WO1994002058A1 - Carpet having improved appearance retention - Google Patents
Carpet having improved appearance retention Download PDFInfo
- Publication number
- WO1994002058A1 WO1994002058A1 PCT/US1993/005991 US9305991W WO9402058A1 WO 1994002058 A1 WO1994002058 A1 WO 1994002058A1 US 9305991 W US9305991 W US 9305991W WO 9402058 A1 WO9402058 A1 WO 9402058A1
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- WO
- WIPO (PCT)
- Prior art keywords
- carpet
- fiber
- cross
- fibers
- nylon
- Prior art date
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
-
- D—TEXTILES; PAPER
- D05—SEWING; EMBROIDERING; TUFTING
- D05C—EMBROIDERING; TUFTING
- D05C17/00—Embroidered or tufted products; Base fabrics specially adapted for embroidered work; Inserts for producing surface irregularities in embroidered products
- D05C17/02—Tufted products
- D05C17/026—Tufted products characterised by the tufted pile surface
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2503/00—Domestic or personal
- D10B2503/04—Floor or wall coverings; Carpets
Definitions
- This invention relates to carpet having improved appearance retention characteristics.
- Another aspect of this invention relates to cross-linked fibers for use in the fabrication of the carpet of this invention and in processes for forming said cross-linked fibers.
- Crosslinked polymer materials are known. See for example Khim Volokna pp. 20-32 (1965); U.S. Patent Nos. 3,801,347 and 3,286,322; DE 2,707,066; DE 1,444,076; BP 1 565 820 and Chem. Vlakna, 1971, 21 pp. 28-33.
- a desirable characteristic of carpet is that the carpet retains its appearance when subjected to normal traffic. Unfortunately, most carpet made from
- the term “appearance retention” is used to describe the ability of carpet to retain its initial appearance with respect to tuft endpoint definition and lack of matting after being subjected to repeated traffics, where each "traffic” is the occurrence of an individual walking across the carpet.
- the present invention is directed to an improved carpet of the type having a primary backing and heat set pile fiber (tuft) in the form of individual lengths of plied fiber, each of which projects upwardly form said backing terminating at a cut end, the improvement comprising pile fiber formed from a crosslinked
- the carpet of this invention has several advantages. For example, the carpet of this invention exhibits improved appearance retention. The carpet of this invention also has a pleasing initial appearance and hand.
- This invention also relates to (an improved process of forming cross-linked fibers which provide carpets having improved appearance retention which comprises treating a twisted and heat set fiber formed from a polymeric material with an effective
- crosslinking agent under conditions suitable for crosslinking an effective number of polymer chains to form a fiber comprised of a crosslinked polymeric material having an effective cross-link density) .
- Yet another embodiment of this invention relates to the crosslinked fiber formed by the process of this
- the carpet of this invention comprises as an essential component fiber formed from a crosslinked polymeric material having an effective "cross-link density" in the amorphous or non-crystalline regions of the material.
- fiber means multifilament fiber or monofilament fiber and includes individual staple fibers or continuous fiber;
- crosslinked polymeric material means a polymeric material in which two or more polymeric chains are crosslinked by a "crosslinking moiety;
- crosslinking moiety means a multivalent moiety which links two or more polymer chains together by ionic bonds, covalent bonds or a combination thereof; and the term “crosslink density” means the number of cross-linking occurrences per chain, where cross-links exists between two linear or branched polymer chains to form a network ("See “Principles of Polymer Chemistry,” P.J. Flory, Cornell U. Press, Ithaca, NY 1973).
- crosslink density in the amorphous regions of the polymeric material forming the fiber component of the carpet is critical. While we do not wish to be bound by any theory, it is believed that the appearance retention characteristics of the carpet of this
- the invention result from use of a crosslinked polymeric material having an effective crosslink density in the amorphous regions of the material. If the cross-link density is less than the effective cross-link density the carpet does not exhibit the desired appearance retention characteristics and where the cross-link density is greater than the effective cross-link density then the carpet does not exhibit the desired hand.
