WO1991009427A1 - Solar generator - Google Patents

Solar generator Download PDF

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Publication number
WO1991009427A1
WO1991009427A1 PCT/EP1990/002265 EP9002265W WO9109427A1 WO 1991009427 A1 WO1991009427 A1 WO 1991009427A1 EP 9002265 W EP9002265 W EP 9002265W WO 9109427 A1 WO9109427 A1 WO 9109427A1
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WO
WIPO (PCT)
Prior art keywords
connector
solar
solar generator
generator according
solar cells
Prior art date
Application number
PCT/EP1990/002265
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German (de)
French (fr)
Inventor
Armin Rukwied
Original Assignee
Daimler-Benz Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daimler-Benz Aktiengesellschaft filed Critical Daimler-Benz Aktiengesellschaft
Publication of WO1991009427A1 publication Critical patent/WO1991009427A1/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/05Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Definitions

  • the invention relates to a solar generator with a large number of solar cells connected in series and / or in parallel, in which adjacent solar cells are electrically and mechanically connected to one another by metallic connectors.
  • Such a solar generator is described for example in "ESA SP-140" (November 1978), pages 33 to 40.
  • a large number of solar cells are connected in an electrically conductive manner for the production of photovoltaic solar generators.
  • a chain of solar cells connected in series results from the fact that the more or less rigid cells made of silicon are arranged one behind the other by means of ductile connectors.
  • metallic tapes with a thickness of approximately 30 ⁇ m made of silver or silver-coated molybdenum have been used as connectors, which are connected to the cell metallization by resistance welding or by soldering.
  • a so-called solar cell module is then created.
  • the expansion coefficients of the solar cells, the connector material and the substrate material differ are such that the expansion coefficient of the substrate (about 20 x 10 " 6 IC -1 ) is usually greater than the expansion coefficient of the connector (for Ag 19 x 10" 6 K ⁇ l ) and this in turn is greater than that Expansion coefficient of the solar cell (approx. 2.5 x 10 -6 K " x ).
  • the generators have to go through a large number of thermal cycles, with temperature changes of up to 250 ° K Thermal expansion differences should be accommodated by the solar cell connector as a flexible material that can be deformed into the plastic area, if possible up to a service life of 50,000 or even 100,000 cycles.
  • the solar cell connector is guided from the back of one cell to the front of the next cell and must therefore accommodate the entire difference in elongation (typically approx. 0.05 mm) of a straight connecting line.
  • the cell connector between the two solar cells is given a U-shaped elevation, which causes a so-called geometric expansion as a compensation arch, thus allowing the connector to be relieved to a certain extent. Since, as already mentioned, the connector is subject to constant expansion and alternating stresses,
  • the contact point of the connector with the cell metallization is particularly stressed by the effect of the expansion differences due to thermal cycles, which is reflected in the shear fractures that occur there. All previously used substrate / cell / connector material combinations caused damage at the latest after going through 15,000 to 30,000 thermal cycles Form of cracks at first and later breaks of the welds or the connectors.
  • the invention has for its object to provide a connector for a solar generator, which can undergo an even higher number of thermal cycles without breaking or cracking of the material and in particular also avoiding dynamic consolidation of the same.
  • thermal cycles of 50,000 to 100,000 can be realized in the orbital use of a satellite without defects in the mechanical or electrical connection of the interconnected cells.
  • the group of pseudo-elastic materials are materials that can withstand reversible deformations that go far beyond the elastic limit (end of the Hooke 'see straight line) of the material.
  • Metall 39 1985, pages 34 to 38.
  • These materials are also known as shape memory alloys. Due to a thermoelastic martensitic transformation, they show a temperature-dependent change in shape after suitable treatment. Is z. B. such an alloy permanently deformed at low temperature, it remembers when heated to a critical temperature to its original shape and takes it back.
  • the figure shows a semi-schematic representation of two solar cells 1, 1 ', each using a. Glue 2, 2 'are attached to a base element 3.
  • the top of the solar cell 1 is connected to the bottom of the solar cell 1 'by means of a connector 4 made of pseudo-elastic material.
  • the tops of the two solar cells are covered with a cover glass 5, 5 'which is connected to the respective surface of the solar cell via an adhesive 6, 6'.
  • the corresponding contacting areas are metallized, preferably with a pseudo-elastic material.
  • the contacting itself can be carried out in a known manner by welding or soldering.
  • the connector 4 has a U-shaped elevation, which contributes to the absorption of temperature stresses.

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  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Photovoltaic Devices (AREA)

Abstract

A solar generator comprises a plurality of solar cells connected in series and/or parallel. Adjacent solar cells can be connected to each other electrically and mechanically by metallic connectors (4) made from a pseudo elastic material.

