WO1992020728A1 - Method for producing an ionomer - Google Patents

Method for producing an ionomer Download PDF

Info

Publication number
WO1992020728A1
WO1992020728A1 PCT/NL1992/000086 NL9200086W WO9220728A1 WO 1992020728 A1 WO1992020728 A1 WO 1992020728A1 NL 9200086 W NL9200086 W NL 9200086W WO 9220728 A1 WO9220728 A1 WO 9220728A1
Authority
WO
WIPO (PCT)
Prior art keywords
plastic
conducting medium
medium
electrical field
elec
Prior art date
Application number
PCT/NL1992/000086
Other languages
French (fr)
Inventor
Robert Ross
Original Assignee
N.V. Kema
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by N.V. Kema filed Critical N.V. Kema
Priority to DE69232733T priority Critical patent/DE69232733T2/en
Priority to DK92917395T priority patent/DK0647249T3/en
Priority to EP92917395A priority patent/EP0647249B1/en
Priority to AT92917395T priority patent/ATE222272T1/en
Priority to US08/146,076 priority patent/US5427662A/en
Priority to JP51016392A priority patent/JP3268531B2/en
Publication of WO1992020728A1 publication Critical patent/WO1992020728A1/en
Priority to NO934030A priority patent/NO308477B1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0093—Chemical modification
    • B01D67/00931—Chemical modification by introduction of specific groups after membrane formation, e.g. by grafting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
    • B29C71/0081—After-treatment of articles without altering their shape; Apparatus therefor using an electric field, e.g. for electrostatic charging
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2096/00—Use of specified macromolecular materials not provided for in a single one of main groups B29K2001/00 - B29K2095/00, as moulding material
    • B29K2096/005—Ionomers

