USRE27969E - Hc-co(ch,cho)xh - Google Patents
Hc-co(ch,cho)xh Download PDFInfo
- Publication number
- USRE27969E USRE27969E US27969DE USRE27969E US RE27969 E USRE27969 E US RE27969E US 27969D E US27969D E US 27969DE US RE27969 E USRE27969 E US RE27969E
- Authority
- US
- United States
- Prior art keywords
- compound
- alkyl
- phosphorus
- compounds
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 abstract description 66
- 239000002253 acid Substances 0.000 abstract description 34
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 30
- 239000011574 phosphorus Substances 0.000 abstract description 30
- 238000000034 method Methods 0.000 abstract description 25
- 238000006243 chemical reaction Methods 0.000 abstract description 24
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 20
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract description 19
- -1 CARBOXYL GROUP Chemical group 0.000 abstract description 15
- 239000004814 polyurethane Substances 0.000 abstract description 8
- 229920002635 polyurethane Polymers 0.000 abstract description 8
- 238000002360 preparation method Methods 0.000 abstract description 5
- 150000003018 phosphorus compounds Chemical class 0.000 abstract description 3
- 125000000217 alkyl group Chemical group 0.000 description 40
- 229910052739 hydrogen Inorganic materials 0.000 description 34
- 239000001257 hydrogen Substances 0.000 description 33
- 125000004432 carbon atom Chemical group C* 0.000 description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 22
- 150000008064 anhydrides Chemical class 0.000 description 22
- 230000008569 process Effects 0.000 description 22
- 239000000203 mixture Substances 0.000 description 19
- 239000000047 product Substances 0.000 description 17
- 125000002947 alkylene group Chemical group 0.000 description 12
- 125000003118 aryl group Chemical group 0.000 description 12
- 150000002431 hydrogen Chemical class 0.000 description 11
- 238000007792 addition Methods 0.000 description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 10
- 150000002903 organophosphorus compounds Chemical class 0.000 description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- 125000001931 aliphatic group Chemical group 0.000 description 8
- 125000003545 alkoxy group Chemical group 0.000 description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 7
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000005056 polyisocyanate Substances 0.000 description 5
- 229920001228 polyisocyanate Polymers 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 125000003710 aryl alkyl group Chemical group 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 125000001309 chloro group Chemical group Cl* 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 3
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- WLJVNTCWHIRURA-UHFFFAOYSA-N Heptanedioic acid Natural products OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N Suberic acid Natural products OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- QHWKHLYUUZGSCW-UHFFFAOYSA-N Tetrabromophthalic anhydride Chemical compound BrC1=C(Br)C(Br)=C2C(=O)OC(=O)C2=C1Br QHWKHLYUUZGSCW-UHFFFAOYSA-N 0.000 description 2
- NGFFLHMFSINFGB-UHFFFAOYSA-N [chloro(methoxy)phosphoryl]oxymethane Chemical compound COP(Cl)(=O)OC NGFFLHMFSINFGB-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 150000003017 phosphorus Chemical class 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000011496 polyurethane foam Substances 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical class O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 1
- KAUDXYPROPQHMN-UHFFFAOYSA-N 3-[[chloro(2-ethylhexoxy)phosphoryl]oxymethyl]heptane Chemical compound CCCCC(CC)COP(Cl)(=O)OCC(CC)CCCC KAUDXYPROPQHMN-UHFFFAOYSA-N 0.000 description 1
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 1
- 235000003625 Acrocomia mexicana Nutrition 0.000 description 1
- 244000202285 Acrocomia mexicana Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 101150065749 Churc1 gene Proteins 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- INWVTRVMRQMCCM-UHFFFAOYSA-N N=C=O.N=C=O.C=1C=CC=CC=1C(C)(C)C1=CC=CC=C1 Chemical compound N=C=O.N=C=O.C=1C=CC=CC=1C(C)(C)C1=CC=CC=C1 INWVTRVMRQMCCM-UHFFFAOYSA-N 0.000 description 1
- GQSIVKYXTYPKIX-UHFFFAOYSA-N N=C=O.N=C=O.C=1C=CC=CC=1C(Cl)(Cl)C1=CC=CC=C1 Chemical compound N=C=O.N=C=O.C=1C=CC=CC=1C(Cl)(Cl)C1=CC=CC=C1 GQSIVKYXTYPKIX-UHFFFAOYSA-N 0.000 description 1
- JEQBFCJBVVFPGT-UHFFFAOYSA-N N=C=O.N=C=O.N=C=O.C1=CC=C(C=CC=C2)C2=C1 Chemical compound N=C=O.N=C=O.N=C=O.C1=CC=C(C=CC=C2)C2=C1 JEQBFCJBVVFPGT-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 102100038239 Protein Churchill Human genes 0.000 description 1
- 239000004280 Sodium formate Substances 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 101150061302 och1 gene Proteins 0.000 description 1
- 125000005429 oxyalkyl group Chemical group 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5075—Polyethers having heteroatoms other than oxygen having phosphorus
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/091—Esters of phosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
- C08G18/4684—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing phosphorus
Definitions
- Phosphorus-containing compounds which are useful in the preparation of polyurethanes and which are derived from (1) phosphorus compounds containing at least one active function, (2) alkylene oxides or epihalohydrin and (3) dicarboxylic acid anhydrides are provided.
- the compounds are those prepared by reacting a dicarboxylic acid anhydride with a phosphorus acid which has been partially or completely reacted with an alkylene oxide or epihalohydrin, followed by reaction of the carboxyl group thus formed with additional alkylene oxide or epihalohydrin. Methods for preparation of the compounds are also provided.
- This invention relates to new and novel phosphorus compounds and to a process for their manufacture. More particularly, the invention is concerned with compounds prepared from compounds of phosphorus containing at least one active site, dicarboxylic acid anhydrides, alcohols, phenols, and alkylene oxides or epihalohydrins.
- R is a member of the group consisting of (lower) alkoxy (lower) alkyl, alkyl containing from 1 to 18 carbon atoms, aryl, alkyl-substituted aryl, wherein the alkyl contains from 1 to 18 carbon atoms, chloro-substituted aryl bromo-substituted aryl, aralkyl, and
- R is a member of the group consisting of hydrogen
- alkyl containing from 1 to 18 carbon atoms containing from 1 to 18 carbon atoms
- pheny R" is a member of the group consisting of alkyl containiug from 1 to 13 carbon atoms and (lower) alkoxy (lower) alkyl;
- A is the nucleus of a member of the group consisting of aromatic dicarboxylic anhydrides and aliphatic dicarboxylic anhydrides;
- D is a member of the group consisting of hydrogen, lower alkyl and chloro (lower) alkyl;
- F is a member of the group consisting of hydrogen and G is a member of the group consisting of hydrogen and wherein R and R are as hereinabove defined and a and b are as hereinafter defined;
- a and b are each 0 to 2 their sum being 2;
- r, s, and t are, respectively, 0 to 2, 0 to 2 and 1 to 3, their sum being 3;
- W is the hydrocarbyl nucleus of a polyhydroxy compound containing from 2 to 4 hydroxyls
- x has an average value of from about 1.0 to about 5.0;
- z is an integer corresponding to the number of hydroxyls in W.
- the second class of compounds contemplated by the present invention is prepared by the simultaneous reaction of an aromatic or aliphatic dicarboxylic acid anhydride, a compound of phosphorus containing at least one reactive hydrogen atom, and an alkylene oxide.
- the compounds of this class are monomeric with respect to each reactive hydrogen and anhydride, they are neutral, and they may contain as many anhydrides as there are active hydrogens in the phosphorus compound used.
- the following members will illustrate the scope contemplated by this second class.
- the compounds of this class my be prepared in a three-step process, involving (1) the oxyalkylation of the phosphorus compound, (2) the reaction of the product thus formed with the anhydride, and (3) the neutralization of this product with additional alkylene oxide.