Description

EP90/02265 EP90 / 02265
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SolargeneratorSolar generator
Die Erfindung betrifft einen Solargenerator mit einer Vielzahl von in Reihe und/oder parallelgeschalteten Solarzellen, bei dem jeweils benachbarte Solarzellen durch metallische Verbinder elektrisch und mechanisch miteinander verbunden sind.The invention relates to a solar generator with a large number of solar cells connected in series and / or in parallel, in which adjacent solar cells are electrically and mechanically connected to one another by metallic connectors.
Ein derartiger Solargenerator ist beispielsweise in "ESA SP-140", (November 1978), Seiten 33 bis 40, beschrieben. Für die Herstellung photovoltaischer Solargeneratoren wird eine Vielzahl von Solarzellen elektrisch leitend miteinander verbunden. Eine Kette von in Serie geschalteten Solarzellen entsteht dadurch, daß die mehr oder weniger starren Zellen aus Silicium mittels duktiler Verbinder in Folge hintereinander angeordnet sind. Als Verbinder wurden bisher metallische Bänder mit einer Dicke von etwa 30 μm aus Silber oder aus silberbeschichtetem Molybdän verwendet, die mit der Zellenmetallisierung durch Widerstandsschweißen oder durch Löten verbunden werden.Such a solar generator is described for example in "ESA SP-140" (November 1978), pages 33 to 40. A large number of solar cells are connected in an electrically conductive manner for the production of photovoltaic solar generators. A chain of solar cells connected in series results from the fact that the more or less rigid cells made of silicon are arranged one behind the other by means of ductile connectors. So far, metallic tapes with a thickness of approximately 30 μm made of silver or silver-coated molybdenum have been used as connectors, which are connected to the cell metallization by resistance welding or by soldering.
Diese in Reihe elektrisch und mechanisch miteinander verbundenen Solarzellen werden mit Hilfe eines elastischen Siliconklebers auf eine starre oder flexible Unterlage aufgeklebt. Durch Parallelschaltung mehrerer derartigerThese solar cells, which are electrically and mechanically connected to each other in series, are glued to a rigid or flexible base with the help of an elastic silicone adhesive. By connecting several such in parallel
Solarzellenketten entsteht dann ein sogenannter Solarzellenmodul.A so-called solar cell module is then created.
Schwierigkeiten ergeben sich nun dadurch, daß die Ausdehnungskoeffizienten der Solarzellen, des Verbinderwerkstoffs und des Substratmaterials unterschiedlich sind, und zwar derart, daß in der Regel der Ausdehnungskoeffizient des Substrats (etwa 20 x 10"6 IC-1 ) größer als der Ausdehnungskoeffizient des Verbinders ( für Ag 19 x 10"6 K~ l ) ist und dieser wiederum größer als der Ausdehnungskoeffizient der Solarzelle (ca. 2,5 x 10-6 K"x ) . Insbesondere bei der Anwendung derartiger Solargeneratoren zur Stromversorgung von Satelliten müssen die Generatoren eine Vielzahl thermischer Zyklen durchlaufen, und zwar mit Temperaturänderungen bis zu 250 °K. Die dabei auftretenden thermischen Dehnungsdifferenzen soll der Solarzellenverbinder als flexibles, bis in den plastischen Bereich verformbares Material möglichst bis zu einer Lebensdauer von 50 000 oder sogar 100 000 Zyklen akkommodieren.Difficulties now arise from the fact that the expansion coefficients of the solar cells, the connector material and the substrate material differ are such that the expansion coefficient of the substrate (about 20 x 10 " 6 IC -1 ) is usually greater than the expansion coefficient of the connector (for Ag 19 x 10" 6 K ~ l ) and this in turn is greater than that Expansion coefficient of the solar cell (approx. 2.5 x 10 -6 K " x ). Especially when using such solar generators for the power supply of satellites, the generators have to go through a large number of thermal cycles, with temperature changes of up to 250 ° K Thermal expansion differences should be accommodated by the solar cell connector as a flexible material that can be deformed into the plastic area, if possible up to a service life of 50,000 or even 100,000 cycles.
