WO1991003847A1 - Graphite composite structures exhibiting electrical conductivity - Google Patents
Graphite composite structures exhibiting electrical conductivity Download PDFInfo
- Publication number
- WO1991003847A1 WO1991003847A1 PCT/US1990/004862 US9004862W WO9103847A1 WO 1991003847 A1 WO1991003847 A1 WO 1991003847A1 US 9004862 W US9004862 W US 9004862W WO 9103847 A1 WO9103847 A1 WO 9103847A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fibers
- graphite
- epoxy
- conductor
- plated
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01P—WAVEGUIDES; RESONATORS, LINES, OR OTHER DEVICES OF THE WAVEGUIDE TYPE
- H01P11/00—Apparatus or processes specially adapted for manufacturing waveguides or resonators, lines, or other devices of the waveguide type
- H01P11/001—Manufacturing waveguides or transmission lines of the waveguide type
- H01P11/005—Manufacturing coaxial lines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01Q—ANTENNAS, i.e. RADIO AERIALS
- H01Q9/00—Electrically-short antennas having dimensions not more than twice the operating wavelength and consisting of conductive active radiating elements
- H01Q9/04—Resonant antennas
- H01Q9/16—Resonant antennas with feed intermediate between the extremities of the antenna, e.g. centre-fed dipole
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01Q—ANTENNAS, i.e. RADIO AERIALS
- H01Q9/00—Electrically-short antennas having dimensions not more than twice the operating wavelength and consisting of conductive active radiating elements
- H01Q9/04—Resonant antennas
- H01Q9/16—Resonant antennas with feed intermediate between the extremities of the antenna, e.g. centre-fed dipole
- H01Q9/20—Two collinear substantially straight active elements; Substantially straight single active elements
- H01Q9/22—Rigid rod or equivalent tubular element or elements
Definitions
- the subject invention relates to electrically conductive composite materials and, more particularly, to graphite epoxy composite materials formed into conductive structures.
- aircraft wings may, in addition to providing the necessary airfoil for lift purposes, house radio or radar antennas, and wing heaters for deicing purposes. While typically these three functions are provided by different materials which are interconnected in some manner, the mere use of three different materials results in a certain weight accumu ⁇ lation. It would be an advance in the art if all three functions could be provided by a single material, and if such material were more lightweight than prior tech ⁇ niques. Once again, a high stiffness-to-weight ratio would be required to meet the stresses placed on an aircraft wing.
- a structure is formed of a composite material comprising elongated fibers including graphite and a binder such as epoxy.
- a binder such as epoxy.
- the structure is rendered a good conductor.
- the binder material is removed from about the fibers in a selected area, leaving the fibers exposed. Conductive material is then applied so as to make electrical contact with the exposed fibers.
- the wrap angle of the fibers may be selected to achieve a desired electrical conductivity.
- nickel plated graphite fibers may advantageously be employed with silver being used to make electrical contact to the exposed nickel plated graphite fibers in the selected areas in which the binder material is removed.
- the use of graphite fibers bound with an epoxy material results in a structure exhibiting a high stiffness-to-weight ratio and much less weight than aluminum or steel.
- the resulting conductive structure may be used to configure an antenna, coaxial transmission line, or other conducting devices, as hereafter described in more detail.
- FIGS, la and lb show perspective views of a graphite composite material in accordance with the invention formed into coaxial conductors according to the preferred embodiment;
- FIG. 2 is a graph illustrating the variation of conductivity over a certain frequency band with the wrap angle of graphite fibers in a graphite/epoxy composite in accordance with the invention
- FIG. 3 is a graph illustrating the variation in conductivity of coaxial cables fabricated according to the preferred embodiment with various graphite/epoxy materials
- FIG. 4 is a schematic view of a simple dipole employing conductors formed in accordance with a preferred embodiment.
- FIG. 5 is a schematic diagram of one-half of a dipole antenna employing four cross-dipoles fabricated from tubular conductors in accordance with the preferred embodiment.
- FIG. la illustrates a coaxial conductor 11 fabricated of graphite/epoxy material.
- long, parallel, graphite fibers are bound in an epoxy matrix.
