WO1991005751A1 - Selective diethylation of naphthalene to 2,6-diethylnaphthalene - Google Patents
Selective diethylation of naphthalene to 2,6-diethylnaphthalene Download PDFInfo
- Publication number
- WO1991005751A1 WO1991005751A1 PCT/US1990/005916 US9005916W WO9105751A1 WO 1991005751 A1 WO1991005751 A1 WO 1991005751A1 US 9005916 W US9005916 W US 9005916W WO 9105751 A1 WO9105751 A1 WO 9105751A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- catalyst
- diethylnaphthalene
- naphthalene
- ethylnaphthalene
- deactivated
- Prior art date
Links
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 title claims abstract description 62
- CJJFFBINNGWEBO-UHFFFAOYSA-N 2,6-diethylnaphthalene Chemical compound C1=C(CC)C=CC2=CC(CC)=CC=C21 CJJFFBINNGWEBO-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000003054 catalyst Substances 0.000 claims abstract description 118
- 239000010457 zeolite Substances 0.000 claims abstract description 39
- 238000006243 chemical reaction Methods 0.000 claims abstract description 31
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 30
- RJTJVVYSTUQWNI-UHFFFAOYSA-N 2-ethylnaphthalene Chemical compound C1=CC=CC2=CC(CC)=CC=C21 RJTJVVYSTUQWNI-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 26
- 238000005804 alkylation reaction Methods 0.000 claims abstract description 13
- 230000029936 alkylation Effects 0.000 claims abstract description 12
- UUCHLIAGHZJJER-UHFFFAOYSA-N 1,2-diethylnaphthalene Chemical compound C1=CC=CC2=C(CC)C(CC)=CC=C21 UUCHLIAGHZJJER-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims description 62
- 230000008569 process Effects 0.000 claims description 52
- 239000011148 porous material Substances 0.000 claims description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 34
- 230000002378 acidificating effect Effects 0.000 claims description 21
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 18
- 239000005977 Ethylene Substances 0.000 claims description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 16
- 239000000377 silicon dioxide Substances 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 239000012021 ethylating agents Substances 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 claims description 6
- WYMDQXZJSAYJIC-UHFFFAOYSA-N 2,7-diethylnaphthalene Chemical compound C1=CC(CC)=CC2=CC(CC)=CC=C21 WYMDQXZJSAYJIC-UHFFFAOYSA-N 0.000 claims description 4
- 239000011260 aqueous acid Substances 0.000 claims description 4
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 claims description 4
- 239000008139 complexing agent Substances 0.000 claims description 4
- 229960003750 ethyl chloride Drugs 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- YGYNBBAUIYTWBF-UHFFFAOYSA-N 2,6-dimethylnaphthalene Chemical compound C1=C(C)C=CC2=CC(C)=CC=C21 YGYNBBAUIYTWBF-UHFFFAOYSA-N 0.000 claims 4
- 239000003153 chemical reaction reagent Substances 0.000 claims 3
- 230000001590 oxidative effect Effects 0.000 claims 3
- 239000002253 acid Substances 0.000 description 16
- 238000001354 calcination Methods 0.000 description 16
- 230000000694 effects Effects 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 10
- 238000006200 ethylation reaction Methods 0.000 description 9
- 239000002808 molecular sieve Substances 0.000 description 8
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 8
- -1 aromatic carboxylic acids Chemical class 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 241000894007 species Species 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 5
- 238000005342 ion exchange Methods 0.000 description 5
- 229910052680 mordenite Inorganic materials 0.000 description 5
- IAUKWGFWINVWKS-UHFFFAOYSA-N 1,2-di(propan-2-yl)naphthalene Chemical compound C1=CC=CC2=C(C(C)C)C(C(C)C)=CC=C21 IAUKWGFWINVWKS-UHFFFAOYSA-N 0.000 description 4
- QIMMUPPBPVKWKM-UHFFFAOYSA-N 2-methylnaphthalene Chemical compound C1=CC=CC2=CC(C)=CC=C21 QIMMUPPBPVKWKM-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000006203 ethylation Effects 0.000 description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- DSNHSQKRULAAEI-UHFFFAOYSA-N 1,4-Diethylbenzene Chemical compound CCC1=CC=C(CC)C=C1 DSNHSQKRULAAEI-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000002168 alkylating agent Substances 0.000 description 2
- 229940100198 alkylating agent Drugs 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 238000006317 isomerization reaction Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229910052665 sodalite Inorganic materials 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- JREJWHNDQOGSQT-UHFFFAOYSA-N 1,2,3,4,5-pentaethylbenzene Chemical compound CCC1=CC(CC)=C(CC)C(CC)=C1CC JREJWHNDQOGSQT-UHFFFAOYSA-N 0.000 description 1