Definitions

  • the invention relates to a method for producing an ionomer.
  • the invention relates more in particular to the producing of an ionomer from a plastic which initially usual ⁇ ly contains no incorporated ion compounds in addition to the normal organic covalent bonds.
  • This new method for producing ionomers comprises of: i) providing a plastic; ii) placing an electrically conducting medium in contact with a plastic surface of the plastic; and iii) applying an electrical field over the plastic surface. It has been found, namely, that if a plastic is loaded with an electrical field in the presence of an electrically conducting medium, groups are radicalized or ionized from the external and/or internal plastic surface in the direction of the electrical field in the plastic, which groups are con ⁇ verted as a result for instance of oxidation reactions into for example carboxylic acids and/or sulphonic acids. Under ⁇ stood by plastic surface is, among other things, an external plastic surface optionally provided with grooves, scratches or other surface defects and walls of cavities in the plastic which may contain contaminants.
  • hydrophilic channels which are however se i- p rmeable.
  • the electrically conducting medium for instance water, is mobile in these channels but hydrated ions can only displace in these channels under the influence of the elec- trical field.
  • an ionomer according to the invention can also be provided with cavities in which salts are entrapped. Both liquids and gases can be used as electrically conducting medium.
  • the latter has the particular objective that the oxidized groups can dissociate and form an ionoge- nic, functional group with the metal ions supplied by the medium.
  • the electrically conducting medium can be an inorga ⁇ nic medium such as water and ammonia.
  • the electrically con ⁇ ducting medium can likewise be an organic medium such as alkanols, for instance methanol and ethanol. If the electri ⁇ cally conducting medium has an inherent insufficient activi- ty, diverse reactive components can be added to the medium and/or to the plastic.
  • One group of reactive components consists of gases such as oxygen, ozone, sulphur oxide, for instance sulphur dioxide. Such gases can sustain and assist the radical-form- ing or ion-forming reactions as well as the oxidation reac ⁇ tions.
  • gases such as oxygen, ozone, sulphur oxide, for instance sulphur dioxide.
  • gases can sustain and assist the radical-form- ing or ion-forming reactions as well as the oxidation reac ⁇ tions.
  • Another group of reactive components is formed by salts, particularly salts of multivalent metal ions such as copper, tin and manganese.
  • salts particularly salts of multivalent metal ions such as copper, tin and manganese.
  • metal ions accelerate the growth of the hydrophilic channels, possibly partly due to a catalytic acceleration of the oxidation reactions.
  • Another group of reactive components is formed by surface-active substances such as a soap.
  • surface-active substances for example a stearate, can on the one hand effect the same function as the salts and on the other reduce the surface tension so that the electrically conduct ⁇ ing, more or less polar medium can penetrate more rapidly into the apolar plastic.
  • Other examples of soaps for use comprise alkyl sulphonates, aryl sulphonates, alkyl(aryl) sulphonates and ethylene oxide adducts optionally in combina ⁇ tion with alkyl and/or aryl groups.
  • the magnitude of the electrical field applied over the plastic is not limited to a determined value.
  • a first forming of ionogenic, functional groups already takes place from a value of 1 V/mm of plastic.
  • An upper limit for the magnitude of the electrical field is determined by the short-circuit voltage of the plastic, which voltage can change as the iono eric character of the plastic increases.
