USRE24373E - Thickened hair dyeing composition com- - Google Patents
Thickened hair dyeing composition com- Download PDFInfo
- Publication number
- USRE24373E USRE24373E US24373DE USRE24373E US RE24373 E USRE24373 E US RE24373E US 24373D E US24373D E US 24373DE US RE24373 E USRE24373 E US RE24373E
- Authority
- US
- United States
- Prior art keywords
- hair
- composition
- dyeing
- dye
- ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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- 239000000203 mixture Substances 0.000 title description 55
- 210000004209 Hair Anatomy 0.000 title description 50
- 238000004043 dyeing Methods 0.000 title description 37
- 239000000975 dye Substances 0.000 description 21
- 150000001875 compounds Chemical class 0.000 description 18
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 10
- 239000000118 hair dye Substances 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- -1 p-toluylenediamine Chemical class 0.000 description 8
- 125000004432 carbon atoms Chemical group C* 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 239000002562 thickening agent Substances 0.000 description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Tris Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 150000003868 ammonium compounds Chemical class 0.000 description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 description 4
- 239000000600 sorbitol Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-Aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N Diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 102000011782 Keratins Human genes 0.000 description 3
- 108010076876 Keratins Proteins 0.000 description 3
- 239000004166 Lanolin Substances 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 3
- NGPGDYLVALNKEG-UHFFFAOYSA-N azanium;azane;2,3,4-trihydroxy-4-oxobutanoate Chemical compound [NH4+].[NH4+].[O-]C(=O)C(O)C(O)C([O-])=O NGPGDYLVALNKEG-UHFFFAOYSA-N 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 235000019388 lanolin Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 3
- HVYWMOMLDIMFJA-DPAQBDIFSA-N (3β)-Cholest-5-en-3-ol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-Aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N Diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N Resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 230000001476 alcoholic Effects 0.000 description 2
- 150000007824 aliphatic compounds Chemical class 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 230000002708 enhancing Effects 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- QDHHCQZDFGDHMP-UHFFFAOYSA-N monochloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- KZTWOUOZKZQDMN-UHFFFAOYSA-N (4-azaniumyl-2-methylphenyl)azanium;sulfate Chemical compound OS(O)(=O)=O.CC1=CC(N)=CC=C1N KZTWOUOZKZQDMN-UHFFFAOYSA-N 0.000 description 1
- RVGOBWDGAVAVPJ-UHFFFAOYSA-N (4-hydroxyphenyl)azanium;chloride Chemical compound Cl.NC1=CC=C(O)C=C1 RVGOBWDGAVAVPJ-UHFFFAOYSA-N 0.000 description 1
- URLJMZWTXZTZRR-UHFFFAOYSA-N (tetradecyloxy)sulfonic acid Chemical compound CCCCCCCCCCCCCCOS(O)(=O)=O URLJMZWTXZTZRR-UHFFFAOYSA-N 0.000 description 1
- YJISHJVIRFPGGN-UHFFFAOYSA-N 5-[5-[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxy-6-[[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxymethyl]-3,4-dihydroxyoxan-2-yl]oxy-6-(hydroxymethyl)-2-methyloxane-3,4-diol Chemical compound O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)O)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 YJISHJVIRFPGGN-UHFFFAOYSA-N 0.000 description 1
- CWSZBVAUYPTXTG-UHFFFAOYSA-N 5-[6-[[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxymethyl]-3,4-dihydroxy-5-[4-hydroxy-3-(2-hydroxyethoxy)-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxyoxan-2-yl]oxy-6-(hydroxymethyl)-2-methyloxane-3,4-diol Chemical compound O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)OCCO)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 CWSZBVAUYPTXTG-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N Ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- PRKQVKDSMLBJBJ-UHFFFAOYSA-N Ammonium carbonate Chemical compound N.N.OC(O)=O PRKQVKDSMLBJBJ-UHFFFAOYSA-N 0.000 description 1
- VZTDIZULWFCMLS-UHFFFAOYSA-N Ammonium formate Chemical compound [NH4+].[O-]C=O VZTDIZULWFCMLS-UHFFFAOYSA-N 0.000 description 1
- DVARTQFDIMZBAA-UHFFFAOYSA-O Ammonium nitrate Chemical compound [NH4+].[O-][N+]([O-])=O DVARTQFDIMZBAA-UHFFFAOYSA-O 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N Ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229940107161 Cholesterol Drugs 0.000 description 1
- FBPFZTCFMRRESA-KAZBKCHUSA-N D-Mannitol Natural products OC[C@@H](O)[C@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KAZBKCHUSA-N 0.000 description 1
- UNXHWFMMPAWVPI-QWWZWVQMSA-N D-Threitol Natural products OC[C@@H](O)[C@H](O)CO UNXHWFMMPAWVPI-QWWZWVQMSA-N 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N Erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 Erythritol Drugs 0.000 description 1
- FBPFZTCFMRRESA-GUCUJZIJSA-N Galactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-GUCUJZIJSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- 241001072332 Monia Species 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N P-Phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- HEBKCHPVOIAQTA-ZXFHETKHSA-N Ribitol Chemical compound OC[C@H](O)[C@H](O)[C@H](O)CO HEBKCHPVOIAQTA-ZXFHETKHSA-N 0.000 description 1
- 229940083542 Sodium Drugs 0.000 description 1
- 229940091252 Sodium supplements Drugs 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N Triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 229940100445 WHEAT STARCH Drugs 0.000 description 1
- 210000002268 Wool Anatomy 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N Xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 Xylitol Drugs 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002730 additional Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 229940077484 ammonium bromide Drugs 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- CREXVNNSNOKDHW-UHFFFAOYSA-N azaniumylideneazanide Chemical compound N[N] CREXVNNSNOKDHW-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing Effects 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000001419 dependent Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drugs Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N ethanolamine Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propanol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229950005425 sodium myristyl sulfate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 230000002588 toxic Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/411—Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
Definitions
- a hair dyeing composition containing as essential ingredicuts a polyhydroxyl compound which tends to promote absorption and dyeing and an alkanolamine having a carbon chain of low molecular weight which tends to equalize the dyeing.