- (1) abve can be prepared using the three-step process essentially in the following manner:
- these compounds may be prepared by the simultaneous reaction of a phosphorus compound, an anhydride, and an alkylene oxide.
- the products formed in this manner are similar to those obtained using the above-outlined three-step process. This was surprising in view of the normally expected sequence of reactions in a system containing the named components, since the very nature of these reactions would logically exclude any expectation of discrete chemicals.
- alkylene oxides will react with the acid functions of a phosphorus acid to yield a compound which is terminated with one or more hydroxyl groups. It is further known that the active hydrogen thus formed will react with an anhydride, opening its ring to give an ester group and a carboxyl group. In the presence of alkylene oxide, one would expect this carboxyl to compete with the phosphorus acid for oxide addition. If this were to occur there would exist a different ester capable of reacting with the anhydride present, the ester portion being attached to one position of the ruptured ring and another carboxyl being formed at the other position. If this process were repeated many times during the course of a reaction involving the named materials, one would obtain a polymeric product, not one which is essentially monomeric, ie one similar to a product obtained from the three step [stop] process given hereinbefore.
- the single-step, or simultaneous, process for the production of the chemicals of this class does not necessarily mean that all of the anhydride, phosphorus compound and alkylene oxide are brought together initially. This may be impracticable in view of the extreme reactivity of the phosphorus acid and oxide.
- the preferred reaction order involves mixing the anhydride and phosphorus acid, followed by the step-wise addition of oxide to this mixture. It will be obvious, however, that any equivalent variation of this, such as mixing anhydride and oxide, with subsequent addition of phosphorus acid to this mixture, can be used and still be within the one-step process contemplated by the present invention.
- a dicarboxylic acid anhydride and acid of phosphorus are placed together within a pressure apparatus.
- Alkylene oxide is then fed into the mixture, the addition thereof is begun at room temperature, and the heat of reaction is allowed to carry the temperature to -95 C., the temperature of reaction being maintained at or near the top of this range until all of the oxide is added.
- the mixture may be heated to [form] from 70 to C. prior to beginning addition of oxide.
- excess oxide preferably in a total molar ratio of (2 to 2.5) times the number of acid functions to be neutralized is fed into the reaction vessel, the temperature is raised to l20l25 C. and maintained there for from 1 to 8 hours to complete neutralization of the carboxyl hydrogens formed upon the reaction between the alkoxylated acid and anhydride. Excess oxide is removed in vacuo. The mixture is continously stirred throughout the reaction.
- the temperature of reaction may be as high as about 160 C. during the process without any adverse eflects on the desired product, but is usually, and preferably, within the range of about 80 to about C.
- the times to complete the reaction will vary with the temperature used, and with the kind and amount of anhydride employed, but will generally run from about 1 to 8 hours. If the temperature of the reaction is permitted to exceed about C., it will have a detrimental eifect on the product. Since it is known that high temperatures are required for esterwherein R, R, a and b is as defined hereinbefore and Hal is halogen. Generally, this is done by reacting a quantity of equivalent to the amount of hydroyls present in the compound in question.
- dicarboxylic acid anhydrides which are suitable for the purposes of this invention are:
- ALIPHATIC ANHYDRIDES Adipic, azelic, glutaric, suheric, itaconic, pimelic, suecinic, acetonedicarboxylic, maleic, chloromaleic, dichioromaleic (and other halo-substituted aliphatic), dimethylmaleic, n-decylsuccinic (and other alkylsubstituted anhydrides wherein the alkyl has from 1 to 12 carbon atoms), hydrophthalic (as dihydrophthalic, tetrahydrophthalic and hexahydrophthalic), endomethylene phthalic, camphoric, 5-norbornene-2, and chlorendic [l,4,5,6,7,7-hexachlorobicyclo- (2,2,2) -5-heptene-2,S-dicarboxylic]
- AROMATIC ANHYDRIDES Phthalic, 3-chlorophthalic, 4-chlorophthalic, tet
- PHOSPHORUS ACIDS [Unsubstituted phosphoric, pyrophosphoric, and polyphosphoric acids] acids PHOSPHONIC ACID RP( 0) 0H OR where R is methyl, ethyl, propyl, butyl, pentyl, hexyl, octyl, decyl, dodecyl, octadecyl, and phenyl;
- R and R are selected from methyl, ethyl, propyl, butyl, pentyl, hexyl, octyl, nonyl, decyl, dodecyl, octadecyl, and phenyl.
- R,P(0)OH where R is methyl, ethyl, propyl, butyl, pentyl, hexyl, and phenyl.
- epoxides may be ethylene oxide, propylene oxide, butylene oxide and epichlorohydrin.
- the hexane was removed in vacuo to a final pot temperature of 125 C. and a final pressure of 10 mm. of Hg.
- the product a clear, light golden yellow liquid, had the following properties:
- EXAMPLE 2 0 can (CHIO)2P(O)C1 G 0(CH3CH1) mi 0 0 C li l 4101 EO(CHQCHIO)LIIP(O) (0011;): N/
- the product had an acid number of 126 mg. KOH/gm.
- the product was heated for a further hour at 119-423 C., after which the acid content was 0.9 mg. KOH/gm.
- Excess oxide was removed in vacuo, the final pot temperature being 110' C., at mm. Hg.
- the product a golden brown, viscous liquid, had the following properties:
- reaction products of mixtures of phosphoric acids such as those obtained from the reaction of alcohols or phenols with P 0 with anhydrides and oxides are embodied herein. This is in addition to the individual members of the mixtures which are set forth in the examples which follow.
- C(CH corresponds to W, defined hereinabove, and is derived from tetravalent pentaerythritol.
- Other radicals which are at least divalent may be derived from ethylene glycol, propylene glycol, butylene glycol, glycerol, trimethylol ethane, trimethylol propane, and similar compounds.
- the new compounds especially those containing at least one active hydrogen per molecule, have been found to be useful as flame retardants for polyurethane foams and resins. They markedly improve the flame properties of polyurethanes without any adverse effect on the polymer itself.
- the degree of fire-retardance will depend upon the amount of phosphorus per se in the finished polyurethane, but as a general statement the compounds of the present invention will be effective at phosphorus concentrations of about 0.5% to about 5.0%, with the preferred amount falling with the range of from about 1.0% to about 3.0%.
- the compound, or a mixture thereof with a normally used polyol is mixed with a catalyst and a surfactant, and this is blended with a polyisocyanate, whereupon reaction occurs to produce a polyurethane polymer. If a foam is desired, a slight excess of polyisocyanate will be present in the mixture to be reacted with water (which produces CO upon reaction with the excess NCO, thereby supplying the foaming agent).
- stoichiometric NCO may be used, and a low boiling inert liquid, such as a chlorofluorocarbon, may take the place of the internally produced CO
- a low boiling inert liquid such as a chlorofluorocarbon
- polyisocyanates which are useful are those which are well-known in the polyurethane art, and no elaborate discussion of them is believed necessary. As examples, however, the following polyisocyanates may be used to advantage with the inventive compounds. They are: tolylene diisocyanate (a commercial mixture of the 2,4- and the 2,6-ismers); polymethylene polyphenyl isocyanate, having the formula at a where n is greater than zero; hexamethylene diisocyanate; naphthalene-1,S-diisocyanate; naphthalene triisocyanate; dichloro diphenyl methane diisocyanate; dimethyl diphenylmethane diisocyanate, and other aromatic or aliphatic polyisocyanates containing 2 or more functional or isocyanate groups.
