WO1990015097A1 - Composition de dispersion et son procede de fabrication et d'utilisation - Google Patents

Composition de dispersion et son procede de fabrication et d'utilisation Download PDF

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Publication number
WO1990015097A1
WO1990015097A1 PCT/US1990/003254 US9003254W WO9015097A1 WO 1990015097 A1 WO1990015097 A1 WO 1990015097A1 US 9003254 W US9003254 W US 9003254W WO 9015097 A1 WO9015097 A1 WO 9015097A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
water
compositions
component
dispersible
Prior art date
Application number
PCT/US1990/003254
Other languages
English (en)
Inventor
Allen Andrew Sales
Original Assignee
Amoco Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Amoco Corporation filed Critical Amoco Corporation
Publication of WO1990015097A1 publication Critical patent/WO1990015097A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C08L23/286—Chlorinated polyethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes

Definitions

  • This invention relates to dispersion compositions comprising a water- dispersible binder component comprising a film-forming, water-dispersible, carboxyl group-containing, elastomeric polymer composition; a thickener component; a chlorinated polyolefin component; a polyorganosiloxane component; and water.
  • the invention also relates to a method for preparing such compositions and to coating and printing of substrates therewith.
  • Background Of The Invention and the Prior Art U.S. 4,598,120, issued July 1 , 1986, to Thoma et al. discloses aqueous dispersion compositions useful as spreadabie coating or printing pastes.
  • compositions also is disclosed as is application thereof to a textile substrate and heating to dry and react the compositions.
  • textile substrates are woven polyamide, polyester/cotton blend and polyester/rayon fabrics.
  • U.S. 3,529,990, issued September 22, 1970, to Becker et al. discloses a finishing treatment for improving tear strength, crease-resistance, abrasion resistance and shape retention of various fabrics.
  • the fabrics are treated with an aqueous bath containing polymers or copolymers of vinyl or divinyl monomers, including acrylic or methacrylic acid; a reaction product containing free isocyanate groups prepared from a polyisocyanate and an organic compound having at least two active hydrogen atoms selected from compounds having molecular weights of 500-10,000, organopolysiloxanes and combinations thereof; and water-soluble, carboxylic acid salts of Group I, II or VIII metals.
  • the treated fabrics are subsequently treated with water or steam.
  • Aqueous coating and printing compositions are poorly suited for use with hydrophobic and inert substrates, such as polyolefins, due to poor adherence thereto, poor abrasion, weather and stain resistance and poor launderability.
  • the patent discloses inks with about 3-25 wt.% of a so-called "randiopropylene,” defined as a diethyl ether-soluble polypropylene prepared by steric rearrangement of so-called “isotactic" polypropylene using a free radical initiator and a bromine compound; about 20-80 wt.% organic solvent, such as xylene, toluene, diethyl ether, methyl ethyl ketone, methyl isobutyl ketone, diisopropyl ether, ortho- dichlorobenzene, Solvesso 150, mixed aromatic solvent, hexane, heptane, decane and blends thereof; about 15-60 wt.% pigment; and, if needed, tackifiers, detackifiers, thickeners and other additives.
  • randiopropylene defined as a diethyl ether-soluble polypropylene prepared by steric rear
  • a further object of this invention is to provide improved dispersion compositions.
  • a further object of the invention is to provide dispersion compositions suitable for use in printing and coating polyolefin substrates, including polypropylene fabrics.
  • a further object of the invention is to provide improved printed or coated polyolefin substrates in which adhesion to the substrate, abrasion resistance, crock resistance and ability to withstand laundering are improved. Other objects of the invention will be apparent.
  • dispersion compositions comprising a water-dispersible binder component comprising a film-forming, water-dispersible, carboxyl group- containing, elastomeric polymer composition; a thickener component; a chlorinated polyolefin component; a polyorganosiloxane component; and water.
  • these objects are attained by providing such compositions additionally comprising a crosslinking agent.
  • the latter compositions when applied to substrates and cured, show excellent adhesion to the substrates.
  • Such compositions also are suitable vehicles for colorants and, with addition thereto of colorant compositions, can be used for printing.
  • Also provided according to this invention is a method for preparing such dispersion compositions comprising combining components comprising a water-dispersible binder component comprising a film-forming, water- dispersible, carboxyl group-containing, elastomeric polymer composition, a thickener component and water to form a thickened aqueous dispersion and adding to such dispersion components comprising a chlorinated polyolefin component, a polyorganosiloxane component, a crosslinking agent and, optionally, a colorant composition, under shear sufficient to form a substantially uniform aqueous dispersion composition.
  • compositions For use in printing and coating, such compositions, with and without a colorant composition dispersed therein, respectively, are applied to a substrate and cured.
  • Colorant compositions that can be included in the invented compositions are materials dispersible therein and include a wide range of materials known to the art. Examples include titanium dioxide, a well known white pigment, as well as various organic colorant compositions such as organic colorant dispersions and micronized powders capable of being dispersed in the invented compositions. Specific examples of organic colorant compositions include resin-dispersed pigments such as Flexiverse pigments from Sun Chemical Co. comprising colorants dispersed in acrylic resin compositions and those known as Hi-Fast N pigments from BASF.
  • aqueous-based acrylic polymer latex 52% solids.
  • polyacrylic acid salt dispersed in aliphatic petroleum distillate, 26-28% solvent content.
  • compositions can be applied to substrates by any suitable technique such as by spreading and other coating and printing techniques.
  • Flat bed screen printing and rotaty printing equipment can be used as can cylinder presses and gravure and fiexographic printing equipment.
  • viscosity of the compositions preferably is about 14,000 to about 20,000 CP as higher viscosities can be difficult to apply uniformly while lower viscosities may result in pour coating integrity after curing.
  • Application rates depend on substrate characteristics, number of colors, design and other factors and preferably range from about 0.1 to about 2 ounces per square yard in the case of fabric substrates.
  • the thickened dispersion was subjected to shear by mixing at 2000-3000 rpm and to the vortex of the sheared dispersion were added 0.075 parts by weight polyorganosiloxane component identified as Silicone Fluid Y-9229 from Union Carbide Corporation, 0.375 parts by weight of a 40 wt.% solution of chlorinated polyolefin in Aromatic 100 solvent, identified as CP-515-2, 0.25 parts by weight of an acrylic resin-dispersed colorant identified as Flexiverse from Sun Chemical Co. and 0.75 parts by weight carbodiimide crosslinking agent as a 50% solids content solution in propylene glycol monomethyl ether acetate identified as Ucarlink XL-25 SE from Union Carbide Corporation. Shearing was continued for about 15-30 minutes after component addition was completed.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

