WO1994023937A1 - Preparation d'articles coules in situ, utilisant un revetement en elastomere - Google Patents

Preparation d'articles coules in situ, utilisant un revetement en elastomere Download PDF

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Publication number
WO1994023937A1
WO1994023937A1 PCT/GB1994/000776 GB9400776W WO9423937A1 WO 1994023937 A1 WO1994023937 A1 WO 1994023937A1 GB 9400776 W GB9400776 W GB 9400776W WO 9423937 A1 WO9423937 A1 WO 9423937A1
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WO
WIPO (PCT)
Prior art keywords
mold
covering
coating
foamable composition
pour
Prior art date
Application number
PCT/GB1994/000776
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English (en)
Inventor
John William Miller
Original Assignee
Imperial Chemical Industries Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Plc filed Critical Imperial Chemical Industries Plc
Priority to AU65078/94A priority Critical patent/AU6507894A/en
Priority to CA002158654A priority patent/CA2158654A1/fr
Publication of WO1994023937A1 publication Critical patent/WO1994023937A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
    • B29C44/12—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
    • B29C44/1261—Avoiding impregnation of a preformed part
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material

Definitions

  • This invention relates to the preparation of pour-in-place articles. More particularly, this invention relates to the employment of coatings in the preparation of pour-in-place, material covered articles.
  • pour-in-place articles are generally prepared by placing a material covering, such as a piece of vinyl or fabric, into a mold and then pouring a liquid foam forming reaction mixture, such as a polyurethane composition, into the mold.
  • a vacuum is often used to insure that the material covering snugly fits the contour of the mold.
  • U.S. Patent No. 4,806,088 discloses an apparatus for preparing textile covered cushions in which a fabric cover is adapted to the contour of a mold cavity by the application of a vacuum and then a foam forming reaction mixture is introduced into the mold.
  • U.S. Patent Nos. 4,046,611 and 4,637,789 also disclose the preparation of cushions by vacuum molding.
  • U.S. Patent No. 4,610,923 discloses a process for preparing laminated fabric structures in which a flexible elastomeric skin containing microspheres is adhered to a stretchable fabric, the laminate is placed into a vacuum mold, and a liquid foamable composition is added to the mold and foamed.
  • the film must be adhered to the material covering in order for there to be sufficient adhesion between the covering, the film and the foam substrate of the upholstered article.
  • the film or sheet is usually adhered to the covering by using an adhesive or by flame bonding. Attaining the appropriate adhesion adds a step to the preparation of material covered articles thereby increasing the cost and time of production.
  • Another problem is that many of the thermoplastic films employed and/or the methods used to adhere the film to the covering give the covering a boardy and uncomfortable feel, i.e. a "poor hand".
  • U.S. Patent No. 4,975,135 discloses a process for preparing a vehicle seat in which a composite insert is prepared by laminating a porous fabric to a polymeric foam sheet, placing the composite into a vacuum mold, and adhering a foam bun to the composite insert.
  • This method is not as convenient as preparing the foamed body in the mold by the pour-in-place method and adds an additional step to the preparation of material covered articles, namely the step of adhering the material to an already formed foam body.
  • the invention is a process for preparing material covered, pour-in-place articles comprising the steps of:
  • a polymeric coating which is prepared by reacting a polyisocyanate and an isocyanate reactive material at an isocyanate index in the range of 30 to 1500, to one side of a material covering before or after placing the material covering in a mold;
  • a textile fabric is used as the material covering and the process comprises the steps of:
  • a polymeric coating which is prepared by reacting a polyisocyanate and an isocyanate reactive material at an isocyanate index in the range of 30 to 100, to one side of a textile fabric covering before or after placing the covering in a vacuum mold; (b) pouring a liquid foamable composition onto the coated side of the textile fabric covering in the mold;