- tolylene diisocyanate a commercial mixture of the 2,4- and the 2,6-ismers
- polymethylene polyphenyl isocyanate having the formula at a where n
- EXAMPLE [35] 32 One hundred and eighty-four parts of propoxylated sucrose having about 1.2 oxypropylenes per equivalent of hydroxyl, 139 parts of the mixture of Example [27,] 24, 4 parts of a silicone-type surfactant L-5310, 3 parts of triethylenediamine catalyst and 87 parts of trichlorofluoromethane were blended together by stirring. To this mixture was added 250 parts of PAP] (polymethylene polyphenyl isocyanate), and this total mixture was stirred vigorously for 23 seconds and poured into a container for foaming. The foam was fully risen and tack free in 98 seconds. It was allowed to stand overnight.
- PAP polymethylene polyphenyl isocyanate
- the product a rigid foam, was fine-celled, and had a density of 2.5 pounds per cubic foot. It had good hydrolytic and dimensional stability at both high humidities (up to 100%) and high temperatures (l00-l20 C.). The foam burned less than one inch when tested according to ASTM D-l692.
- a control prepared from the agents of this example, less the phosphorus-containing compound, was non-selfextinguishing when tested in accordance with ASTM D-l692.
- the chemicals of this invention are also useful as flame retardants and plasticizers for vinyl resins, polyesters, and the like.
- x is an average value which, when multiplied by the number of xs in the molecule, will enable one to determine the actual amount of oxyalkyl present in the chemical in question.
- the values of x in the appended claims are to be interpreted in view of this explanation.
- R is a member of the group consisting of hydrogen, alkyl containing from 1 to 18 carbon atoms, and phenyl;
- R" is a member of the group consisting of alkyl containing from 1 to 13 carbon atoms and (lower) alkoxy (lower) alkyl;
- A is the nucleus of a member selected from the group consisting of aromatic dicarboxylic acid anhydrides and aliphatic dicarboxylic acid anhydrides;
- D is a member of the group consisting of hydrogen
- a and b are each 0 to 2, their sum being 2;
- r, s, and t are, respectively, 0 to 2, 0 to 2 and 1 to 3,
- W is the hydrocarbyl nucleus of a polyhydroxy compound containing from 2 to 4- hydroxyls
- x has an average value of from about 1.0 to about 5.0;
- z is an integer corresponding to the number of hydroxyls in W[.],
- G is hydrogen, .9 is at least 1.
- A is the nucleus of a dicarboxylic acid anhydride selected from the group consisting of (1) phthalic, halogen-substituted phthalic, nitro substituted phthalic, alkyl substituted phthalic, homophthalic, naphthalic, (2) adipic, azelaic, glutanic, snberic, itaconic, pimelic, succinic, maleic, (3) the halogen-substituted and alkyl-substituted members of the aforesaid group (2), (3) chlorendic, hydrophthalic, and endomethylene phthalic anhydrides.
- a dicarboxylic acid anhydride selected from the group consisting of (1) phthalic, halogen-substituted phthalic, nitro substituted phthalic, alkyl substituted phthalic, homophthalic, naphthalic, (2) adipic, azelaic, glutanic, snberic, itaconic,
- An organo-phosphorus compound selected from the formulas 0 ion" (B!)-
- R is a member of the group consisting of hydrogen, alkyl containing from 1 to 18 carbon atoms, and phenyl;
- R" is a member of the group consisting of alkyl containing from 1 to 13 carbon atoms and (lower) alkoxy (lower) alkyl;
- A is the nucleus of a member selected from the group consisting of phthalic, chloro-substituted phthalic, bromo-substituted phthalic, iodo-substituted phthalic, nitro-substituted phthalic, alkyl-substituted phthalic wherein the alkyl contains from 1 to 12 carbon atoms, homophthalic and naphthalic anhydrides;
- D is a member of the group consisting of hydrogen
- CH3, C2H5 and F is a member of the group consisting of hydrogen and G is a member of the group consisting of hydrogen and wherein R and R are as hereinbefore defined, and
- a and b are as defined hereinafter; a and b are each 0 to 2, their sum being 2; r, s, and t are, respectively, 0 to 2, 0 to 2 and 1 to 3,
- W is the hydrocarbyl nucleus of a polyhydroxy compound containing from 2 to 4 hydroxyls
- x has an average value of from about 1.0 to about 5.0
- z is an integer corresponding to the number of hydroxyls in W. provided that where G is hydrogen, [S] is at least 1.
- the compound of claim 4 having the structure B1 CH: Br 930(61101-130 IJ P(O)(OCHJ)I 9.
- A is the nucleus of a member selected from the group consisting of hydrophthalic, endomethylene phthalic, camphoric, -norbornene-2, and chlorendic anhydrides
- D is a member of the group consisting of hydrogen, CH C- -H and CICHg.
- A is the nucleus of a member selected from the group consisting of: (1) adipic, azelaic, glutaric, suberic, itaconic, pimelic, and succinic acid anhydrides; (2) the chloro-substituted members of (1); and (3) the alkyl-substituted members of (I), wherein alkyl contains from 1 to 12 carbon atoms; and D is selected from the group consisting of hydrogen, CH3, CQH5, and ClCH 12.
- Formula 2 wherein r is 0, R is methyl, G is hydrogen, D is CH; and A is the nucleus of maleic anhydride.
- the compound of claim 12 having the structure [17.
- the process of claim 18 which comprises the steps of mixing the dicarboxylic acid anhydride and phosphorus compound and subsequently adding said oxide thereto, the oxide being in excess of the amount necessary to react with all of the acid functions of the said phosphorus compound and the subsequently formed carboxyl group, at temperatures sufiiciently high to react the said oxide and the said acid functions, and removing the excess oxide from the organo-phosphorus compound thus formed] 26.
- An organo-phosphorus compound formula 0 boa" (R'). LOO(CH,CHO) (O) D r( lh wherein:
- R is a member of the group consisting of (lower) alkoxy (lower) alkyl, alkyi containing from 1 to 18 carbon atoms, aryl, alkyl-substituted aryl wherein the alkyl contains from I to l 8 carbon atoms, chloro-substituted aryl, homo-substituted aryl, aralkyl, and
- R is a member of the group consisting of hydrogen, alkyl containing from 1 to 18 carbon atoms, and phenyl;
- R" is a member of the group consisting of alkyl conraining from I to 13 carbon atoms and (low'er) alkoxy (lower) alkyl;
- A is the nucleus of a member selected from the group consisting of aromatic dicarboxylic acid anhydrides and aliphatic dicarboxylic acid anhydrides;
- D is a member of the group consisting of hydrogen
- 0 and b are each 0 to 2, their sum being 2;
- z has an average value of from about 1.0 to about 5.0.
- R is a member of the group consisting of (lower) all:-
- alkyl containing from I to 18 carbon atoms, aryl, alkyl-substituted aryl wherein the alkyl contains from 1 to 18 carbon atoms, chloro-substituted aryl, bronze-substituted aryl, aralkyl, and
- R is a member of the group consisting of hydrogen, alkyl containing from I to 18 carbon atoms, and phenyl;
- alkyl containing from 1 to 13 carbon atoms, and (lower) alkoxy (lower) alkyl;
- a and b are as defined hereinafter; a and b are each 0 to 2, their sum being 2; W is the hydrocarbyl nucleus of a polyhya'roxy compound containing from 2 to 4 hydroxyls; x has an average value of from about 1.0 to about 5.0,-
- z is an integer corresponding to the number of hydroxyls in W.
- D H H l i CH should read --CH--. line &5, "abve” should read --ahove--. line 23, "hydroyls” should read --hydroxyls--. line 7, 2,2,2)” should read "(2,2,1)”. line 5, and other alkyl-substituted) should --(and other alkyl-substituted phthalics Where the alkyl has from 1 to 12 carbon atoms line 52, "dialkyl' should read -dialkyl--.