Bei einem Abstand der Solarzellen von ca. 1 mm ist der Solarzellenverbinder von der Zellenrückseite der einen Zelle zur Zellenvorderseite der nächsten geführt und muß somit die gesamte Dehnungsdifferenz (typisch ca. 0,05 mm) einer geradlinigen Verbindungslinie aufnehmen. Zur Schonung des Materials wird dem Zellenverbinder zwischen den beiden Solarzellen eine U-förmige Überhöhung gegeben, die als Ausgleichsbogen eine sogenannte geometrische Dehnung bewirkt und damit eine gewisse Entlastung des Verbinders ermöglicht. Da der Verbinder, wie bereits erwähnt, ständigen Dehn- Wechselbeanspruchungen unterliegt, treten imAt a distance of approx. 1 mm between the solar cells, the solar cell connector is guided from the back of one cell to the front of the next cell and must therefore accommodate the entire difference in elongation (typically approx. 0.05 mm) of a straight connecting line. In order to protect the material, the cell connector between the two solar cells is given a U-shaped elevation, which causes a so-called geometric expansion as a compensation arch, thus allowing the connector to be relieved to a certain extent. Since, as already mentioned, the connector is subject to constant expansion and alternating stresses,
Verbinderwerkstof Gefügeveränderungen auf, die als zyklische Verfestigungen nach einer bestimmten Anzahl von Lastspielen zum Anriß und schließlich zum Bruch des Verbinders führen.Changes in the structure of the connector material which, as cyclical hardening, lead to the cracking and finally to the breakage of the connector after a certain number of load cycles.
Die Kontaktierungsstelle des Verbinders mit der Zellenmetallisierung ist durch die Auswirkung der Dehnungsunterschiede infolge thermischer Zyklen besonders stark beansprucht, was sich in dort auftretenden Scherbrüchen äußert. Alle bisher eingesetzten Werkstoffkombinationen Substrat/Zelle/Verbinder führten spätestens nach Durchlaufen von 15 000 bis 30 000 thermischen Zyklen zu Schädigungen in Form von zunächst Anrissen und später Brüchen der Schweißstellen oder der Verbinder.The contact point of the connector with the cell metallization is particularly stressed by the effect of the expansion differences due to thermal cycles, which is reflected in the shear fractures that occur there. All previously used substrate / cell / connector material combinations caused damage at the latest after going through 15,000 to 30,000 thermal cycles Form of cracks at first and later breaks of the welds or the connectors.
Der Erfindung liegt die Aufgabe zugrunde, einen Verbinder für einen Solargenerator verfügbar zu machen, der eine noch höhere Anzahl thermischer Zyklen durchlaufen kann, ohne daß ein Bruch oder ein Anriß des Materials auftritt und insbesondere auch eine dynamische Verfestigung desselben vermieden wird.The invention has for its object to provide a connector for a solar generator, which can undergo an even higher number of thermal cycles without breaking or cracking of the material and in particular also avoiding dynamic consolidation of the same.
Diese Aufgabe wird bei einem Solargenerator der eingangs definierten Art dadurch erzielt, daß der Verbinder aus einem pseudoelastischen Werkstoff besteht.This object is achieved in a solar generator of the type defined in the introduction in that the connector consists of a pseudo-elastic material.
Bei Verwendung eines derartigen Verbinders in einem photovoltaischen Solargenerator lassen sich im orbitalen Einsatz eines Satelliten thermische Zyklen von 50 000 bis 100 000 realisieren, ohne daß Defekte in der mechanischen oder elektrischen Verbindung der miteinander verbundenen Zellen auftreten.If such a connector is used in a photovoltaic solar generator, thermal cycles of 50,000 to 100,000 can be realized in the orbital use of a satellite without defects in the mechanical or electrical connection of the interconnected cells.
Bei der Gruppe der pseudoelastischen Werkstoffe handelt es sich um Werkstoffe, die reversible Verformungen ertragen können, die weit über die elastische Grenze (Ende der Hooke' sehen Gerade) des Werkstoffs hinausgehen. Hierzu wird beispielsweise auf "Metall 39", 1985, Seiten 34 bis 38, verwiesen. Diese Werkstoffe werden auch als Formgedächtnis- Legierungen bezeichnet. Sie zeigen aufgrund einer thermoelastischen martensitischen Umwandlung nach geeigneter Behandlung eine temperaturabhängige Gestaltsänderung. Wird z. B. eine derartige Legierung bei tiefer Temperatur bleibend verformt, so erinnert sie sich bei Erwärmung über eine kritische Temperatur an ihre ursprüngliche