- FEWANSQOXSIFOK-UHFFFAOYSA-N 1,2,3,4-tetraethylbenzene Chemical compound CCC1=CC=C(CC)C(CC)=C1CC FEWANSQOXSIFOK-UHFFFAOYSA-N 0.000 description 1
- WNLWIOJSURYFIB-UHFFFAOYSA-N 1,2,4-triethylbenzene Chemical compound CCC1=CC=C(CC)C(CC)=C1 WNLWIOJSURYFIB-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- KRVWMPNTAYTOGS-UHFFFAOYSA-N 2-methyl-6-propan-2-ylnaphthalene Chemical compound C1=C(C)C=CC2=CC(C(C)C)=CC=C21 KRVWMPNTAYTOGS-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 229920000106 Liquid crystal polymer Polymers 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910008051 Si-OH Inorganic materials 0.000 description 1
- 229910006358 Si—OH Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 239000004974 Thermotropic liquid crystal Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- GUNJVIDCYZYFGV-UHFFFAOYSA-K antimony trifluoride Chemical compound F[Sb](F)F GUNJVIDCYZYFGV-UHFFFAOYSA-K 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 229910052663 cancrinite Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- MNKYQPOFRKPUAE-UHFFFAOYSA-N chloro(triphenyl)silane Chemical group C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(Cl)C1=CC=CC=C1 MNKYQPOFRKPUAE-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 239000011968 lewis acid catalyst Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
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- 239000002798 polar solvent Substances 0.000 description 1
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- 230000006207 propylation Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000000066 reactive distillation Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
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- 230000000630 rising effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 229910052678 stilbite Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- OEIMLTQPLAGXMX-UHFFFAOYSA-I tantalum(v) chloride Chemical compound Cl[Ta](Cl)(Cl)(Cl)Cl OEIMLTQPLAGXMX-UHFFFAOYSA-I 0.000 description 1
- PUGUQINMNYINPK-UHFFFAOYSA-N tert-butyl 4-(2-chloroacetyl)piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCN(C(=O)CCl)CC1 PUGUQINMNYINPK-UHFFFAOYSA-N 0.000 description 1
- 238000010555 transalkylation reaction Methods 0.000 description 1
- GRVPDGGTLNKOBZ-UHFFFAOYSA-M triethyl(methyl)azanium;bromide Chemical compound [Br-].CC[N+](C)(CC)CC GRVPDGGTLNKOBZ-UHFFFAOYSA-M 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7034—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
- C07C2/68—Catalytic processes with halides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
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- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7023—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
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- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
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- B01J29/90—Regeneration or reactivation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
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-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/861—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/865—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an ether
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- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J2229/30—After treatment, characterised by the means used
- B01J2229/37—Acid treatment
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Definitions
- This invention relates to the production of 2,6-diethylnaphthalene by the alkylation of naphthalene compounds.
- acidic zeolite catalysts such as ZSM-12, SAPO-11, and EU-1
- ZSM-12, SAPO-11, and EU-1 acidic zeolite catalysts
- 2,6-dicarboxynaphthalene the latter compound being an important monomer for the production of polyester film.
- the compound 2,6-dicarboxynaphthalene is a key monomer used as a precursor for polyester film. As such, the search for an inexpensive source of 2,6-dicarboxynaphthalene has been the object of intense investigation.
- Alkylaromatic compounds may be converted to their analagous aromatic carboxylic acids by free radical oxidation using various catalytic combinations of cobalt, manganese and bromide salts in an acetic acid solvent.