  • a reasonable speed for the forming of the ionogenic, functional groups occurs with an electrical field of 0.2 to 20 kV/mm. If for instance the plastic consists of polyethylene, optimum speeds for the forming of ionogenic, functional groups are obtained when the electrical field amounts to 0.5 to 10 kV/ m. In general, the strongest possible electrical field will be applied, having in practice a value approximately equal to half the short-circuit voltage.
  • the frequency of the applied field amounts generally to 1 to 10 5 Hz, preferably 10 Hz to 25 kHz. It has been found however that the magnitude of the frequency can influence the properties of the formed ionomers. For instance at lower frequencies of 5 Hz to 10 kHz mainly electrochemical reac ⁇ tions will occur (oxidation reactions) whereby mainly hydro ⁇ philic channels are formed. At higher frequencies, for exam- pie from 100 Hz, the ion conduction phenomenon will occur to a greater extent whereby, when the electrically conducting medium contains salts, salts can penetrate into cavities inside the hydrophilic channels and possibly contribute to cavity forming. Once enclosed in these cavities and in the absence of an electrical field, these salts are irreversibly entrapped inside the ionomer.
  • the ionomer produced according to the invention gene ⁇ rally has the form of a sheet.
  • This sheet form may already be present in the plastic subjected to the method. It is however possible that a for example hollow cylindrical plastic is subjected to a radially oriented electrical field, whereafter an ionomer in the form of a sheet is formed from this hollow cylindrical plastic by means of delamination, optionally by peeling.
  • An optimum method for producing ionomers is obtained if the plastic is placed in contact with the conducting medium on surfaces facing away from each other.
  • a preferred embodiment for performing the method according to the invention comprises the use of a strip-like plastic which is converted into a channel shape, into which channel liquid, electrically conducting medium is introduced.
  • the channel-shaped plastic is guided through a bath of liquid electrically conducting medium.
  • an electrode for applying the electrical field over the plastic strip.
  • the plastic in this case in the form of a plastic foil, can form a parti ⁇ tion between two medium chambers each containing for instance gaseous electrically conducting medium (for instance water vapour) and an electrode for generating the electrical field. If a good sealing with the chamber walls is ensured, this method can likewise be converted into a continuous method.
  • gaseous electrically conducting medium for instance water vapour
  • Plastics which can be converted into ionomers with the method according to the invention are in principle not limi ⁇ ted to a specific group of plastics, plastics which can particularly be used comprise polyethylene, polypropylene, polystyrene and polytetrafluoroethylene.
  • the ionomers produced in accordance with the method according to the invention can be applied in very many fie ⁇ lds.
  • An example which might be quoted is as ion conductor in for instance polymer batteries, in which the ionomer func ⁇ tions as an electrolyte.
  • the ionomer can also be applied as a semi-permeable membrane with a selective permeability for particular types of molecules and ions, wherein the permeabi ⁇ lity can moreover be adjusted as a function of the electrical field and/or the temperature.
  • the ionomers can be used for purifying solutions, dispersions and emulsions of both chemical and medicinal nature.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Medicinal Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Transplantation (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Saccharide Compounds (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)

Abstract

The invention relates to a method for producing an ionomer comprising of: (i) providing a plastic; (ii) placing an electrically conducting medium in contact with a plastic surface of the plastic; and (iii) applying an electrical field over the plastic surface, such that electrically bonded, ionogenic groups occur in the plastic.

