USRE32454E - Process for desulfurization of coal and ores - Google Patents
Process for desulfurization of coal and ores Download PDFInfo
- Publication number
- USRE32454E USRE32454E US06/266,631 US26663181A USRE32454E US RE32454 E USRE32454 E US RE32454E US 26663181 A US26663181 A US 26663181A US RE32454 E USRE32454 E US RE32454E
- Authority
- US
- United States
- Prior art keywords
- sulfur
- solvent
- ore
- solvent solution
- crystalized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/027—Recovery of sulfur from material containing elemental sulfur, e.g. luxmasses or sulfur containing ores; Purification of the recovered sulfur
- C01B17/033—Recovery of sulfur from material containing elemental sulfur, e.g. luxmasses or sulfur containing ores; Purification of the recovered sulfur using a liquid extractant
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/02—Treating solid fuels to improve their combustion by chemical means
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/11—Removing sulfur, phosphorus or arsenic other than by roasting
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C1/00—Building elements of block or other shape for the construction of parts of buildings
- E04C1/40—Building elements of block or other shape for the construction of parts of buildings built-up from parts of different materials, e.g. composed of layers of different materials or stones with filling material or with insulating inserts
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B2/00—Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls
- E04B2/02—Walls, e.g. partitions, for buildings; Wall construction with regard to insulation; Connections specially adapted to walls built-up from layers of building elements
- E04B2002/0202—Details of connections
- E04B2002/0232—Undercut connections, e.g. using undercut tongues and grooves
- E04B2002/0234—Angular dovetails
Definitions
- This invention relates to a process for desulfurization of ores, particularly coal, that is continuous and which recovers a high grade sulfur crystal.
- a primary use of the process is for production of a sulfurless coal powder than can be fired in powder form, or further processed into briquettes by conventional means.
- the crystaline sulfur is suitable for general sulfur products or in continuous steps may be melted and cast into construction blocks. This process is adaptable to other ores for recovery of tungsten, cinabar, etc. which are relatively high in sulfur content.
- Natural gas similarly should not be used either as a power source or for heating. Because of its particularly clean burning, natural gas should be reserved for open flame uses such as cooking and other clean combustion applications.
- Stationary power sources are ideally suited for burning of coal which is available in abundance in certain geographical areas and particularly throughout North America.
- Much of the available coal is contaminated with sulfur, which generates a noxious pollutant when the coal is combusted.
- Expensive pollution control devices installed to wash the combustion gases are only partially successful in removing sulfur, sulfur compounds and oxidants before releasing such combustion gases to the atmosphere. Consequently, much of the coal mined that is not of low sulfur content or is otherwise highly contaminated with impurities is simply left in gob piles.
- the sulfur contaminant should be removed prior to combustion.
- Past processes are of limited efficiency and contribute excessively to the cost of coal as a common fuel.
- the process devised is economical and is operable as a continuous rather than batch method. Furthermore, the process recovers and recycles the solvent used to separate sulfur from the ore maintaining solvent losses at a minimum.
- the large quantities of sulfur recovered are usable in a coupled process stage to produce building blocks at a cost competitive with similar concrete blocks.
- the process is particularly applicable to gob pile coal that has been abandoned and exists in huge quantities. Other features of this process are described in greater detail in the detailed description of the preferred embodiment hereinafter.
- the desulfurization process of this invention is a continuous process for desulfurizing ores, particularly coal.
- the process recovers a high grade sulfur and extracts other solids which may be further refined for recovery of precious metals or by-products that are economically justifiable to recover.
- the coal is refined to a high grade coal powder suitable for modern powder handling techniques which approximate the advantages of liquid handling.
- the process begins by crushing the ore, a sulfur bearing coal ore in the preferred use, to approximately a 28 mesh size.
- the crushed ore is mixed with a solvent, preferably perchlorethylene, forming a solvent liquor in which the sulfur dissolves in solution.
- the solvent liquor is centrifuged separating the sulfur and solvent solution from the coal slurry in a continuous process centrifuging drum.
- a second centrifuging drum separates the lighter weight coal particles from the heavier earth tailings or sedimentary-type residuals in a continuous process.