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Abstract
PHOSPHORUS-CONTAINING COMPOUNDS WHICH ARE USEFUL IN THE PREPARATION OF POLYURETHANES AND WHICH ARE DERIVED FROM (1) PHOSPHORUS COMPOUNDS CONTAINING AT LEAST ONE ACTIVE FUNCTION (2) ALKYLENE OXIDES OR EPIHALOHYDRIN AND (3) DICARBOXYLIC ACID ANHYDRIDES ARE PROVIDED. AMONG THE COMPOUNDS ARE THOSE PREPARED BY REACTING A DICARBOXYLIC ACID ANHYDRIDE WITH A PHOSPHORUS ACID WHICH HAS BEEN PARTIALLY OR COMPLETELY REACTED WITH AN ALKYLENE OXIDE OR EPIHALOHYDRIN, FOLLOWED BY REACTION OF THE CARBOXYL GROUP THUS FORMED WITH ADDITIONAL ALKYLENE OXIDE OR EPIHALOHYDRIN. METHODS FOR PREPARATION OF THE COMPOUNDS ARE ALSO PROVIDED.
Description
United States Patent Re. 27,969 Reiasued Apr. 16, 1974 Office Matter enclosed in heavy brackets [1 appears in the original patent but forms no part of this reissue specification; matter printed in italics indicates the additions made by reissue.
ABSTRACT OF THE DISCLOSURE Phosphorus-containing compounds which are useful in the preparation of polyurethanes and which are derived from (1) phosphorus compounds containing at least one active function, (2) alkylene oxides or epihalohydrin and (3) dicarboxylic acid anhydrides are provided. Among the compounds are those prepared by reacting a dicarboxylic acid anhydride with a phosphorus acid which has been partially or completely reacted with an alkylene oxide or epihalohydrin, followed by reaction of the carboxyl group thus formed with additional alkylene oxide or epihalohydrin. Methods for preparation of the compounds are also provided.
This invention relates to new and novel phosphorus compounds and to a process for their manufacture. More particularly, the invention is concerned with compounds prepared from compounds of phosphorus containing at least one active site, dicarboxylic acid anhydrides, alcohols, phenols, and alkylene oxides or epihalohydrins. Specifically the compounds of the present invention are represented by the formulas R is a member of the group consisting of (lower) alkoxy (lower) alkyl, alkyl containing from 1 to 18 carbon atoms, aryl, alkyl-substituted aryl, wherein the alkyl contains from 1 to 18 carbon atoms, chloro-substituted aryl bromo-substituted aryl, aralkyl, and
wherein D and x are hereinafter defined;
R is a member of the group consisting of hydrogen,
alkyl containing from 1 to 18 carbon atoms, and pheny R" is a member of the group consisting of alkyl containiug from 1 to 13 carbon atoms and (lower) alkoxy (lower) alkyl;
A is the nucleus of a member of the group consisting of aromatic dicarboxylic anhydrides and aliphatic dicarboxylic anhydrides;
D is a member of the group consisting of hydrogen, lower alkyl and chloro (lower) alkyl;
F is a member of the group consisting of hydrogen and G is a member of the group consisting of hydrogen and wherein R and R are as hereinabove defined and a and b are as hereinafter defined;
a and b are each 0 to 2 their sum being 2;
r, s, and t are, respectively, 0 to 2, 0 to 2 and 1 to 3, their sum being 3;
W is the hydrocarbyl nucleus of a polyhydroxy compound containing from 2 to 4 hydroxyls;
x has an average value of from about 1.0 to about 5.0;
and
z is an integer corresponding to the number of hydroxyls in W.
provided that when G is hydrogen, .1 is at least I.
There are several categories of chemicals which fall within the above generic definition, but for purposes of illustrating this invention, three will be discussed in general and specific terms, particularly with respect to methods for their preparation.
The simplest class of products falling within the above generic definitions may be represented by the compound 0 0 (CHIsCIHOLi (OCHa):
which is prepared by (1) reacting phthalic anhydn'de with an equimolar quantity of methyl alcohol, (2) neutralizing the acid function thus formed with propylene oxide, and (3) reacting this neutral product with dimethyl phosphorochloridate, in the presence of a halogen acid acceptor, if desired. Whereas the particular phosphorus-containing compound shown is a derivative of phosphoric, the class, as is evident from the generic formulas shown above, includes phosphorus-containing compounds which have one or two carbon-to-phosphorus bonds in the molecule,
The second class of compounds contemplated by the present invention is prepared by the simultaneous reaction of an aromatic or aliphatic dicarboxylic acid anhydride, a compound of phosphorus containing at least one reactive hydrogen atom, and an alkylene oxide. The compounds of this class are monomeric with respect to each reactive hydrogen and anhydride, they are neutral, and they may contain as many anhydrides as there are active hydrogens in the phosphorus compound used. The following members will illustrate the scope contemplated by this second class.
(CHICHO] H and the same type of compound wherein one [or both] of the right-hand phosphorous ester portions may be replaced with one [or two] aromatic or aliphatic groups bound to carbon.
O(CHzCHO);H
O CH: CH; O atimolmmms toa The compounds of this class my be prepared in a three-step process, involving (1) the oxyalkylation of the phosphorus compound, (2) the reaction of the product thus formed with the anhydride, and (3) the neutralization of this product with additional alkylene oxide. For example, (1) abve can be prepared using the three-step process essentially in the following manner:
0 (CHaO):P(O)O(CHgCHO);
(b) CH; CHCH,
O (C s h 0 (FHOh It is obvious from this series of steps that only discrete molecules are possible, since under normal conditions the carboxyl groups formed in step (b) will not react with the remaining anhydride to open its ring, nor with a1coholic OH groups present in the mixture to form additional polyester links by splitting out water.
As mentioned previously, these compounds may be prepared by the simultaneous reaction of a phosphorus compound, an anhydride, and an alkylene oxide. The products formed in this manner are similar to those obtained using the above-outlined three-step process. This was surprising in view of the normally expected sequence of reactions in a system containing the named components, since the very nature of these reactions would logically exclude any expectation of discrete chemicals.
It is well-known that alkylene oxides will react with the acid functions of a phosphorus acid to yield a compound which is terminated with one or more hydroxyl groups. It is further known that the active hydrogen thus formed will react with an anhydride, opening its ring to give an ester group and a carboxyl group. In the presence of alkylene oxide, one would expect this carboxyl to compete with the phosphorus acid for oxide addition. If this were to occur there would exist a different ester capable of reacting with the anhydride present, the ester portion being attached to one position of the ruptured ring and another carboxyl being formed at the other position. If this process were repeated many times during the course of a reaction involving the named materials, one would obtain a polymeric product, not one which is essentially monomeric, ie one similar to a product obtained from the three step [stop] process given hereinbefore.
The single-step, or simultaneous, process for the production of the chemicals of this class does not necessarily mean that all of the anhydride, phosphorus compound and alkylene oxide are brought together initially. This may be impracticable in view of the extreme reactivity of the phosphorus acid and oxide. Thus, the preferred reaction order involves mixing the anhydride and phosphorus acid, followed by the step-wise addition of oxide to this mixture. It will be obvious, however, that any equivalent variation of this, such as mixing anhydride and oxide, with subsequent addition of phosphorus acid to this mixture, can be used and still be within the one-step process contemplated by the present invention.
In practicing the preferred form of the process for producing this second class of chemicals, a dicarboxylic acid anhydride and acid of phosphorus are placed together within a pressure apparatus. Alkylene oxide is then fed into the mixture, the addition thereof is begun at room temperature, and the heat of reaction is allowed to carry the temperature to -95 C., the temperature of reaction being maintained at or near the top of this range until all of the oxide is added. Alternatively, the mixture may be heated to [form] from 70 to C. prior to beginning addition of oxide. Upon the completion of this initial reaction, excess oxide, preferably in a total molar ratio of (2 to 2.5) times the number of acid functions to be neutralized is fed into the reaction vessel, the temperature is raised to l20l25 C. and maintained there for from 1 to 8 hours to complete neutralization of the carboxyl hydrogens formed upon the reaction between the alkoxylated acid and anhydride. Excess oxide is removed in vacuo. The mixture is continously stirred throughout the reaction.