- the polymeric material used to form the fiber has a crosslink density in its amorphous regions of from about 1 to about 20. In the preferred embodiments of the invention, cross-link density is from about 3 to about 15. The crosslink density is more preferably from about 4 to about 5 and is most preferably about 7.
- the crosslinking moiety employed to crosslink the polymeric material may vary widely and may be a crosslinking moiety which crosslinks by way of covalent bonds, ionic bonds or a combination thereof.
- the crosslinking moiety employed in any situation will usually depend on the chemical structure and reactivity of the polymer chains of the polymeric material.
- those polymeric materials having polymer chains containing anionic moieties or cationic moieties such as sulfonated aryl groups as for example,
- sulfonated styrene or sulfonated pyridine carboxylate groups or neutralized forms thereof, as for example, methacrylate groups or acrylate groups and the like; tetra alkyl anmonium groups; protonated amine groups; and the like can be crosslinked by way of ionic
- alkali metal cations e.g. sodium and potassium
- multivalent cations such as alkaline earth metal cations (e.g. calcium and
- Group IVa and Group IIIb metal cations e.g. zirconium and aluminum
- low molecular weight polyanionic molecules such as
- polyphosphates polysulfates, poly carboxylates, and the like.
- Those polymeric materials in which the polymer chains contain nucleophilic or electrophilic moieties such as pendant ester, carboxylic acid, sulfonic acid, urethane, hydroxy, mercapto or amino functions can be crosslinked by way of reaction with complementary covalent crosslinking moieties formed from displacement reactions, addition reactions and the like such as aliphatic or aromatic compounds having two or more moieties select from the group consisting of acids, esters, hydroxy, amino, isocyanate and the like.
- Examples of such polymeric materials include natural polymeric materials as for example celluloses (rayon), cellulose esters such as cellulose acetate and
- polystyrene resin such as groundnut protein, zein, soya bean protein and collagen; and synthetic polymeric materials such as polyamides as for example nylon 6, nylon 6,6, nylon 11 and nylon 6, 10; polyesters such as poly (ethylene terephthalate) or poly (1,4-cyclohexylene dimethylene terephthalate) which include or have been derivatized with a suitable nucleophilic or electrophilic group such as amino, hydroxy, ethenyl, ethynyl, isocyanate, ureido, dienyl, sulfhydryl, halo, carboxylic acid ester, cyano and the like; polyvinyls and polyolefins, such as poly(acrylonitrile), poly(vinyl chloride), poly (vinylidene chloride), poly(vinyl alcohol), poly(vinyl styrene), poly(vinylidene dinitrile), poly(ethylene) and poly (propylene) which have been der
- nucleophibic or electrophibic groups in the polymeric chain such as one or more double bonds, sulfone, amide, imide, ester, amine or like linkages; polyurethanes such as those made from polyisocyanates and polyols by methods known to those skilled in the art, (see for example "The Encyclopedia of Polymer Science and
- the polymer is crosslinked covalently by a divalent organic moiety such as an alkylene, alkenylene, alkynylene or arylene group which may include various functional groups containing one or more heteroatoms such as -O-, -N(R)- (where R is hydrogen or alkyl) ,-S(O) 2 -, -C(O)-, -C(O)O-,-N(H)C(O)-, -N(H)C(O)N(H), -, -S-, -S 2 - and the like.
- a divalent organic moiety such as an alkylene, alkenylene, alkynylene or arylene group which may include various functional groups containing one or more heteroatoms such as -O-, -N(R)- (where R is hydrogen or alkyl) ,-S(O) 2 -, -C(O)-, -C(O)O-,-N(H)C(O)
- useful polymeric materials are those which include nitrogen in the polymeric backbone substituted with a displaceable group (e.g. hydrogen) as for example a polyamides (e.g. nylon 6, and nylon 6,6,) and polyurethanes, and the crosslinking moieties are alkylene or alkenylene groups which may optionally include a divalent oxygen group.
