlling the growth of micro-organisms in conjunction with construction of buildings comprising applying a non-woven fabric containing at least one antimicrobial agent to floor or wall surfaces where micro-organisms can reside; applying a covering thereover, the fabric forming a barrier between the surface and the covering, whereby passage of micro-organisms through the covering to the underlying surface is inhibited by the fabric.
  • the present invention also provides non-woven fabrics for controlling the growth of micro-organisms in buildings comprising from 50 to about 100 percent by weight of a synthetic fiber, containing at least one antimicrobial agent, in an amount of about 25 to about 50,000 parts by weight per million of the fiber and, from 0 to about 50 percent by weight of a synthetic fiber, devoid of antimicrobial agents, the non-woven fabric being employed to surfaces beneath subsequent covering materials.
  • FIG. 1 is a perspective view, partially broken away, depicting carpet applied over a non-woven antimicrobial barrier fabric, on a floor surface, according to the method of the present invention-
  • Fig. 2 is a perspective view, partially broken away, depicting the use of the non-woven antimicrobial barrier fabric of the present invention, having been applied behind wallpaper;
  • Fig. 3 is a perspective view, partially broken away, depicting the use of the non-woven antimicrobial barrier fabric of the present invention, having been applied behind tile;
  • Fig. 4 is a perspective view, partially broken away, depicting the use of the non-woven antimicrobial barrier fabric of the present invention, having been applied beneath stucco.
  • the present invention is directed toward a method for controlling the growth and spread of micro-organisms, including but not limited to various strains of bacteria, fungi, algae and related living contaminants which spread and cause disease, as well as mold, mildew, related odors and occasionally, staining of affected areas and surrounding surfaces.
  • micro-organisms including but not limited to various strains of bacteria, fungi, algae and related living contaminants which spread and cause disease, as well as mold, mildew, related odors and occasionally, staining of affected areas and surrounding surfaces.
  • dampness such as in basement areas, mold and mildew and the accompanying odor can be inhibited and virtually eliminated by treating the affected areas according to the present invention.
  • carpet is applied over floor surfaces, and occasionally some of the vertical wall surfaces, for reasons of aesthetics, sound barrier properties, comfort and safety, among others.
  • carpet can collect and house many micro-organisms, particularly due to spillage.
  • carpet is a covering, dampness and wetness are not readily removed.
  • the base or backing of the carpet becomes a breeding area for the various micro-organisms which can cause and spread disease as well as mold, mildew and the like.
  • carpet is typically applied to concrete floor surfaces in residential and commercial settings, the problem also exists over wooden flooring, various wall surfaces and virtually any surface onto which a covering can be applied. These surfaces include, without limitation, wallboard and floors behind and beneath tile; framework, sheathing, plywood and particle board used in construction behind stucco and other forms of exterior fascia; walls, behind wallpaper and other wall covering materials and substantially any other horizontal, vertical or sloping surfaces (roofs) where moisture can accumulate and/or bacteria, mold, fungus, mildew and the like can reside.
  • the method of this invention includes the use of a non-woven fabric comprising synthetic fibers.
  • the manufacture of non- woven fabric is well known and thus, does not require disclosure here.
  • the preferred fabric comprises 50 percent by weight rayon and 50 percent by weight polypropylene.
  • the polypropylene is, in turn, produced from antimicrobial fibers while the rayon is devoid of antimicrobial agents.
  • the fabric has a weight of approximately 0.5 to about 50 ounces per square yard, with ranges of from about 0.5 to 15 ounces per square yard being preferred and ranges of from about 0.5 to 5 ounces per square yard being most preferred.
  • the non-woven fabric can comprise 100 percent by weight of a single fiber type, such as polypropylene.
  • polyolef ins such as polyethylene and polymethyl pentene; polyesters; nylon; acrylics; acetates; and polyvinyl chlorides and any other typical fiber-forming polymeric materials.
  • polyolef ins such as polyethylene and polymethyl pentene; polyesters; nylon; acrylics; acetates; and polyvinyl chlorides and any other typical fiber-forming polymeric materials.
  • Still other polymeric materials suitable, but less preferred, as fibers for the present invention include acrylonitrile-butadiene- styrene terpolymer (ABS), polysulphone, polybutylene terephthalate (PBT) and polyurethane.
  • Amorphous polyolef ins such as polyethylene, polypropylene, and polymethyl pentene are generally most preferred because these fiber-forming polymers provide spaces or "zones" which are suitable for the deposition of antimicrobial agents within the fibers.
  • Crystalline polymers such as nylon and polyester, while capable of being used to the purposes of the present invention, generally provide less suitable environments in which to place the antimicrobial agents. Any polymeric fibers which include sufficient space or large enough "zones" to deposit the antimicrobial agents without deleteriously altering the molecular structure or physical properties of the antimicrobial agents are desirable.
  • useful fiber lengths can range from about 0.04 to about 6 inches, with about 0.75 to about 3 inches being preferred and from about 0.9 to about 2.1 inches being most preferred.
  • Useful fiber diameters can range from about 0.00011 to about 0.0038 inches, with about 0.0007 to about 0.0022 inches being preferred and from about 0.0007 to about 0.0014 inches being most preferred although broader ranges are not to be necessarily precluded. It is also customary to refer to the fiber yield, i.e., denier (determined by the weight in grams of a 9000 yard length), rather than diameter. Accordingly, useful deniers preferably range from about 0.04 to about 60 with about 2 to about 20 being preferred and from about 2 to 8 being most preferred.
  • Antimicrobial agents useful for practice of the present invention preferably are non-toxic and environmentally safe both during use and disposal. Most antimicrobial agents control the growth of organisms by penetrating the thin cell walls of the organism, thereby disrupting the metabolic function of the organism and ultimately killing the organism. However, non-toxic antimicrobial agents cannot successfully attack human and red-blooded animal cells, which have thick cell walls, thereby making these antimicrobial agents toxicologically safe in the dosage range indicated hereinbelow.