  • the present invention further comprises a process for preparing an upholstered, vacuum molded pour-in-place article, comprising the steps of:
  • a polymeric coating which is prepared by reacting a polyisocyanate and a polyol at an isocyanate index in the range of 30 to 1500, to one side of a textile fabric covering before or after placing the covering in a mold;
  • the material covered, pour-in-place, article produced by the present process is comprised of: (a) a material covering; (b) a polymeric coating, prepared by reacting a polyisocyanate and an isocyanate reactive material at an isocyanate index in the range of 30 to 150-0, affixed to one side of the material covering; and (c) a foam body adhered to the coating.
  • the process can be used to make a wide variety of upholstered articles. It is particularly useful for making upholstered seats for vehicles.
  • the articles prepared according to the process of this invention are foamed articles having a material covering.
  • the material covering can be any material to which the polyurethane coating firmly adheres. Suitable materials include vinyl, leather, and textile fabric coverings.
  • the preferred covering is a textile
  • the term "textile fabric covering” includes any porous fabric or cloth that can be employed as a covering.
  • the textile fabric covering can be made from synthetic or natural fibers or a blend of synthetic and natural fibers.
  • the size and shape of the material covering of course depends upon the type of foamed article being prepared.
  • the material covering is usually comprised of a single piece of material which has been cut to fit the contour of a mold.
  • the material covering can be prepared from several pieces of material which are attached to each other, e.g. by sewing.
  • the material covering is coated on one side with a polymeric coating.
  • the coating can be applied either before or after the material covering is placed into a mold. If the coating is applied before the material covering is placed into the mold, the covering is placed into the mold so that the uncoated side is against the interior surface of the mold. Preferably, the material covering is vacuum formed after being placed into the mold so that the material snugly fits the contour of the mold. If the material coating is placed into a vacuum mold before being coated, it is preferred to coat one side of the material covering before the covering is vacuum formed.
  • the polymeric coating applied to the material covering is preferably a polyurethane and/or polyurea coating (i.e. a polyurethane coating, a polyurea coating, or a coating having both polyurethane and polyurea linkages) . More preferably, the coating is a polyurethane coating.
  • the coating can be prepared at an isocyanate index in the range of 30 to 1500. However, an isocyanate index above 200 will generally only be used when a coating having isocyanurate linkages is used or when a moisture-cure system is used to prepare the coating.
  • isocyanate index is the ratio of isocyanate (-NCO) equivalents to the total number of equivalents of isocyanate-reactive groups expressed as a percentage.
  • the polyurethane and/or polyurea coating is soft and flexible so that the material covering is not boardy or stiff, and the coating is strong enough so that if it is stretched by a vacuum, it remains intact.
  • the polyurethane and/or polyurea coating is preferably prepared at an isocyanate index in the range of 30 to 100, more preferably in the range of 40 to 80, still more preferably in the range of 45 to 60, and most preferably in the range of 45 to 55.
  • the resulting coating will be tacky and will not completely cure. As a result, the coated material covering will be difficult to handle and to process. On the other hand, if the isocyanate index exceeds about 100, the covering may be stiff and boardy once the coating cures.
  • the organic polyisocyanates which may be used in the preparation of the polyurethane coating include any of the aliphatic, cycloaliphatic,- araliphatic or aromatic polyisocyanates known in polyurethane or polyurea chemistry, especially those that are liquid at room temperature.
  • polyisocyanates examples include ethylene diisocyanate, 1,6- hexamethylene diisocyanate, isophorone diisocyanate, cyclohexane 1,4-diisocyanate, 4,4'-dicyclohexylmethane diisocyanate, 1,4-xylylene diisocyanate, 1,4-phenylene diisocyanate, 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, 4,4'-diphenylmethane diisocyanate (4,4'- MDI) , 2,4'-diphenylmethane diisocyanate (2,4'-MDI), polymethylene polyphenylene polyisocyanates (crude MDI) and 1,5-naphthylene diisocyanate.