- the sulfur liquor, contaminated with a microparticle ash suspension is filtered to remove the ash.
- the sulfur in solution is crystalized by cooling and centrifugally separated from the solvent.
- the sulfur is dried and the remaining solvent recovered.
- the resultant sulfur is suitable for marketing or at this stage heated to a higher melting temperature and the liquid sulfur cast for building materials. All of the solvent from the separating and drying processes, less minimal losses, is recycled in the process.
- the desulfurization process is so effective that less than 0.01 percent sulfur remains in the final coal product after drying.
- This process is designed to utilize standardized equipment in the various stages which can be shifted or stage rotated to maximize a uniformity of wear.
- the process is able to capitalize on gravity to convey materials and liquids from one stage to another wherever possible.
- FIG. 1 is a schematic illustration of the process.
- FIG. 2 is a block diagram summary of the process.
- FIG. 3 is a perspective view of a processor.
- FIG. 4 is a perspective view of interlocked construction block.
- the desulfurization process can be described with relation to the various circuits that make up the process when used for production of sulfur and the refining of coal for generating a coal product that is virtually sulfur-free.
- the coal ore, high in impurities in bulk form is delivered by conventional handling equipment, for illustration, a dump truck 10 and front end loader 12, to an initial crushing station 14 which receives batch quantities of ore 16 in a jaw crusher 18 and by a feeder mechanism delivers aggregate size coal ore 22 in a continuous flow to a belt conveyor 24.
- the belt conveyor feeds the crushed coal ore 22 to a roll crusher 26 which reduces the aggregate size ore to a powder 28 of approximately 28 mesh size.
- a belt conveyor 30 transports the powder 28 to one or more heated mixer processors 32 into which a heated solvent is introduced.
- the mixer processor employed throughout this process must be continuous in nature and in certain cases must be capable of collecting products of evaporation where the processors function as dryers.
- processors manufactured under the trademark Holo-Fite by Joy Manufacturing Company are suitable for multiple processing functions involved herein.
- These processors employ double conveyance screws 36 rotatable in an elongated conduit 38.
- the augers 36 are hollow to provide for a heat transfer fluid for cooling or heating.
- the conduit 38 similarly includes a fluid jacket 40 for a heat transfer fluid to provide a controllable temperature or temperature gradient in the substance processed through the processor.
- the fluid, a liquid or gas, is supplied to the processors from external sources.
- Other features of the processor are detailed hereinafter.
- the mixer processors 32 as in the schematic illustration of FIG. 1 are provided with steam from a supply line 42 to achieve a mix temperature, preferably approximately 245° F.
- the solvent, perchlorethylene is preheated and supplied from solvent supply line 44.
- the mixing process leaches and dissolves sulfur into the solvent solution, forming a hot mother liquor.
- the steam for heating processors 32 is obtained from water storage tank 46, where water is supplied by a pump 48 through water supply line 50 to a filter 52 to remove impurities before delivery to a recirculating tank 54.
- supply water if needed is preheated by system recirculated condensation water by pump 56 before added to water in a boiler 58.
- the boiler is fired by fuel from a fuel supply line 62.
- a heating line 64 for cold climates to steam heat the storage fuel to reduce viscosity.
- the solvent is supplied from a steam heated solvent supply tank 66 by pump 68. Heating of the solvent to 250° F. is accomplished by a heat exchange jacket supplied with steam from the boiler 56 through line 70. Loses, which are minimal from the closed system design, are replenished from solvent storage tanks 72 through feed line 74.
- the mother liquor with coal particles and heavier undissolvable suspended and sedimentary impurities is delivered through a conduit 76 to a continuous process centrifuge separator 78.
- the centrifuge separator 78 separates the sulfur and solvent solution from a coal and residue slurry.
- the slurry is drawn off and conveyed by a screw conveyer 79 to a second centrifuge separator 80 where the lighter weight coal slurry is separated from the heavier residue or tailings.
- the heavier residue or tailings are in many instances suitable for refining by conventional methods to recover valuable materials, particularly rare metals.