  • antimicrobial agents includes any substance which effectively protects the fibers, the carpet, related adhesives for the application of carpet and, the surfaces to which the carpet is applied from biological attack from organisms including, but not necessarily limited to, fungi, bacteria, mold, mildew, algae, and other thin-celled organisms.
  • an antimicrobial agent suitable for use in the present invention is a phenolic-based product with an extremely low toxicity level (LD 50 of 3000-5000 mg/kg at 100%) currently available from Microban Products Company of Huntersville, North Carolina, under the tradename "Microban B". "Microban” is believed to be a registered trademark owned by Microban
  • Microban B is a polymer additive engineered to provide a controlled migration to the surface of the product in which it is incorporated, providing long-term efficacy, as detailed hereinbelow.
  • Dosage rates for the addition of antimicrobial agents to the fibers employed in the present invention vary signi icantly depending upon the strength required to inhibit targeted bacteria, fungi, mold, mildew and the like and can be coordinated with the amount of antimicrobial-containing fibers employed in the non-woven fabric.
  • the effective dosage will vary from about 25 parts per million to about 50,000 parts per million (ppm) by weight per weight of the fibers, with 250 to about 25,000 ppm being preferred and 400 to 20,000 ppm being most preferred, although lesser or additional quantities may be used to achieve suitable efficacy.
  • a preferred amount is 5000 ppm of the foregoing antimicrobial agent in the polypropylene fiber.
  • the selection of any specific amount will depend upon the antimicrobial objective to be achieved.
  • the preferred method of adding antimicrobials to the fibers is in the spinning, or extrusion, portion of the fiber-forming process. At this point, the antimicrobial materials are introduced while the fiber-forming polymers or materials are in the molten or liquid state, either from heat or chemical action. As the fibers harden, the antimicrobial agents are seated into the amorphous zones of the fiber. Less preferred, but nevertheless suitable, is topical coating of antimicrobials onto the fiber surface.
  • the fibers when it is indicated that the fibers "include” an effective amount of at least one antimicrobial agent, it is meant that the antimicrobial agent may either be incorporated into or coated onto the fibers.
  • the antimicrobial agents when the antimicrobial agents are added to the fiber while the fiber is in its molten or liquid stage, the agent lodges in an amorphous, or clear zone within the fiber as it hardens. At this point, due to a process known as “solid state migration", the antimicrobial agent migrates to the surface of the fiber until equilibrium is reached in the internal vapor pressure of the polymer. When equilibrium is reached, the migration ceases and the antimicrobial agent is available to control organisms that contact it, or are in its zone of inhibition.
  • the floor is protected against becoming an environment and home to the micro-organisms.
  • Bacteria and the like passing downwardly through the carpet or other permeable floor covering, as well as various micro-organisms propagated from bodily fluids, will be controlled upon contact with the barrier fabric.
  • passage of micro-organisms down into the floor and other support surfaces or substrates is inhibited, as is further transmission of the micro-organisms to the surface of the carpet or floor covering where they can directly pass to humans, animals, equipment and the like.
  • the present invention provides antimicrobial activity in and around carpet or other coverings which reduces the labor of disinfecting such areas.
  • a greater life can also be imparted to the carpet and, in turn, the contiguous flooring and wall surfaces, thereby reducing the interval between take-up and replacement, as well as the labor and material attendant thereto.
  • a typical carpet is denoted generally by the numeral 10 in Fig. 1.
  • Such a carpet 10 includes a plurality of face yarns 12 which are tufted or sewn into and through a primary backing fabric 14 and which are more securely held in place by the secondary backing fabric 16 attached to the backstitched side of primary backing fabric 14.
  • the secondary backing fabric 16 aids in providing improved dimensional stability and strength of the carpet and covers the back of the primary backing fabric 14.
  • a non-woven fabric 18 is placed between the floor 20 and carpet 10. Although depicted in use with carpet, it is to be appreciated that the non-woven fabric 18 could be utilized with other floor covering materials and possibly with some wall covering materials.
  • Figs. 2-4 the use of the non-woven fabric barrier 18 of the present invention in other building environments has been presented.
  • the fabric 18 has been applied to wall surfaces 22 prior to the application of wallpaper 24.
  • the fabric 18 has been applied to wall surfaces 26 of shower areas prior to the application of tile 28.
  • the fabric 18 has been applied to base structure wall surfaces 30 prior to the application of exterior stucco 32. From the foregoing depictions, it is to be appreciated that the non-woven barrier fabric 18 could be utilized in many other applications where mold, mildew, bacteria and/or fungus and the like are desirably controlled.
  • the phenol-based antimicrobial agent, Microban B was added at a level of about approximately 5000 ppm during the extrusion process. More particularly, the antimicrobial agent was added at a rate of about 2.27 grams per pound of fiber. The resultant fiber was then extruded to about 0.04 to 60 DPF, with about 2 to 20 DPF being preferred and about 2 to 8 DPF being most preferred.
  • the carpet square was sold for commercial use as antimicrobial and was about 4 years old.
  • the non-woven fabric underneath was installed approximately six months earlier.
  • the dampness of the carpet surface was noticed as was a pronounced heavy sour odor in the area that became stronger when the carpet square that did not have the non-woven fabric underneath was removed. Results of the test are reported in Table I.
  • the method of the present invention is useful in controlling the growth of bacteria, mold, mildew, fungus and the like.
  • Practice includes the use of the non-woven fabric as described herein.
  • the method and related components are particularly suited for use in commercial buildings and the like, but are not necessarily limited thereto, inasmuch as controlling mildew in damp basements, constitutes an important residential use.
  • the non-woven barrier fabric of the present invention can be manufactured with known equipment and methods, as well as with materials other than those disclosed herein.
  • the antimicrobial agents disclosed herein have been provided for purposes of exemplification only and thus, it is to be appreciated that other materials can be substituted without falling outside of the scope of this invention.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Plant Pathology (AREA)
  • Microbiology (AREA)
  • Biochemistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Building Environments (AREA)

