WO1994022299A1 - Insecticidal compositions - Google Patents
Insecticidal compositions Download PDFInfo
- Publication number
- WO1994022299A1 WO1994022299A1 PCT/GB1994/000555 GB9400555W WO9422299A1 WO 1994022299 A1 WO1994022299 A1 WO 1994022299A1 GB 9400555 W GB9400555 W GB 9400555W WO 9422299 A1 WO9422299 A1 WO 9422299A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- insect
- composition
- insecticidally active
- granules
- adult
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
- A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
Definitions
- This invention relates to novel insecticidal compositions and particularly to compositions which may be useful in the control of adult and immature stages of insect pests, particularly dipterous pests which are associated with the transmission of disease and which represent a hazard to human and animal health.
- flying insect can act as vectors for the transmission of diseases which are hazardous to to the well being of humans or animals.
- dipterous insects such as houseflies (Musca domestica) which feed on food wastes, excrement, animal cadavers and the like in the course of which they become contaminated with bacterial and like microorganisms some of which may subsequently be transferred to food products intended for human or animal consumption; and blowflies (Chrvsomva me ⁇ acephala) which are associated with domestic animals being kept for food production, eg cattle, sheep, goats, pigs, poultry, particularly where these are kept in enclosures or animal houses.
- the present invention is concerned with a novel type of formulation in which a combination of insecticidally active ingredients is present and which is capable of combatting and controlling both the larval and adult stages of such dipterous insect pests.
- the present invention provides an solid insecticidal composition which comprises a mixture of two insecticidally active ingredients in association with an insect-attracting bait substance characterised in that the first insecticidally active ingredient is an insect growth regulator active against larval stages, and the second insecticidally active ingredient is a direct toxicant having knock-down and lethal effects on adult stages, the insect-attracting bait substance being attractive to both adult and larval stages of the insect.
- compositions are preferably used in granular form, which is suitable for scattering at the site where it is desired to control the insect pests.
- Suitable active ingredients which act as insect growth regulators (IGRs) for use in the compositions include those identified by the ISO-approved common names as flufenoxuron, triflu uron, cyro azine, diafenthiuron, hexaf1umuron, diflubenzuron, pyriproxifen, fenoxycarb, chlorfluazuron, hydra ethylnon, methoprene and hydroprene.
- IGRs insect growth regulators
- Suitable direct toxicants which may be used include carba ate insecticides such as propoxur, carbosulfan and bendiocarb; organophosphorus insecticides such as fenthion, aza ethifos, diazinon, chlorpyrifos, methomyl, propetamphos, piri iphos-methyl , and fenitrothion; and pyrethroid insecticides such as permethrin, cypermethrin, alpha-cypermethrin, zeta-cyper ethrin, deltamethrin, tralomethrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, flucythrinate, fenvalerate, esfenvalerate, and fluvalinate.
- carba ate insecticides such as propoxur, carbosulfan and bendio
- IGR for use in the invention compositions is that known by the ISO-approved common name of pyriproxifen, which has the chemical name 2[l-methyl-2-(4-phenoxyphenoxy)ethoxy]pyridine.
- Preferred toxicants include cypermethrin, permethrin, fenvalerate, deltamethrin, lambda-cyhalothrin, pirimiphos-methyl and chlorpyrifos-methyl.
- the insect-attracting bait substance is preferably sucrose or another crystalline sugar attractive to insects.
- the IGR is pyriproxifen
- the toxicant is lambda-cyhalothrin or pirimiphos-methyl
- the bait substance is sucrose.
- compositions or the invention are solid dusts or, preferably granules.
- Sugar based granules can provide optimum efficacy at a single application rate if the ratio of the two active ingredients is carefully controlled.
- the granules not only act as a highly attractive bait source on which the adult insects feed but also provide a soluble support for the active ingredient which will break down over a period of time.
- compositions intended to control houseflies Musca domestica.
- the pheromonal attractant Z-9- tricosene may be added, whilst yellow or red coloration, for example that afforded by oil soluble dyestuffs such as those sold under the trade name "Waxoline” yellow (“Waxoline” is a registered Trade Mark of ZENECA Limited), will also act to attract the target insects.
- compositions may contain bittering agents to deter accidental ingestion of the granules by non-target avian and mammalian species, including humans.
- a suitable bittering agent is denatonium benzoate, which is sold under the trade name "Bitrex" (Registered Trade Mark) .