- the slurry is conveyed by a conveyer 81 to a continuous process dryer 82 which comprises a similar processor to the mixer processors 32, but equipped with a domed collector 84 for recovering solvent vapors generated by evaporation during the drying process.
- the dryer 82 includes a steam supply line 83 for the processor's heat exchanger and a condenser 86 to condense the solvent vapors collected by the domed collector.
- the coal is delivered in a dry powder form for further processing into briquettes and the like, bagging, or bulk shipment.
- the gradient centrifuge which has the capability of separating suspensions of different mass, is not required.
- a more enconomical filter drum centrifuge with internal scrapers for continuous operation may be used to separate the suspensions or tailings as an aggregate from the sulfur liquor.
- the hot sulfur solution together with microparticle suspensions from the centrifuge separator 78 is pumped by pump 88 through line 89 to a pair of pre-coat filters 90 for removal of the suspensions from the sulfur solution.
- the filters can be of a continuous process-type with in process scrapers or a pair of intermittent filters that are periodically scraped in alternating fashion.
- the ash recovered is either used in fabricating construction materials or refined by conventional methods if analysis indicates the presence of recoverable materials.
- the purified sulfur solution flows through line 92 to a receiving tank 94 where cooling begins for crystalization of the sulfur in solution.
- the actual crystalization occurs in a set of three series arranged processors 96 which are chilled by solvent pumped by pump 98 from a heat exchanger 100 to the processors in cooling lines 102.
- the three crystalization processors 96 are again similar to the processor of FIG. 3, with dual screw mechanisms constructed to function as a heat exchanger using a lean solvent as the cooling medium.
- the temperature has been reached to 80° F. and the sulfur has crystalized, existing in part as a suspension and in part as a precipitate.
- the crystalized sulfur and solvent solution flow to a centrifugal separator 104 where the solvent is removed, leaving crystalized sulfur.
- the sulfur is conveyed directly to a dryer 106 similar to the dryer 82 for the coal.
- the dryer is heated by a steam line 83 from the boiler to a temperature of approximately 180° F.
- the dryer 106 recovers and collects solvent from the sulfur crystal by the domed collector 106.
- the solvent vapors are condensed in condenser 110 before returning to solvent recovery line 112.
- any vapors that remain are condensed when the recovery line 112 joins the solvent return line 114 from the separator 104 where relatively cool solvent is introduced in large quantities.
- the solvent is returned to a preheater receiving tank 116.
- the preheater includes one or more vapor condensers 118 which act as pressure buffers as well as condensers to reduce to liquid form any solvent vapors that may exist.
- the receiving tank 116 is heated by steam connection line 120 which taps the steam supply line 83.
- the immediate maintenance and subsequent raising of the solvent temperature is necessary to prevent any further crystalization of residue sulfur dissolved in the solvent which may interfere with free flow of the solvent in the flow lines.
- the presence of residue sulfur is unimportant since the solvent is immediately pumped by pump 112 through feed line 124 to the main solvent heating tank 66 where it is heated to a high temperature for introduction to the first stage mixing with the crushed ore in the mixer processors 32.
- the dried sulfur crystals are either fully dried in the dryer 106, which is equipped with a heat exchange unit 126, for use in a conventional commercial manner for pesticides, soil amendments, chemical manufacture, etc.
- the crystals are conveyed by a conveyer 128 from the dryer 106 to a hopper 130 for mixing with a preheated aggregate in a high temperature steam heated mixer 132.
- the dryer need not be as thorough, and its operation is dictated by economics as to the degree of solvent recovery since the sulfur in mixer 132 is raised to the melting point 285° F.
- the liquid sulfur and aggregate mix are poured into suitable molds for construction materials.
- the molds can produce construction blocks 136 having a configuration as shown in FIG. 4.
- the male and female ends, 138 and 140 are easily assembled by the simple interlock of the projection and recess.