Abstract

A method for controlling the growth of micro-organisms in conjunction with construction of building includes the steps of applying a non-woven fabric containing at least one antimicrobial agent to floor or wall surfaces where micro-organisms can reside; applying a covering thereover, the fabric forming a barrier between the surface and the covering, whereby passage of micro-organisms through the covering to the underlying surface is inhibited by the fabric. Non-woven fabrics (18) for controlling the growth of micro-organisms in buildings comprise from 50 to about 100 percent by weight of a synthetic fiber, containing at least one antimicrobial agent, in an amount of about 25 to 50,000 parts per million of the fiber, by weight and, from 0 to about 50 percent by weight of a synthetic fiber, devoid of antimicrobial agents, the non-woven fabric being employed to surfaces beneath subsequent covering materials.

Description

METHODS FOR CONTROLLING BACTERIA, MOLD, MILDEW AND ODORS IN CONJUNCTION WITH CONSTRUCTION OF BUILDINGS AND RELATED ARTICLES THEREFOR
TECHNICAL FIELD
The present invention relates to a method for controlling bacteria, mold, mildew and related odors which frequently occur in areas where dampness and moisture are present as well as where bacteria can flourish. Typical examples of such environments include floors and wall surfaces of hospitals, nursing homes, hotels, commercial kitchens, exercise facilities and the like.
Residential areas are also affected and in particular, where dampness occurs or prevails, such as basement areas, porches and slab foundations. The method of the present invention involves the usage of a non-woven antimicrobial material, located between a floor covering, such as carpet, and the flooring and surrounding areas. The present invention also provides non-woven fabrics having antimicrobial properties.
BACKGROUND OF THE INVENTION
Historically, antimicrobial carpets are known which are topically treated with minimal doses of antimicrobial agents. While these applications meet Government Standards for commercial carpets, namely Method GS-20, as the test for effectiveness, this test has inherent deficiencies. For one, by the nature of the test, minimal additions of antimicrobial agent have proven effective in the test; for another, the way the test is administered, topically treating the face fibers or the backing will pass the test and finally, the low dosage levels historically used in the industry have not translated in proven product performance to the end consumer and therefore, these have not been viewed as effective or as offering value added benefits. Another disadvantage with topical treatments other than the minimal amount of agent that is employed is that the agent is readily removed, particularly by cleaning operations. The latter often effect a trade-off, however, because the cleaning operation can employ antimicrobial agents whose residue is left on and in the carpet for subsequent duty in killing the bacteria that is present. This too, can lead to erroneous evaluations of the initial treatment.
It is also known to employ antimicrobial agents within the fibers, from which various fabrics are woven, for a variety of end uses. One such technique is described in U.S. Pat. No. 3,959,556 which describes composite antimicrobial yarns comprising a mixture of natural and synthetic fibers, the latter having incorporated therein certain antimicrobial agents which are capable of migrating to the surface of the fiber and then transferring their antimicrobial properties to the natural fibers. U.S. Pat. No. 4,401,712 discloses non-woven fabrics having antimicrobial properties. The invention is directed toward the addition of antimicrobial agents to the binding agent which is used to bind a web of textile fibers. The antimicrobial agent migrates to the surface of the binder and onto the fibers, continuously until the supply is exhausted. Such non-woven fabrics are useful in the manufacture of washing and wiping cloths, hospital gowns, sheets, pillow cases, and curtains, and as backing agents for garments, bed spreads and the like.
U.S. Pat. No. 4,769,268, relates to the stabilization of antimicrobial agents, thermoplastic compositions containing the same, and a method of melt processing such thermoplastic compositions. The patent discloses that it is known to form fibers from the thermoplastic compositions and to utilize the fibers to form articles such as carpets.
U.S. Pat. No. 4,343,853 discloses two-face fabrics containing antimicrobial agents and a method for imparting antimicrobial characteristics to two-face fabrics. The construction of the latter involves the formation of a face fabric, having no antimicrobial additives, and a backing fabric, having an antimicrobial additive incorporated therein. The patent discloses and claims such fabrics and a method of imparting antibacterial characteristics to untreated yarns in a two-face fabric. Typical examples include the construction of athletic sweatshirts and of carpets. The two fabrics are tied together in a conventional manner and one of the objects achieved is migration of the antimicrobial agent into the untreated, face fabric. The patent states that growth of mildew and other odor forming bacteria is significantly decreased by the invention, as compared to other known approaches, where one face fabric is treated to protect against antimicrobial growth on the other.
While the art has dealt with the manufacture of fibers, fabrics and even carpet, having antimicrobial properties, it has not provided a method for controlling micro-organisms growing in, on and around floors and wall surfaces or for controlling mold, mildew and related odors. The method of the present invention can be practiced utilizing a non-woven antimicrobial fabric. Such fabrics and related articles are also novel.
SUMMARY OF INVENTION
It is, therefore, an object of the present invention to provide a method for controlling biological attack from micro-organisms which come into contact with floors, floor coverings and wall surfaces.
It is another object of the present invention to provide a method, as above, which can control the growth of bacteria, mold, mildew and the generation of related odors in damp areas of residential, commercial and public buildings.
It is still another object of the present invention to provide a non- woven fabric, containing one or more antimicrobial agents, for use in conjunction with practice of the method of the present invention.