The temperature of reaction may be as high as about 160 C. during the process without any adverse eflects on the desired product, but is usually, and preferably, within the range of about 80 to about C. The times to complete the reaction will vary with the temperature used, and with the kind and amount of anhydride employed, but will generally run from about 1 to 8 hours. If the temperature of the reaction is permitted to exceed about C., it will have a detrimental eifect on the product. Since it is known that high temperatures are required for esterwherein R, R, a and b is as defined hereinbefore and Hal is halogen. Generally, this is done by reacting a quantity of equivalent to the amount of hydroyls present in the compound in question.
Included among the dicarboxylic acid anhydrides which are suitable for the purposes of this invention are:
ALIPHATIC ANHYDRIDES Adipic, azelic, glutaric, suheric, itaconic, pimelic, suecinic, acetonedicarboxylic, maleic, chloromaleic, dichioromaleic (and other halo-substituted aliphatic), dimethylmaleic, n-decylsuccinic (and other alkylsubstituted anhydrides wherein the alkyl has from 1 to 12 carbon atoms), hydrophthalic (as dihydrophthalic, tetrahydrophthalic and hexahydrophthalic), endomethylene phthalic, camphoric, 5-norbornene-2, and chlorendic [l,4,5,6,7,7-hexachlorobicyclo- (2,2,2) -5-heptene-2,S-dicarboxylic] AROMATIC ANHYDRIDES Phthalic, 3-chlorophthalic, 4-chlorophthalic, tetrachlorophthalic, 3-bromophthalic, 4-bromophthalic, tetrahromophthalic, S-iodophthalic, 4-iodophthalic (and other halo-substituted phthalics), 3-nitrophthalic (and other nitro-substituted phthalics), B-methylphthalic, 4-methylphthalic (and other alkyl-substituted), homophthalic, and naphthalic.
Included among the phosphorus acids are:
PHOSPHORUS ACIDS [Unsubstituted phosphoric, pyrophosphoric, and polyphosphoric acids] acids PHOSPHONIC ACID RP( 0) 0H OR where R is methyl, ethyl, propyl, butyl, pentyl, hexyl, octyl, decyl, dodecyl, octadecyl, and phenyl;
RP(O) 0H(OR') where R and R are selected from methyl, ethyl, propyl, butyl, pentyl, hexyl, octyl, nonyl, decyl, dodecyl, octadecyl, and phenyl.
6 PHOSPHINIC ACID lt wmn where R is methyl, ethyl, propyl, butyl, pentyl, hexyl, octyl, decyl, dodecyl, and octadecyl;
R,P(0)OH where R is methyl, ethyl, propyl, butyl, pentyl, hexyl, and phenyl.
The following examples will illustrate the compounds of the present invention. It is to be understood, however, that they are merely for the purpose of illustration, and are not necessarily to limit the invention.
EPOXIDES o eth c!!!) where D is hydrogen, CH cgH5 and CICH,, that is,
where the epoxides may be ethylene oxide, propylene oxide, butylene oxide and epichlorohydrin.
EXAMPLE 1 t i1 ):P(O)Cl I ocnHu Ethoxylated tridecyl acid phthalate, 344.6 parts, pyridine, 69.6 parts, and hexane, 395 parts, were placed in means for cooling. 274.2 parts of bis(2-ethylhexyl) phosphorochloridate was added to this solution, with stirring, at 10 C. or below. When the addition was completed, the cooling means was removed, and the mixture was stirred for 2 hours and 15 minutes, after which it was washed with 1000 parts of water, then with 500 parts of 8% sodium carbonate solution, and finally with two portions of water, 1000 parts of each wash.
The hexane was removed in vacuo to a final pot temperature of 125 C. and a final pressure of 10 mm. of Hg. The product, a clear, light golden yellow liquid, had the following properties:
Total acid 3.2 mg. KOH/g. P(calculated) 4.2%; P (found) 4.3%
EXAMPLE 2 0 can (CHIO)2P(O)C1 G 0(CH3CH1) mi 0 0 C li l 4101 EO(CHQCHIO)LIIP(O) (0011;): N/
In a process similar to that of Example 1, 430.7 parts of the ethoxylated acid phthalate, 151.7 parts of dimethyl phosphorochloridate, 87.0 parts of pyridine, and 378 parts of benzene gave a product which was light yellow in color, and which had a total acid of 2.5 mg. KOH/g. Theoretical phosphorus was calculated as 5.8%; 5.1% phosphorus was detected in the product.
The following table summarizes other compounds which have been prepared using a process similar to that of Example 1.
Totai acid, P, percent mg. KOHI Density, Refractive Compound gm. 20/4 index at C. Calcd. Found Example:
3 O 0. 62 1. 289 1.4994 at 28 OCH;
i (CHzC H: )M1 3):
EOC H C 0(CH1CI'I10)Q.I3P(O) (0 C 2):
5 (a? 0. 44 1. 163 1.4840 at 27 COC|H11 E0 (CH:CHaO)i.aP(O) (0 CH1):
6 O 2. 39 1. 243 1.495 at 27.5
C O (CH1CHO)Q.55P(0) (0 CH1): 1; E
7 (I) 1. 50 1.198 1.4.878 at 27 doom.
C ()(CH2CHO)1.|"P(0)(OCH1)| ti 3m.
8 (I) 3.59 1. 134 1.4846 at 27 (EOCuHu ("30 (CH:CHO):P(O) (OCHa):
G0 CisHar (?O(CH=CHO)1.5P(O) (0 CH1);
(a 7.1 1.024 1.4726 at 24.--- 4.20 4. 38
C OCn M I aCHO)I-M J 01E102 11 (H) 0. 54 1. 228 1.4877 at C O CHzCHrO (34 E0(CH2CH:O)1.MP(O) (0 CH2):
6O Phthalic anhydride, 145.2 parts and 322.4 parts of his EXAMPLE 12 (Z-ethylhexyl) hydrogen phosphate were placed into a pressure apparatus equipped with a stirrer, thermometer and means for adding oxide. The mixture was heated to 70 C., and while stirring, 232.3 parts of propylene oxide was added over a period of 8 minutes. During the addition of oxide, the temperature increased to a maximum of 91 (1., and the pressure increased to 26 p.s.i. Immediately after completing the addition, the temperature dropped to 68 C. During a two hour stirring period, the temperature was carried, by external heating means, to a maximum of 102 C., the last one hour being within the range of -102" C. The maximum pressure, which increased gradually over this period, was 69 p.s.i.
At the end of this heating period, the product had an acid number of 126 mg. KOH/gm. The product was heated for a further hour at 119-423 C., after which the acid content was 0.9 mg. KOH/gm. Excess oxide was removed in vacuo, the final pot temperature being 110' C., at mm. Hg.
The product, a golden brown, viscous liquid, had the following properties:
OH (calculated), 89 mg. KOH/gm.; OH (found), 104.5
10 EXAMPLE 20 mg. KOH/gm. 0 P (calculated), 5.02%; P (found), 4.96%. 10 g Q J I 1 Density 20/4, 1.093. Refractive index at 26 C., 1.4790.
00 CH CHO B Total acid 0.14 mg. KOH/gm. 1
In a manner similar in all material aspects to Example 12, the following compounds were prepared: where x=2.25 (average).
