WO1992007546A1 - Compositions pour l'entretien des cheveux comprenant des compositions de mousse et de shampooing pour mise en plis - Google Patents

Compositions pour l'entretien des cheveux comprenant des compositions de mousse et de shampooing pour mise en plis Download PDF

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Publication number
WO1992007546A1
WO1992007546A1 PCT/US1991/005074 US9105074W WO9207546A1 WO 1992007546 A1 WO1992007546 A1 WO 1992007546A1 US 9105074 W US9105074 W US 9105074W WO 9207546 A1 WO9207546 A1 WO 9207546A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
hair
mousse
composition
surfactant
Prior art date
Application number
PCT/US1991/005074
Other languages
English (en)
Inventor
Michael W. Helioff
Krystyna Plochocka
Mohammed Tazi
Original Assignee
Isp Investments Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/608,949 external-priority patent/US5066481A/en
Priority claimed from US07/615,184 external-priority patent/US5118498A/en
Application filed by Isp Investments Inc. filed Critical Isp Investments Inc.
Publication of WO1992007546A1 publication Critical patent/WO1992007546A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

Definitions

  • This invention relates to hair care compositions such as shampoo cosmetic formulations which provides a subtle, temporary set for the hair of the user, and mousse hair compositions which provide a stable and expandable foam, a soft hold, and effective luster and shine for the hair of the user.
  • Current hair setting shampoo formulations generally are comprised of anionic surfactants and resins in combination with auxiliary ingredients designed to improve combability, luster, shine and manageability.
  • auxiliary ingredients designed to improve combability, luster, shine and manageability.
  • Such a setting shampoo formulation also should prevent frizziness which often occurs after shampooing.
  • Mousse hairstyling products have become popular with the public. Such products are dispensed from an aerosol can as a pressure sensitive foam which is released upon the hair, typically after the hair is shampooed and towel dried.
  • a mousse gives an appearance of penetration of the hair as the foam collapses and has ingredients that perform functions that are needed for the improved styling of hair. In particular, some of the purposes of these ingredients are to add body to the hair, thereby making it appear fuller on the head of the user, and to enhance the combability of the hair in order to make it more manageable.
  • a mousse • some of the collapsed foam may be designed to be combed out of the hair during the process of styling.
  • Mousses are distinguished from hairsprays or hair setting sprays which are typically used during the final step in holding the set of the hair. Such hairsprays tend to form a film, with flexibility provided by plasticizers that allow the hair to have some freedom of motion.
  • the hair care compositions of the invention comprise a resin provided by 1-15% by weight of a 20-50% resin active alcoholic solution of the alkyl half-ester of a C- j ⁇ -Cg alkyl vinyl ether-maleic anhydride copolymer having a molecular weight of at least one million, which is about 5-90% neutralized, preferably with about 0.01-1% by weight of ammonium hydroxide or
  • the hair setting shampoo composition includes 5-60% by weight of a surfactant, optionally 0-10% by weight of added ethanol, and about 30-90% by weight of water.
  • the mousse hair composition includes 60-95% water, about 0.3-2.0% of a surfactant, and about 0-30% of added ethanol.
  • the composition can contain also preservatives, chelating agents, fragrance etc.
  • the shampoo composition provides a subtle temporary set on hair of the user without the use of auxiliary fixatives in the composition.
  • the mousse composition provides a stable and expandable foam, a soft hold, and effective luster and shine for the hair of the user.
  • the thick, clear setting shampoo composition includes the alkyl half-ester of a high molecular weight c l ⁇ c 5 al * l ⁇ y 1 vinyl ether-maleic anhydride copolymer.
  • the copolymer with C 1 -vinyl ether is available commercially in powder form as Gantrez ® AN-169, which is a methyl vinyl ether-maleic anhydride copolymer having a molecular weight of about one million, or more.
  • Suitable alkyl half-esters of this copolymer include the ethyl or butyl compounds. Solutions of such Gantrez ® AN-169 half-esters are prepared as a 20-50% resin active solution in ethanol.
  • the composition of the hair setting composition is given in Table 1 below.
  • Resin Neutralizing Agent e.g. AMP 0.01-1 0.05-0.5 0.1
  • a typical setting shampoo formulation is the following:
  • the surfactant component of the composition of the invention suitably is present in an amount of about 5-60% by weight of the composition and may be selected from conventional surfactants known in the art and used in hair shampoo formulations.
  • the major portion of the surfactant is ammonium lauryl sulfate, although mixtures with such commonly used surfactant materials as ammonium laureth sulfate and lauric diethanolamide may be used as well.
  • Other surfactants such as Alipal ® HF-433 (Rhone-Poulenc) and Surfadone ® LP-300 (GAF) may be included, if desired.
  • the preferred resin neutralizing agent is 2-amino-2-methyl-l-propanol (AMP) , although ammonium hydroxide may be used as well.
  • AMP 2-amino-2-methyl-l-propanol
  • the added ethanol component is optional and may be included to provide a sufficient amount of alcohol to solubilize the composition.
  • a volatile solubilizer such as dimethyl ether, also may be used.
  • the water phase is provided by deionized water, usually in an amount of about 30-90% by weight.
  • the composition is prepared by heating the water component to about 70°C. , stirring, and then slowly adding the surfactant ingredients over about a 30-minute period. Then the mixture is cooled to 25-30°C. and the chelating agent is added. Then ethanol, AMP and the resin solution components are admixed in a separate vessel, and the water-surfactant mixture is added thereto. Then the preservative and fragrance is added thereto.
  • the resulting formulation is a thick, clear hair setting shampoo. In use on short and curly hair, or short and wavy hair, this setting shampoo composition provides a subtle, temporary set with effective combability, luster, shine and manageability. In addition, frizziness is avoided during use.
  • composition of the mousse hair composition is given below.
  • the water-based phase of the composition includes water as a solvent and a foam-forming chemical.
  • the alcohol-based phase includes the hair styling and a body forming resin, a neutralizing agent and alcohol as a secondary solvent.
  • the aerosol mousse product comprises about 80-95% by weight of the mousse hair composition and about 5-20% by weight of propellant.
  • the propellant is a mixture of 70% propane and 30% isobu ane.
  • the aerosol mousse provides a stable and expandable foam, a soft hold, an excellent bubble distribution pattern, and effective luster and shine on the hair of the user.
  • the product is stable in aluminum or tin plate steel aerosol containers.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Composition de shampooing conditionneur pour mise en plis comprenant une résine dans des proportions comprises entre environ 1 à 15 % en poids d'environ 20 à 50 % d'une solution alcoolique active de résine d'un copolymère anhydride éther-maléique de vinyle alkyle C1-C5 dont le poids moléculaire est au moins égal à un million, qui est neutralisé approximativement à 5-90 %, de préférence avec environ 0,01 % à 1 % en poids de 2-amino-2-méthyle-1-propanol, environ 5 % à 60 % en poids d'un tensio-actif, facultativement de 0 % à 10 % en poids d'éthanol ajouté, et environ de 30 % à 90 % en poids d'eau. Ladite composition produit un léger conditionnement temporaire des cheveux de l'utilisateur(trice) sans avoir besoin d'incorporer dans la composition d'autres fixatifs. La composition de mousse pour le cheveux comprend de 3 % à 15 % en poids de la solution alcoolique de la résine, de 60 % à 95 % en poids d'eau, de 0,3 % à 2,0 % en poids d'un tensio-actif, et de 0 % à 30 % en poids d'éthanol ajouté.
PCT/US1991/005074 1990-11-05 1991-07-18 Compositions pour l'entretien des cheveux comprenant des compositions de mousse et de shampooing pour mise en plis WO1992007546A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/608,949 US5066481A (en) 1990-11-05 1990-11-05 Mousse hair composition
US608,949 1990-11-05
US07/615,184 US5118498A (en) 1990-11-19 1990-11-19 Hair setting shampoo composition
US615,184 1990-11-19

