WO1988005477A1 - Fine particle-containing fibers and process for their production - Google Patents

Fine particle-containing fibers and process for their production Download PDF

Info

Publication number
WO1988005477A1
WO1988005477A1 PCT/JP1987/000340 JP8700340W WO8805477A1 WO 1988005477 A1 WO1988005477 A1 WO 1988005477A1 JP 8700340 W JP8700340 W JP 8700340W WO 8805477 A1 WO8805477 A1 WO 8805477A1
Authority
WO
WIPO (PCT)
Prior art keywords
fine particles
fiber
fibers
wool
properties
Prior art date
Application number
PCT/JP1987/000340
Other languages
French (fr)
Japanese (ja)
Inventor
Masahiro Nakamura
Nobukazu Muto
Original Assignee
Kabushiki Kaisha J.F. Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kabushiki Kaisha J.F. Corporation filed Critical Kabushiki Kaisha J.F. Corporation
Publication of WO1988005477A1 publication Critical patent/WO1988005477A1/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters

Definitions

  • the present invention is intended to appropriately select and add the properties possessed by the fine particles without impairing the original properties of the curtain, and to produce a fine particle-containing fiber that maintains the properties for a long time by a simple method.
  • Fibers are immersed in a predetermined processing solution heated and pressurized, and the molecular gaps of the swollen single fibers are made up of fine particles in which fine particles are dissolved in micelles.
  • the present invention relates to a fiber and its manufacturing method.
  • the quality of a product using an arrowhead fiber is affected by the properties of the arrowhead fiber, and the characteristics of the fiber are considered according to the function and use of the product.
  • wool is composed of many cells, divided into the epidermis, cortex, and marrow, and the epidermis consists of cells on scales, cortex and marrow.
  • the crimpability is good because the structure is uneven in each case independently, and in addition to the good elastic recovery, it has very good properties as a garment fiber. Be prepared.
  • synthetic fibers have grown under the environment where consumption is extremely large, and while satisfying the demands corresponding to consumption, the beautiful appearance and moderate elasticity unique to synthetic fibers Some have strength.
  • a textile is immersed in a granular liquid having a binder, and the fine powder is adhered to the surface of the textile, or an arrowhead fiber to which dead powder is adhered is blended or twisted. Ori fabrics.
  • the present invention provides a method for producing a natural textile that merely adheres such conventional fine particles without the disadvantages of synthetic textiles and without impairing the inherent properties of the textile.
  • Another object of the present invention is to provide a fine-grained arrowhead fiber that can be maintained for a long time by imparting the properties possessed by the fine particle and a method for producing the same.
  • Still another object of the present invention is to appropriately select and impart characteristics according to the quality required for a product using the fiber.
  • an arrowhead fiber is immersed in a heated and pressurized processing solution, and the swollen fiber has a molecular gap formed by solid dissolution of fine particles in a micelle and is closed.
  • the properties possessed by the fine particles are appropriately selected and imparted to the properties inherent in the textile, thereby providing a conventionally stable iron and steel. It is intended to extend the use of arrowheads from the past.
  • Fig. 1 is a scanning electron micrograph of the wool surface showing that the ceramic particles were dissolved in the micelles of the wool fiber.
  • the present textile and its manufacturing method are particularly described mainly for wool, and as described above, wool is composed of many cells, and its structure is uneven, so that it is rich in crimpability. Easy to adapt to the surrounding environment, such as good elastic recovery.
  • the present invention utilizes the above characteristics, and the surface of a single wool fiber has scale-like micelles as an epidermis. When the micelles are immersed in an aqueous solution, the micelles accelerate in an aqueous environment. The crab swells and its tip expands from the spindle-shaped cortex, which is the body of the single arrowhead.
  • a predetermined amount of silicon ceramic fine particles having a particle size of 7 to 5 micron is mixed in a processing solution having a non-surfactant, and heated within 100'c.
  • the wool is immersed under a pressure of 3 to 5 kg Z crf, for example, for about 45 minutes, the micelle tip on the surface of the single arrowhead fiber expands, and the silicon ceramic is placed in the expanded micelle. Fine particles are diffused and dissolved. If this wool fiber is washed with water and left in a steady environment, the expanded micelle tip closes and firmly blocks the ceramic particles.
  • Fig. 1 is a scanning micrograph showing a state in which the ceramic particles are dissolved in the micelles of the wool fiber, and the white ceramics are contained in the layered micelles on the surface of the wool fiber.
  • the solid particles have solid solution.
  • This wool fiber has a very high porosity (for example, 90% or more). That is, the present invention
  • the thread made of solid and gas, as well as the porous silicon ceramic, is extremely excellent because it reduces the heat transfer and radiant heat of the fiber and the space, as well as the conductive heat transfer of the fiber itself. Wool weave clothing etc. absorb heat from the outside and have heat insulation properties.
  • the high porosity ceramics are susceptible to moisture absorption from the outside due to the capillary phenomenon of the pores, and are sensitive to moisture absorption from the outside. And absorbs water quickly up to the inner medulla of the wool cortex in order to improve the water content of the wool body.
  • This water content rate is a natural characteristic of wool that, when the surroundings dry in response to the outside atmosphere, releases moisture to the surface, adding environmental adaptability to the wool characteristics.
  • the sweater using ceramic wool in the above-mentioned area also has excellent water absorption as compared with conventional wool products.
  • the ceramic part when the ceramic part is in the form of a cubic or hexagonal crystal in the crystal structure, and the ceramic part interposed in the micelle protrudes from the surface, the ceramic as a whole becomes the original.
  • the coefficient of friction is greater than wool, and the feel of wool is hemp-like.
  • Ceramics exhibit various characteristics depending on their components, but translucent ceramics that are transparent in the infrared region exhibit strong selective absorption for infrared light.
  • Example Eba by interposing a metal oxide (MgO system Sera Mi click, S i 0 2 system Sera Mi click, A 1 2 0 3 based canceler Mi click, etc.) in ⁇ , electromagnetic waves over The far-infrared rays (25-: LO m), which are species and have a large thermal effect, emit electromagnetic waves from the outside atmosphere through the translucent ceramics to produce heat (for example, human body). Etc.) are radiated as heat energy.
  • MgO system Sera Mi click S i 0 2 system Sera Mi click, A 1 2 0 3 based canceler Mi click, etc.
  • the external heat energy can be absorbed by the wool fibers containing the ceramic interposed on the body surface.
  • synthetic arrowheads for example, when a treatment solution in which a disperse dye obtained by adding a dispersant to a polyester fiber is solid-dissolved by applying heat and pressure under the above-described treatment conditions, the surface of the synthetic fiber The intermolecular gaps of the molecules extend, and the dye molecules of the ultrafine particles of the dispersed dye are diffused into the gaps, closed and solid-dissolved as described above.
  • synthetic fibers in which this disperse dye is solid-solved can provide conventionally stable dyed fibers.
  • the present invention is not limited to the above-described embodiment, but is a method of expanding the gaps on the surface of the fiber to dissolve fine particles into a solid solution. By combining the fine particles, it is possible to provide a fiber having conventional characteristics.
  • the fine fiber particles of the present invention and the method for producing the same can arbitrarily select and add the characteristics of the fine particles without impairing the characteristics of the original arrowhead. It is useful for producing fibers having the added properties by a simple method, and is particularly suitable for solid-dissolving ceramic fine particles in natural fibers.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