- This technology has been commercialized for the conversion of p-xylene to terephthalic acid.
- the preferential synthesis of particular isomers of a dialkylnaphthalene has been the subject of investigation by numerous research groups.
- U.S. Patent Application Serial No. 254,284, filed on October 5, 1988 the preparation of 2,6-diisopropylnaphthale ⁇ e was described using a specific group of twelve-ring zeolite catalysts.
- U.S. Patent No. 4,891,448, the Dow Chemical Company teaches the use of acidic mordenite zeolite catalysts to produce para-isomers useful in the preparation of thermotropic liquid crystal polymers.
- German Patent Application No. DE 370,3291 A discloses and claims the use of ZSM-5 as a preferred catalyst for the conversion of methanol and naphthalene or 2-methylnaphthalene into 2,6-dimethylnaphthaIene.
- Japanese Patent Application No. 63-211243 teaches that 2-methylnaphthalene can be alkylated with propylene, using a non-shape selective solid acid catalyst to yield 2-methyl 6-isopropylnaphthalene in high yield.
- U.S. Patent No. 4,873,385 shows the selective production 2,6- diethylnaphthalene via a transalkylation process.
- the reaction includes the liquid phase contact of at least one of naphthalene or 2-ethylnaphthalene with at least one of 1 ,4-diethylbenzene; 1,2,4-triethylbenzene, at least one tetraethylbenzene, or pentaethylbenzene as the ethylating agent at a level of from one to about ten moles of the ethylating agent per mole of the feed in the presence of a Lewis acid catalyst selected from the group consisting of aluminum chloride, aluminum bromide, tantalum chloride, antimony fluoride, or red oil.
- a Lewis acid catalyst selected from the group consisting of aluminum chloride, aluminum bromide, tantalum chloride, antimony fluoride, or red oil.
- the catalyst is introduced at a level of from about 0.01 to about one mole of the catalyst per mole of the feed (for red oil, based on the content of aluminu i chloride content of the red oil) and the reaction is then carried out at a temperature in the range of from about 10°C to about 100°C.
- a Japanese patent namely Japanese Patent No. 51-6953 filed on behalf of Mitsubishi Chemical Co., describes the diethylation of naphthalene using the non-shape selective catalyst AICI 3 .
- the ethylation reaction takes place in contact with the catalyst at 135°C over nine hours.
- the amount of the desired 2,6-diethylnaphthalene produced was between 17% and 20% of the total dialkylate yield.
- the ratio of the 2,6/2,7-diethylnaphthalene isomers was observed to be approximately one. This result is consistent with other efforts conducted in this area.
- This invention is a process in which naphthalene or 2-ethylnaphthalene is reacted with ethylene or ethanol in the presence of an acidic zeolite catalyst, preferably ZSM-12, EU-1, or SAPO-11 (and most preferably ZSM-12) under conditions sufficient to convert the naphthalene or 2-ethylnaphthalene to 2,6-diethylnaphthalene.
- an acidic zeolite catalyst preferably ZSM-12, EU-1, or SAPO-11 (and most preferably ZSM-12) under conditions sufficient to convert the naphthalene or 2-ethylnaphthalene to 2,6-diethylnaphthalene.
- the ethylation of naphthalene would be expected to proceed in a step-wise manner much like the way in which the isopropylation of naphthalene is conducted.
- the ethylation reaction should be slower than the propylation reaction since the initial ethylation reaction step is the acid-catalyzed formation of a carbonium ion.
- equilibrium represents the highest yield for the 2,6- isomer since the 2,6- and 2,7- isomers are the ⁇ , ⁇ isomers and are the preferred form at equilibrium.
- the ratio of the 2,6/2,7 isomers is expected to be about one.
- the ⁇ isomer in the total monoalkylate using AICI 3 at equilibrium is 98.5% the for isopropylation reaction but only 90.5% for the ethylation reaction.
- G.A. Olah et al. J. Amer. Chem. Soc. 98, 1839 (1976).
- the present invention is a process for producing 2,6-diethylnaphthalene using a suitable shape selective catalyst.
