WO1998058546A1 - Fungicidal and bactericidal compositions for plants containing compounds in the form of heavy metal chelates - Google Patents
Fungicidal and bactericidal compositions for plants containing compounds in the form of heavy metal chelates Download PDFInfo
- Publication number
- WO1998058546A1 WO1998058546A1 PCT/US1998/012264 US9812264W WO9858546A1 WO 1998058546 A1 WO1998058546 A1 WO 1998058546A1 US 9812264 W US9812264 W US 9812264W WO 9858546 A1 WO9858546 A1 WO 9858546A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heavy metal
- eddha
- aqueous solution
- plants
- metal chelate
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
- A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
Definitions
- the present invention is broadly concerned with fungicidal and bactericidal
- compositions, and methods of use which provide improved efficacy in controlling
- compositions and methods of use of the invention including fungicidally and
- Fungicides as well as bactericides, are chemical agents used to protect
- CUTRINE Cu salt of triethanole amine is quite effective as an aquatic algaecide.
- cupric hydroxide including for example, cupric hydroxide, tri basic copper sulfate and tank mix
- cupric ion is extremely phytotoxic. Therefore, relatively
- insoluble forms of inorganic copper compounds such as cupric hydroxide
- fungicidal or bactericidal are fungicidal or bactericidal. It is known that the in vitro fungicidal activity is
- fungicidal or bactericidal properties may be desired to for specific fungicidal or bactericidal properties.
- the present invention address the problems outlined above, and provides an
- an object of the present invention is to provide a fungicidal
- composition for protection of plants against a fungal infection is provided.
- Another object of the invention is to provide such an antifungal protection
- Another object of the invention is to provide a method for treating plants
- Another object of the invention is to provide an anti-fungal composition for treating plants
- an object of the present invention is to provide a bactericide
- composition for protection of plants against a bacterial infection is provided.
- Another object of the invention is to provide a composition employing heavy
- protection of plants preferably contain, as an active material, a fungicidally effective
- anti-bacterial such as water.
- anti-bacterial such as water.
- compositions for the protection of plants preferably contain, as an active material, a
- agriculturally acceptable carrier such as water.
- agriculturally acceptable carrier such as water.
- the fungicidal and bactericidal compositions each preferably employ a heavy
- metal chelate selected from the group consisting of Fe-EDDHA (ethylene-diamine di
- the amount of heavy metal is the amount of heavy metal
- chelate is from about 0.01 to about 1.0 pounds Al per acre.
- Fig 1 is the chemical structure for Fe EDTA (iron chelate of ethylene diamine
- Fig 2 is the chemical structure for FE DTPA (iron chelate of diethylene-triamine
- Fig 3 is the chemical structure for Fe EDDHA (iron chelate of ethylene
- ferric- APC A iron chelates of ethylene bis(alpha imino-ortho-hydroxyphenylacetic
- Fig 4 is the chemical structure for Fe pEDDHA (iron chelate of para ethylene
- Fig 5 is the chemical structure for Fe EDDHMA (iron chelate of ethylene diamine
- Fig 6 is the chemical structure for Cu EDDHA (copper chelate of ethylene diamine
- Cu-EDDHA was and can be prepared using the process disclosed in U.S.
- ferrous and ferric- APC A iron chelates of
- the preferable method of application is foliar, either by ground or aerial
- compositions have utility on fruit crops, and agronomic crops
- Cu-EDDHA sodium cupric ethylene-diamine di (o-hydroxyphenylacetate).
- KOCIDE 101 available from Griffin Corp., Valdosta, Ga.
- perithecia spore production body of fungus
- Treatments were allowed to dry for one hour and then placed in a commercial
- CGA-115944 and CGA-164058 were safer than CGA115944 which was marginally unacceptable at 0.5 g ai/1.
- PLOT SIZE Single Row X 25 ft. X 4 reps in a RCB design.
- Second rating was 25 days after last fungicide application. Plots were
- K-PHOS Commercially available and is sold under trademark "K-Phos" by Foliar
- K-PHOS - (K 2 HPO 4 , 0-18-20)
- K-Phos is a trademark of Foliar Nutrients, Inc.