Form und nimmt diese wieder an. Bei einem pseudoelastischen Werkstoff tritt bei Erreichen einer bestimmten Beanspruchungsspannung eine martensitische Gefügeumwandlung statt, die eine weitere Verformung zuläßt, die nicht auf einer versetzungsbedingten elastischen Verformung beruht. Wird nach einer derartigen Verformung die mechanische Spannung weggenommen, so tritt eine Rückdehnung bis zur ursprünglichen Gestalt ein, wobei der ursprüngliche Gefügezustand erhalten bleibt.The group of pseudo-elastic materials are materials that can withstand reversible deformations that go far beyond the elastic limit (end of the Hooke 'see straight line) of the material. For this, reference is made, for example, to "Metall 39", 1985, pages 34 to 38. These materials are also known as shape memory alloys. Due to a thermoelastic martensitic transformation, they show a temperature-dependent change in shape after suitable treatment. Is z. B. such an alloy permanently deformed at low temperature, it remembers when heated to a critical temperature to its original shape and takes it back. In the case of a pseudoelastic material, a martensitic structural transformation takes place when a certain stress is reached, which permits further deformation that is not based on an elastic deformation caused by displacement. If the mechanical tension is removed after such a deformation, one occurs Stretching back to the original shape, while maintaining the original structural state.
Bei Einsatz eines pseudoelastischen Werkstoffes als Verbinder für einen Solargenerator lassen sich Werkstoffdehnungen von bis zu 8 % pseudoelastisch akkom odieren. Die Anzahl der durchf hrbaren thermischen Zyklen läßt sich noch dadurch erhöhen, daß dem Verbinder eine geeignete Geometrie gegeben wird, beispielsweise in Form einer U-förmigen Überhöhung in dem Bereich zwischen den beiden Solarzellen, die von dem Verbinder miteinander verbunden werden.When using a pseudo-elastic material as a connector for a solar generator, material expansions of up to 8% can be accommodated pseudo-elastically. The number of thermal cycles that can be carried out can be increased further by giving the connector a suitable geometry, for example in the form of a U-shaped elevation in the area between the two solar cells which are connected to one another by the connector.
Weiterbildungen der Erfindung sind den Unteransprüchen zu entnehmen.Further developments of the invention can be found in the subclaims.
Das Wesen der Erfindung soll anhand eines in der Zeichnung dargestellten Ausführungsbeispiels näher erläutert werden.The essence of the invention will be explained in more detail with reference to an embodiment shown in the drawing.
Die Figur zeigt in halbschematischer Darstellung zwei Solarzellen 1, 1' , die jeweils mittels eines. Klebers 2, 2' auf einem Basiselement 3 befestigt sind. Die Oberseite der Solarzelle 1 wird mit der Unterseite der Solarzelle 1 ' mittels eines Verbinders 4 aus pseudoelastischem Werkstoff verbunden. Die Oberseiten der beiden Solarzellen sind mit einem Deckglas 5, 5' abgedeckt, das über einen Kleber 6, 6' mit der jeweiligen Oberfläche der Solarzelle in Verbindung steht. Zur Kontaktierung des Verbinders 4 mit den Solarzellen 1, 1' sind die entsprechenden Kontaktierungsbereiche metallisiert, und zwar bevorzugt mit einem pseudoelastischen Werkstoff. Die Kontaktierung selbst kann durch Schweißen oder Löten in bekannter Weise durchgeführt werden. In dem Ausführungsbeispiel weist der Verbinder 4 eine U-förmige Überhöhung auf, die zur Aufnahme von Temperaturspannungen beiträgt. The figure shows a semi-schematic representation of two solar cells 1, 1 ', each using a. Glue 2, 2 'are attached to a base element 3. The top of the solar cell 1 is connected to the bottom of the solar cell 1 'by means of a connector 4 made of pseudo-elastic material. The tops of the two solar cells are covered with a cover glass 5, 5 'which is connected to the respective surface of the solar cell via an adhesive 6, 6'. For contacting the connector 4 with the solar cells 1, 1 ', the corresponding contacting areas are metallized, preferably with a pseudo-elastic material. The contacting itself can be carried out in a known manner by welding or soldering. In the exemplary embodiment, the connector 4 has a U-shaped elevation, which contributes to the absorption of temperature stresses.