Description

Method for producing an ionomer
The invention relates to a method for producing an ionomer. The invention relates more in particular to the producing of an ionomer from a plastic which initially usual¬ ly contains no incorporated ion compounds in addition to the normal organic covalent bonds.
This new method for producing ionomers comprises of: i) providing a plastic; ii) placing an electrically conducting medium in contact with a plastic surface of the plastic; and iii) applying an electrical field over the plastic surface. It has been found, namely, that if a plastic is loaded with an electrical field in the presence of an electrically conducting medium, groups are radicalized or ionized from the external and/or internal plastic surface in the direction of the electrical field in the plastic, which groups are con¬ verted as a result for instance of oxidation reactions into for example carboxylic acids and/or sulphonic acids. Under¬ stood by plastic surface is, among other things, an external plastic surface optionally provided with grooves, scratches or other surface defects and walls of cavities in the plastic which may contain contaminants. Under the influence of the electrically conducting medium these oxidized groups will dissociate and in the presence of metal ions form the charac¬ teristic ionogenic, functional groups, i.e. chemically bonded salt groups. Thus formed in the generally amorphous phase of the plastic are hydrophilic channels which are however se i- p rmeable. The electrically conducting medium, for instance water, is mobile in these channels but hydrated ions can only displace in these channels under the influence of the elec- trical field. Depending on the nature and composition of the electrically conducting medium and the applied electrical field an ionomer according to the invention can also be provided with cavities in which salts are entrapped. Both liquids and gases can be used as electrically conducting medium. The latter has the particular objective that the oxidized groups can dissociate and form an ionoge- nic, functional group with the metal ions supplied by the medium. The electrically conducting medium can be an inorga¬ nic medium such as water and ammonia. The electrically con¬ ducting medium can likewise be an organic medium such as alkanols, for instance methanol and ethanol. If the electri¬ cally conducting medium has an inherent insufficient activi- ty, diverse reactive components can be added to the medium and/or to the plastic.
One group of reactive components consists of gases such as oxygen, ozone, sulphur oxide, for instance sulphur dioxide. Such gases can sustain and assist the radical-form- ing or ion-forming reactions as well as the oxidation reac¬ tions.
Another group of reactive components is formed by salts, particularly salts of multivalent metal ions such as copper, tin and manganese. Such metal ions accelerate the growth of the hydrophilic channels, possibly partly due to a catalytic acceleration of the oxidation reactions.
Another group of reactive components is formed by surface-active substances such as a soap. These surface- active substances, for example a stearate, can on the one hand effect the same function as the salts and on the other reduce the surface tension so that the electrically conduct¬ ing, more or less polar medium can penetrate more rapidly into the apolar plastic. Other examples of soaps for use comprise alkyl sulphonates, aryl sulphonates, alkyl(aryl) sulphonates and ethylene oxide adducts optionally in combina¬ tion with alkyl and/or aryl groups.
The magnitude of the electrical field applied over the plastic is not limited to a determined value. A first forming of ionogenic, functional groups already takes place from a value of 1 V/mm of plastic. An upper limit for the magnitude of the electrical field is determined by the short-circuit voltage of the plastic, which voltage can change as the iono eric character of the plastic increases. A reasonable speed for the forming of the ionogenic, functional groups occurs with an electrical field of 0.2 to 20 kV/mm. If for instance the plastic consists of polyethylene, optimum speeds for the forming of ionogenic, functional groups are obtained when the electrical field amounts to 0.5 to 10 kV/ m. In general, the strongest possible electrical field will be applied, having in practice a value approximately equal to half the short-circuit voltage.
The frequency of the applied field amounts generally to 1 to 105Hz, preferably 10 Hz to 25 kHz. It has been found however that the magnitude of the frequency can influence the properties of the formed ionomers. For instance at lower frequencies of 5 Hz to 10 kHz mainly electrochemical reac¬ tions will occur (oxidation reactions) whereby mainly hydro¬ philic channels are formed. At higher frequencies, for exam- pie from 100 Hz, the ion conduction phenomenon will occur to a greater extent whereby, when the electrically conducting medium contains salts, salts can penetrate into cavities inside the hydrophilic channels and possibly contribute to cavity forming. Once enclosed in these cavities and in the absence of an electrical field, these salts are irreversibly entrapped inside the ionomer.
The ionomer produced according to the invention gene¬ rally has the form of a sheet. This sheet form may already be present in the plastic subjected to the method. It is however possible that a for example hollow cylindrical plastic is subjected to a radially oriented electrical field, whereafter an ionomer in the form of a sheet is formed from this hollow cylindrical plastic by means of delamination, optionally by peeling. An optimum method for producing ionomers is obtained if the plastic is placed in contact with the conducting medium on surfaces facing away from each other.
A preferred embodiment for performing the method according to the invention comprises the use of a strip-like plastic which is converted into a channel shape, into which channel liquid, electrically conducting medium is introduced. The channel-shaped plastic is guided through a bath of liquid electrically conducting medium. Into both the bath and into the medium present in the channel is inserted an electrode for applying the electrical field over the plastic strip. By subsequently transporting the strip through the bath, wherein the medium present in the channel moves over the channel- shaped internal surface, the method according to the inven- tion can be performed continuously.
According to a second embodiment of the method accord¬ ing to the invention for producing an ionomer, the plastic, in this case in the form of a plastic foil, can form a parti¬ tion between two medium chambers each containing for instance gaseous electrically conducting medium (for instance water vapour) and an electrode for generating the electrical field. If a good sealing with the chamber walls is ensured, this method can likewise be converted into a continuous method.
Plastics which can be converted into ionomers with the method according to the invention are in principle not limi¬ ted to a specific group of plastics, plastics which can particularly be used comprise polyethylene, polypropylene, polystyrene and polytetrafluoroethylene.
The ionomers produced in accordance with the method according to the invention can be applied in very many fie¬ lds. An example which might be quoted is as ion conductor in for instance polymer batteries, in which the ionomer func¬ tions as an electrolyte. The ionomer can also be applied as a semi-permeable membrane with a selective permeability for particular types of molecules and ions, wherein the permeabi¬ lity can moreover be adjusted as a function of the electrical field and/or the temperature. Finally, the ionomers can be used for purifying solutions, dispersions and emulsions of both chemical and medicinal nature.
*****