- a displaceable group e.g. hydrogen
- the crosslinking moieties are alkylene or alkenylene groups which may optionally include a divalent oxygen group.
- useful crosslinking moieties are divalent alkylene of from 1 to about 7 carbon atoms (preferably methylene or methylene substituted with one or more alkyl groups of from 1 to 4 carbon atoms), or such alkylene groups which include one or more divalent ether like oxygen groups (preferably divalent methyleneoxymethylene) or methyleneoxymethylene in which the methyleneoxy moiety, the methylene moiety or a combination thereof is substituted with alkyl having from 1 to about 4 carbon atoms); and the polymeric material is a polyamide
- nylon 6, nylon 6,6, nylon 11, or nylon 6,10 preferably nylon 6,6 or nylon 6,6 and most preferably nylon 6
- the fiber for use as a component of the carpet of this invention may have been subjected to various kinds of processing to which conventional carpet fibers are subjected.
- the fibers may have been drawn, textured, twisted, caliled, heat set, tufted or dyed.
- Such carpet fiber treatment processes are well known in the art and will not be described herein in great detail. See for example "Carpets", by G.
- the fibers may consist of continuous fibers or staple fibers. Because of a number of factors known to those of skill in the art including ease of manufacture and the like, the fibers are preferably continuous fibers.
- the carpet fibers may consist of a mixture (blend) of carpet fibers having, for example, different cross-sectional shapes and/or different deniers and/or different lengths and/or different polymer composition (e.g. nylon 6 or nylon 6,6) for the purpose of providing, for example, special dyeing effects or to improve the economics and/or luster and/or body of the carpet.
- crosslinked fibers for use in the carpet of this invention may be manufactured by any suitable conventional method for crosslinking a polymeric material. See for example "Chemical Fiber",
- the fiber is preferably crosslinked by treating a twisted fiber with an appropriate crosslinking agent which is capable of crosslinking said fiber.
- an appropriate crosslinking agent which is capable of crosslinking said fiber.
- Suitable crosslinking agents will depend on the chemical
- the crosslinking agent is an aliphatic
- the cross-linking process can be carried out employing a number of procedures using the twisted fiber, either as the fiber before incorporation in the carpet or after incorporation in the carpet. It has been discovered that cross-linking the fiber before the fiber is twisted causes the resulting carpet to wear more quickly than carpet where the fiber is not cross-linked. While we do not wish to be bound by any theory, it is believed that the cross-links must form or be re-formed after the yarn has been twisted if good wear is to be obtained. Otherwise, the yarn may untwist when walked on.
- the cross linked fiber can conveniently be prepared by treating the twisted fiber with the cross-linking agent, such as formaldehyde in the gaseous phase under conditions suitable for cross-linking the fiber.
- the cross-linking agent such as formaldehyde in the gaseous phase under conditions suitable for cross-linking the fiber.
- the twisted nylon fiber either as the fiber or as the carpet, is placed into a vacuum fiber
- the fiber treating chamber for a time sufficient to remove all or substantially all of the moisture.
- the fiber treating chamber is evacuated and kept under live vacuum, and is vented with dry inert gas (e.g. argon or nitrogen) for a time necessary to remove the desired amount of water.
- dry inert gas e.g. argon or nitrogen
- the amount of cross-linking agent, e.g.
- paraformaldehyde required to provide the desired cross-link density is put into the fiber treating chamber which is then re-evacuated.
- formaldehyde is the cross-linking agent
- dry HCl gas is introduced into the fiber treating chamber.
- evacuated fiber treating chamber is put into an oven at a temperature and for a time sufficient to obtain the desired crosslink density.
- the fiber treating chamber is vented with a suitable inert gas such as argon or nitrogen and the crosslinked fiber or carpet containing the crosslinked fiber is removed.