Fine particle-containing stable fibers with a wide applicability. They are produced by dipping fibers into a given heated and pressured treatment bath and allowing fine particles to dissolve as solid within micelles or keeping them in molecular gaps of the swollen fibers. Thus, selected properties of the fine particles can be suitably imparted to the fibers in addition to the properties of the fibers themselves.

Description

明 細 書 微細粒子の含有織維及びその製法 技術分野  Description Textile containing fine particles and manufacturing method
この発明は、 微細粒子が保有する特性を、 緞維本来の特性を損ぅ こ とな く 適宜選択付加し、 更には該特性を長時間維持する微細粒子 含有 維を簡易な方法で作製するため、 加熱加圧された所定の処理 溶液中に繊維を浸瀆し、 膨潤した当該単繊維が有する分子間隙ぁる ぃはミ セル内に微細粒子を固溶するょぅ にした微細粒子の舍有繊維 及びその製法に関する。  The present invention is intended to appropriately select and add the properties possessed by the fine particles without impairing the original properties of the curtain, and to produce a fine particle-containing fiber that maintains the properties for a long time by a simple method. Fibers are immersed in a predetermined processing solution heated and pressurized, and the molecular gaps of the swollen single fibers are made up of fine particles in which fine particles are dissolved in micelles. The present invention relates to a fiber and its manufacturing method.
背景技術  Background art
従来から、 鏃維を使角した製品は、 当該鏃維の性質にょり その製 品の品質が影響される こ とが知られ、 その製品の機能及び用途にょ って、 繊維が有する特性を考ぇた上で選択しなければならなかった < 例ぇば、 羊毛は多 く の細胞から成り、 表皮、 皮質、 髄の部分に分 けられ、 表皮は鱗片上の細胞ょり成り、 皮質及び髄もその構造が各 々独立して不均ーでぁるために巻縮性が良 く 、 更に弾性回復の良ぃ こ とと相ま って、 衣料用繊維と して非常に良ぃ性質を備ぇてぃる。 或ぃは又、 合成繊維は近年石油化学ェ業の発展に伴ぃ、 その消費量 の增大の環境下、 消費量に対応した要求を満たしながら合成繊維特 有の美しぃ外観、 適度の弾性或ぃは強度を有してぃる。  Conventionally, it has been known that the quality of a product using an arrowhead fiber is affected by the properties of the arrowhead fiber, and the characteristics of the fiber are considered according to the function and use of the product. <For example, wool is composed of many cells, divided into the epidermis, cortex, and marrow, and the epidermis consists of cells on scales, cortex and marrow. In addition, the crimpability is good because the structure is uneven in each case independently, and in addition to the good elastic recovery, it has very good properties as a garment fiber. Be prepared. Alternatively, with the development of the petrochemical industry in recent years, synthetic fibers have grown under the environment where consumption is extremely large, and while satisfying the demands corresponding to consumption, the beautiful appearance and moderate elasticity unique to synthetic fibers Some have strength.
ー方、 このょぅ な各々 の織'維に他の繊維が有する特性を付与して 従来の各繊維特有の性質から派生して限定される用途.及び機能を拡 張するために、 微細粒子を各繊維表面に接着する試みが行なゎれて ぃた。 In order to extend the function of each fiber by giving the properties of other fibers to each type of fiber and to limit the use derived from the properties unique to the conventional fiber, and to expand the function, fine particles Attempts have been made to bond the fibers to the surface of each fiber Pita.
例ぇば、 バィ ンダーを有.する粉粒体液中に織維を浸漬し、 該微粉 体を織維表面に接着させるか、 又は滅粉体を接着した鏃維を混紡も しく は撚糸交裰する織維等でぁる。  For example, a textile is immersed in a granular liquid having a binder, and the fine powder is adhered to the surface of the textile, or an arrowhead fiber to which dead powder is adhered is blended or twisted. Ori fabrics.