- non-metal atoms may be attached to the
- metal ions by from one to six linkages and, thus, are called uni-, bi-, tri- dentate,
- Heavy metals such as cobalt, copper, iron, nickel,
- heavy metal chelate structures examples include:
- Fe-HEEDTA hydroxy ethylenediamine triacetic acid
- Fe-EDDHA ethylene dihydroxyphenylacetic acid
- Phytotoxicity is also rated on an international scale of 0-10 where 0 is equal to no
- Heavy metal chelates disclosed herein are possess water solubility acceptable
- Sequestrene 138 Fe contains 6% Iron as metallic, or 8.5%
- the commercial product has a moisture content of not more than
- Fe may be applied foriarly at much reduced rates when compared to inorganic salts
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU79635/98A AU743922B2 (en) | 1997-06-25 | 1998-06-12 | Fungicidal and bactericidal compositions for plants containing compounds in the form of heavy metal chelates |
NZ501984A NZ501984A (en) | 1997-06-25 | 1998-06-12 | Fungicidal and bacterial (kocide-cupric hydroxide) compositions selected from Fe-EDDHA (ethylene-diamine di-O-hydroxyphenylacetate), Cu-EDDHA, Mn-EDDHA and Zn-EDDHA |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US88196897A | 1997-06-25 | 1997-06-25 | |
US08/881,968 | 1997-06-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998058546A1 true WO1998058546A1 (en) | 1998-12-30 |
Family
ID=25379599
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1998/012264 WO1998058546A1 (en) | 1997-06-25 | 1998-06-12 | Fungicidal and bactericidal compositions for plants containing compounds in the form of heavy metal chelates |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU743922B2 (en) |
NZ (1) | NZ501984A (en) |
WO (1) | WO1998058546A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002056680A2 (en) * | 2000-10-31 | 2002-07-25 | Foliar Nutrients, Inc. | Fungicidal and bactericidal compositions for plants containing phosphonate and phosphate salts, metal chelates, and derivatives thereof |
EP1363492A2 (en) * | 2001-01-29 | 2003-11-26 | Agricare Ltd. | Methods and compositions for controlling plant pathogen |
US9980479B2 (en) | 2004-06-07 | 2018-05-29 | Syngenta Crop Protection, Llc | Method of reducing nematode damage |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2921847A (en) * | 1955-10-10 | 1960-01-19 | Geigy Chem Corp | Iron chelates of ethylene bis(alphaimino-ortho-hydroxyphenylacetic acid) and method of overcoming iron deficiencies in growing plants therewith |
US3494945A (en) * | 1967-11-14 | 1970-02-10 | Rohm & Haas | Alkylene bis-iminodithiocarbonic acid chelates |
DE3524629A1 (en) * | 1985-07-10 | 1987-01-15 | Stepan Safronovic Kukalenko | Zinc and copper complex salts of ethylenebisdithiocarbamic acid and of methyl N-(2-benzimidazolyl)carbamate, and process for the preparation and the use thereof |
EP0401059A1 (en) * | 1989-05-29 | 1990-12-05 | Roquette Freres | Plant-protecting composition, process for its preparation and its use, particularly for controlling downy vine mildew |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3852444A (en) * | 1973-02-22 | 1974-12-03 | Monsanto Co | Fungicidal and bactericidal 2-(n-2-cyanoethyldithiocarbamylmethylene-5-hydroxy-4h-pyran-4-one and metal chelates |
IL95241A (en) * | 1990-07-31 | 1991-06-30 | Yoram Zivion | Fertilizer compositions for administering ionic metal microelements to plant roots |
-
1998
- 1998-06-12 WO PCT/US1998/012264 patent/WO1998058546A1/en active IP Right Grant
- 1998-06-12 AU AU79635/98A patent/AU743922B2/en not_active Ceased
- 1998-06-12 NZ NZ501984A patent/NZ501984A/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2921847A (en) * | 1955-10-10 | 1960-01-19 | Geigy Chem Corp | Iron chelates of ethylene bis(alphaimino-ortho-hydroxyphenylacetic acid) and method of overcoming iron deficiencies in growing plants therewith |
US3494945A (en) * | 1967-11-14 | 1970-02-10 | Rohm & Haas | Alkylene bis-iminodithiocarbonic acid chelates |
DE3524629A1 (en) * | 1985-07-10 | 1987-01-15 | Stepan Safronovic Kukalenko | Zinc and copper complex salts of ethylenebisdithiocarbamic acid and of methyl N-(2-benzimidazolyl)carbamate, and process for the preparation and the use thereof |
EP0401059A1 (en) * | 1989-05-29 | 1990-12-05 | Roquette Freres | Plant-protecting composition, process for its preparation and its use, particularly for controlling downy vine mildew |
Non-Patent Citations (6)
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002056680A2 (en) * | 2000-10-31 | 2002-07-25 | Foliar Nutrients, Inc. | Fungicidal and bactericidal compositions for plants containing phosphonate and phosphate salts, metal chelates, and derivatives thereof |
WO2002056680A3 (en) * | 2000-10-31 | 2002-09-19 | Foliar Nutrients Inc | Fungicidal and bactericidal compositions for plants containing phosphonate and phosphate salts, metal chelates, and derivatives thereof |
AU2002245052B2 (en) * | 2000-10-31 | 2005-07-21 | Foliar Nutrients, Inc. | Fungicidal and bactericidal compositions for plants containing phosphonate and phosphate salts, metal chelates, and derivatives thereof |
EP1363492A2 (en) * | 2001-01-29 | 2003-11-26 | Agricare Ltd. | Methods and compositions for controlling plant pathogen |
EP1363492A4 (en) * | 2001-01-29 | 2004-03-10 | Agricare Ltd | Methods and compositions for controlling plant pathogen |
US9980479B2 (en) | 2004-06-07 | 2018-05-29 | Syngenta Crop Protection, Llc | Method of reducing nematode damage |
Also Published As
Publication number | Publication date |
---|---|
AU743922B2 (en) | 2002-02-07 |
AU7963598A (en) | 1999-01-04 |
NZ501984A (en) | 2001-08-31 |
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