- a suitable inert gas such as argon or nitrogen
- the cross-linked fibers are washed in suitable base, such as an aqueous 50:50 NaHCO 3 -Na 2 CO 3 solution, to neutralize and remove the remaining HCl, rinsed and air dried to provided cross-linked fibers having the desired cross-link density.
- the cross-linked fibers can be prepared by treatment of the fibers, either as the fiber or in a carpet, in a solution process.
- polyamide fiber such as nylon 6 or nylon 6,6 fiber may be crosslinked by treatment with formaldehyde in a solution process.
- a treatment reactor can be charged with a suitable solvent for formaldehyde such as toluene and the like, and an amount of dry HCl and para formaldehyde sufficient to provide the desired crosslink density.
- a suitable solvent for formaldehyde such as toluene and the like
- an amount of dry HCl and para formaldehyde sufficient to provide the desired crosslink density.
- the fiber in any suitable form i.e. fiber or carpet.
- the reactor is sealed and heated in an inert atmosphere such as nitrogen or argon optionally with stirring at a temperature and for a period of time sufficient to crosslink the fiber to the desired crosslink density.
- the fiber is removed from the reactor and is washed with a suitable base such as 50:50 aqueous NaHCO 3 -Na 2 CO 3 solution to neutralize and remove residual HCl.
- the crosslinked fiber is then rinsed two times with
- the fiber is crosslinked in a modified aqueous process.
- a reactor is charged with a suitable cross-linking agent for
- polyamides e.g. nylon 6 and nylone 6,6 as for
- paraformaldehyde The mixture is heated to a suitable temperature preferably 70-80oC. Then
- crosslinking composition is then continuously
- circulating means such a peristaltic pump fitted with tubing, for a time and at a temperature sufficient to achieve the desired crosslinking density.
- crosslinking composition may be heated to the desired crosslinking temperature employing any conventional heating means as for example by passing through a heat exchanger made from a glass condenser set a temperature designed to provide a fiber treating solution of the desired temperature.
- the heat exchanger can be heated with a recirculating water bath set at 75oC, giving a stabilized temperature in the tank of about 45oC.
- the fibers are exposed to recirculating crosslinking composition at a suitable temperature (preferably about 45oC) for an effective period of time, as for example, for from about 0.5 hrs. to about 4 hrs.
- the crosslinking composition is pumped away and water is recirculated across the fibers, without heating.
- the washing step is
- the fibers are suspended for time to allow the water to drain and to allow the fibers to dry.
- the fibers are heated in a "vacuum" oven for a time period and at a temperature sufficient to complete the crosslinking reaction.
- the fibers are heated to a temperature of about 95°C for about 8 hrs.
- a brisk flow of dry inert gas, such as nitrogen, is passed through the oven using the vacuum port as inlet and the vent port as outlet.
- a glass tube is preferably fitted inside the oven to insure that the flow passes from front to back. The flow of inert gas purges water vapor, HCl and formaldehyde from the oven.
- the heat is turned off, but the nitrogen flow is left on a lower flow rate, while the oven is cooled down.
- the carpet or fiber is removed and soaked in a base such as NaHCO 3 solution to neutralize any remaining HCl, washed once with fresh H 2 O and dried to form a crosslinked fiber having the desired
- the crosslinking density is directly proportional to the concentration of the crosslinking agents, the type and the reactivity of the cross-linking agent and the efficiency of the cross-linking reaction.
- concentration of the crosslinking agents the concentration of the crosslinking agents
- crosslinking agent is relatively high and to prepare carpet with lower cross-link density the crosslinking agent concentration is relatively low.
- the amount of crosslinking agent is at least about 1 mole % based on total number of reactive moieties in the polymer material.
- the reaction moiety is the recurring amide linkages.