- a suitable shape selective catalyst is one having a longest pore aperture dimension between about 5.6A and about 7.0 A, preferably between 5.6A and 6.4A.
- molecular sieves with their longest pore aperture dimension in the desired range are shown in the following table.
- ZSM-12, SAPO-11, and EU-1 are synthetic zeolites and, as such, are more widely available.
- zeolites are naturally occurring zeolites and their purity, stability, and availability vary. It is quite possible that offretite and MAPSO-46 could be selective catalysts but they are also difficult to obtain.
- the preferred zeolites are ZSM-12, EU-1, and SAPO-11. Most preferred is the zeolite catalyst ZSM-12.
- the pore structure of ZSM-12 consists of linear, non-interpenetrating channels which are formed by twelve-member rings and possess pore aperture dimensions of 5.5A X 5.7A x 6.2A. See Jacobs, P.A., et al., "Synthesis of High Silica Aluminosilicate Zeolites", Studies in Surface Science and Catalysis, No.
- pore aperture dimension or width we mean (for non-circular zeolite openings) the longest dimension of the pore.
- ZSM-12 is an irregularly shaped zeolite with pore aperture dimensions of 5.5A x 5.7A X 6.2A.
- SAPO-11 has pore aperture dimensions of 3.9A x 6.3A. SO for ZSM-12, the "pore aperture dimension” is 6.2A; for SAPO-11, 6.3A; for EU-1 the dimension is 5.7A.
- Shape selective reactions occur when the zeolite framework and its pore structure allow substrate molecules of a given size and shape to reach active sites located in the intracrystalline free space and allow product molecules of a given size and shape to diffuse out of the intracrystalline free space. It is, therefore, important to characterize accurately the pore structure that is encountered in the various crystalline molecular sieve frameworks.
- Crystalline sieve structures are often defined in terms of the number of the tetrahedral units [J. atoms).
- the silica and alumina tetrahedra are linked together to form a cubooctahedron, an octahedron truncated perpendicularly to all C 4 -axes.
- the sodalite unit is built from 4- and 6-member oxygen rings.
- SAPO-11 belongs to the family of silicoaluminophosphate molecular sieves, first reported in 1984 in U.S. Patent No. 4,440,871.
- the pore structure of SAPO-11 consists of linear, non-interconnected channels which are limited by 10- membered rings and possess pore aperture dimensions of 3.9A and 6.3A. See Bennett, J.M., et al.. Zeolites, j (1987) 160. See also Meyer, W.M., and Olson, D.H., "Atlas of Zeolite Structure Types", 2nd Ed., Structure Commission of the International Zeolite Association. Butterworths, 1987.
- ZSM-12 and EU-1 are available in cationic form. Calcination may be necessary if the zeolite contains an organic template; only an ion exchange with an ammonium cation followed by calcination under suitable conditions is needed then to convert these to the hydrogen form.
- the catalysts may be optimized to yield greater selectivities of the desired diethylnaphthalene without substantially altering its pore aperture dimensions.
- One such modification to the preferred catalysts is dealumination.
- the dealumination of acidic crystalline molecular sieve materials may be achieved by exposing the solid catalyst to acid mixtures such as HF up to 2.0 N (preferably up to 1.5 N) and HN0 3 (up to 16 N). The desired degree of dealumination will dictate the strength of acid used and the time during which the crystalline structure is exposed to the acid. Other methods of dealumination are via steam treatment followed by a mild acid treatment and calcination.
- the preferred steam treatment parameters are as follows:
- One method of dealumination which has been found to produce such a preferred material is a steam treatment (in one or more stages) followed by a mild acid leach.
- a dealuminated crystalline molecular sieve may be calcined at temperatures between 400°C and 1000°C, preferably between 400°C and '
- calcination conditions of a catalyst can critically effect the catalytic activity.
- the selected calcination gas for example, oxygen or nitrogen
- calcination temperatures for crystalline molecular sieve catalysts can vary from 300°C to 1000°C.
- a zeolite such as ZSM-12 the optimal temperature ranges were found experimentally to lie between 400°C and 1000°C.
- the calcination temperature and the calcination gas are both important.