- the unidirectionally oriented fibers in the matrix are continuous and contact each other to form a conductive matrix.
- Carbon (graphite) fibers are made by pyrolysis of organic precursor fibers in an inert atmosphere. Pyrolysis temperatures generally range from 1000°C to 3000°C. Currently three precursor materials, rayon, polyacrylonitrile, and pitch (from coal tar products) , are the most widely used raw materials in the manufacture of carbon (graphite) fibers. Physical properties such as Young's Modulus, ultimate strength, elongation to failure, and electrical conductivity are determined by processing techniques, i.e., fiber tension and pyrolitic temperatures.
- Bundles consisting of 1,000 to 150,000 continuous fibers may be formed of straight (tow) or twisted (roving) fibers to suit subsequent manufacturing processes, i.e., unidirectional tape for hand layup or filament winding, respectively. While graphite has been found to be a relatively strong material, it will buckle under compressive loads. The addition of an epoxy binder contributes strength to the composite so that compressive loads may be handled without compressive instability. It has been found that a composite having 60-65% graphite by weight works well in the application to be described below in detail.
- Graphite fibers may also be nickel plated and are commercially available in that form, as described below.
- a loose roving or tow is nickel plated with, e.g., one-half Angstrom of nickel and then spun tight.
- the tightened roving or tow (whether nickel plated or not) may be impregnated with epoxy resin and placed on a spool or a support backing to form a tape.
- the tape or spool is frozen to prevent premature curing of the epoxy.
- the tape or spool may be thawed out, wrapped on a mandrel as hereafter described in more detail, and then cured at 250 to 350"F in an oven to establish a desired shape.
- graphite fibers are used because of their relatively low weight, their electrical conductivity properties, and their relatively high strength. Due to the problem with compressive loads, they are bound together in a nonelectrically conductive material such as a resin. Epoxy was discussed above, but if in a particular application, melting temperature were not a concern, a thermoplastic binder may be selected rather than epoxy.
- a material which may be used for the graphite/ epoxy composite according to the preferred embodiment is nickel plated Hercules AS4 graphite/epoxy material available from American Cyanamid and having a part number of 985NCGT3290.
- This material employs continuous graphite fibers of 8-micron diameter which have been nickel plated as described above and which are bound together with an epoxy.
- the material is in the form of tape with the graphite fibers oriented longitudinally on the tape.
- the graphite/epoxy composite may be formed into the outer conductor 12 by wrapping the composite in its thawed, flexible, room temperature state around a mandrel and applying suitable pressure to squeeze out air and any excess epoxy. It has been found that the lowest loss is achieved when the wrap-angle ⁇ at which the graphite fibers are wound is such that the graphite fibers 14 are aligned in the direction of radio frequency current propagation.
- the center conductor 15 is from a .325-inch (.825 cm) coaxial line, and is held in place at the longitudinal centerline of the outer conductor 12 by means of five dielectric splines.
- FIG. la presents a wrap-angle ⁇ of approximately 15 degrees
- FIG. lb presents a wrap-angle ⁇ of 0 degrees
- wrap angle in these figures has been measured from the longitudinal dimension of the outer conductor 12.
- FIG. 2 graphs insertion loss in dB versus frequency in MHz for various wrap angles of a 28-inch (71.12 cm) length of five spline, .325-inch (.827 cm), nickel plated AS4 graphite/ epoxy conductor coaxial cable with TNC connectors and copper inner conductor.
- lines 101, 103, 105, 107 represent wrap angles of 0 degrees, 15 degrees, 30 degrees and 45 degrees, respectively.
- These wrap angles are referenced to the insertion loss of a .325-inch (.827 cm) diameter, five spline, standard copper coaxial cable represented by line 109.
- FIG. 3 illustrates the conductivity of various graphite epoxy materials wrapped at an angle ⁇ of 15-degrees.
- the materials are nickel plated HMU, manufactured by Hercules Aerospace Company, Magna, Utah, line 111 (estimated) ; IM6, as manufactured by Hercules, line 113; T300 as manufactured by Amoco Performance Products, Inc., Concord, California, line 115; and, finally, the AS4 material, line 117.