- crosslinking agent is preferably from about 1 to about 5000 mole %, more preferably from about 100 to about 5000 mole % and most preferably from about 1000 to about 4000 mole % on the aforementioned basis.
- Process temperature may vary widely depending on the reactivity of the polymer forming the fiber and the crosslinking agent.
- the preferred polymeric material preferably nylon 6 or nylon 6,6
- reaction temperatures are equal to or less than about 200oC. Reaction temperatures are more preferably equal to or less than abut 100oC and most preferably from about 50oC to about 75°C.
- reaction times may vary widely and usually depend on factors known to those of skill in the art such as reactivity of the polymer forming the fiber and the crosslinking agent, reaction temperature and the like.
- reaction times can be as long as twenty-four hours or more or as short as one or two minutes. More preferred reaction times are from about 5 minutes to about 5 hours, and most preferred reaction times are from about 30 minutes to about 3 hours.
- the carpets of this invention may be formed entirely of the crosslinked fibers of this invention.
- the carpet of this invention may also contain in addition to the crosslinked carpet fibers other fibers so long as the carpet exhibits the above-mentioned appearance retention characteristics.
- carpet may contain such other fibers made from wool, cotton, metal, or carbon, or fibers that contain additives such as carbon black or titanium dioxide.
- the fibers may include conventional fiber additives such as delustering agents (e.g. titanium dioxide), dyes and colorants and fiber finishers, and that all or a portion of the fibers of the carpet of this invention may be coated with
- materials such as fluorocarbons and/or stain blockers for the purpose of improving the soil and stain
- carpets of this invention such as the primary backing, secondary backing, latex for attaching the secondary backing, and the like are conventional and one or more of such conventional components can be used.
- the carpets of this invention can be of any conventional style, as for example saxony carpets, greige carpets, or thin cut pile tufted carpet made in the conventional manner with crosslinked fibers of this invention instead of
- the carpet of this invention can be used for conventional purposes.
- the carpet can be used as a floor covering, wall coverings and the like.
- Examples 1 through 19 describe the preparation of cross-linked nylon fiber, in the form of greige carpet, according to the aqueous method of the invention. A summary of these examples is set forth in the following Table I.
- Aqueous, acidulated, formalin was prepared by warming a slurry of paraformaldehyde powder in aqueous hydrochloric acid.
- a slurry of paraformaldehyde powder in aqueous hydrochloric acid.
- 560 g of paraformaldehyde, 70 ml of concentrated hydrochloric acid and enough water to make a total, final, volume of 1435 ml were slurred together and heated to 90°C until the paraformaldehyde had dissolved. The solution was cooled to room temperature.
- the room temperature formalin solution was poured over the greige carpet, completely immersing it. This was allowed to stand at room temperature for 4 hr 5 min, after which time the formalin was poured off and the carpet washed 3 times with 2 liters of water each time. After being hung to drain for 15 min the carpet was left overnight flat on an absorbent surface, such as a sponge, to dry.
- Example 2 The fibers of example 2 were prepared similarly to example 1 except that no formalin was used. In example 3 the fibers were not treated in any way. Examples 2 and 3 are included in Table I.
- Examples 4 through 8 were prepared in a manner similar to example 1 except that a metal tray, rather than a plastic tray, was used as the reaction vessel. In addition, the sample prepared in example 4 was washed with methanol two times, after the three water washes, and then dried. Examples 4 through 8 are included in Table I.
- the fibers of examples 9 through 19 were prepared similarly to the fibers of example 1 except that the formalin solution was pumped through the reaction vessel during the formalin soaking step. This is indicated in Table I by “Flow” as opposed to “Static” under the heading “Soaking Conditions.” Also, the baking step performed during examples 9 through 19 was not done under vacuum, but rather under a flowing stream of dry nitrogen gas to purge volatile products from the oven. The greige carpet was supported on a glass-rod frame so vapors could move freely around it. Finally, a bicarbonate washing step (15 g NaHCO 3 per 5 liters water) was added in examples 10 through 19. The purpose of this step is to remove residual acid from the fibers. The use of this wash step is indicated in Table I by “Yes” under the heading "Bicarbonate Wash” and the wash was done within 24 hours of the final baking step.