- an atmosphere preferably nitrogen
- the atmosphere is changed to oxygen at a temperature sufficient to combust the carbonized residue to C0 2 while minimizing water formation.
- the preferred zeolites ZSM-12, SAPO-11, and EU-1 In using the preferred zeolites ZSM-12, SAPO-11, and EU-1, it was surprisingly found that they would form 2,6-diethylnaphthalene in high yield by the combination of ethylene with naphthalene or 2-ethylnaphthalene under equilibrium conditions.
- the synthesis procedure in creating ZSM-12 was described in Jacobs, et al., supra, page 303.
- the Si/AI ratio of these catalysts are in the range of from five to 2000, preferably from ten to 1000, more preferably from 20 to 500, and most preferably from 20 to 100.
- the ZSM-12 particle diameters are preferably less than about 4.0 j_m, preferably 0.1 ⁇ to 3.75 ⁇ .
- the as-synthesized ZSM-12 In order to convert the as-synthesized ZSM-12 into the active acidic form, it is first calcined at temperatures between 400°C to 1000°C for 0.5 to eight hours in flowing air or oxygen. Preferably, the calcining temperature is from 400°C to 700°C. Subsequently, any residual cations are removed by either ion exchange with NH 4 CI (0.01 N to 6 N) at temperatures between 20°C to 100°C for ten to 300 minutes or by treatment with strong acids such as HCI, HN0 3 , H 2 SO A etc. (0.01 N to 6 N) at temperatures between 20 to 100°C for ten to 30 minutes.
- the catalyst may be dried in air at temperatures between 50°C to 200°C for one to 20 hours and then activated by calcining in air or nitrogen at temperatures between 400°C to 1000°C for 0.5 to eight hours.
- the calcining temperature is between 400°C to 700°C.
- a catalyst treatment according to the present invention involves catalyst external surface acid site removal or blockage.
- the reason for external surface acid site removal or blockage is that by deactivating the external surface of zeolite catalyst will increase its shape selective character as otherwise, the external surface acts as a non-shape selective catalyst.
- An additional reason for external surface acid site blockage or removal relates to coking on the catalyst surface.
- External surface acid site deactivation can be obtained by either acid site blockage or acid removal.
- the acidic sites on the external sufrace of the catalyst may be deactivated by contacting the catalyst with a deactivatiing agent selected from the group selected from the halogen, hydridic, and organic derivatives of Groups IMA, IVA, IVB, and VA.
- a deactivatiing agent selected from the group selected from the halogen, hydridic, and organic derivatives of Groups IMA, IVA, IVB, and VA.
- the deactivating agent should be selected to preclude internal surface diffusion. This limitation is easily met by the use of deactivation agents in either liquid or gas phase, whose molecules are too large to fit within even the largest pores of known zeolites.
- triphenylchlorosilane is triphenylchlorosilane. See Martens, J.A. et al., Zeolites, 1984, 4, April, pp. 98-100. Additionally, the surface may be deactivated by precoking with one of the substitutes or another precoking agent.
- the intracrystalline pores may be filled with a hydrocarbon to obtain an internally protected catalyst. Thereafter, either an aqueous acid or complexing agent, which is insoluble in the hydrocarbon contained within the intracystalline pore, is contacted with the protected catalyst. Once the external surface has been deactivated, then the hydrocarbon is removed from said intracrystalline pores.
- a non-polar organic substance is added to the zeolite to fill its pores. Subsequently, a deactivating agent solution (in polar solvent) is introduced to the catalyst. Alkali metal salt solutions, acting as ion exchange atoms to remove the acidic proton associated with aluminum, are described as suitable deactivating agents. See also U.S. Patent No.
- the naphthalene compound may be in liquid form or in a solution.
- the alkylating agent may be in a liquid or gaseous form and, depending upon the reaction device chosen, may be added continuously or in a single batch at the beginning of a reaction cycle in the batch reactor.
- the catalyst may be also in the particulate or granular form and may be placed in a fluidized bed, a stirred bed, a moving bed, or a fixed bed. The catalyst may be in suspension or in a spouted bed. Reactive distillation columns may also be utilized.