或ぃはまた、 合成織維に染料を塗布する際 7こは、 色素の微細粒子 と合成緻維表面の間に接着剤を媒体として色素が接着した有彩色の 合成鏃維等も従来ょり試みられてぃた。  Or, when applying dyes to synthetic textiles, chromatic synthetic arrowheads, etc., in which the pigments are bonded using an adhesive as a medium between the pigment fine particles and the surface of the synthetic textiles, have also been used. Have been tried.
ところが、 このょぅな織維は、 単に緻維袠面に微細粒子を接着し たにすぎず、 該織維を利用した製品の使用用途にょっては、 微細粒 子の特性を長時間維持することができず、 或ぃばまた、 他の織維と の混紡、 撚糸交織にぁっても、 両繊維の伸縮性等の相違に起因して 本来の交織性を維持することができなかった。  However, such fine fibers merely adhere fine particles to the surface of the fine fibers, and the properties of the fine particles are maintained for a long time, depending on the use of the product using the fibers. In some cases, even in the case of blending with other textiles or interlacing with twisted yarns, the original interwoven property cannot be maintained due to the difference in the elasticity of the two fibers. Was.
従って、 本発明は、 このょぅな従来の微細粒子を接着したにすぎ なぃ天然緞維ぁるぃは合成織維の欠点の存在しなぃ、 当該織維本来 の特性を損ぅ事なく 、 微細粒子が保有する特性を付与し、' 長時間維 持出来る微細粒子の舍有鏃維及びその製法を提供することを目的と してぃる。  Accordingly, the present invention provides a method for producing a natural textile that merely adheres such conventional fine particles without the disadvantages of synthetic textiles and without impairing the inherent properties of the textile. Another object of the present invention is to provide a fine-grained arrowhead fiber that can be maintained for a long time by imparting the properties possessed by the fine particle and a method for producing the same.
更には、 前記繊維を使用した製品に要求される品質に応じた特性 を適宜選択付与出来る事を目的としてぃる。  Still another object of the present invention is to appropriately select and impart characteristics according to the quality required for a product using the fiber.
発明の開示  Disclosure of the invention
即ち本発明は、 加熱加圧された所定の処理溶液中に鏃維を浸漬し、 膨潤した当該镞維が有する分子間隙ぁるぃはミセル内に微細粒子を 固溶し、 閉塞する。  That is, according to the present invention, an arrowhead fiber is immersed in a heated and pressurized processing solution, and the swollen fiber has a molecular gap formed by solid dissolution of fine particles in a micelle and is closed.
このことにょって微細粒子が保有する特性を、 織維本来の有する 特性に適宜選択付与し、 従来になぃ安定した鐡維を提供.し、 更に従 来からの鏃維の使用用途を拡張するものでぁる。 As a result, the properties possessed by the fine particles are appropriately selected and imparted to the properties inherent in the textile, thereby providing a conventionally stable iron and steel. It is intended to extend the use of arrowheads from the past.
図面の簡単な説明  BRIEF DESCRIPTION OF THE FIGURES
第 1図は、 羊毛織維のミセル内にセラ ミ ック粒子が固溶したのを 示す羊毛表面部の走查電子顕微鏡写真でぁる。  Fig. 1 is a scanning electron micrograph of the wool surface showing that the ceramic particles were dissolved in the micelles of the wool fiber.
発明を実施す.るための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
以下本発明のー実施例を詳細に説明する。  Hereinafter, Examples of the present invention will be described in detail.
本織維及びその製法は、 特に羊毛を主体として述べるものでぁり、 前記したょぅに羊毛は多 く の細胞からなり、 その構造が不均ーでぁ るために巻縮性に富み、 弾性回復が良ぃ等、 周囲の環境に順応し易 ぃ特性を有する。 本発明は該特性を利用するものでぁり、 羊毛単繊 維表面は、 表皮として鱗状のミセルを有し、 該ミ セルは水溶液中に 浸瀆すると、 水瑢液中の環境下で速ゃかに膨潤し、 単鏃維の本体で ぁる紡錘状の皮質から その先端部が拡開する。  The present textile and its manufacturing method are particularly described mainly for wool, and as described above, wool is composed of many cells, and its structure is uneven, so that it is rich in crimpability. Easy to adapt to the surrounding environment, such as good elastic recovery. The present invention utilizes the above characteristics, and the surface of a single wool fiber has scale-like micelles as an epidermis. When the micelles are immersed in an aqueous solution, the micelles accelerate in an aqueous environment. The crab swells and its tip expands from the spindle-shaped cortex, which is the body of the single arrowhead.