Claims

1. Method for producing an ionomer comprising of: i) providing a plastic; ii) placing an electrically conducting medium in contact with a plastic surface of the plastic; and iii) applying an electrical field over the plastic surface, this such that electrically bonded, ionogenic groups occur in the plastic.
2. Method as claimed in claim 1 , wherein the electri¬ cally conducting medium is chosen from liquids and/or gases.
3. Method as claimed in claim 1 or 2, wherein the electrically conducting medium comprises an inorganic medium such as water and ammonia and/or an organic medium such as alkanols, for instance methanol and ethanol.
4. Method as claimed in claims 1-3, wherein the elec- trically conducting medium contains a reactive gas such as oxygen, ozone, sulphur oxide.
5. Method as claimed in claims 1-4, wherein the elec¬ trically conducting medium and/or the plastic contains a salt.
6. Method as claimed in claims 1-5, wherein the elec¬ trically conducting medium and/or the plastic contains a surface-active substance such as a soap.
7. Method as claimed in claims 1-6, wherein the elec¬ trical field is in the order of 1 Volt/mm plastic to the short-circuit voltage of the plastic.
8. Method as claimed in claim 7, wherein the electrical field amounts to 0.2-20 kV/mm plastic.
9. Method as claimed in claim 7 or 8, wherein the plastic is polyethylene and the electrical field amounts to 0.5-10 kV/mm polyethylene.
10. Method as claimed in claims 1-9, wherein the frequency of the electrical field amounts to l-105Hz, prefe¬ rably 10 Hz-25 kHz.
11. Method as claimed in claims 1-10, wherein the plastic is sheet-like.
12. Method as claimed in claims 1-11, wherein plastic surfaces facing away from each other are placed in contact with the conducting medium.
13. Method as claimed in claims 1-12, wherein the plastic has a strip form and is converted into a channel shape, wherein liquid electrically conducting medium is added to the channel.
14. Method as claimed in claims 1-12, wherein the plastic forms a partition between two medium chambers.
*****
PCT/NL1992/000086 1991-05-10 1992-05-08 Method for producing an ionomer WO1992020728A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE69232733T DE69232733T2 (en) 1991-05-10 1992-05-08 METHOD FOR PRODUCING AN IONOMER
DK92917395T DK0647249T3 (en) 1991-05-10 1992-05-08 Process for preparing an ionomer
EP92917395A EP0647249B1 (en) 1991-05-10 1992-05-08 Method for producing an ionomer
AT92917395T ATE222272T1 (en) 1991-05-10 1992-05-08 METHOD FOR PRODUCING AN IONOMER
US08/146,076 US5427662A (en) 1991-05-10 1992-05-08 Method for producing an ionomer
JP51016392A JP3268531B2 (en) 1991-05-10 1992-05-08 Manufacturing method of ionomer
NO934030A NO308477B1 (en) 1991-05-10 1993-11-08 Process for preparing an ionomer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL9100815 1991-05-10
NL9100815A NL9100815A (en) 1991-05-10 1991-05-10 METHOD FOR MANUFACTURING AN IONOMER

Publications (1)

Publication Number Publication Date
WO1992020728A1 true WO1992020728A1 (en) 1992-11-26

Family

ID=19859237

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NL1992/000086 WO1992020728A1 (en) 1991-05-10 1992-05-08 Method for producing an ionomer

Country Status (12)

Country Link
US (1) US5427662A (en)
EP (1) EP0647249B1 (en)
JP (1) JP3268531B2 (en)
AT (1) ATE222272T1 (en)
AU (1) AU1874592A (en)
CA (1) CA2102510A1 (en)
DE (1) DE69232733T2 (en)
DK (1) DK0647249T3 (en)
ES (1) ES2179041T3 (en)
NL (1) NL9100815A (en)
NO (1) NO308477B1 (en)
WO (1) WO1992020728A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996033293A1 (en) * 1995-04-19 1996-10-24 Korea Institute Of Science And Technology Modification of surfaces of polymers, metal or ceramic
NL1005418C2 (en) * 1997-03-03 1998-09-07 Kema Nv Method for treating a base material to obtain specific properties.
WO2002031030A1 (en) * 2000-10-12 2002-04-18 Osaka Gas Co., Ltd. Formed resin article
EP1548447A1 (en) * 2002-09-26 2005-06-29 ARKRAY, Inc. Method of producing analytical tool

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009026376A1 (en) 2009-08-14 2011-02-24 Karl August Dr. Brensing Device for introducing gas into liquids

Citations (5)

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Publication number Priority date Publication date Assignee Title
DE1128644B (en) * 1958-03-01 1962-04-26 Kalle Ag Process for modifying the surface properties of deformed thermoplastics
US3124729A (en) * 1957-06-04 1964-03-10 Method for preparing surfaces com-
FR2119546A5 (en) * 1970-12-22 1972-08-04 Monsanto Chemicals
GB2013213A (en) * 1978-01-26 1979-08-08 Troester Gmbh Method of cross linking plastics and/or rubber materials
US4353799A (en) * 1976-05-19 1982-10-12 Baxter Travenol Laboratories, Inc. Hydrophobic diffusion membranes for blood having wettable surfaces