Claims

265Patentansprüche 265Patent claims
1. Solargenerator mit einer Vielzahl in Reihe und/oder parallel geschalteten Solarzellen, bei dem jeweils benachbarte Solarzellen durch metallische Verbinder elektrisch und mechanisch miteinander verbunden sind, dadurch gekennzeichnet, daß der Verbinder (4) aus einem pseudoelastischen Werkstoff besteht.1. Solar generator with a plurality of solar cells connected in series and / or in parallel, in which adjacent solar cells are electrically and mechanically connected to one another by metallic connectors, characterized in that the connector (4) consists of a pseudo-elastic material.
2. Solargenerator nach Anspruch 1, dadurch gekennzeichnet, daß der Verbinder (4) aus einer Titan- Nickel-Legierung besteht.2. Solar generator according to claim 1, characterized in that the connector (4) consists of a titanium-nickel alloy.
3. Solargenerator nach Anspruch 2 , dadurch gekennzeichnet, daß der Verbinder (4) aus einer Ti-50, 5% Ni-Legierung besteht.3. Solar generator according to claim 2, characterized in that the connector (4) consists of a Ti-50, 5% Ni alloy.
4. Solargenerator nach Anspruch 1 , dadurch gekennzeichnet, daß der Verbinder (4) aus einer Kupfer-Zink-Aluminium-Legierung besteht,4. Solar generator according to claim 1, characterized in that the connector (4) consists of a copper-zinc-aluminum alloy,
5. Solargenerator nach Anspruch 1 , dadurch gekennzeichnet, daß der Verbinder (4) aus einer Kupfer-Aluminium-Nickel-Legierung besteht.5. Solar generator according to claim 1, characterized in that the connector (4) consists of a copper-aluminum-nickel alloy.
6. Solargenerator nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß der Verbinder (4) die Rückseite einer Solarzelle (1') mit der Vorderzelle einer benachbarten Solarzelle (1) verbindet.6. Solar generator according to one of claims 1 to 5, characterized in that the connector (4) connects the back of a solar cell (1 ') with the front cell of an adjacent solar cell (1).
7. Solargenerator nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß der Verbinder (4) die Rückseiten zweier benachbarter Solarzellen verbindet.7. Solar generator according to one of claims 1 to 5, characterized in that the connector (4) connects the rear sides of two adjacent solar cells.
8. Solargenerator nach Anspruch 6 , dadurch gekennzeichnet, daß der Verbinder (4) in den Bereich zwischen den beiden Solarzellen (1, 1') einen Ausg'leichsbereich in Form eines Ausgleichsbogens aufweist.8. Solar generator according to claim 6, characterized in that the connector (4) in the area between the two solar cells (1, 1 ') has a compensation area in the form of a compensation sheet.
ERSATZBLATT REPLACEMENT LEAF
9. Solargenerator nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, daß die Solarzellen (1, 1') mindestens in dem Bereich, in dem sie mit dem Verbinder (4) kontaktiert sind, mit einem pseudoelastischen Werkstoff metallisiert sind.9. Solar generator according to one of claims 1 to 8, characterized in that the solar cells (1, 1 ') are metallized with a pseudo-elastic material at least in the region in which they are contacted with the connector (4).
ERSATZBLATT REPLACEMENT LEAF
PCT/EP1990/002265 1989-12-20 1990-12-20 Solar generator WO1991009427A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP3942031.0 1989-12-20
DE3942031A DE3942031C1 (en) 1989-12-20 1989-12-20

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
US8916410B2 (en) 2011-05-27 2014-12-23 Csi Cells Co., Ltd Methods of manufacturing light to current converter devices
US9153713B2 (en) 2011-04-02 2015-10-06 Csi Cells Co., Ltd Solar cell modules and methods of manufacturing the same

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DE19617220A1 (en) * 1996-04-30 1997-11-06 Julian Dipl Ing Schueren Solar generator
US6555739B2 (en) * 2001-09-10 2003-04-29 Ekla-Tek, Llc Photovoltaic array and method of manufacturing same
DE10235048A1 (en) * 2002-07-31 2004-02-12 Astrium Gmbh Solar cell connector with frame-shaped compensation section and method of manufacture
DE102010004004A1 (en) 2010-01-04 2011-07-07 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 80686 Contacted solar cell and method for its production

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US3375141A (en) * 1963-07-22 1968-03-26 Aiken Ind Inc Solar cell array
US3378407A (en) * 1964-03-16 1968-04-16 Globe Union Inc Solar cell module
EP0048830A2 (en) * 1980-09-26 1982-04-07 Licentia Patent-Verwaltungs-GmbH Solar cell arrangement
DE3733645A1 (en) * 1987-10-05 1989-04-20 Telefunken Electronic Gmbh SPACE SOLAR CELL

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9153713B2 (en) 2011-04-02 2015-10-06 Csi Cells Co., Ltd Solar cell modules and methods of manufacturing the same
US8916410B2 (en) 2011-05-27 2014-12-23 Csi Cells Co., Ltd Methods of manufacturing light to current converter devices
US9209342B2 (en) 2011-05-27 2015-12-08 Csi Cells Co., Ltd Methods of manufacturing light to current converter devices
US9281435B2 (en) 2011-05-27 2016-03-08 Csi Cells Co., Ltd Light to current converter devices and methods of manufacturing the same

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