- the ratio of alkylating agent to naphthalene compound should be between 0.01 and 100 and preferably between 1.0 and 10.0.
- the reaction is preferably carried out in the liquid state and the temperature should be between 100°C and 400°C, preferably between 225°C and 350°C and the pressure should be between one to 100 atmospheres.
- the amount of catalyst is easily determinable and in general should be enough to promote the reaction to produce a product having, in general, a 2,6-diethylnaphthalene product in excess of that expected on an equilibrium catalyst such as silica/alumina.
- the weight ratio of aromatic compound to catalyst would be in the range of 1:1 to 200:1. Some optimization within that range would obviously be appropriate.
- Separation of the 2,6-DEN product may be by standard techniques such as a distillation, crystallization, adsorption, or the like.
- a silica-alumina catalyst for naphthalene alkylation, it became evident that regardless of how the ethylene was fed to the system, the distribution of products was indicative of a non-shape selective catalyst.
- the percentage of any one isomer of diethylnaphthalene remained essentially unchanged.
- the amounts of diethylnaphthalene were very low and other GLC peaks overlapped with that of the 2,6 isomer. This resulted in artificially high selectivity values for the 2,6 isomer.
- the amount of the 2,6 isomer was approximately 17% or 19% to 22%.
- the ethylating agent may be ethylene, ethanol, ethyl ether, ethyl chloride, or other suitable ethylating materials.
- the agent is ethylene, optionally with added water.
- the reaction used gaseous ethylene.
- the ethylene feed rate was regulated via a mass flow controller or a pressure regulator.
- the former conditions simulate an equilibrium limited reaction.
- the latter conditions simulate a kinetically controlled reaction.
- the analytical results were obtained by gas chromatography.
- 90 g naphthalene and from 0.5 g to 5.0 g of catalyst were charged and gaseous propylene was fed at either a constant flow from a mass flow controller or through a pressure regulator. In all cases unless noted, periodic samples were withdrawn and analyzed by GLC.
- the reactor temperature could be varied between 40 ⁇ C and 355°C although the reaction temperature varied from 225°C and 350° C.
- the ethylene pressure may be from 0.1 to 100 atmospheres, preferably one to ten atmospheres.
- Example 1 Comparative This Example shows the value of the 2,6/2,7 ratio and the percent 2,6 in total DEN isomers at equilibrium. An experiment using the method noted above conducted with silica/alumina showed that these values were 1.0 and between 17% to 22% respectively ( Figure 1) for the ethylation of naphthalene. On the basis of these data, a shape selective effect is evident if either the 2,6/2,7 ratio and the percent 2,6/DEN is greater than 1.0 and 22%, respectively. However, the more reliable parameter is the 2,6/2,7 ratio.
- zeolites were selected.
- a sample of SAPO-11 was r stained from Union Carbide and a sample of EU-1 was prepared according to ⁇ irature procedures.
- a sample of ZSM-11 was also prepared according to literature methods.
- Other comparative catalysts were mordenite and zeolite ⁇ . Mordenite was commercially available and used as received in its acidic form. Zeolite ⁇ was prepared according to literature references.
- Figure 2 shows a comparison of the results of the diethylation reaction using all these catalysts.
- ZSM-12 shows shape selectivity with an initial value for 2,6/2,7 equals 1.7.
- ZSM-11 shows no indication of shape selective catalysis since 2,6/2,7 ⁇ 1.0. Mordenite showed much higher activity indicating that the internal active sites are accessible but still no shape selectivity (i.e. 2,6/2,7 approximately equals one). SAPO-11 did show evidence of shape selectivity. The 2,6/2,7 ratio (approximately equals 1.1) was nearly constant over the run. This was also evident even at very low conversion where the selectivity to 2,6-DEN is highest supporting the concept that SAPO-11 is not the optimum catalyst but is adequate for producing 2,6-DEN. The results with EU-1 were interesting in that the 2,6/2,7 ratio was observed to be quite low initially but rising to a maximum 2,6/2,7 equals 1.3.
- This Example shows the effect of the performance on ZSM-12 catalyst when it is synthezised in nearly the same particle size but different silica/alumina ratios.