Publications (1)

Publication Number Publication Date
WO1992007546A1 true WO1992007546A1 (fr) 1992-05-14

Family

ID=27085916

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1991/005074 WO1992007546A1 (fr) 1990-11-05 1991-07-18 Compositions pour l'entretien des cheveux comprenant des compositions de mousse et de shampooing pour mise en plis

Country Status (2)

Country Link
AU (1) AU8428591A (fr)
WO (1) WO1992007546A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0567326A3 (en) * 1992-04-22 1993-12-22 Unilever Plc Cosmetic emulsion containing a resin material and process for making it
US5650044A (en) * 1994-03-11 1997-07-22 E & M Lamort Paper-pulp deinking method and equipment to implement this method
EP0987000A1 (fr) * 1998-09-10 2000-03-22 GOLDWELL GmbH Shampoo sous forme d'aérosol
WO2000049999A1 (fr) * 1999-02-23 2000-08-31 Hans Schwarzkopf Gmbh & Co. Kg Preparations destinees au traitement de fibres keratiniques
EP2438906A3 (fr) * 2010-08-17 2015-06-03 Henkel AG & Co. KGaA Additif de matage pour décolorations

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4240450A (en) * 1977-03-15 1980-12-23 L'oreal Composition and process for the treatment of keratin materials with polymers
US4402977A (en) * 1979-11-28 1983-09-06 L'oreal Composition for the treatment of keratin fibres, based on amphoteric polymers and anionic polymers
US4900809A (en) * 1989-03-13 1990-02-13 Gaf Chemicals Corporation Process of rendering copolymers of maleic anhydride and alkyl vinyl ethers prepared in benzene solvent substantially benzene-free
US4962185A (en) * 1989-10-02 1990-10-09 Gaf Chemicals Corporation Process of rendering copolymer powders of maleic anhydride and an alkyl vinyl ether prepared in benzene solvent substantially benzene-free

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4240450A (en) * 1977-03-15 1980-12-23 L'oreal Composition and process for the treatment of keratin materials with polymers
US4402977A (en) * 1979-11-28 1983-09-06 L'oreal Composition for the treatment of keratin fibres, based on amphoteric polymers and anionic polymers
US4900809A (en) * 1989-03-13 1990-02-13 Gaf Chemicals Corporation Process of rendering copolymers of maleic anhydride and alkyl vinyl ethers prepared in benzene solvent substantially benzene-free
US4962185A (en) * 1989-10-02 1990-10-09 Gaf Chemicals Corporation Process of rendering copolymer powders of maleic anhydride and an alkyl vinyl ether prepared in benzene solvent substantially benzene-free

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0567326A3 (en) * 1992-04-22 1993-12-22 Unilever Plc Cosmetic emulsion containing a resin material and process for making it
US5650044A (en) * 1994-03-11 1997-07-22 E & M Lamort Paper-pulp deinking method and equipment to implement this method
EP0987000A1 (fr) * 1998-09-10 2000-03-22 GOLDWELL GmbH Shampoo sous forme d'aérosol
AU753154B2 (en) * 1998-09-10 2002-10-10 Kpss-Kao Professional Salon Services Gmbh Aerosol shampoo composition
WO2000049999A1 (fr) * 1999-02-23 2000-08-31 Hans Schwarzkopf Gmbh & Co. Kg Preparations destinees au traitement de fibres keratiniques
EP2438906A3 (fr) * 2010-08-17 2015-06-03 Henkel AG & Co. KGaA Additif de matage pour décolorations

Also Published As

Publication number Publication date
AU8428591A (en) 1992-05-26

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