It is still a further object to provide a method for controlling biological attack from micro-organisms which come into contact with carpet or other floor coverings applied directly to concrete floor surfaces which includes the addition of synthetic fibers, containing one or more antimicrobial agents, to the concrete. At least one or more of the foregoing objects, together with the advantages thereof over the known art relating to methods for controlling the growth of micro-organisms in and around floor and wall surfaces, which shall become apparent from the specification which follows, are accomplished by the invention as hereinafter described and claimed. In general, the present invention provides a method for controlling the growth of micro-organisms in conjunction with construction of buildings comprising applying a non-woven fabric containing at least one antimicrobial agent to floor or wall surfaces where micro-organisms can reside; applying a covering thereover, the fabric forming a barrier between the surface and the covering, whereby passage of micro-organisms through the covering to the underlying surface is inhibited by the fabric.
The present invention also provides non-woven fabrics for controlling the growth of micro-organisms in buildings comprising from 50 to about 100 percent by weight of a synthetic fiber, containing at least one antimicrobial agent, in an amount of about 25 to about 50,000 parts by weight per million of the fiber and, from 0 to about 50 percent by weight of a synthetic fiber, devoid of antimicrobial agents, the non-woven fabric being employed to surfaces beneath subsequent covering materials.
BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a perspective view, partially broken away, depicting carpet applied over a non-woven antimicrobial barrier fabric, on a floor surface, according to the method of the present invention-
Fig. 2 is a perspective view, partially broken away, depicting the use of the non-woven antimicrobial barrier fabric of the present invention, having been applied behind wallpaper;
Fig. 3 is a perspective view, partially broken away, depicting the use of the non-woven antimicrobial barrier fabric of the present invention, having been applied behind tile; and
Fig. 4 is a perspective view, partially broken away, depicting the use of the non-woven antimicrobial barrier fabric of the present invention, having been applied beneath stucco.
PREFERRED EMBODIMENT FOR CARRYING OUT THE INVENTION As noted hereinabove, the present invention is directed toward a method for controlling the growth and spread of micro-organisms, including but not limited to various strains of bacteria, fungi, algae and related living contaminants which spread and cause disease, as well as mold, mildew, related odors and occasionally, staining of affected areas and surrounding surfaces. Thus, where dampness occurs, such as in basement areas, mold and mildew and the accompanying odor can be inhibited and virtually eliminated by treating the affected areas according to the present invention. In addition to damp basement areas, it is desirable to control bacteria and other micro-organisms in hotels, hospitals, nursing homes, day care centers, recreational, exercise and health clubs, commercial kitchens, and the like. In many of these environments, carpet is applied over floor surfaces, and occasionally some of the vertical wall surfaces, for reasons of aesthetics, sound barrier properties, comfort and safety, among others. Unfortunately, carpet can collect and house many micro-organisms, particularly due to spillage. Moreover, because carpet is a covering, dampness and wetness are not readily removed. In the case of spillage, the base or backing of the carpet becomes a breeding area for the various micro-organisms which can cause and spread disease as well as mold, mildew and the like.
Once these liquids and accompanying micro-organisms pass through the carpet to the underlying support structure, it too can and does become infected. While carpet is typically applied to concrete floor surfaces in residential and commercial settings, the problem also exists over wooden flooring, various wall surfaces and virtually any surface onto which a covering can be applied. These surfaces include, without limitation, wallboard and floors behind and beneath tile; framework, sheathing, plywood and particle board used in construction behind stucco and other forms of exterior fascia; walls, behind wallpaper and other wall covering materials and substantially any other horizontal, vertical or sloping surfaces (roofs) where moisture can accumulate and/or bacteria, mold, fungus, mildew and the like can reside.
In its preferred embodiment, the method of this invention includes the use of a non-woven fabric comprising synthetic fibers. The manufacture of non- woven fabric is well known and thus, does not require disclosure here. The preferred fabric comprises 50 percent by weight rayon and 50 percent by weight polypropylene. The polypropylene is, in turn, produced from antimicrobial fibers while the rayon is devoid of antimicrobial agents. Typically, the fabric has a weight of approximately 0.5 to about 50 ounces per square yard, with ranges of from about 0.5 to 15 ounces per square yard being preferred and ranges of from about 0.5 to 5 ounces per square yard being most preferred. It is also to be appreciated that the non-woven fabric can comprise 100 percent by weight of a single fiber type, such as polypropylene.
Other useful synthetic fibers for practice of the present invention preferably include the polyolef ins, such as polyethylene and polymethyl pentene; polyesters; nylon; acrylics; acetates; and polyvinyl chlorides and any other typical fiber-forming polymeric materials. Still other polymeric materials suitable, but less preferred, as fibers for the present invention include acrylonitrile-butadiene- styrene terpolymer (ABS), polysulphone, polybutylene terephthalate (PBT) and polyurethane. Amorphous polyolef ins such as polyethylene, polypropylene, and polymethyl pentene are generally most preferred because these fiber-forming polymers provide spaces or "zones" which are suitable for the deposition of antimicrobial agents within the fibers. Crystalline polymers such as nylon and polyester, while capable of being used to the purposes of the present invention, generally provide less suitable environments in which to place the antimicrobial agents. Any polymeric fibers which include sufficient space or large enough "zones" to deposit the antimicrobial agents without deleteriously altering the molecular structure or physical properties of the antimicrobial agents are desirable. With respect to the preferred dimensions for the fibers, useful fiber lengths can range from about 0.04 to about 6 inches, with about 0.75 to about 3 inches being preferred and from about 0.9 to about 2.1 inches being most preferred. Useful fiber diameters can range from about 0.00011 to about 0.0038 inches, with about 0.0007 to about 0.0022 inches being preferred and from about 0.0007 to about 0.0014 inches being most preferred although broader ranges are not to be necessarily precluded. It is also customary to refer to the fiber yield, i.e., denier (determined by the weight in grams of a 9000 yard length), rather than diameter. Accordingly, useful deniers preferably range from about 0.04 to about 60 with about 2 to about 20 being preferred and from about 2 to 8 being most preferred.