- the catalysts were tested in the stirred autoclave at 325°C, 30 psi ethylene, and a naphthalene/catalyst ratio of 30:1. Samples were withdrawn and analyzed. The results of these analyses are shown below:
- Example 2 shows the effect of dealumination on the performance of the preferred ZSM-12 catalyst.
- the catalyst was treated with 0.5 N HF in 16 N at about 100°C HN0 3 for two hours. After drying and calcining, the catalyst was tested in the same manner as in Example 2.
- the ZSM-12 catalyst having the higher silica/alumina ratio clearly performs better.
- the effect of higher levels of dealumination with larger particles on the performance of the ZSM-12 catalyst is shown below.
- the catalyst was treated with 1.0 N HF in 16 N HN0 3 at about 100°C for two hours. After drying and calcining the catalyst was tested as outlined above.
- This Example shows the synthesis of ZSM-12 in various particle sizes.
- the particle size was varied by changing the silica/alumina ratio in the starting gel.
- the source of the various reactants were: silica equals colloidal Si0 2 , alumina equals AI(N0 3 ) 3 hydrate.
- 160 g water and 3.36 NaOH were combined and stirred.
- 29.6 g triethylmethylammonium bromide was dissolved and 3.36 g of AI(N0 3 ) 3 was added and dissolved by stirring.
- To this solution 42 g of 30% colloidal Si0 2 was added. This gel was placed in a Teflon lined autoclave and heated to 165°C for several days.
- the crystallized ZSM-12 was isolated by filtration and washed with water.
- the bulk ICP analysis showed that the crystallized ZSM-12 has a silica/alumina ratio which is quite similar to the stoichiometry used in the synthesis. In all cases, the zeolite was 100% cr'stalline and free from major contaminants.
- the table below also shows that changes in both the water content and the silica/alumina ratio can dramatically affect the particle size.
- the ZSM-12 obtained from the reaction mixture is in the template-sodium form.
- the ZSM-12 obtained from the reaction mixture was calcined in air at 650°C for eight hours.
- Subsequent ion exchange with 5 N NH 4 CI for two hours at 100°C yielded the ammonium form which after drying at 110°C for two hours followed by calcination at 650°C for twelve hours (both in air) yields the acid form.
- Example 6 This Example shows the diethylation of naphthalene with ethylene using
- ZSM-12 catalysts synthesized in Example 5 and run according to the process discussed below.
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Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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KR1019920700896A KR920703482A (en) | 1989-10-17 | 1990-10-16 | Selective diethylation of naphthalene with 2,6-diethylnaphthalene |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US42278489A | 1989-10-17 | 1989-10-17 | |
US422,784 | 1989-10-17 |
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WO1991005751A1 true WO1991005751A1 (en) | 1991-05-02 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/US1990/005916 WO1991005751A1 (en) | 1989-10-17 | 1990-10-16 | Selective diethylation of naphthalene to 2,6-diethylnaphthalene |
Country Status (5)
Country | Link |
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EP (1) | EP0496831A4 (en) |
JP (1) | JPH05504332A (en) |
KR (1) | KR920703482A (en) |
CA (1) | CA2066205A1 (en) |
WO (1) | WO1991005751A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1400502A2 (en) * | 1998-04-17 | 2004-03-24 | Polimeri Europa S.p.A. | Process for the preparation of 2,6-dimethylnaphthalene |
CN113388430A (en) * | 2021-06-25 | 2021-09-14 | 四川泸天化股份有限公司 | Method for preparing alkyl naphthalene from mixed olefins and application |
Citations (10)