0.. 11 1113. ac xofi P,peree t x, i fin Density, Refractive 1165/ Ex Compound avg. Caled. Found Calcd. Found /4 index 116C. gm. 1a.--- 0 1. 20 05 112.5 5.35 5.17 1.113 1.1810 at a 12 o( 0H|cH10),P(0) (0011111):
CO(CH1CH1O);H
14....- Br 0 1.34 61.5 7014 3.47 3.48 1. 536 1.5285 at 25.5.. 0.05
mowmcmohno (00111.1),
B1 CO(CH:CH:0);H
15-.- 0 0H, 1.15 113.1 107 6.36 6.31 1.124 1.4834 at 24---. 01s
ou momo monomm cowmcno n 16.-- 0 Om 1.45 93.3 5.28 1.5335at24.--- 011 mncmonrwoGcm) I CO(CHzCHO).H]
l O(JJHOHzO);P(O)(O-CH;) I c 0 cH,cH0).H
17..." '0 on; H 1.38 126.2 132.0 668 6.79 0.01
mcnomoniwo cowmonohn 1a Br 1. 21
Br 0( HCH0).P(0)(0CH1):
B CO(CH:CHO),H
10-.--- C1 0 1.0 3.82 ass 1.4958at 000 01 llowmcmo monommm (1-01 01 cowmcmomi Phthalic anhydride, 296.2 parts, 82.0 parts of phosphorus acid and 0.04 part of sodium formate were placed in a pressure apparatus equipped with a stirrer, thermometer and oxide addition means, and the mixture was heated to 70 C. 548.5 parts of propylene oxide was added to the mixture, with stirring, over a period of 4% hours, the temperature varying from about 90' C. to 134 C. The reaction mixture was then stirred for 5 hours at 120- 125' C., after which the excess oxide was removed by stripping at 120-125 C. at mm. of Hg, giving a slightly yellow, viscous product having the following properties: P (calculated) 3.44%; P (found) 3.35%. Total acid, 8.17 mg. KOH/gm.]
Additional compounds, summarized in the following table, were prepared [by a process similar to that outlined in Example 20.]
Total 1253/ 1 percent Density Refractive 1rd?) Compound new. Calod. Found Caled. Found index at'C. gm.
i. 0 OH. "I (311: 1.34 158.9 161.5 4.42 4.11 5:8:;:-I.;;:i;::;2.i53= 0.11]
OdiKCHsO). P=O
CO(CH:CHO);H L 3 (EH: 1 [3].- O OH: OC|H L85 1404 168.5 4.8 4-05 ::.-.'===r. l.5080at2l.;:= 0J3 OGBHCHsO): =O
CO(CH!CHO);H L s B OCH; L21 :i t 0 em l B pJOKBHGHsO): =0
Br cowmcnoms L 3 I511:
Br s m1- 0 001;. 1.0
O( H: Hs0)x i=0 CO(CH:CH:):H
1i m... O CH: 1.75 H5 151 2.84 2.98 37:33:22: Lmstm" La] (O(JHCHs);0-P=O 00(CH3CHOMHJ Ht 1 As is apparent from the generic formula set forth hereinbefore, reaction products of mixtures of phosphoric acids (such as those obtained from the reaction of alcohols or phenols with P 0 with anhydrides and oxides are embodied herein. This is in addition to the individual members of the mixtures which are set forth in the examples which follow.
EXAMPLE [26] 23 tcntomww 0 cntncmc G CHaOPWNOH):
0 cm pso(oncmo)- wxocmg 01-! (calculated), 146 mg. KOH/gm.; OH (found) 149 mg. KOH/ gm.
P (calculated), 5.4%; P (found), 5.08%
Density 20/ 4, 1.235
Specific gravity at 24 0, 1.5006
Total acid, 0.16 mg. KOH/gm.
The following table summarizes other mixtures obtained by processes similar in all material respects to Example [26.] 23.
--- Deuslt Refractive K I Compound ug. Cnlcd. Found Caled- Found 204 lads: atO. gm.
[271.2 0 CH; L8 171 160.5 6.82 6.25 1.238 1.4Bat25.5 0.37
- 0(41HCH|0)-P(0)(0OH:)1
H --CO(OH|CHO)H plus 0 CH: HCgO($HGH:O); -P(O)OOH; H -CO(OH;CHO);HJI
[3].. 0 CH: 1.2 158 5.85 5.52 1.175 LMBMZLH: 0.15
110- O(HCHaO)|P(O)(OU4H H C0(CH;CHO)H plus B CO(CH:CHO).H
B CO(CH:CHO);H
.. 1' Ha I [30]-- 0 CH; 1. I8 115 4. 4.16 1. 217 1.4875 at $5.. 0. 2i
0(2HCHnO)zP(O) (000 111):
O O (CILOHOJJI plus C0(CH:OHO);H
5391] O CH: 1.19 132.5 147.5 5.10 4.09 1.101 1.4610 It 20.--. 0.21
HC-MHOIhOhHO)(OOnHu-l):
HC-CO(CH CHO)|H plus 0 0H: HC-EOJJHCILO) P(O)OCnH11-l H-C0(CH:CHO):H]
III
TABLE- ContinueG Total H, mg. acid, KOH/gm. P, Percent In Density, Refractive KOIf/ Compound 1, avg. Cslcd. Found Calcd. Found /4 index at n 0. gm. [29 ('1; 0.94 143 131.5 5. 47 5. 53 0.15
00 (cntcmo ,r o (oom) C O (CHaCHaO) E plus do cinema) 1 P (0) oom C O (CHaCHzO) 1H E3031" CH: 1. B 118 83 4. 55 4t 52 1.
do (daemon? o) (oon.)
C O (CHICHO):H
plus
- O CH:
dou snomo), rtmoorn ("30(CH:CHO),H L 0 H: a
0 C 1.3 135 111 5. 1B 5. O7 0. 19
Other new and useful compounds may be prepared from the compounds of Examples 12-[31] 28 by reacting one or more of the reactive centers thereof with a compound of the formula M,P(O) Hal, wherein M and Hal are as hereinabove defined, substantially as follows.
CH: (Compound 0! Example 12) COWHaCHOhPWX This type of compound may also be obtained from oxyalkylated dicarboxylic acids and the appropriate chloridate. Thus, by reacting 373 parts of 0 E0 (UIh HI kuH C 0 (CHICHIO )uiH in methylene chloride with 146.2 parts of (CH O),P(O)Cl at 10 C. or below, there is obtained the compound C0 (CHaOHaOhmP (0) (001-15)! having a total acid number of 0.55 and a refractive index of 1.4966 at 25 C.
Additional non-limiting examples of this general class compounds are summarized in the following table.
Moles o! R! R! i 0 Hal 1 0 Hal Compound 0! Example B R 13 (CsHa0)|P(O)Cl 1 7 pounds contemplated, and it is not to be considered as a limitation on the invention with respect thereto.
In this compound, C(CH corresponds to W, defined hereinabove, and is derived from tetravalent pentaerythritol. Other radicals which are at least divalent may be derived from ethylene glycol, propylene glycol, butylene glycol, glycerol, trimethylol ethane, trimethylol propane, and similar compounds.
The new compounds, especially those containing at least one active hydrogen per molecule, have been found to be useful as flame retardants for polyurethane foams and resins. They markedly improve the flame properties of polyurethanes without any adverse effect on the polymer itself. The degree of fire-retardance will depend upon the amount of phosphorus per se in the finished polyurethane, but as a general statement the compounds of the present invention will be effective at phosphorus concentrations of about 0.5% to about 5.0%, with the preferred amount falling with the range of from about 1.0% to about 3.0%.
Briefly, in using the active hydrogen-containing compounds of the invention to obtain fire-retardant polyurethanes, the compound, or a mixture thereof with a normally used polyol, is mixed with a catalyst and a surfactant, and this is blended with a polyisocyanate, whereupon reaction occurs to produce a polyurethane polymer. If a foam is desired, a slight excess of polyisocyanate will be present in the mixture to be reacted with water (which produces CO upon reaction with the excess NCO, thereby supplying the foaming agent). As an alternative, stoichiometric NCO may be used, and a low boiling inert liquid, such as a chlorofluorocarbon, may take the place of the internally produced CO In using the compounds of this invention which contain active hydrogens with conventional polyols, it will be obvious to those skilled in this art that the substitution must be done on the basis of active hydrogen equivalents. That is, the amount of phosphorus compound substituted must contain an amount of active hydrogen equivalent to that in the removed conventional polyol.