  • ethylene diisocyanate 1,6- hexamethylene diisocyanate
  • isophorone diisocyanate cyclohexane 1,
  • polyisocyanates can be used and also polyisocyanates which have been modified by the introduction of urethane, allophanate, urea, biuret, carbodiimide, uretonimine or isocyanurate residues.
  • aromatic polyisocyanates are preferred.
  • the most preferred aromatic polyisocyanates are 4,4'-diphenylmethane diisocyanate, 2,4'-diphenylmethane diisocyanate, polymeric MDI, MDI variants, and mixtures thereof.
  • Suitable MDI variants include compounds in which the MDI has been modified by the introduction of urethane, allophanate, urea, biuret, amide, carbodiimide, uretonimine or isocyanurate residues.
  • Isocyanate-terminated prepolymers may also be employed and are prepared by reacting an excess of polyisocyanate with polyols, including aminated polyols, imine or enamine polymers, or polyamines.
  • a particularly preferred isocyanate terminated prepolymer is the reaction product of a polymeric MDI and a polyether polyol.
  • Pseudo-prepolymers may also be employed.
  • a pseudo-prepolymer is a mixture of a prepolymer and one or more monomeric di- or poly ⁇ isocyanates. Examples of suitable materials include Rubiflex 26A available from ICI Americas.
  • the isocyanate reactive resins that are useful in the preparation of the polyurethane and/or polyurea coatings include polymeric polyols, amines, imino- functional and ena ino-functional compounds having molecular weights in the range of 1500 to 12,000.
  • the isocyanate reactive material is a polyol.
  • Suitable polyols that may be used to prepare polyurethane coatings include those selected from the group consisting of polythioether, polyester, polyester amide, polycarbonate, polyacetal, polyolefin, polysiloxane and polyether polyols. Polyether polyols are preferred.
  • Suitable polyether polyols include products obtained by the polymerization of a cyclic oxide, for example ethylene oxide, propylene oxide or tetrahydrofuran in the presence, where necessary, of polyfunctional initiators.
  • Suitable initiator compounds contain a plurality of active hydrogen atoms and include water, polyols, for example ethylene glycol, propylene glycol, diethylene glycol, resorcinol, bisphenol A, glycerol, trimethylolpropane, 1,2,6-hexanetriol, triethanolamine, pentaerythritol, sorbitol or sucrose, ammonia, primary monoamines, for example aniline or benzylamine, polyamines, for example ethylene diamine, hexamethylene diamine, toluene diamines, diaminodiphenylmethanes and polymethylene polyphenylene polyamines obtained by the condensation of aniline and formaldehyde, and amino alcohols, for example ethanolamine
  • polyether polyols include polyoxypropylene , polyoxyethylene , and poly(oxyethylene-oxypropylene) diols and triols, which are obtained by the simultaneous or sequential addition of ethylene and propylene oxides to appropriate di- or tri-functional initiators as fully described in the prior art. Mixtures of the diols and triols are also useful.
  • the most preferred polyether polyols are polyoxyethylene capped polyoxypropylene diols and triols.
  • Polyester polyols which may be used include hydroxyl terminated reaction products of polyhydric alcohols such as ethylene glycol, propylene glycol, diethylene glycol, 1,4-butanediol, bis(hydroxyethyl) terephthalate, glycerol, trimethylolpropane or pentaerythritol or mixtures thereof with polycarboxylic acids, especially dicarboxylic acids or their ester-forming derivatives, for example, succinic, glutaric and adipic acids or their dimethyl esters, sebacic acid, phthalic anhydride, tetrachlorophthalic anhydride or dimethyl terephthalate. Polyesters obtained by the polymerization of lactones, for example caprolactone, in conjunction with a polyol, may also be used. Polyesteramides may be obtained by the inclusion of aminoalcohols such as ethanolamine in polyesterification mixtures.
  • polyhydric alcohols such as ethylene glycol, propylene glycol, di
  • Polythioether polyols which may be used include products obtained by condensing thiodiglycol either alone or with other glycol ⁇ , dicarboxylic acids, formaldehyde, aminoalcohols or aminocarboxylic acids.