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US3251897A (en) * | 1962-12-20 | 1966-05-17 | Socony Mobil Oil Co Inc | Alkylation of aromatic compounds in the presence of an alumino-silicate catalyst |
US3832449A (en) * | 1971-03-18 | 1974-08-27 | Mobil Oil Corp | Crystalline zeolite zsm{14 12 |
US4026959A (en) * | 1976-05-07 | 1977-05-31 | American Cyanamid Company | Low temperature isomerization process for isopropylnaphthalene (100 percent sieve catalyst) |
US4179472A (en) * | 1978-12-14 | 1979-12-18 | Phillips Petroleum Company | Catalytic alkylation of alkyl-substituted aromatics with monoolefins |
US4469908A (en) * | 1978-12-14 | 1984-09-04 | Mobil Oil Corporation | Alkylation of aromatic hydrocarbons |
JPS6136232A (en) * | 1984-07-28 | 1986-02-20 | Jgc Corp | Production of alkyl aromatic compound |
EP0202752A1 (en) * | 1985-04-22 | 1986-11-26 | Imperial Chemical Industries Plc | Alkylation process |
JPS6314738A (en) * | 1986-07-08 | 1988-01-21 | Shindaikiyouwa Sekiyu Kagaku Kk | Production of mono and/or dialkylnaphthalene |
GB2199590A (en) * | 1986-11-28 | 1988-07-13 | Mitsubishi Chem Ind | Separating 2, 6-dimethylnaphthalene from isomeric mixtures |
US4795847A (en) * | 1987-02-04 | 1989-01-03 | Rutgerswerke Aktiengesellschaft | Preparation of 2,6-dialkyl-naphthalenes |
-
1990
- 1990-10-16 KR KR1019920700896A patent/KR920703482A/en not_active Application Discontinuation
- 1990-10-16 WO PCT/US1990/005916 patent/WO1991005751A1/en not_active Application Discontinuation
- 1990-10-16 JP JP3500397A patent/JPH05504332A/en active Pending
- 1990-10-16 EP EP19900917169 patent/EP0496831A4/en not_active Withdrawn
- 1990-10-16 CA CA002066205A patent/CA2066205A1/en not_active Abandoned
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3251897A (en) * | 1962-12-20 | 1966-05-17 | Socony Mobil Oil Co Inc | Alkylation of aromatic compounds in the presence of an alumino-silicate catalyst |
US3832449A (en) * | 1971-03-18 | 1974-08-27 | Mobil Oil Corp | Crystalline zeolite zsm{14 12 |
US4026959A (en) * | 1976-05-07 | 1977-05-31 | American Cyanamid Company | Low temperature isomerization process for isopropylnaphthalene (100 percent sieve catalyst) |
US4179472A (en) * | 1978-12-14 | 1979-12-18 | Phillips Petroleum Company | Catalytic alkylation of alkyl-substituted aromatics with monoolefins |
US4469908A (en) * | 1978-12-14 | 1984-09-04 | Mobil Oil Corporation | Alkylation of aromatic hydrocarbons |
JPS6136232A (en) * | 1984-07-28 | 1986-02-20 | Jgc Corp | Production of alkyl aromatic compound |
EP0202752A1 (en) * | 1985-04-22 | 1986-11-26 | Imperial Chemical Industries Plc | Alkylation process |
JPS6314738A (en) * | 1986-07-08 | 1988-01-21 | Shindaikiyouwa Sekiyu Kagaku Kk | Production of mono and/or dialkylnaphthalene |
GB2199590A (en) * | 1986-11-28 | 1988-07-13 | Mitsubishi Chem Ind | Separating 2, 6-dimethylnaphthalene from isomeric mixtures |
US4795847A (en) * | 1987-02-04 | 1989-01-03 | Rutgerswerke Aktiengesellschaft | Preparation of 2,6-dialkyl-naphthalenes |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1400502A2 (en) * | 1998-04-17 | 2004-03-24 | Polimeri Europa S.p.A. | Process for the preparation of 2,6-dimethylnaphthalene |
EP1400502A3 (en) * | 1998-04-17 | 2004-12-29 | Polimeri Europa S.p.A. | Process for the preparation of 2,6-dimethylnaphthalene |
CN113388430A (en) * | 2021-06-25 | 2021-09-14 | 四川泸天化股份有限公司 | Method for preparing alkyl naphthalene from mixed olefins and application |
Also Published As
Publication number | Publication date |
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EP0496831A4 (en) | 1992-10-07 |
KR920703482A (en) | 1992-12-18 |
EP0496831A1 (en) | 1992-08-05 |
JPH05504332A (en) | 1993-07-08 |
CA2066205A1 (en) | 1991-04-18 |
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