- ingredients and the formulation of the composition during manufacture may be added, such as sol d diluents and fillers, surfactants and solvents.
- Surfactants may be anionic, non-ionic or cationic.
- Long chain phenyl sulphonates such as calcium dodecylbenzene sulphonate (phenyl sulphonate CALX) is particularly useful.
- Solid diluents and fillers include for example powdered silica, diato aceous earth and clays such as montmorillonite.
- Solvents which may be employed include those which solubilise the insecticidally active ingredients and other compounds so as to achieve a uniform coating of the support.
- a glycol d ester such as propylene glycol diacetate is particularly effective.
- the granular compositions of the invention may be prepared by conventional mechanical agitation methods in which the ingredients are fed to apparatus for producing granules by a process of agglomeration. Suitable apparatus for use in such methods includes pan granulators, rolling drum granulators, and mixers such as those known as Sigma mixers, Lodige mixers, Fielder matrix mixers and Shugi mixers.
- the granular compositions may be obtained by a gaseous agitation method using, for example, a fluid bed granulator, or by pressure methods involving for example, tabletting or pelleting apparatus or, extrusion methods such as ram, screw or marumeriser extrusion.
- a typical process for the production of granular compositions according to the invention by the agglomeration technique involves the steps of (i) preparing a dust concentrate by mixing together the active ingredients in the required proportions with a solid diluent or carrier, such as
- Silica dust (ii) mixing the dry ingredients by a granulation method such as those suggested above, whilst adding sufficient water to the dry mix to cause agglomeration, (iii)continuing the agitation process until granules of the required size range are obtained, and (iv) drying the granules to remove water.
- compositions are in a granular form it is preferred that the majority of the granules fall within a specified size range, this being determined by the accepability of the finished composition as a food source to which the insects are attracted and on which they feed for a sufficient time to ingest a lethal dose.
- the size range of the granules in the composition may be varied by standard methods well known in the granulation art.
- granules within a particular range of size which is found to be more attractive to flies.
- This size range may vary according to the species of insect pest to be attracted. In the case of adult Musca do estica the preferred size of the granules is within the range 500 ⁇ m to 10000 ⁇ , and it is especially preferred that the granules be within the range 2500 ⁇ m to 3500 ⁇ m.
- compositions of the invention are provided in the Examples set out hereinbelow.
- compositions provide a combined effectiveness against both adult and larval forms of insect pests such as Musca domestica (houseflies) and Chrvsomva meoacephala (blowflies).
- the invention provides a method of combatting dipterous insect pests in both their larval and adult stages which comprises treating the locus of such pests with a composition according to the present invention.
- compositions can be integrated into fly management programmes as a scatter bait, in bait stations or dissolved in water and painted onto target surfaces. Flies are attracted to the compositions by the presence of the sugar substrate, and this attraction can be enhanced by the use of visual (colour) or chemical cues, such as the Musca sex hormone Z-9- tricosene. Red and yellow formulations are particularly effective.
- This Example illustrates the preparation of a composition according to the invention in the form of a coated granular formulation.
- This Example illustrates a composition according to the invention comprising an insect pheromone.
- the composition is prepared according to the procedure illustrated in Example 1 except that Z-9-tricosene (0.5 parts) is added to the mixture prior to coating the granules.
- This Example illustrates a composition according to the invention comprising a dyestuff imparting a yellow coloration to the granules.
- the composition is prepared according to the procedure illustrated in Example 1 except that "Waxoline” yellow GFW (0.1 parts "Waxoline” is a Registered Trade Mark) is added to the mixture prior to coating the granules.
- This Example illustrates a composition according to the invention comprising a bittering agent to help prevent accidental ingestion of the composition by non-target avian and mammalian species.
- composition is prepared according to the procedure illustrated in Example 1 except that denatonium benzoate (0.025 parts) is dissolved in the propylene glycol diacetates at room temperature prior to addition of the other ingredients.
- This Example illustrates a composition according to the invention comprising an organo-phosphorus compound.
- the composition is prepared according to the procedure illustrated in Example 1 except that the lambda-cyhalothrin is replaced by pirimiphos-methyl (10 parts).
- This Example illustrates the preparation of a granular composition according to the invention.