- the conductivity of these materials is again referenced against that of a five spline copper coax, line 119.
- FIG. 3 indicates that, the higher the values of Young's Modulus, the greater the RF conductivity. Numerous manufacturers supply graphite fibers. Their desirability as an RF conductor is therefore expected to be directly proportional to their Young's Modulus.
- FIG. 3 shows that HMU has a much lower loss than AS4, HMU has a much higher Young's Modulus, thus making it more brittle and more difficult to form into a desired shape.
- graphite fibers are available which are plated with nickel (approximately .5 microns thick). While nickel is not considered to be the optimum electrical conductor, it permits strong attachment of additional plating, which facilitates electrical connection to structures fabricated according to the preferred embodiment, as will be discussed below. Nickel was found to be an acceptable conductor at dc to low frequencies because the "skin depth" of these frequencies is great enough to prevent adverse results due to nickel's relatively poor conductive characteristics.
- tubular conductor 11 is highly conductive when the surface graphite fibers conduct the RF energy.
- the surface epoxy is bead blasted away from them in a selected area 13 to expose undisturbed, nickel plated graphite fibers 14. It is sufficient to expose the first layer of fibers 14.
- Electrode contact to the exposed nickel plated fibers 14 is then established by plating the area 13 with a conductor such as silver or copper.
- a conductor is then connected to the silver, copper or other plating to electrically join the tube 11 to another conductor, such as another tube 11 or a feed cable.
- a method for removing the epoxy to permit plating of the nickel-plated graphite fibers is required.
- Grit blasting using 50 ⁇ m (micrometer) aluminum oxide grit in a microblaster has proved to be a workable approach to remove the epoxy from about the first layer of nickel plated graphite fibers.
- Grit blasting is easily controlled, was found to not damage the nickel plating or graphite fibers 14, and removes epoxy from between the nickel-plated fibers 14, exposing a large surface area to be subsequently plated.
- FIG. 4 illustrates a simple dipole antenna structure configured from first and second tubes 11 and a coaxial feed 15. Leads 17, 18 are soldered to silver plated areas 19, 20 of the tubes 11.
- a coaxial cable may also be made out of the graphite epoxy material with losses similar to those shown in FIGS. 2 and 3.
- the tubular conductors 11 of the preferred embodiment have also been used to design an ultra- lightweight dipole assembly in the 15- to 75-MHz range.
- One-half of such a dipole is shown in FIG. 5, the other half being the mirror image of the half shown.
- the structure of FIG. 5 was designed and constructed as an electrically flat panel to obtain a bandwidth of at least one octave (30 to 75 MHz) .
- the entire antenna (half dipole shown and its mirror image) is consequently about 18 x 90 inches (45.72 x 228 cm).
- the graphite/epoxy tubes 25, 27, 29, 31, 37, 39, 40 of FIG. 5 are held in place by a truss structure 50.
- This structure 50 includes truss tubes 41, 43, 47, 49 extending from a central truss fitting 53.
- the central truss fitting 53 is mounted on a central truss tube 51 through which each of the dipole elements 27, 29, 37, 39 pass.
- the outer truss tubes 41, 43 fit together with a tip tube 45, while the inner truss tubes 47 are joined with the graphite/epoxy tubes 29, 27, 37, 39 at outer fittings 57.
- Each upper outer graphite/epoxy tube 25, 31 is shown joined to a respective lower tube 37, 39 by respective elbows 35.
- the elbows 35 are graphite epoxy tubes of a slightly wider diameter than the tubes 31, 37; 25, 39 to facilitate joinder.
- the joints between the elbows 35 and tubes 31, 37, 25, 39 employ copper conductors to electrically join the graphite/epoxy tubes according to the attachment method described in connection with FIG. 1.
- the tubes 27, 29, 37, 39 are electrically joined to the lower cross tube 40 in the same manner.
- the mirror image half dipole (not shown) may be made pivotable about the tube 40 if desired.
- Ion vapor deposited aluminum on all radiating surfaces over unplated fiber graphite tubes was considered for achieving RF conductivity for the structure of FIG. 5.
- the weight added necessitated the use of considerably larger tubes which resulted in approximate doubling of the allowable weight.