  • Polycarbonate polyols which may be used include products obtained by reacting diols such as 1,3- propanediol, 1, 4-butanediol, 1, 6-hexanediol, diethylene glycol or tetraethylene glycol with diaryl carbonates, for example diphenyl carbonate or with phosgene.
  • diols such as 1,3- propanediol, 1, 4-butanediol, 1, 6-hexanediol, diethylene glycol or tetraethylene glycol
  • diaryl carbonates for example diphenyl carbonate or with phosgene.
  • Polyacetal polyols which may be used include those prepared by reacting glycols such as diethylene glycol, triethylene glycol or hexanediol with formaldehyde. Suitable polyacetals may also be prepared by polymerizing cyclic acetals.
  • Suitable polyolefin polyols include hydroxy- terminated butadiene homo- and copolymers, and suitable polysiloxane polyols include polydimethylsiloxane diols and triols.
  • Suitable polyols for use in the present invention include FFS-2805 available from ICI Americas.
  • amino functional compounds suitable for the preparation of a polyurea coating are well known to those skilled in the art.
  • Suitable imino- functional and enamino-functional compounds for preparing polyurea coatings are disclosed in U.S. Patent Nos. 4,749,129, 4,866,103, and 4,910,279, which are incorporated herein by reference.
  • the amino-, imino- and enamino-functional compounds are compounds in which all or part of the OH groups on a polyol have been replaced by the respective functional groups.
  • one or more polyisocyanates are reacted with one or more isocyanate reactive materials at an isocyanate index in the ranges given above under substantially anhydrous conditions at a temperature in the range of room temperature to 180°C.
  • Chain extenders and cross-linkers such as amines, glycols, imines and enamines, may be included in the reaction mixture. Generally, the chain extenders and cross- linkers will have molecular weights below about 1500.
  • the polyisocyanates and isocyanate reactive materials can optionally be reacted in the presence of catalysts known in the art, such as dibutyltin dilaurate and tertiary amines such as triethylene diamine.
  • catalysts known in the art, such as dibutyltin dilaurate and tertiary amines such as triethylene diamine.
  • Suitable catalysts are disclosed in U.S. Patent No. 4,794,129, which was previously incorporated by reference.
  • a molecular sieve can be included in the reaction mixture to serve as a water scavenger so that any water that is present will not blow and cause the coating to foam.
  • Suitable catalysts and molecular sieves for use in a specific formulation will be evident to one skilled in the art from the present disclosure.
  • the polyisocyanate and the isocyanate reactive material are usually mixed just prior to applying the coating to one side of the material covering.
  • the isocyanate reactive material and the polyisocyanate can be mixed and applied to the material covering by any suitable means. For example, they can be mixed with a drill mixer and applied by hand, such as with a spatula or knife. However, it is preferred that the isocyanate reactive material and the polyisocyanate be applied by spraying. Most preferably, the isocyanate reactive material and the polyisocyanate are impingement mixed in a spraying apparatus, and the coating is sprayed onto the fabric. Any conventional sprayer for spraying polyurethane and polyurea materials known to those skilled in the art may be employed.
  • the spraying device has a compartment in which the polyisocyanate can be stored and a compartment in which the isocyanate reactive material (as well as chain extenders and other ingredients) can be stored.
  • a sprayer should have a means to pump the polyisocyanate and the isocyanate reactive material from the compartments into a sprayhead.
  • the polyisocyanate and the isocyanate reactive compounds are impingement mixed in the nozzle of the sprayer.
  • a suitable spraying apparatus is a Graco Hydra Cat sprayer and pump unit, which is available from Graco, equipped with a Gusmer GX7 sprayhead, which is available from Gusmer.
  • the polyisocyanate and the isocyanate reactive material Prior to being mixed, the polyisocyanate and the isocyanate reactive material are maintained in their respective compartments at a temperature in the range of 18°C to about 50°C.
  • the polyisocyanate and the isocyanate reactive material are usually metered together at a pressure in the range of 600 to 2000 psi, and the pressure on each component is usually the same.
  • the coating is usually applied at a thickness of about 0.05 millimeters up to about five millimeters to one side of the material covering.