Antimicrobial agents useful for practice of the present invention preferably are non-toxic and environmentally safe both during use and disposal. Most antimicrobial agents control the growth of organisms by penetrating the thin cell walls of the organism, thereby disrupting the metabolic function of the organism and ultimately killing the organism. However, non-toxic antimicrobial agents cannot successfully attack human and red-blooded animal cells, which have thick cell walls, thereby making these antimicrobial agents toxicologically safe in the dosage range indicated hereinbelow. Thus, it will be understood that the term "antimicrobial agents" includes any substance which effectively protects the fibers, the carpet, related adhesives for the application of carpet and, the surfaces to which the carpet is applied from biological attack from organisms including, but not necessarily limited to, fungi, bacteria, mold, mildew, algae, and other thin-celled organisms.
An example of an antimicrobial agent suitable for use in the present invention is a phenolic-based product with an extremely low toxicity level (LD50 of 3000-5000 mg/kg at 100%) currently available from Microban Products Company of Huntersville, North Carolina, under the tradename "Microban B". "Microban" is believed to be a registered trademark owned by Microban
Products Company for use in conjunction with liquid/spray disinfecting, antibacterial, antifungal and deodorizing preparations. The product is EPA registered-#42182-1. More specifically, Microban B is a polymer additive engineered to provide a controlled migration to the surface of the product in which it is incorporated, providing long-term efficacy, as detailed hereinbelow.
Dosage rates for the addition of antimicrobial agents to the fibers employed in the present invention vary signi icantly depending upon the strength required to inhibit targeted bacteria, fungi, mold, mildew and the like and can be coordinated with the amount of antimicrobial-containing fibers employed in the non-woven fabric. In most instances, the effective dosage will vary from about 25 parts per million to about 50,000 parts per million (ppm) by weight per weight of the fibers, with 250 to about 25,000 ppm being preferred and 400 to 20,000 ppm being most preferred, although lesser or additional quantities may be used to achieve suitable efficacy. A preferred amount is 5000 ppm of the foregoing antimicrobial agent in the polypropylene fiber. Nevertheless, it is to be understood that the selection of any specific amount will depend upon the antimicrobial objective to be achieved. The preferred method of adding antimicrobials to the fibers is in the spinning, or extrusion, portion of the fiber-forming process. At this point, the antimicrobial materials are introduced while the fiber-forming polymers or materials are in the molten or liquid state, either from heat or chemical action. As the fibers harden, the antimicrobial agents are seated into the amorphous zones of the fiber. Less preferred, but nevertheless suitable, is topical coating of antimicrobials onto the fiber surface. Thus, it will be understood that, for the purposes of this invention, when it is indicated that the fibers "include" an effective amount of at least one antimicrobial agent, it is meant that the antimicrobial agent may either be incorporated into or coated onto the fibers.
As noted hereinabove, when the antimicrobial agents are added to the fiber while the fiber is in its molten or liquid stage, the agent lodges in an amorphous, or clear zone within the fiber as it hardens. At this point, due to a process known as "solid state migration", the antimicrobial agent migrates to the surface of the fiber until equilibrium is reached in the internal vapor pressure of the polymer. When equilibrium is reached, the migration ceases and the antimicrobial agent is available to control organisms that contact it, or are in its zone of inhibition.
If the surface of the fiber is not abraded, then no additional migration occurs, providing long-term inhibition capability. If abrasion occurs, the process repeats itself. Effective inhibition of organisms continues until all of the antimicrobial agent is exhausted. In the case of usage with and in carpet, in accordance with the method of the present invention, migration of bacteria and the like occurs outwardly, through the carpet and to the surface, as well as inwardly, toward and into the supporting surfaces, such as concrete, flooring, walls and the like.
In other words, by first laying down the non-woven antimicrobial barrier fabric against the floor, the floor is protected against becoming an environment and home to the micro-organisms. Bacteria and the like, passing downwardly through the carpet or other permeable floor covering, as well as various micro-organisms propagated from bodily fluids, will be controlled upon contact with the barrier fabric. As a result, passage of micro-organisms down into the floor and other support surfaces or substrates is inhibited, as is further transmission of the micro-organisms to the surface of the carpet or floor covering where they can directly pass to humans, animals, equipment and the like.
Thus, once the fabric is applied beneath the floor covering, a through- and-through zone of inhibition is achieved which effectively controls or otherwise inhibits any organisms which may contact the carpet or are within the zone of inhibition. Consequently, the present invention provides antimicrobial activity in and around carpet or other coverings which reduces the labor of disinfecting such areas. A greater life can also be imparted to the carpet and, in turn, the contiguous flooring and wall surfaces, thereby reducing the interval between take-up and replacement, as well as the labor and material attendant thereto.