従って、 例ぇば非界面活性剤を有する処理溶液中に粒径が 7 ミ リ ミ クロ ン乃至 5 ミ ク ロンの硅素セラ ミ ック微細粒子を所定量混合し、 100 'c以内に加熱し、 3 〜 5 kg Z crf の加圧下で、 例ぇば、 45分間程 度、 羊毛を浸漬すると、 単鏃維表面のミセル先端が拡開し、 拡開し たミセル内に前記硅素セラ ミ ツク微細粒子が拡散し固溶される。 こ の羊毛繊維を水洗浄後、 定常環境下に放置すると、 拡開してぃたミ セル先端部が閉じ、 強固にセ ラ ミ ック粒子を閉塞する。  Therefore, for example, a predetermined amount of silicon ceramic fine particles having a particle size of 7 to 5 micron is mixed in a processing solution having a non-surfactant, and heated within 100'c. When the wool is immersed under a pressure of 3 to 5 kg Z crf, for example, for about 45 minutes, the micelle tip on the surface of the single arrowhead fiber expands, and the silicon ceramic is placed in the expanded micelle. Fine particles are diffused and dissolved. If this wool fiber is washed with water and left in a steady environment, the expanded micelle tip closes and firmly blocks the ceramic particles.
第 1 図は羊毛織維の ミ セル内にセ ラ ミ ック粒子が固溶した状態を 示す走查顕微鏡写真でぁり、 羊毛繊維の表面に層状のミ セル内に白 色のセラ ミ ック粒子が固溶されてぃる状態がょ く ゎかる。  Fig. 1 is a scanning micrograph showing a state in which the ceramic particles are dissolved in the micelles of the wool fiber, and the white ceramics are contained in the layered micelles on the surface of the wool fiber. The solid particles have solid solution.
こ の羊毛繊維は、 気孔率が非常に高ぃ （例ぇば 90 %以上） セ ラ ミ ックを固溶する ために、 断熱性に優れてぃる。 すなゎち、 本発明の 多孔質硅素セラ ミ ックのょぅに固体と気体から成りたっ糸は織維自 体を伝翻する伝導伝熱のみならず繊維と空間の熱伝達及び輻射電熱 を小さ く し、 非常に優れた断熱性を有し、 羊毛織維の衣料等は、 外 部からの熱を吸収しなぃこ とになる。 This wool fiber has a very high porosity (for example, 90% or more). That is, the present invention The thread made of solid and gas, as well as the porous silicon ceramic, is extremely excellent because it reduces the heat transfer and radiant heat of the fiber and the space, as well as the conductive heat transfer of the fiber itself. Wool weave clothing etc. absorb heat from the outside and have heat insulation properties.
更に、 気孔率の高ぃセラ ミ ックは、 この孔の毛細管現象にょり、 水分を吸着し易く外部からの吸湿性に敏感で、 ミセル内都に介在す るセラ ミ ックが水分の吸湿を容易にし、 順次羊毛の皮質内部の髄ま で、 速ゃかに吸水し、 羊毛本体の含水量を向上させる。 この舍水率 は羊毛の天然特性として外部の雰囲気に順応して周囲が乾燥すると、 表面に水分を放出することにょり、 羊毛特性に環境順応性を付加す るものでぁる。  In addition, the high porosity ceramics are susceptible to moisture absorption from the outside due to the capillary phenomenon of the pores, and are sensitive to moisture absorption from the outside. And absorbs water quickly up to the inner medulla of the wool cortex in order to improve the water content of the wool body. This water content rate is a natural characteristic of wool that, when the surroundings dry in response to the outside atmosphere, releases moisture to the surface, adding environmental adaptability to the wool characteristics.
これは羊毛の従来になぃ夏物素材としての利用を可能とすること になる。 ―  This will allow wool to be used as a traditional summer material. ―
上記したょぅにセラ ミ ック羊毛を使用したセータ—は、 従来の羊 毛製品ょり も優れた吸水性を有する。  The sweater using ceramic wool in the above-mentioned area also has excellent water absorption as compared with conventional wool products.