  • the coating is allowed to cure for several seconds to several minutes (generally not more than about two minutes) before the coated covering is placed into a mold.
  • the length of cure time varies with the type of formulation used to prepare the coating.
  • the covering is placed into a mold.
  • the shape of the mold will of course depend upon the type of article that is desired. After the covering is placed into the mold, it is preferred to pull a vacuum so that the material covering snugly fits the contour of the mold.
  • Suitable vacuum molds are well known to those skilled in the art. Suitable vacuum molds are described in U.S. Patent Nos. 4,046,611, 4,637,789, 4,740,260, 4,860,415 and 4,975,135, all of which are incorporated herein by reference.
  • a liquid foamable composition is poured onto the coated side of the covering and foamed.
  • the type of liquid foamable composition is not critical, and virtually any type of composition which can be poured into a mold and foamed and which will adhere to the polyurethane and/or polyurea coating can be employed. Neither is the type of foam produced from the liquid foamable composition critical.
  • Both flexible and rigid foams may be used, depending upon the end use of the product which is produced.
  • the type of product being prepared will determine the type of liquid foamable composition that is needed as well as the nature of the resulting foam (i.e. flexible or rigid) that is needed.
  • the preferred liquid foamable compositions are polyurethane, polyurea and/or polyisocyanurate liquid foamable compositions.
  • the preparation of polyurethane, polyurea and/or polyisocyanurate foams is well known.
  • the foam body is a polyurethane foam
  • the liquid foamable reaction system from which the polyurethane foam is prepared is comprised of one or more polyisocyanates, one or more polyols, and a blowing agent.
  • the liquid foamable composition is a polyurea liquid foamable composition, it will be comprised of one or more polyisocyanates, one or more amino, imino or enamino functional compounds, and a blowing agent.
  • the composition is a polyisocyanurate
  • it will be prepared at an isocyanate index exceeding about 200 and with a catalyst suitable for the isocyanurate reaction.
  • catalysts and the preparation of polyisocyanurate foams are well known in the art.
  • a presently preferred foam is that formed by the reaction of Rubiflex 26A isocyanate prepolymer and
  • FFS-3066B polyol both available from ICI Americas.
  • the polyisocyanates listed above which are suitable for preparing the polymeric coating may be used to prepare the liquid foamable composition. All the isocyanate reactive resins listed above as being suitable for preparing the coating may be used to prepare a liquid foamable composition.
  • Suitable blowing agents include water, dissolved or dispersed gases, such as air, carbon dioxide, nitrogen oxides and nitrogen, and low boiling halogenated hydrocarbons, such as methylene chloride and trichloromonofluoromethane. The amount of blowing agent used is preferably less than about four percent by weight of the total reactants.
  • any of the conventional chain extenders and additives such as surfactants, foam stabilizers, fire retardants and fillers, known in the art may also be employed. Suitable examples of such chain extenders and additives are described in U.S. Patent No. 4,935,460, which is incorporated herein by reference. Since the coating on the material covering is preferably prepared at an isocyanate index in the range of 30 to 100, there may be unreacted sites in the coating which can react with the liquid foamable composition. As a result, the coating and the foam body produced from the liquid foamable composition will, in most cases, be strongly bonded to one another.
  • the process of this invention can be used to prepare a wide variety of upholstered articles.
  • the process finds particular application in the automotive industry where it can be used to prepare interior trim parts of vehicles, such as door panels and package trays, head rests and seats.
  • the most preferred application of the process is to prepare pour-in-place upholstered vehicle seats.
  • the vacuum molds disclosed in U.S. Patent Nos. 4,740,260, 4,860,415, and 4,975,135 can be used to prepare such seats.
  • the articles prepared by the process of this invention can have material coverings which are soft and flexible, have a good hand, and are not marred by strike- through.