The polyisocyanates which are useful are those which are well-known in the polyurethane art, and no elaborate discussion of them is believed necessary. As examples, however, the following polyisocyanates may be used to advantage with the inventive compounds. They are: tolylene diisocyanate (a commercial mixture of the 2,4- and the 2,6-ismers); polymethylene polyphenyl isocyanate, having the formula at a where n is greater than zero; hexamethylene diisocyanate; naphthalene-1,S-diisocyanate; naphthalene triisocyanate; dichloro diphenyl methane diisocyanate; dimethyl diphenylmethane diisocyanate, and other aromatic or aliphatic polyisocyanates containing 2 or more functional or isocyanate groups.
The example which follows will illustrate the usefulness of the compounds of this invention as flame retardants for polyurethane foams.
EXAMPLE [35] 32 One hundred and eighty-four parts of propoxylated sucrose having about 1.2 oxypropylenes per equivalent of hydroxyl, 139 parts of the mixture of Example [27,] 24, 4 parts of a silicone-type surfactant L-5310, 3 parts of triethylenediamine catalyst and 87 parts of trichlorofluoromethane were blended together by stirring. To this mixture was added 250 parts of PAP] (polymethylene polyphenyl isocyanate), and this total mixture was stirred vigorously for 23 seconds and poured into a container for foaming. The foam was fully risen and tack free in 98 seconds. It was allowed to stand overnight.
The product, a rigid foam, was fine-celled, and had a density of 2.5 pounds per cubic foot. It had good hydrolytic and dimensional stability at both high humidities (up to 100%) and high temperatures (l00-l20 C.). The foam burned less than one inch when tested according to ASTM D-l692.
A control, prepared from the agents of this example, less the phosphorus-containing compound, was non-selfextinguishing when tested in accordance with ASTM D-l692.
In addition to their utility as flame retardant agents for polyurethanes, the chemicals of this invention are also useful as flame retardants and plasticizers for vinyl resins, polyesters, and the like.
It is understood that various other modifications will be apparent to and can be made by those having skill in this art without departing from the spirit and scope of the invention. Accordingly, it is not intended that the scope of the claims appended hereto be limited to the description and examples set forth herein, but rather that the claims be construed as encompassing all of the features of patentable novelty which reside in the present invention, including all features which would be treated as equivalents thereof by those skilled in the art to which the invention pertains.
With respect to the value of x in Examples 12 through [31,] 28, it will be further understood that the value assigned may not be the exact number of oxyalltyl units attached at the designated center. The values given for x in the various compounds, however, will not vary widely from these actual values. Each x was determined by dividing the total equivalents of alkylene oxide reacted by the number of equivalents of acid hydrogen in the reaction mixture. As an illustration, in Example 13 a total of 2.58 equivalents of ethylene oxide reacted, and this was assumed to be divided equally between the two acid hydrogens present--one from the phosphorus moiety and one from the opening of the anhydride ring. Thus x is an average value which, when multiplied by the number of xs in the molecule, will enable one to determine the actual amount of oxyalkyl present in the chemical in question. The values of x in the appended claims are to be interpreted in view of this explanation.
We claim:
1. An organo-phosphorus compound selected from the formulas wherein D and x are as hereinafter defined R is a member of the group consisting of hydrogen, alkyl containing from 1 to 18 carbon atoms, and phenyl;
R" is a member of the group consisting of alkyl containing from 1 to 13 carbon atoms and (lower) alkoxy (lower) alkyl;
A is the nucleus of a member selected from the group consisting of aromatic dicarboxylic acid anhydrides and aliphatic dicarboxylic acid anhydrides;
D is a member of the group consisting of hydrogen,
lower alkyl, and chloro (lower) alkyl;
F is a member of the group consisting of hydrogen and ($3M G is a member of the group consisting of hydrogen and 1 wherein R and R are as hereinbefore defined, and
a and b are as defined hereinafter;
a and b are each 0 to 2, their sum being 2;
r, s, and t are, respectively, 0 to 2, 0 to 2 and 1 to 3,
their sum being 3;
W is the hydrocarbyl nucleus of a polyhydroxy compound containing from 2 to 4- hydroxyls;
x has an average value of from about 1.0 to about 5.0;
and
z is an integer corresponding to the number of hydroxyls in W[.],
provided that where G is hydrogen, .9 is at least 1.
2. The compound of claim 1 wherein A is the nucleus of a dicarboxylic acid anhydride selected from the group consisting of (1) phthalic, halogen-substituted phthalic, nitro substituted phthalic, alkyl substituted phthalic, homophthalic, naphthalic, (2) adipic, azelaic, glutanic, snberic, itaconic, pimelic, succinic, maleic, (3) the halogen-substituted and alkyl-substituted members of the aforesaid group (2), (3) chlorendic, hydrophthalic, and endomethylene phthalic anhydrides.
3. An organo-phosphorus compound selected from the formulas 0 ion" (B!)- |-CO(CH;CHO),-P(O) (R'), O D t (i F 0 HCH;O J) I t R).
-cowmcnono and FOR D O (ilP (O) (OCHIAlH) -O F [O CHCHah-O 0 R is a member of the group consisting of (lower) alkoxy (lower) alkyl, alkyl containing from 1 to 18 carbon atoms, aryl, alkyl-substituted aryl wherein the alkyl contains from 1 to 18 carbon atoms, chlorosubstituted aryl, bromo-substituted aryl, aralkyl, and
wherein D and x are as hereinafter defined;
R is a member of the group consisting of hydrogen, alkyl containing from 1 to 18 carbon atoms, and phenyl;
R" is a member of the group consisting of alkyl containing from 1 to 13 carbon atoms and (lower) alkoxy (lower) alkyl;
A is the nucleus of a member selected from the group consisting of phthalic, chloro-substituted phthalic, bromo-substituted phthalic, iodo-substituted phthalic, nitro-substituted phthalic, alkyl-substituted phthalic wherein the alkyl contains from 1 to 12 carbon atoms, homophthalic and naphthalic anhydrides;
D is a member of the group consisting of hydrogen,
CH3, C2H5 and F is a member of the group consisting of hydrogen and G is a member of the group consisting of hydrogen and wherein R and R are as hereinbefore defined, and
a and b are as defined hereinafter; a and b are each 0 to 2, their sum being 2; r, s, and t are, respectively, 0 to 2, 0 to 2 and 1 to 3,
their sum being 3; W is the hydrocarbyl nucleus of a polyhydroxy compound containing from 2 to 4 hydroxyls; x has an average value of from about 1.0 to about 5.0; and z is an integer corresponding to the number of hydroxyls in W. provided that where G is hydrogen, [S] is at least 1.
4. The compound of claim 3, Formula 2, in which 1' is 0, R is methyl, G is hydrogen, D is CH and A is the nucleus of tetrabromophthalic anhydride.
5. The compound as defined in claim 4, having the C O (CHzQHOhH Br CH: 3
Br CH; 1
7. The compound of claim 4, having the structure B1 CH: Br 930(61101-130 IJ P(O)(OCHJ)I 9. The compound of claim 1 wherein A is the nucleus of a member selected from the group consisting of hydrophthalic, endomethylene phthalic, camphoric, -norbornene-2, and chlorendic anhydrides, and D is a member of the group consisting of hydrogen, CH C- -H and CICHg.
10. The compound of claim 1, having the structure or 0 o hocmcmo-rtoxoo nn),
l C1-C1 Cl I cocincrnon 11. The compound of claim 1 wherein A is the nucleus of a member selected from the group consisting of: (1) adipic, azelaic, glutaric, suberic, itaconic, pimelic, and succinic acid anhydrides; (2) the chloro-substituted members of (1); and (3) the alkyl-substituted members of (I), wherein alkyl contains from 1 to 12 carbon atoms; and D is selected from the group consisting of hydrogen, CH3, CQH5, and ClCH 12. The compound of claim 1, Formula 2, wherein r is 0, R is methyl, G is hydrogen, D is CH; and A is the nucleus of maleic anhydride.