- a premix consisting of lambda-cyhalothrin (5 parts), pyriproxifen (25 parts) and silica FK320 (1000 parts) is combined by dry mixing with Z-9-tricosene (2.5 parts), denatonium benzoate (0.1 parts), "Monolyte” yellow GNV (0.5 parts, “Monolyte” is a Registered Trade Mark) and finely divided (icing sugar grade) sucrose (8967 parts). Water is then added sparingly to the mixture in a pan granulator and the pan rotated until the majority of granules have a size within the range 2800 to 3350 ⁇ m, after which the granules are subjected to drying to remove water and are seived to remove fines.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Food Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Insects & Arthropods (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6521785A JPH08508287A (en) | 1993-03-31 | 1994-03-18 | Insecticide composition |
BR9406243A BR9406243A (en) | 1993-03-31 | 1994-03-18 | Solid insecticidal composition and processes for the preparation of a granulated composition and to combat the larvae and adult stages of dipterous insect pests |
EP94909259A EP0691809A1 (en) | 1993-03-31 | 1994-03-18 | Insecticidal compositions |
AU62173/94A AU6217394A (en) | 1993-03-31 | 1994-03-18 | Insecticidal compositions |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9306769.2 | 1993-03-31 | ||
GB939306769A GB9306769D0 (en) | 1993-03-31 | 1993-03-31 | Insecticidal compositions |
GB9312207.5 | 1993-06-14 | ||
GB939312207A GB9312207D0 (en) | 1993-06-14 | 1993-06-14 | Insecticidal compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994022299A1 true WO1994022299A1 (en) | 1994-10-13 |
Family
ID=26302682
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB1994/000555 WO1994022299A1 (en) | 1993-03-31 | 1994-03-18 | Insecticidal compositions |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0691809A1 (en) |
JP (1) | JPH08508287A (en) |
CN (1) | CN1120303A (en) |
AU (1) | AU6217394A (en) |
BR (1) | BR9406243A (en) |
CA (1) | CA2158069A1 (en) |
CZ (1) | CZ252595A3 (en) |
HU (1) | HUT72027A (en) |
WO (1) | WO1994022299A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100840197B1 (en) | 2007-06-26 | 2008-06-23 | 퀀틴 패트릭 | A materials for mothproof and method of manufacturing the same |
LU91484B1 (en) * | 2008-10-10 | 2010-04-12 | Jeyes Deutschland Gmbh | Bait |
CN101971803A (en) * | 2010-11-03 | 2011-02-16 | 沈阳师范大学 | Dye mixed liquid for killing houseflies |
EP2446742A1 (en) * | 2010-10-28 | 2012-05-02 | Bayer CropScience AG | Insecticide or acaricide compositions containing mono- or disaccharides as activity enhancers |
US8834909B2 (en) | 2003-07-29 | 2014-09-16 | Novartis Ag | Granule baits |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4677676B2 (en) * | 2001-02-23 | 2011-04-27 | 凸版印刷株式会社 | Food packaging container with pest repellent function |
DE102004001271A1 (en) * | 2004-01-08 | 2005-08-04 | Bayer Cropscience Ag | Drug combinations with insecticidal properties |
AP3632A (en) * | 2010-05-19 | 2016-03-08 | Sumitomo Chemical Co | Pest control material |
CN102246806A (en) * | 2011-04-30 | 2011-11-23 | 江西海科瑞特作物科学有限公司 | Insecticidal composition containing pyriproxyfen and lambda-cyhalothrin |
CN106259419A (en) * | 2015-05-20 | 2017-01-04 | 江苏扬农化工股份有限公司 | One kills fly compositions and application thereof |
CN113598163A (en) * | 2021-09-10 | 2021-11-05 | 姜兆伟 | Mosquito-repellent incense liquid for preventing children from eating by mistake and application of bitter essence as raw material |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5428824A (en) * | 1977-08-05 | 1979-03-03 | Nissan Chem Ind Ltd | Insecticidal composition |