- Examples 20 through 27 illustrate using a non-aqueous solvent during the treatment process. Note that using this method of the invention it is not necessary to bake the carpets after the treatment as they are already cross-linked at that time.
- Example 20 depicts the cross-linking of nylon fibers in the form of greige carpet using the non-aqueous, toluene solvent, method of the invention.
- a piece of greige carpet 11" by 24" was submerged in a previously prepared solution consisting of 3.75 liters of 2.0 ⁇ 10 -2 molar HCl in toluene and 11.36 grams of suspended, finely powdered paraformaldehyde.
- the reactor vessel was a 4 liter resin kettle approximately 13 cm in diameter by 34 cm high and the carpet was rolled up, tufts toward the inside, so that it would fit into it.
- the reactor was allowed to stand at room temperature for 5 minutes. Then it was placed into a preheated boiling water bath, a
- Example 20 is included in Table II.
- Example 28 illustrates the treatment of nylon fibers in the form of greige carpet with gas phase formaldehyde.
- Example 29 is the control experiment for these fibers.
- a 12" by 24" piece of greige carpet was loosely rolled up (tufts facing inward) and was placed into a large vacuum desiccator. The weight of the carpet was about 240 grams. The air was removed from the
- the desiccator in a small beaker.
- the desiccator was reevacuated and then 5 millimoles of HCl gas were allowed to pass into the desiccator and it was sealed off.
- the HCl was generated by addition of 10 millimoles of NaCl to 15 ml concentrated H 2 SO 4 ; a 50% yield and transfer efficiency was assumed.
- the desiccator was put into a preheated oven at 115oC for 10 hours. The desiccator was vented with dry argon and the carpet was allowed to cool. Finally the carpet was washed in bicarbonate solution as in example 10.
- Example 30 illustrates the treatment of nylon fiber in the form of knitted sleeve with the gas phase formaldehyde method of the invention.
- Example 31 illustrates the treatment of nylon fiber in the form of yarn skeins with the gas phase formaldehyde method of the invention.
- Example 32 illustrates the treatment of nylon fiber in the form of yarn skeins using the aqueous formalin method of the invention.
- Skeins of doubled yarn were treated using aqueous formalin in a manner similar to example 10, except that the skeins were placed into the cylindrical reactor described in example 20 and the formalin was pumped from bottom to top during the reaction period. In addition, the skeins were put into the oven without the glass-rod frame. These skeins were made from doubled yarn which had been twisted from singles yarn and heat set in a manner similar to the yarn used to manufacture the greige carpets of examples 1 through 29.
- Examples 33 through 61 depict the preparation of test carpets from the fiber samples prepared in examples 1 through 32. A summary of these examples is shown in the following Table III.
- the treated greige carpet of example 1 was prepared for wear testing by first coating its back with latex and applying a jute secondary backing.
- the latex was cured by baking in an oven following the directions of the latex supplier.
- the back-coated carpet was then lightly sheared to even the carpet's surface. This carpet sample was then ready for floor wear testing.
- Examples 62 through 64 depict the preparation of test carpets from the yarn samples prepared in examples 30, 31 and 32.
- the yarn prepared in example 30 was de-knitted and wound onto two packages. These two packages were cabled together, twist at 3% turns per inch and heat set at 270°F using the Superba process.
- the doubled, heat set yarn was wound onto 65 cones and used to feed 65 needles in the center of a 24" wide carpet needlepunching unit.
- the remaining needles were fed with untreated, standard nylon yarn of the type used in preparing the greige carpets of examples 1 through 29.