- An additional application of the preferred embodiment is in the fabrication of the leading edge of an aircraft wing.
- a graphite epoxy dipole is disposed along the leading edge of the wing within another material such as FiberglassTM or KevlarTM.
- the graphite epoxy has sufficient resistance to serve as a deicing element for the wing, and the strength to withstand the lift forces to which the leading edge of the wing is subjected.
- the invention may also be used for lightning protection of composite aircraft.
- graphite fibers in an epoxy matrix perform well as an RF radiator.
- RF components such as spacecraft antennas, horns, phased arrays, and transmission lines are potential applications in addition to those discussed herein.
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US40018789A | 1989-08-29 | 1989-08-29 | |
US400,187 | 1989-08-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1991003847A1 true WO1991003847A1 (en) | 1991-03-21 |
Family
ID=23582566
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1990/004862 WO1991003847A1 (en) | 1989-08-29 | 1990-08-27 | Graphite composite structures exhibiting electrical conductivity |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0441954A1 (en) |
JP (1) | JPH04501649A (en) |
CA (1) | CA2036373A1 (en) |
WO (1) | WO1991003847A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993026013A1 (en) * | 1992-06-15 | 1993-12-23 | Robert Lenes Matthews | Telescopic antenna |
DE202010013085U1 (en) * | 2010-12-08 | 2012-03-12 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Self-expanding helix antenna |
GB2529689B (en) * | 2014-08-29 | 2018-11-14 | Secr Defence | Radio with a deployable antenna |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2312864A1 (en) * | 1975-05-29 | 1976-12-24 | Etud Rech Chimique Lab | Composite construction antennae using carbon fibres - has high mechanical strength and gain particularly for transmitters and vehicles |
EP0040674A1 (en) * | 1980-05-27 | 1981-12-02 | Kathrein-Werke Kg | Whip antenna |
EP0118239A2 (en) * | 1983-02-24 | 1984-09-12 | Westland Group plc | Carbon fibre structures |
FR2591807A1 (en) * | 1985-12-18 | 1987-06-19 | Eurofarad | Dielectric antenna |
-
1990
- 1990-08-27 JP JP51340290A patent/JPH04501649A/en active Pending
- 1990-08-27 CA CA 2036373 patent/CA2036373A1/en not_active Abandoned
- 1990-08-27 EP EP19900914286 patent/EP0441954A1/en not_active Withdrawn
- 1990-08-27 WO PCT/US1990/004862 patent/WO1991003847A1/en not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2312864A1 (en) * | 1975-05-29 | 1976-12-24 | Etud Rech Chimique Lab | Composite construction antennae using carbon fibres - has high mechanical strength and gain particularly for transmitters and vehicles |
EP0040674A1 (en) * | 1980-05-27 | 1981-12-02 | Kathrein-Werke Kg | Whip antenna |
EP0118239A2 (en) * | 1983-02-24 | 1984-09-12 | Westland Group plc | Carbon fibre structures |
FR2591807A1 (en) * | 1985-12-18 | 1987-06-19 | Eurofarad | Dielectric antenna |
Non-Patent Citations (1)
Title |
---|
FREQUENZ. vol. 35, no. 6, June 1981, BERLIN DE pages 155 - 162; "Hochfrequenzbauteile aus kohlefaserverstärktem Kunststoff für Satelliten-Nutzlasten" see pages 157 - 158, left-hand column * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993026013A1 (en) * | 1992-06-15 | 1993-12-23 | Robert Lenes Matthews | Telescopic antenna |
DE202010013085U1 (en) * | 2010-12-08 | 2012-03-12 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Self-expanding helix antenna |
US8730124B2 (en) | 2010-12-08 | 2014-05-20 | Deutsches Zentrum Fuer Luft-Und Raumfahrt E.V. | Self-deploying helical antenna |
GB2529689B (en) * | 2014-08-29 | 2018-11-14 | Secr Defence | Radio with a deployable antenna |
Also Published As
Publication number | Publication date |
---|---|
CA2036373A1 (en) | 1991-03-01 |
EP0441954A1 (en) | 1991-08-21 |
JPH04501649A (en) | 1992-03-19 |
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