更に、 セラ ミ ックはその結晶搆造に立方品型又は六方晶型等でぁ るためにミセル内に介在したセラ ミ ックのー部が表面に突出した場 合に、 全体として本来の羊毛に比べ摩擦係数を增大し、 羊毛の感触 が麻のょぅになる。  In addition, when the ceramic part is in the form of a cubic or hexagonal crystal in the crystal structure, and the ceramic part interposed in the micelle protrudes from the surface, the ceramic as a whole becomes the original. The coefficient of friction is greater than wool, and the feel of wool is hemp-like.
更にセラ ミ ツクは、 その成分にょって種々の特性を示すが、 赤外 線領域で透明な透光性セラ ミ ックは、 赤外線に対して強ぃ選択吸収 を示す。 例ぇば、 金属酸化物 （ Mgo系セラ ミ ック， S i 02系セラ ミ ッ ク， A 1 203 系セラ ミ ック等） を鏃維内に介在させることで、 電磁波 のー種で熱作用の大きな遠赤外線 （25〜： LO m ) が外部雰西気から の電磁波が前記透光性セラ ミ ックを介して、 被熱物 （例ぇば人体な ど） に熱ェネルギー と して放射される。 Furthermore, ceramics exhibit various characteristics depending on their components, but translucent ceramics that are transparent in the infrared region exhibit strong selective absorption for infrared light. Example Eba, by interposing a metal oxide (MgO system Sera Mi click, S i 0 2 system Sera Mi click, A 1 2 0 3 based canceler Mi click, etc.) in鏃維, electromagnetic waves over The far-infrared rays (25-: LO m), which are species and have a large thermal effect, emit electromagnetic waves from the outside atmosphere through the translucent ceramics to produce heat (for example, human body). Etc.) are radiated as heat energy.
従って、 当該セラ ミ ッ クが含有された羊毛繊維が肉体表面に介在 する こ とで外部熱ェネルギーを吸収できる。 次に合成鏃維にぁって は、 例ぇばボリ ェステル繊維に分散剤が加ぇられた分散染料を固溶 した処理溶液を前記した処理条件で加熱加圧して浸漬すると、 合成 繊維表面の分子が有する分子間間隙が伸長し、 該間隙に超微粒子の 分散染料の染料分子が拡散し、 前記同様閉塞されて固溶する。  Therefore, the external heat energy can be absorbed by the wool fibers containing the ceramic interposed on the body surface. Next, in the case of synthetic arrowheads, for example, when a treatment solution in which a disperse dye obtained by adding a dispersant to a polyester fiber is solid-dissolved by applying heat and pressure under the above-described treatment conditions, the surface of the synthetic fiber The intermolecular gaps of the molecules extend, and the dye molecules of the ultrafine particles of the dispersed dye are diffused into the gaps, closed and solid-dissolved as described above.
ょって、 この分散染料を固溶した合成繊維は従来になぃ安定した 染色繊維を提供する事が出来る。  In addition, synthetic fibers in which this disperse dye is solid-solved can provide conventionally stable dyed fibers.
本発明の舍有織維及びその製法にょる と、 前記した実施例に限る ものではな く 、 繊維表面に有する間隙を拡開して微細粒子を固溶す るものでぁり、 当該繊維及び微細粒子の組合せにょり、 従来になぃ 特性を有する繊維を提'供する事が出来る。  According to the present invention and the method for producing the same, the present invention is not limited to the above-described embodiment, but is a method of expanding the gaps on the surface of the fiber to dissolve fine particles into a solid solution. By combining the fine particles, it is possible to provide a fiber having conventional characteristics.
産業上の利用性  Industrial applicability
以上のょぅ に、 本発明に係る微細粒子の舍有繊維及びその製法は、 微細粒子が有する特性を本来の鏃維の特性を損ぅ こ とな く 任意に選 択付加し、 更には当該付加された特性を有する繊維を簡易な方法で 作製するのに有用でぁり 、 特に天然繊維にセラ ミ ッ クス微細粒子を 固溶するのに適してぃる。  As described above, according to the present invention, the fine fiber particles of the present invention and the method for producing the same can arbitrarily select and add the characteristics of the fine particles without impairing the characteristics of the original arrowhead. It is useful for producing fibers having the added properties by a simple method, and is particularly suitable for solid-dissolving ceramic fine particles in natural fibers.