One floor covering that can house various organisms and which is subject to mold and mildew in damp environs is carpet. A typical carpet is denoted generally by the numeral 10 in Fig. 1. Such a carpet 10 includes a plurality of face yarns 12 which are tufted or sewn into and through a primary backing fabric 14 and which are more securely held in place by the secondary backing fabric 16 attached to the backstitched side of primary backing fabric 14. The secondary backing fabric 16 aids in providing improved dimensional stability and strength of the carpet and covers the back of the primary backing fabric 14. A non-woven fabric 18 is placed between the floor 20 and carpet 10. Although depicted in use with carpet, it is to be appreciated that the non-woven fabric 18 could be utilized with other floor covering materials and possibly with some wall covering materials.
In Figs. 2-4, the use of the non-woven fabric barrier 18 of the present invention in other building environments has been presented. In Fig. 2, the fabric 18 has been applied to wall surfaces 22 prior to the application of wallpaper 24.
In Fig. 3, the fabric 18 has been applied to wall surfaces 26 of shower areas prior to the application of tile 28. In Fig. 4, the fabric 18 has been applied to base structure wall surfaces 30 prior to the application of exterior stucco 32. From the foregoing depictions, it is to be appreciated that the non-woven barrier fabric 18 could be utilized in many other applications where mold, mildew, bacteria and/or fungus and the like are desirably controlled.
In order to demonstrate practice of the invention, and in an effort to evaluate efficacy of the invention, the phenol-based antimicrobial agent, Microban B, was added at a level of about approximately 5000 ppm during the extrusion process. More particularly, the antimicrobial agent was added at a rate of about 2.27 grams per pound of fiber. The resultant fiber was then extruded to about 0.04 to 60 DPF, with about 2 to 20 DPF being preferred and about 2 to 8 DPF being most preferred.
An actual field test was conducted in the Men's Locker Room of the
Life Center exercise facility at the Greenville Hospital System, Greenville, S.C.
Areas were swabbed with six swabs each and sent to NAMSA® Laboratories for total aerobic count. The general area tested was immediately at the exit of the shower room, which was damp to the touch. The two tests were:
1. The top of the carpet square.
2. Under the same square applied over the non-woven fabric of the present invention.
The carpet square was sold for commercial use as antimicrobial and was about 4 years old. The non-woven fabric underneath was installed approximately six months earlier. Upon removal of the carpet square, the dampness of the carpet surface was noticed as was a pronounced heavy sour odor in the area that became stronger when the carpet square that did not have the non-woven fabric underneath was removed. Results of the test are reported in Table I.
TABLE I
SUMMARY OF NAMSA TESTS FOR TOTAL AEROBIC COUNT
Test Numbers Location Results
1 Under Carpet High 120,000
Without Fabric Low 420 Ave. 95,000
2 Under Carpet High 29,000
With Fabric Low 330 Ave. 4,400
With reference to the values presented in Table I, it is apparent that the migration of mold and mildew to the under side of the carpet and adjacent floor area was significantly reduced in Test 2 by use of the non-woven barrier fabric 18. In particular, the average values show a reduction of almost 20 times the aerobic count.
Next, to demonstrate that the microbes pass through the carpet, or other material, are effectively controlled by the non-woven barrier fabric 18, four additional tests were conducted at the Greenville Hospital facility, results being reported in Colony Forming Units (CFU's), by using a modified AATCC 100 test on hard surfaces.
TABLE II
SUMMARY OF NAMSA TESTS FOR COLONY FORMING UNITS
Test Numbers Location Results
1 Top of Carpet High 5.0 CFU
Without Fabric
2 Bottom of Carpet High 53.0 CFU
Without Fabric
3 Top of Carpet High 8.0 CFU with Fabric
4 Bottom of Carpet High 7.0 CFU with Fabric
With reference to the values presented in Table II, it is apparent that the migration of mold and mildew to the under side of the carpet and adjacent floor area was significantly reduced in Test 4, compared directly with Test 2, by use of the non-woven barrier fabric 18.
Interpretation of the foregoing results revealed that the carpet having no non-woven antimicrobial barrier fabric under it had very high levels of bioburden. The non-woven antimicrobial barrier fabric of the present invention showed good bioburden control after six months, despite having bioburden levels nearly 12 times higher in the unprotected area adjacent to it, and nearly 6 times higher on the surface of the same square. Previous conclusions that the carpet squares would not support significant bioburdens, and that the type of carpet backing would prevent water infiltration and significant bioburden growth, were at odds with the foregoing results.
Thus, it should be evident that the method of the present invention is useful in controlling the growth of bacteria, mold, mildew, fungus and the like. Practice includes the use of the non-woven fabric as described herein. The method and related components are particularly suited for use in commercial buildings and the like, but are not necessarily limited thereto, inasmuch as controlling mildew in damp basements, constitutes an important residential use. It will be appreciated that the non-woven barrier fabric of the present invention can be manufactured with known equipment and methods, as well as with materials other than those disclosed herein. Moreover, the antimicrobial agents disclosed herein have been provided for purposes of exemplification only and thus, it is to be appreciated that other materials can be substituted without falling outside of the scope of this invention. Those skilled in the art can readily determine suitable antimicrobial agents and the appropriate manner of formulating synthetic fibers to contain such agents for the manufacture of non- woven fabrics according to the present invention. Based upon the foregoing disclosure, it should now be apparent that the method and related components described herein will carry out the objects set forth hereinabove. It is, therefore, to be understood that any variations evident fall within the scope of the claimed invention and thus, the selection of specific component elements can be determined without departing from the spirit of the invention herein disclosed and described. Thus, the scope of the invention shall include all modifications and variations that may fall within the scope of the attached claims.