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JPS62263361A (en) * 1986-05-09 1987-11-16 東レ株式会社 Production of nonwoven fabric
US4988419A (en) * 1988-01-20 1991-01-29 Industrial Management Co. Method and apparatus for producing conductivity in materials
EP0436918B1 (en) * 1990-01-03 1995-06-28 Wolff Walsrode Aktiengesellschaft Process for treating a polyolefin film

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US3124729A (en) * 1957-06-04 1964-03-10 Method for preparing surfaces com-
DE1128644B (en) * 1958-03-01 1962-04-26 Kalle Ag Process for modifying the surface properties of deformed thermoplastics
FR2119546A5 (en) * 1970-12-22 1972-08-04 Monsanto Chemicals
US4353799A (en) * 1976-05-19 1982-10-12 Baxter Travenol Laboratories, Inc. Hydrophobic diffusion membranes for blood having wettable surfaces
GB2013213A (en) * 1978-01-26 1979-08-08 Troester Gmbh Method of cross linking plastics and/or rubber materials

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Title
CHEMICAL ABSTRACTS, , 10 December 1979, Columbus, Ohio, US; abstract no. 91-193764N, GELAZOV KERIMOV: 'THERMOLUMINESCENCE OF POLYETHYLENE CAUSED BY A STRONG ELECTRIC FIELD' *
CHEMICAL ABSTRACTS, , 15 November 1982, Columbus, Ohio, US; abstract no. 97-163621V, GEZALOV KERIMO: 'PRE-BREAKDOWN FREE RADICAL STATES IN POLYETHYLENE' *
CHEMICAL ABSTRACTS, , 3 July 1989, Columbus, Ohio, US; abstract no. 110-95925G, RAGIMOV MAMEDOV ABASOV ALEKPEROV: 'STRONG ELECTRICAL FIELD EFFECT ON MOLECULAR MECHANISM OF POLYETHYLENE DEGRADATION' *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996033293A1 (en) * 1995-04-19 1996-10-24 Korea Institute Of Science And Technology Modification of surfaces of polymers, metal or ceramic
NL1005418C2 (en) * 1997-03-03 1998-09-07 Kema Nv Method for treating a base material to obtain specific properties.
WO1998039092A1 (en) * 1997-03-03 1998-09-11 N.V. Kema Method of treating a base material for obtaining specific properties
US6342130B1 (en) 1997-03-03 2002-01-29 N.V. Kema Method of treating a base material for obtaining specific properties
WO2002031030A1 (en) * 2000-10-12 2002-04-18 Osaka Gas Co., Ltd. Formed resin article
EP1548447A1 (en) * 2002-09-26 2005-06-29 ARKRAY, Inc. Method of producing analytical tool
EP1548447A4 (en) * 2002-09-26 2010-11-03 Arkray Inc Method of producing analytical tool

Also Published As

Publication number Publication date
CA2102510A1 (en) 1992-11-11
NO934030D0 (en) 1993-11-08
EP0647249A1 (en) 1995-04-12
JP3268531B2 (en) 2002-03-25
NO308477B1 (en) 2000-09-18
ATE222272T1 (en) 2002-08-15
US5427662A (en) 1995-06-27
ES2179041T3 (en) 2003-01-16
DE69232733T2 (en) 2003-04-24
EP0647249B1 (en) 2002-08-14
NL9100815A (en) 1992-12-01
JPH06507657A (en) 1994-09-01
AU1874592A (en) 1992-12-30
DE69232733D1 (en) 2002-09-19
NO934030L (en) 1993-11-08
DK0647249T3 (en) 2002-11-25

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