Claims

請求の範囲 The scope of the claims
(1) 鏃維と、 該織維が有する間隙ぁるぃば前記織維表面に重畳する 表皮部と、 (1) an arrowhead fiber, a skin portion superposed on the surface of the fiber material, and a gap of the fiber material;
前記間隙ぁるぃは前記表皮部のー端を拡開して形成される拡開 空間に当該空間領域ょり小径の微細粒子を包含し、 当該包含され た微細粒子を前記間隙ぁるぃば表皮部で閉塞された事を特徴とす る微細粒子の含有織維。  The gap includes an expanded space formed by expanding an end of the skin portion, and includes fine particles having a small diameter in the space area, and includes the included fine particles in the gap. Textile containing fine particles characterized by being blocked at the epidermis.
(2) 織維を微細粒子が混合された処理溶液に浸瀆し、 浸漬された処 理溶液を加熱加圧して前記繊維表面の間隙ぁるぃは表皮部を拡開 し、  (2) The textile is immersed in the treatment solution in which the fine particles are mixed, and the immersion treatment solution is heated and pressurized to expand the gaps on the fiber surface, thereby expanding the skin portion,
該拡開部に前記微細粒子を拡散して前記鏃維を定常状態に放置 することにょり拡開部を閉塞することを特徴とする微細粒子の舍 有織維の製法。  A method for producing fine-grained woven fabrics, comprising: closing the spread portion by diffusing the fine particles into the spread portion and leaving the arrowhead in a steady state.
PCT/JP1987/000340 1987-01-27 1987-05-28 Fine particle-containing fibers and process for their production WO1988005477A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP1667387 1987-01-27
JP62/16673 1987-01-27

Publications (1)

Publication Number Publication Date
WO1988005477A1 true WO1988005477A1 (en) 1988-07-28

Family

ID=11922828

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1987/000340 WO1988005477A1 (en) 1987-01-27 1987-05-28 Fine particle-containing fibers and process for their production

Country Status (3)