- FIG. 2 A block diagram shown in FIG. 2 provides a summary for the process. Beginning from a primary crushing stage 200, ore passes to a secondary crushing stage 202. At a juncture 204, solvent is added to the crushed ore and a leaching stage 206 is encountered where sulfur is leached into solution. Following leaching, a separation stage 208 is encountered, where a coal and residue slurry is separated in one process line and conveyed to a second separation stage 210, and a sulfur liquor is separated in another process line and conveyed to a purification stage 212.
- a residue is separated at 214 and is discarded, used in fabrication of construction materials, or is further refined at step 216, as indicated.
- the coal slurry is conveyed to a drying stage 218.
- a solvent recovery step 220 where solvent is evaporated from the slurry, condensed and returned to the solvent supply at juncture 204.
- the dried coal is in powder form and is processed in a bulk or bagged step 216 before a final market stage 222.
- the separated sulfur liquor in the purification stage 212 removes impurities as an ash residue by filtration.
- the separated ash 226 may be disposed or used in fabricating construction materials.
- the purified liquor enters a crystalizing stage 228 where the dissolved sulfur in solution crystalizes as a precipitate.
- the separation of the crystalized sulfur is accomplished in a separation stage 230 where the liquid solvent is removed, preferably by a centrifuge separator.
- the crystalized sulfur in a slurry is conveyed to a drying stage 232 accompanied by a solvent recovery stage 234 in which the remaining solvent is evaporated recovered and condensed and subsequently returned to the solvent supply at juncture 204.
- the sulfur is ready for market at final stage 236.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Architecture (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Mechanical Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (26)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/266,631 USRE32454E (en) | 1978-03-02 | 1981-05-26 | Process for desulfurization of coal and ores |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/882,866 US4213793A (en) | 1978-03-02 | 1978-03-02 | Process for desulfurization of coal and ores |
US06/266,631 USRE32454E (en) | 1978-03-02 | 1981-05-26 | Process for desulfurization of coal and ores |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US05/882,866 Reissue US4213793A (en) | 1978-03-02 | 1978-03-02 | Process for desulfurization of coal and ores |
Publications (1)
Publication Number | Publication Date |
---|---|
USRE32454E true USRE32454E (en) | 1987-07-07 |
Family
ID=26951954
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/266,631 Expired - Lifetime USRE32454E (en) | 1978-03-02 | 1981-05-26 | Process for desulfurization of coal and ores |
Country Status (1)
Country | Link |
---|---|
US (1) | USRE32454E (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5217503A (en) * | 1991-03-18 | 1993-06-08 | Midwest Ore Processing Company, Inc. | Process for desulfurization of coal and ores |
US5316751A (en) * | 1991-02-11 | 1994-05-31 | Gordon Kingsley | Methods for mine tailing clean-up using recovery technologies |
WO1994029411A1 (en) * | 1992-12-31 | 1994-12-22 | Sunggyu Lee | Processes for desulfurizing coal |
US5935313A (en) * | 1998-04-20 | 1999-08-10 | Ficinski; Marek B. | Building material |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1963921A (en) * | 1933-01-07 | 1934-06-19 | Delaware Chemical Engineering | Extracting sulphur |
US2785059A (en) * | 1953-02-26 | 1957-03-12 | American Sulphur & Refining Co | Solvent extraction of sulphur |
US2897065A (en) * | 1956-06-18 | 1959-07-28 | Gulf Research Development Co | Recovery of elemental sulfur from sulfur bearing solid mineral matter |