Claims

CLAIMS What is claimed is: 1. A method for controlling the growth of micro-organisms in conjunction with construction of buildings comprising: applying a non-woven fabric containing at least one antimicrobial agent to surfaces where micro-organisms can reside; and applying a covering thereover, said fabric forming a barrier between said surface and the covering, whereby passage of micro-organisms through the covering to the underlying surface is inhibited by said fabric.
2. A method for controlling the growth of micro-organisms, as set forth in claim 1, wherein said synthetic fibers are selected from the group consisting of polyolefins, polyesters, nylon, acrylics, acetates, polyvinyl chlorides, acrylonitrile-butadiene-styreneterpolymer(ABS),polysulphone,polybutylene terephthalate (PBT), polyurethane and mixtures thereof.
3. A method for controlling the growth of micro-organisms, as set forth in claim 2, wherein said non-woven fabric comprises polypropylene fibers.
4. A method for controlling the growth of micro-organisms, as set forth in claim 1, wherein said non-woven fabric has a weight of from about 0.5 to about 50 ounces per square yard.
5. A method for controlling the growth of micro-organisms, as set forth in claim 1, wherein said fibers have a length of from about 0.04 to about 6 inches and a diameter ranging from about 0.00011 to about 0.0038 inches.
6. A method for controlling the growth of micro-organisms, as set forth in claim 1, including the step of placing said non-woven fabric upon floor surfaces beneath an overlying floor covering.
7. A method for controlling the growth of micro-organisms, as set forth in claim 6, wherein said overlying floor covering is carpet.
8. A method for controlling the growth of micro-organisms, as set forth in claim 1, including the step of placing said non-woven fabric upon a wall surface beneath wallpaper.
9. A method for controlling the growth of micro-organisms, as set forth in claim 1, including the step of placing said non-woven fabric upon a wall surface beneath tile.
10. A method for controlling the growth of micro-organisms, as set forth in claim 1, including the step of applying said non-woven fabric to base structures of wall surfaces prior to the application of stucco.
11. A non-woven fabric for controlling the growth of micro-organisms in buildings comprising: from 50 to about 100 percent by weight of a synthetic fiber, containing at least one antimicrobial agent, in an amount of about 25 to 50,000 parts per million of said fiber, by weight and, from 0 to about 50 percent by weight of a synthetic fiber, devoid of antimicrobial agents, said non-woven fabric being employed to surfaces beneath subsequent covering materials.
12. A non-woven fabric for controlling the growth of micro-organisms, as set forth in claim 11, wherein said synthetic fibers are selected from the group consisting of polyolef ins, polyesters, nylon, acrylics, acetates, poly vinyl chlorides, acrylonitrile-butadiene-styrene terpolymer (ABS), polysulphone, polybutylene terephthalate (PBT), polyurethane and mixtures thereof.
13. A non-woven fabric for controlling the growth of micro-organisms, as set forth in claim 12, wherein said non-woven fabric comprises polypropylene fibers.
14. A non-woven fabric for controlling the growth of micro-organisms, as set forth in claim 11, wherein said non-woven fabric has a weight of from about 0.5 to about 50 ounces per square yard.
15. A non-woven fabric for controlling the growth of micro-organisms, as set forth in claim 11, wherein said fibers have a length of from about 0.04 to about 6 inches and a diameter ranging from about 0.00011 to about 0.0038 inches.
16. A non-woven fabric for controlling the growth of micro-organisms, as set forth in claim 11, applied upon floor surfaces beneath an overlying floor covering.
17. A non-woven fabric for controlling the growth of micro-organisms, as set forth in claim 16, wherein said overlying floor covering is carpet.
18. A non-woven fabric for controlling the growth of micro-organisms, as set forth in claim 11, applied upon a wall surface beneath wallpaper.
19. A non-woven fabric for controlling the growth of micro-organisms, as set forth in claim 11, applied upon said upon a wall surface beneath tile.
20. A non-woven fabric for controlling the growth of micro-organisms, as set forth in claim 11, applied upon base structures of wall surfaces prior to the application of stucco.
PCT/US1998/020509 1997-10-02 1998-10-01 Methods for controlling bacteria, mold, mildew and odors in conjunction with construction of buildings and related articles therefor WO1999017932A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU96746/98A AU9674698A (en) 1997-10-02 1998-10-01 Methods for controlling bacteria, mold, mildew and odors in conjunction with construction of buildings and related articles therefor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US94289797A 1997-10-02 1997-10-02
US08/942,897 1997-10-02