  • Example 1 A 38 centimeter by 38 centimeter piece of automotive fabric was placed flat on a table.
  • the polyurethane coating was prepared by mixing 5.4 parts of Rubiflex 26A, which is available from ICI Americas Inc. and which is an MDI prepolymer having a free isocyanate content of 25.3 to 26.5 percent and prepared by reacting a mixture of 2,4'-MDI and 4,4'- MDI with a polyoxypropylene polyol and then with a poly(oxyethylene-oxypropylene) triol, 100 parts of FFS-2805, which is an ethylene oxide diol and which is available from ICI Americas Inc.
  • Uniseive Paste which is a solid molecular sieve available from UOP of Des Plaines, Illinois, and 1 part of Dabco 33LV, a triethylene diamine in glycol catalyst available from Air Products, Inc.
  • the Uniseive Paste served as a water scavenger and prevented the coating from foaming.
  • the isocyanate index of the coating was 50.
  • the ingredients were mixed in a vessel with a drill mixer at 1500 RPM for 30 seconds.
  • the reaction mixture was then poured from the vessel directly onto the exposed side of the fabric and spread evenly with a spatula to form a coating having a thickness of 2 to 5 millimeters.
  • the coated fabric was placed into a vacuum mold so that the uncoated side was in contact with the interior surface of the mold.
  • a vacuum was applied to draw the fabric to the shape of the mold.
  • a polyurethane liquid foamable composition was then prepared by mixing Rubiflex 26A (the "A component”) and FFS-3066B (the "B component”) , both available from ICI Americas Inc., in a ratio of 0.589 (Rubiflex 26A to FFS-3066B) .
  • the components were mixed in a high impingement pouring machine.
  • the composition was then poured onto the coating on the fabric, foamed and allowed to cure.
  • the fabric on the resultant article had a soft feel and there was no strike-through of the foam.
  • Example 2 Example 1 was repeated except that the ingredients for the coating were placed into a high pressure sprayer and were impingement mixed as they were fed into the spray nozzle and the polyurethane coating was sprayed onto the fabric at a thickness of about 2 to 3 millimeters.
  • the fabric on the resulting article had a soft feel, and there was no strike-through of the foam.
  • Example l was repeated except that the amounts of Rubiflex 26A and FFS-2805 were adjusted so that the isocyanate index of the coating was 25. Although the resulting article had a fabric covering with a good hand, the polyurethane coating was quite tacky thereby making it difficult to handle the fabric when the fabric was placed into the vacuum mold.
  • Example 4 Example 1 was repeated except that the amounts of Rubiflex 26A and FFS-2805 were adjusted so that the isocyanate index of the coating was 105. The resulting article had a fabric covering which was stiff and boardy.
  • the examples illustrate that upholstered fabric covered articles without strike-through and with a good hand can be prepared by the pour-in-place method.
  • the examples further illustrate that vacuum formed articles with good exterior properties can be prepared without the step of adhering a preformed film or sheet to the material covering to prevent strike-through. It can also be seen from the examples that when the isocyanate index is too low, the polyurethane coating is too tacky to be easily handled, and that when the isocyanate index is too high, the material covering may be stiff and boardy.
  • Example 1 was repeated, except that the following foamable composition was used.
  • the foam formulation comprised 100 parts of F2805; 80.5 parts of Rubiflex 26A; 1.0 part of X-8162; 1.0 part of SPF; 2.0 parts of Unilink 4200; and 4.0 parts of water.
  • F2805 is a polyol available from ICI Americas;
  • X-8162 is an amine catalyst available from Air Products Inc.;
  • SPF is an amine catalyst available from Toyo Soda;
  • Unilink 4200 is a chain extender available from UOP.
  • the foam formulation was mixed using a drill press and a mixing blade.
  • the fabric was then coated with the formulation and the fabric was then placed into a vacuum mold so that the uncoated side of the fabric was in contact with the interior surface of the mold. A vacuum was applied to draw the fabric to the shape of the mold.
  • the foam formulation was then poured directly onto the fabric and was allowed to cure.
  • the foamed article had a soft feel and there was no strike