- the needle punching machine was set up to manufacture fabric with the same characteristics as the greige carpet of examples l through 29. This resulted in the manufacture of a "banded,” cut pile carpet where the center 10 inches were of treated yarn and the 7 inches on either side were of untreated control yarn.
- the banded carpet was then further processed by coating the backside with latex and applying a jute secondary backing, curing the latex according to the directions of the latex supplier, dyeing the carpet using the "beck” process and an acid dye and, finally, lightly shearing the surface to assure that the top surface was level.
- the control and treated parts of the carpet had the same appearance and the carpet was ready for weartesting. This carpet appears in Table III as example 62.
- the carpets of examples 63 and 64 were prepared by processing the skeins prepared in examples 31 and 32, respectively, in a manner similar to that of example 62 except that the twisting and heat setting steps were omitted since the yarn was already doubled. That is to say, the skeins were wound directly onto 65 cones, and the yarn on these cones was used to feed the needle punching machine. The rest of the process was
- Example 65 The carpet prepared in Example 33 was placed directly on the floor with the machine direction parallel to the walking direction, secured with tape at the edge and walked on. The number of foot treads were recorded and the wear test stopped at 50,000
- the wear rating in this case was 2 (slightly worn). The most worn part of the carpet is used for the rating.
- W T is the total weight of fibers plus absorbed formic acid
- W F is the weight of the fibers alone.
- This equation was previously established as a valid approximation for the region of interest by using solid-state 13 C NMR on a series of 13 CH 2 O cross-linked nylon-6 fibers. In the present example there were found to be 3.3 cross-links per chain.
- the carpet prepared in example 60 was tested in a manner similar to examples 65 through 90 except that the wear rating was determined at 10,000 and 25,000 as well as 50,000 equivalent treads.
- the results from examples 91, 92 and 93 are tabulated in Table IV.
- Example 98 indicates the control wore less (had a lower wear rating) than the treated area.
- Example 99 indicates the control and treated areas wear at the same rate.
- Control » X-link indicates that the control wore more (had a higher wear rating) than the treated area.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Carpets (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP93915463A EP0651620A1 (en) | 1992-07-20 | 1993-06-22 | Carpet having improved appearance retention |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US916,554 | 1986-10-08 | ||
US91655492A | 1992-07-20 | 1992-07-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994002058A1 true WO1994002058A1 (en) | 1994-02-03 |
Family
ID=25437459
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1993/005991 WO1994002058A1 (en) | 1992-07-20 | 1993-06-22 | Carpet having improved appearance retention |
Country Status (2)
Country | Link |
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EP (1) | EP0651620A1 (en) |
WO (1) | WO1994002058A1 (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2425334A (en) * | 1943-01-18 | 1947-08-12 | Ici Ltd | Modification of filaments, etc., derived from synthetic linear polyamides |
WO1992004486A1 (en) * | 1990-09-07 | 1992-03-19 | E.I. Du Pont De Nemours And Company | Carpet yarns and carpets with improved balance of newness retention and bulk |
WO1992014879A1 (en) * | 1991-02-18 | 1992-09-03 | Albany International Corp. | Improvements in and relating to paper machine clothing |
-
1993
- 1993-06-22 WO PCT/US1993/005991 patent/WO1994002058A1/en not_active Application Discontinuation
- 1993-06-22 EP EP93915463A patent/EP0651620A1/en not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2425334A (en) * | 1943-01-18 | 1947-08-12 | Ici Ltd | Modification of filaments, etc., derived from synthetic linear polyamides |
WO1992004486A1 (en) * | 1990-09-07 | 1992-03-19 | E.I. Du Pont De Nemours And Company | Carpet yarns and carpets with improved balance of newness retention and bulk |
WO1992014879A1 (en) * | 1991-02-18 | 1992-09-03 | Albany International Corp. | Improvements in and relating to paper machine clothing |
Also Published As
Publication number | Publication date |
---|---|
EP0651620A1 (en) | 1995-05-10 |
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