Publications (2)

Publication Number Publication Date
WO1999017932A2 true WO1999017932A2 (en) 1999-04-15
WO1999017932A3 WO1999017932A3 (en) 1999-07-29

Family

ID=25478788

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/020509 WO1999017932A2 (en) 1997-10-02 1998-10-01 Methods for controlling bacteria, mold, mildew and odors in conjunction with construction of buildings and related articles therefor

Country Status (2)

Country Link
AU (1) AU9674698A (en)
WO (1) WO1999017932A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10094125B2 (en) * 2015-06-29 2018-10-09 Keene Building Products Co., Inc. Floor drainage and ventilation device, system, and method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4343853A (en) * 1980-03-06 1982-08-10 Morrison Willard L Antimicrobially treated fabric construction
US4629645A (en) * 1983-02-07 1986-12-16 Tetsuhiko Inoue Mold inhibitive coated film with powder coating material used
WO1990014107A1 (en) * 1989-05-15 1990-11-29 Interface, Inc. Antimicrobial carpet and carpet tile
WO1992016683A1 (en) * 1991-03-21 1992-10-01 Sommer S.A. Products for covering floors and/or walls having acaricide effects and production method
WO1996039032A1 (en) * 1995-06-06 1996-12-12 Kimberly-Clark Worldwide, Inc. Microporous fabric containing a microbial adsorbent

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08120551A (en) * 1994-10-21 1996-05-14 Komatsu Felt Seizosho:Kk Mothproofing and antimicrobial felt and nonwoven fabric and their production
JP3130235B2 (en) * 1995-03-23 2001-01-31 出光石油化学株式会社 Nonwoven fabric, laminate thereof and method for producing nonwoven fabric

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4343853A (en) * 1980-03-06 1982-08-10 Morrison Willard L Antimicrobially treated fabric construction
US4629645A (en) * 1983-02-07 1986-12-16 Tetsuhiko Inoue Mold inhibitive coated film with powder coating material used
WO1990014107A1 (en) * 1989-05-15 1990-11-29 Interface, Inc. Antimicrobial carpet and carpet tile
WO1992016683A1 (en) * 1991-03-21 1992-10-01 Sommer S.A. Products for covering floors and/or walls having acaricide effects and production method
WO1996039032A1 (en) * 1995-06-06 1996-12-12 Kimberly-Clark Worldwide, Inc. Microporous fabric containing a microbial adsorbent

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch, Week 9629 Derwent Publications Ltd., London, GB; Class A94, AN 96-284007 XP002103126 & JP 08 120551 A (KOMATSU FELT SEIZOSHO KK), 14 May 1996 *
DATABASE WPI Section Ch, Week 9708 Derwent Publications Ltd., London, GB; Class A17, AN 97-083978 XP002103127 & JP 08 325915 A (IDEMITSU PETROCHEM CO) , 10 December 1996 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10094125B2 (en) * 2015-06-29 2018-10-09 Keene Building Products Co., Inc. Floor drainage and ventilation device, system, and method

Also Published As

Publication number Publication date
WO1999017932A3 (en) 1999-07-29
AU9674698A (en) 1999-04-27

Similar Documents

Publication Publication Date Title
US6641829B1 (en) Topical application of solid antimicrobials to carpet pile fibers during carpet manufacture
CA1208124A (en) Antimicrobial non-woven fabric
RU2350376C2 (en) Process for making filter containing nonwoven fabric, and/or filter injected structures or sheets produced with using specified process and designed to filter and remove legionella pneumofilla and filter made by this process
KR102136900B1 (en) Antimicrobial Fabrics
US6288076B1 (en) Antimicrobial compositions
US7314748B1 (en) Odor control agent
AU689125B2 (en) Reinforced concrete containing antimicrobial-enhanced fibers
US20070092556A1 (en) Anti-microbial material and method of making the same
JP4512225B2 (en) Carpet with deodorant function
US20040076792A1 (en) Topically applied antimicrobial carpet treatment
WO1999017932A2 (en) Methods for controlling bacteria, mold, mildew and odors in conjunction with construction of buildings and related articles therefor
EP1024694B1 (en) Method of controlling house dust mites and bedmites
EP1468137A1 (en) Odor control agent
JP4276052B2 (en) Flooring
JPH0420102Y2 (en)
JPS5838516A (en) Carpet
JP2002020970A (en) Fiber product using seashell powder
JPH0256886B2 (en)
JPH049792Y2 (en)
JP3106678B2 (en) Insect repellent fiber
JP3024095U (en) Carpet laying structure with antibacterial and antifungal and deodorant function
JPS598613Y2 (en) carpet or pine
JP2004308092A (en) Woven or knit product and tatami mat surface
JPH09117365A (en) Carpet laying structure having antibacterial, antimycotic, deodorizing and mothproofing functions
JPH0241472A (en) Mattress cover cloth

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE GH GM HR HU ID IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG UZ VN YU ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW SD SZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
AK Designated states

Kind code of ref document: A3

Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE GH GM HR HU ID IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG UZ VN YU ZW

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): GH GM KE LS MW SD SZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

NENP Non-entry into the national phase

Ref country code: KR

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: CA