GB858056A (en) * | 1957-03-05 | 1961-01-04 | American Sulphur And Refining | Solvent extraction of sulphur |
US3063817A (en) * | 1958-02-07 | 1962-11-13 | Charles H Simpson | Process for extracting sulphur from material containing elemental sulphur |
US3535089A (en) * | 1968-09-12 | 1970-10-20 | Jean Mcpherson | Sulfur extraction using trichloroethylene in presence of limestone,trona,and soda ash |
US3607143A (en) * | 1968-06-24 | 1971-09-21 | Alscoke Ltd | Sulfur extraction by sequential contact with vapor and with liquid perchloroethylene |
GB1274737A (en) * | 1968-09-12 | 1972-05-17 | Brameda Resources Ltd | Process and apparatus for the separation of sulfur from elemental sulfur bearing ores |
US3997355A (en) * | 1974-03-18 | 1976-12-14 | Chevron Research Company | Sulfur composition |
US4076505A (en) * | 1976-11-22 | 1978-02-28 | Mobil Oil Corporation | Coal desulfurization process |
-
1981
- 1981-05-26 US US06/266,631 patent/USRE32454E/en not_active Expired - Lifetime
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1963921A (en) * | 1933-01-07 | 1934-06-19 | Delaware Chemical Engineering | Extracting sulphur |
US2785059A (en) * | 1953-02-26 | 1957-03-12 | American Sulphur & Refining Co | Solvent extraction of sulphur |
US2897065A (en) * | 1956-06-18 | 1959-07-28 | Gulf Research Development Co | Recovery of elemental sulfur from sulfur bearing solid mineral matter |
GB858056A (en) * | 1957-03-05 | 1961-01-04 | American Sulphur And Refining | Solvent extraction of sulphur |
US3063817A (en) * | 1958-02-07 | 1962-11-13 | Charles H Simpson | Process for extracting sulphur from material containing elemental sulphur |
US3607143A (en) * | 1968-06-24 | 1971-09-21 | Alscoke Ltd | Sulfur extraction by sequential contact with vapor and with liquid perchloroethylene |
US3535089A (en) * | 1968-09-12 | 1970-10-20 | Jean Mcpherson | Sulfur extraction using trichloroethylene in presence of limestone,trona,and soda ash |
GB1274737A (en) * | 1968-09-12 | 1972-05-17 | Brameda Resources Ltd | Process and apparatus for the separation of sulfur from elemental sulfur bearing ores |
US3997355A (en) * | 1974-03-18 | 1976-12-14 | Chevron Research Company | Sulfur composition |
US4076505A (en) * | 1976-11-22 | 1978-02-28 | Mobil Oil Corporation | Coal desulfurization process |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5316751A (en) * | 1991-02-11 | 1994-05-31 | Gordon Kingsley | Methods for mine tailing clean-up using recovery technologies |
US5217503A (en) * | 1991-03-18 | 1993-06-08 | Midwest Ore Processing Company, Inc. | Process for desulfurization of coal and ores |
WO1994029411A1 (en) * | 1992-12-31 | 1994-12-22 | Sunggyu Lee | Processes for desulfurizing coal |
US5935313A (en) * | 1998-04-20 | 1999-08-10 | Ficinski; Marek B. | Building material |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: AG-CON MATERIALS OF NV, INC. A CORP OF NV Free format text: LICENSE;ASSIGNOR:BLS, A GENERAL PARTNERSHIP OF NV;REEL/FRAME:004317/0744 Effective date: 19831205 Owner name: MIDWEST ORE PROCESSING COMPANY AN IN PARTNERSHIP Free format text: LICENSE;ASSIGNOR:PURE FUEL OF NEVADA, INC. A NV CORP;REEL/FRAME:004317/0730 Effective date: 19840521 Owner name: BLS, A GENERAL PARTNERSHIP OF NV CONSISTING OF ART Free format text: ASSIGNMENT OF ASSIGNORS INTEREST. SUBJECT TO LICENSE RECITED;ASSIGNOR:STARBUCK, ARTHUR E.;REEL/FRAME:004317/0741 Effective date: 19831205 Owner name: PURE FUEL OF NEVADA, INC. A CORP OF NV Free format text: LICENSE;ASSIGNOR:BLS, A GENERAL PARTNERSHIP OF NV;REEL/FRAME:004317/0744 Effective date: 19831205 |
|
AS | Assignment |
Owner name: UFB DEVELOPMENT CORPORATION, A CORP. OF IN., INDIA Free format text: SECURITY INTEREST;ASSIGNORS:PURE FUEL OF NEVADA, INC., A CORP. OF NV.;MIDWEST ORE PROCESSING COMPANY, AN INDIANA PARTNERSHIP;AG-CON MATERIALS OF NEVADA, A CORP. OF NV.;REEL/FRAME:005267/0162 Effective date: 19900228 |