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  • Polyurethanes Or Polyureas (AREA)
  • Laminated Bodies (AREA)

Abstract

Un procédé pour préparer un article coulé in situ avec un revêtement, consiste à: (a) appliquer un revêtement polymère, qui est préparé en faisant réagir un polyisocyanate et un matériau réagissant avec l'isocyanate dans des conditions telles que l'indice d'isocyanate soit la plage de 30 à 1500, sur un côté d'une couverture en matériau avant ou après avoir placé la couverture en matériau dans un moule; (b) verser une composition liquide capable de former une mousse sur le côté revêtu du matériau; (c) transformer en mousse la composition capable de former une mousse; et (d) à enlever du moule l'article stratifié constitué de mousse recouvert du matériau. L'invention concerne également les articles préparés par le procédé.
PCT/GB1994/000776 1993-04-16 1994-04-13 Preparation d'articles coules in situ, utilisant un revetement en elastomere WO1994023937A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU65078/94A AU6507894A (en) 1993-04-16 1994-04-13 Preparation of pour-in-place articles employing elastomer coating
CA002158654A CA2158654A1 (fr) 1993-04-16 1994-04-13 Preparation d'articles solidifiables utilisant un revetement d'elastomere

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US4868793A 1993-04-16 1993-04-16
US08/048,687 1993-04-16

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WO1994023937A1 true WO1994023937A1 (fr) 1994-10-27

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2814110A1 (fr) * 2000-09-20 2002-03-22 Cera Procede et dispositif de fabrication d'une garniture, garniture et siege muni de celle-ci
ES2394689R1 (es) * 2010-12-02 2013-04-12 Ct Tecnologico Del Mueble Y La Madera De La Region De Murcia Procedimiento de tratamiento de tejidos para piezas espumadas en molde y utilizacion de dicho tejido
EP3112117A1 (fr) * 2015-07-01 2017-01-04 Construplas, S.L. Procédé de moulage d'une feuille sur un support

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2151651A5 (en) * 1971-09-03 1973-04-20 Altramouss Ets Stool upholstery - of skinned polyurethane foams moulded with traditional surface decorations or inserts
FR2216142A1 (fr) * 1973-01-31 1974-08-30 Storey Brothers & Co
EP0259810A2 (fr) * 1986-09-05 1988-03-16 Inoac Corporation Membres intérieurs de véhicule et leur procédé de fabrication
WO1991008886A1 (fr) * 1989-12-11 1991-06-27 Henderson's Industries Pty. Ltd. Siege protege contre le vandalisme

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2151651A5 (en) * 1971-09-03 1973-04-20 Altramouss Ets Stool upholstery - of skinned polyurethane foams moulded with traditional surface decorations or inserts
FR2216142A1 (fr) * 1973-01-31 1974-08-30 Storey Brothers & Co
EP0259810A2 (fr) * 1986-09-05 1988-03-16 Inoac Corporation Membres intérieurs de véhicule et leur procédé de fabrication
WO1991008886A1 (fr) * 1989-12-11 1991-06-27 Henderson's Industries Pty. Ltd. Siege protege contre le vandalisme

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ANONYMOUSLY: "Automotive Seat Assembly Process", RESEARCH DISCLOSURE, no. 302, June 1989 (1989-06-01), EMSWORT GB, pages 443, XP000035092 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2814110A1 (fr) * 2000-09-20 2002-03-22 Cera Procede et dispositif de fabrication d'une garniture, garniture et siege muni de celle-ci
ES2394689R1 (es) * 2010-12-02 2013-04-12 Ct Tecnologico Del Mueble Y La Madera De La Region De Murcia Procedimiento de tratamiento de tejidos para piezas espumadas en molde y utilizacion de dicho tejido
EP3112117A1 (fr) * 2015-07-01 2017-01-04 Construplas, S.L. Procédé de moulage d'une feuille sur un support

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