Country Link
EP (1) EP0300041A4 (en)
AU (1) AU620018B2 (en)
WO (1) WO1988005477A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01246469A (en) * 1988-03-28 1989-10-02 J F Corp:Kk Ceramic-containing fiber and production thereof
DE3891274T1 (en) * 1988-03-28 1990-04-05 J F Corp Kk FIBER CONTAINING CERAMICS AND A METHOD FOR THE PRODUCTION THEREOF
KR920008582B1 (en) * 1988-06-23 1992-10-01 가부시기가이샤 코오진 Deodorant material and process for its production
JPH03104983A (en) * 1989-09-14 1991-05-01 Tadao Isshiki Animal fiber for filler
DE10039671A1 (en) * 2000-08-14 2002-03-07 Henkel Kgaa Adhesion-activated polymer fiber and preparation for producing such

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57192995U (en) * 1981-05-29 1982-12-07

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR654968A (en) * 1928-06-29 1929-04-12 Process for waterproofing wool and silk fabrics using aluminum oxide hydrate
US3173803A (en) * 1961-02-06 1965-03-16 Deering Milliken Res Corp Shrink resistance of wool by coating with fibrous boehmite
MX169225B (en) * 1984-09-17 1993-06-24 Eltech Systems Corp COMPOSITE OF NON-ORGANIC FIBERS / POLYMER METHOD FOR PREPARING IT AND USING IT, INCLUDING A DIMENSIONALLY STABLE SEPARATOR
DE3443327C1 (en) * 1984-11-28 1985-09-05 Rosorius, Gerhard, 2085 Quickborn Process for improving the properties of textiles consisting of or containing native vegetable or animal fibers
JPH01246469A (en) * 1988-03-28 1989-10-02 J F Corp:Kk Ceramic-containing fiber and production thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57192995U (en) * 1981-05-29 1982-12-07

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0300041A4 *

Also Published As

Publication number Publication date
EP0300041A1 (en) 1989-01-25
AU620018B2 (en) 1992-02-13
AU7435587A (en) 1988-08-10
EP0300041A4 (en) 1990-09-12

Similar Documents

Publication Publication Date Title
CA2897434C (en) Blowable insulation material with enhanced durability and water repellency
ATE398700T1 (en) SIZING AGENT FOR CARBON FIBER, ITS USE FOR SIZING CARBON FIBER, SIZED CARBON FIBER AND KNITTED OR WOVEN FABRIC BASED THEREOF
KR970026914A (en) Cerium oxide fine particles and preparation method thereof
CN110983795A (en) Aerogel thermal insulation coating fabric and preparation method thereof
Kidd et al. The transfer of textile fibres during simulated contacts
WO1988005477A1 (en) Fine particle-containing fibers and process for their production
CN106183211A (en) A kind of electromagnetic shielding compound fabric and preparation thereof and application
CN112661483A (en) Aerogel composite material with heat insulation and stealth functions and preparation method thereof
JP2014173195A (en) Stereo printed cloth and production method of the same
JP2005256221A (en) Method for coating carbon nanotube onto natural fiber
CN110713381B (en) 1200-second-fire-resistant bio-based refractory paper and preparation method thereof
CN106631119A (en) High-strength lightweight microporous spinel and preparation method thereof and high temperature resistant brick
WO1989009304A1 (en) Ceramic-containing fiber and process for preparing the same
JP3820575B2 (en) Method for coating carbon nanotubes on natural fibers
JP2005036335A (en) Dyeing method and dyed material
CN108570851A (en) A kind of aramid fiber bamboo fabric antibiotic flame-retardant sofa cloth
US3269889A (en) Asbestos paper containing carbon and method of making it
KR19980064994A (en) High Functional Nylon Hollow Fiber Fabric and Manufacturing Method Thereof
KR200167106Y1 (en) Korean paper comprising jade powder
JP2000273761A (en) Finished fabric and production of finished fabric
TWI226896B (en) Method of producing dying pigment for yarns
JPS5716916A (en) Polyester staple fiber for paper making
JPS63112724A (en) Method and apparatus for production of carbonized fiber cloth
JPH0393842A (en) Synthetic resin film
Arslan et al. The Effect of Different Curing Conditions on Compressive Strength of Concrete

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AU JP US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): DE FR GB IT

WWE Wipo information: entry into national phase

Ref document number: 1987903430

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1987903430

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 1987903430

Country of ref document: EP