Des compositions de dispersion aqueuses comprennent un composant de liaison comportant une composition polymère élastomère contenant un groupe carboxyle filmogène, dispersible dans l'eau, un composant épaissant, un composant de polyoléfines chlorées, ainsi qu'un composant de polyorganosiloxane dispersés dans un liquide aqueux. Lesdites compositions comprennent en outre un agent de réticulation et, facultativement, une composition colorante. Elle servent de substrats de revêtement et d'impression.
PCT/US1990/003254 1989-06-09 1990-06-08 Composition de dispersion et son procede de fabrication et d'utilisation WO1990015097A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US36460289A 1989-06-09 1989-06-09
US364,602 1989-06-09

Publications (1)

Publication Number Publication Date
WO1990015097A1 true WO1990015097A1 (fr) 1990-12-13

Family

ID=23435255

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1990/003254 WO1990015097A1 (fr) 1989-06-09 1990-06-08 Composition de dispersion et son procede de fabrication et d'utilisation

Country Status (2)

Country Link
AU (1) AU5934990A (fr)
WO (1) WO1990015097A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2760407A1 (fr) * 1997-03-10 1998-09-11 Sylvie Lebufnoir Feuille pouvant etre coloriee de facon reversible et son application
EP2486572A4 (fr) * 2009-10-07 2017-04-26 Federal-Mogul Powertrain, Inc. Manchon textile souple doté d'un revêtement protecteur résistant à l'effilochage d'extrémité et son procédé de fabrication
WO2019126501A1 (fr) * 2017-12-21 2019-06-27 Vf Jeanswear Lp Revêtement étirable liquide pour vêtements et ses procédés d'application

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4598120A (en) * 1984-04-28 1986-07-01 Bayer Aktiengellschaft Dispersion compositions, a process for their production and their use
US4608415A (en) * 1980-04-15 1986-08-26 Asahipen Corporation Composition of modified chlorinated resins

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4608415A (en) * 1980-04-15 1986-08-26 Asahipen Corporation Composition of modified chlorinated resins
US4598120A (en) * 1984-04-28 1986-07-01 Bayer Aktiengellschaft Dispersion compositions, a process for their production and their use

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
EASTMAN CHEMICALS, Publication No. GN-363, Chlorinated Polyolefin CP-515-2, February 1985. See front page. *
NL CHEMICALS, Inc. Spensol L56, 1988. See front page. *
Union Carbide, UCARLINK CROSSLINKERS, Crosslinker XL-25 SE, Date unknwon, see front page. *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2760407A1 (fr) * 1997-03-10 1998-09-11 Sylvie Lebufnoir Feuille pouvant etre coloriee de facon reversible et son application
EP2486572A4 (fr) * 2009-10-07 2017-04-26 Federal-Mogul Powertrain, Inc. Manchon textile souple doté d'un revêtement protecteur résistant à l'effilochage d'extrémité et son procédé de fabrication
WO2019126501A1 (fr) * 2017-12-21 2019-06-27 Vf Jeanswear Lp Revêtement étirable liquide pour vêtements et ses procédés d'application

Also Published As

Publication number Publication date
AU5934990A (en) 1991-01-07

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