13. The compound as defined in claim 12, having the structure 0 CH: I Hobo(bHcmo),-P(0)ooH, H -oo(oH,oH0),H 2 14. The compound of claim 12, having the structure 0 CH; Ito-b0(bHcm0)1.=-P(o)0cHi H 0o oH,oHO)|.iHJ CH1 2 15. The compound as defined in claim 12, having the structure O CH: H0-bo(bHoH=0),-P(0)(oonur H oo(oH,oH0),H
6H. 16. The compound of claim 12, having the structure [17. A process for the manufacture of an organo-phosphorus compound as defined in claim 1, Formulas 2 and 3, which comprises the simultaneous reaction of the appropriate phosphorus compound having at least one acid function, a dicarboxylic acid anhydride having A as its nucleus, and a compound selected from the group consisting of ethylene oxide, propylene oxide, butylene oxide and epichlorohydrin.]
[18. A process for the manufacture of an organophosphorus compound as defined in claim 3, Formulas 2 and 3, which comprises the simultaneous reaction of the appropriate phosphorus compound having at least one acid function, a dicarboxylic acid anhydride selected from the group consisting of phthalic, chloro-substituted phthalic, bromo-substituted phthalic, iodo-substituted phthalic, nitro-substituted phthalic, alkyl-substituted phthalic wherein the alkyl contains from 1 to 12 carbon atoms, homophthaiic and naphthalic anhydrides, and a compound selected from the group consisting of ethylene oxide, propylene oxide, butylene oxide, and epichlorohydrin.]
[19. The process as defined in claim 18 wherein the compound produced falls within Formula 2 in which r is O, R is methyl, G is hydrogen, D is CH and A is the nucleus of tetrabromophthalic anhydride] [20. The process as defined in claim 19 wherein the organo-phosphorous compound obtained is Br 0 CH; B. Miscellanea [22. The process as defined in claim 19 wherein the organo-phosphorus compound is [23. The process as defined in claim 22 wherein at is 1.2.]
[24. The process as defined in claim 18 which comprises mixing the dicarboxylic acid anhydride and phosphorus compound, subsequently adding thereto an excess of said oxide at a temperature of from about 70 C. to about C., heating at a temperature sufliciently high to complete neutralization of the carboxyl acid functions formed, but not higher than about C., and then removing the excess oxide from the said organo-phosphorus compound] [25. The process of claim 18 which comprises the steps of mixing the dicarboxylic acid anhydride and phosphorus compound and subsequently adding said oxide thereto, the oxide being in excess of the amount necessary to react with all of the acid functions of the said phosphorus compound and the subsequently formed carboxyl group, at temperatures sufiiciently high to react the said oxide and the said acid functions, and removing the excess oxide from the organo-phosphorus compound thus formed] 26. An organo-phosphorus compound formula 0 boa" (R'). LOO(CH,CHO) (O) D r( lh wherein:
R is a member of the group consisting of (lower) alkoxy (lower) alkyl, alkyi containing from 1 to 18 carbon atoms, aryl, alkyl-substituted aryl wherein the alkyl contains from I to l 8 carbon atoms, chloro-substituted aryl, homo-substituted aryl, aralkyl, and
wherein D and X are as hereinafter defined,
R is a member of the group consisting of hydrogen, alkyl containing from 1 to 18 carbon atoms, and phenyl;
R" is a member of the group consisting of alkyl conraining from I to 13 carbon atoms and (low'er) alkoxy (lower) alkyl;
A is the nucleus of a member selected from the group consisting of aromatic dicarboxylic acid anhydrides and aliphatic dicarboxylic acid anhydrides;
D is a member of the group consisting of hydrogen,
lower alkyl, and chloro (lower) alkyl;
0 and b are each 0 to 2, their sum being 2; and
z has an average value of from about 1.0 to about 5.0.
27. An organo-phosphorus compound of the formula:
F OCHCI'I: 0G t wherein:
R is a member of the group consisting of (lower) all:-
oxy (lower) alkyl, alkyl containing from I to 18 carbon atoms, aryl, alkyl-substituted aryl wherein the alkyl contains from 1 to 18 carbon atoms, chloro-substituted aryl, bronze-substituted aryl, aralkyl, and
D (CHh3HO);H wherein D and x are as hereinafter defined;
R is a member of the group consisting of hydrogen, alkyl containing from I to 18 carbon atoms, and phenyl;
" is a member of the group consisting of alkyl containing from 1 to 13 carbon atoms, and (lower) alkoxy (lower) alkyl;
A is the nucleus of a member selected from the group consisting of aromatic dicarboxylic acid anhydrides and aliphatic dicarboxylic acid anhydrides; D is a member of the group consisting of hydrogen,
lower alkyl, and chloro (lower) alkyl; F is a member of the group consisting of hydrogen and R) wherein R and R are as hereinbefore defined, and
a and b are as defined hereinafter; a and b are each 0 to 2, their sum being 2; W is the hydrocarbyl nucleus of a polyhya'roxy compound containing from 2 to 4 hydroxyls; x has an average value of from about 1.0 to about 5.0,-
and z is an integer corresponding to the number of hydroxyls in W.
References Cited The following references, cited by the Examiner, are of record in the patented file of this patent or the original patent.
UNITED STATES PATENTS 3,419,642 12/1968 McGary et al. 260 -952 3,092,543 6/1963 Richter 260952 X LORRAINE A. WEINBERGER, Primary Examiner R. L. RAYMOND, Assistant Examiner US. Cl. X.R.
252-8.); 2602.5 FP, 77.5 AR, 453 AM, 928, 929, 930, 971, 973, 978
um'rsn sums PATENT omcr: CERTIFICATE OF CORRECTION a April 16, 197A Io-wau (5/09) Paton: No. R 7,9 9
humor) Vasco G. Camacho, James J. Anderson 80 Wendell M. Byrd I: in certified that error appura in the above-identified patent and that aid Letters Patent are hereby corructsdDaa shown below:
D H H l i CH should read --CH--. line &5, "abve" should read --ahove--. line 23, "hydroyls" should read --hydroxyls--. line 7, 2,2,2)" should read "(2,2,1)". line 5, and other alkyl-substituted) should --(and other alkyl-substituted phthalics Where the alkyl has from 1 to 12 carbon atoms line 52, "dialkyl' should read -dialkyl--. line 67, "RP O)OH(OR')" should read --R"l (O)(OH) line 36-87, 'were placed in means for cooling should read --were placed in a reaction vessel provided with a stirrer, thermometer and means for cooling;--. line A l, "1000 parts of each wash should read 1000' parts for each wash--.
Column 1, line 59, Column 3, Column 5, Column 5, Column 5,
read
Column 5, Column 5, Column 6,
Column 6,
Signed and sealed this 8th day of October 1974.
(SEAL) Attest:
C. MARSHALL DANN Commissioner of Patents McCOY M. GIBSON JR. Attesting Officer
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US26095772A | 1972-06-08 | 1972-06-08 |
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Family
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US27969D Expired USRE27969E (en) | 1972-06-08 | 1972-06-08 | Hc-co(ch,cho)xh |
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Cited By (1)
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---|---|---|---|---|
US5614573A (en) * | 1995-03-27 | 1997-03-25 | Nicca Chemical Co., Ltd. | Flame retardants and flame retardant finishing method for polyester-based synthetic fiber materials |
-
1972
- 1972-06-08 US US27969D patent/USRE27969E/en not_active Expired
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US5614573A (en) * | 1995-03-27 | 1997-03-25 | Nicca Chemical Co., Ltd. | Flame retardants and flame retardant finishing method for polyester-based synthetic fiber materials |
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