JPS6036403A (en) * | 1983-08-08 | 1985-02-25 | Sumitomo Chem Co Ltd | Mixed insecticidal composition |
EP0229191A1 (en) * | 1985-07-18 | 1987-07-22 | Earth Chemical Co., Ltd. | Fly-attractive composition |
AU576034B2 (en) * | 1984-12-10 | 1988-08-11 | R & C Products Pty Limited | Non-crumbly solid edible insect bait |
JPH02111702A (en) * | 1988-10-20 | 1990-04-24 | Earth Chem Corp Ltd | Stomach poison composition against insect pests |
ZA917192B (en) * | 1990-10-23 | 1992-05-27 | Ciba Geigy Proprietary Limited | A pesticidal composition |
EP0518821A2 (en) * | 1991-06-11 | 1992-12-16 | Sandoz Ltd. | Bait station |
-
1994
- 1994-03-18 AU AU62173/94A patent/AU6217394A/en not_active Abandoned
- 1994-03-18 BR BR9406243A patent/BR9406243A/en not_active Application Discontinuation
- 1994-03-18 CN CN 94191668 patent/CN1120303A/en active Pending
- 1994-03-18 CA CA 2158069 patent/CA2158069A1/en not_active Abandoned
- 1994-03-18 WO PCT/GB1994/000555 patent/WO1994022299A1/en not_active Application Discontinuation
- 1994-03-18 CZ CZ952525A patent/CZ252595A3/en unknown
- 1994-03-18 HU HU9502718A patent/HUT72027A/en unknown
- 1994-03-18 EP EP94909259A patent/EP0691809A1/en not_active Ceased
- 1994-03-18 JP JP6521785A patent/JPH08508287A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5428824A (en) * | 1977-08-05 | 1979-03-03 | Nissan Chem Ind Ltd | Insecticidal composition |
JPS6036403A (en) * | 1983-08-08 | 1985-02-25 | Sumitomo Chem Co Ltd | Mixed insecticidal composition |
AU576034B2 (en) * | 1984-12-10 | 1988-08-11 | R & C Products Pty Limited | Non-crumbly solid edible insect bait |
EP0229191A1 (en) * | 1985-07-18 | 1987-07-22 | Earth Chemical Co., Ltd. | Fly-attractive composition |
JPH02111702A (en) * | 1988-10-20 | 1990-04-24 | Earth Chem Corp Ltd | Stomach poison composition against insect pests |
ZA917192B (en) * | 1990-10-23 | 1992-05-27 | Ciba Geigy Proprietary Limited | A pesticidal composition |
EP0518821A2 (en) * | 1991-06-11 | 1992-12-16 | Sandoz Ltd. | Bait station |
Non-Patent Citations (6)
Title |
---|
CHEMICAL ABSTRACTS, vol. 103, no. 7, 19 August 1985, Columbus, Ohio, US; abstract no. 49777t * |
CHEMICAL ABSTRACTS, vol. 113, no. 15, 8 October 1990, Columbus, Ohio, US; abstract no. 128094c * |
DATABASE WPI Week 7915, Derwent World Patents Index; AN 79-28582B [15] * |
DATABASE WPI Week 8514, Derwent World Patents Index; AN 85-084631 [14] * |
DATABASE WPI Week 9022, Derwent World Patents Index; AN 90-169073 [22] * |
DATABASE WPI Week 9306, Derwent World Patents Index; AN 93-053145 [06] * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8834909B2 (en) | 2003-07-29 | 2014-09-16 | Novartis Ag | Granule baits |
KR100840197B1 (en) | 2007-06-26 | 2008-06-23 | 퀀틴 패트릭 | A materials for mothproof and method of manufacturing the same |
LU91484B1 (en) * | 2008-10-10 | 2010-04-12 | Jeyes Deutschland Gmbh | Bait |
WO2010040852A2 (en) * | 2008-10-10 | 2010-04-15 | Jeyes Deutschland Gmbh | Bait |
WO2010040852A3 (en) * | 2008-10-10 | 2011-04-28 | Jeyes S.R.O. | Bait |
EP2446742A1 (en) * | 2010-10-28 | 2012-05-02 | Bayer CropScience AG | Insecticide or acaricide compositions containing mono- or disaccharides as activity enhancers |
CN101971803A (en) * | 2010-11-03 | 2011-02-16 | 沈阳师范大学 | Dye mixed liquid for killing houseflies |
Also Published As
Publication number | Publication date |
---|---|
EP0691809A1 (en) | 1996-01-17 |
JPH08508287A (en) | 1996-09-03 |
CN1120303A (en) | 1996-04-10 |
CA2158069A1 (en) | 1994-10-13 |
HUT72027A (en) | 1996-03-28 |
HU9502718D0 (en) | 1995-11-28 |
CZ252595A3 (en) | 1996-01-17 |
AU6217394A (en) | 1994-10-24 |
BR9406243A (en) | 1996-01-09 |
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