- This combination of ingredients makes it possible to dispense with the alkaline peroxide pretreatment heretofore required, even in the case of coarse hair. Because this combination of components is effective at a pH below about 9, to which pH the composition can be adjusted by addition of an ammonium compound, the harmful effects of a high alkalinity in the hair dyeing composition also are reduced or eliminated.
- a further advantage of this composition is that hair can be dyed to a uniformly lighter shade than its natural color without pretreatment.
- the composition also contains a thickening agent in an amount to increase its viscosity to a point at which the thickened composition will adhere to the hair for the time required to dye it.
- composition is effective with the usual oxidation dyes, i. e., aromatic diamines or aminophenols, such as p-toluylenediamine, p-aminophenol, and their salts.
- aromatic diamines or aminophenols such as p-toluylenediamine, p-aminophenol, and their salts.
- aminophenols such as p-toluylenediamine, p-aminophenol, and their salts.
- p-Phenylenediamine is toxic and would not ordinarily be used.
- Polyhydroxyl compounds which promote absorption and dyeing have from 2 to about 12 carbon atoms and from 2 to about 12 hydroxyl groups.
- the compound preferably is an aliphatic polyhydroxyl compound, such as'sorbitol, ethylene glycol, glycerine, pentaerythritol, xylitol, adonitol, diethylene glycol, mannitol, triethylene glycol, erythritol, dulcitol, propanediol-1,2, butyleneglycol-1,3 and propylene glycol.
- the above examples are all of saturated aliphatic compounds. Unsaturated aliphatic compounds can also be employed, if desired. Further, polyhydroxyl compounds containing aromatic and cycloaliphatic groups can also be utilized. The polyhydroxyl compound should be water-soluble or -dis persible.
- Alkanolamines having at least one alkylol chain of low molecular weight, up to about 12 carbon atoms, and preferably from 6 to 9 carbon atoms and from [6] I to [9] 3 hydroxyl groups are effective dye equalizers.
- Typical alkylol groups for example, are methylol, ethylol, and propylol.
- the amino nitrogen can be primary, secondary or tertiary, thus bearing at least one alkylol group, up to three alkylol groups, the remaining nitrogen valences being taken with hydrogen or alkyl groups of low molecular weight such as methyl, ethyl and propyl.
- Triethanolarnine and its salts has been found to be very satisfactory and is preferred by reason of its availablity and cost. However, diethanolamine, tripropa-nolamine, monoethanolamine, monobutylolamine,
- the pH of the thickened hair dyeing composition according to the invention should be between about 7 and about 9, which is below that of the alkaline thickened hair dyeing compositions used heretofore.
- the protection thus afforded to the hair is particularly noticeable in the gloss and firmness of the hair after treatment.
- the pH can be adjusted by adding an ammonium compound, i. e., either free ammonia, ammonium hydroxide or an ammonium salt, such as ammonium carbonate, ammonium acetate, ammonium phosphate, ammonium chloride, ammonium tartrate, ammonium sulfate, ammonium nitrate, ammonium formate, and ammonium bromide.
- alkanolamine salts am monia or ammonium hydroxide would be used, but ammonium salts would be added if an alkanolamine is employed.
- the ammonium compound is employed in an amount to provide a pH within the stated range, and preferably approximating 8.5 to 9.0.
- the hair dye may contain a thickening agent, which may be a watersoluble cellulose derivative, such as hydroxyethyl cellulose, methyl cellulose and carboxymethylcellulose (glycolic acid cellulose ethers), usually used as the sodium salt, or a water-soluble alginate.
- a thickening agent which may be a watersoluble cellulose derivative, such as hydroxyethyl cellulose, methyl cellulose and carboxymethylcellulose (glycolic acid cellulose ethers), usually used as the sodium salt, or a water-soluble alginate.
- These thickening agents are employed in an amount to transform the composition into a smooth cream or paste which will tend to adhere to the hair for as long a time as desired.
- the composition desirably flows only slowly, and preferably flows only under pressure.
- thickening agents have the additional property of producing a. transparent or clear composition, thus facilitating the observation of the progress of the dyeing.
- Many of the compositions thickened with these agents in accordance with the invention have thixotropic properties. Where transparency is not required, however, it is possible to employ other thickening agents, such as starch, wheat flour. Usually from 1 to 10% of a thickening agent will produce a composition having the desired viscosity.
- a small amount of a surface active agent such as a synthetic detergent, can also be included, usually about 1%, in order to facilitate wetting of the hair by the dye and do away with a subsequent soap shampoo to remove excess dye.
- a surface active agent such as a synthetic detergent
- paraflin sulfonates, sulfonated alcohols,'sulfonated fatty acids, fatty alcohol sulfates and fatty acid sulfates can be mentioned.
- sulfonated coconut oil fatty acids, lauryl sulfate, myristyl sulfate, and sodium palmitic methyl tauride can be employed.
- fatty alcohols or colloidally soluble wool wax derivatives in particular, condensation products of these substances with polyhydroxyalkylene sorbitol, can be added for the care of the hair.
- hydrocarbons such as paraffin oil
- the transparency of the thickened hair dyeing composition of the invention is not affected by the addition of the above-mentioned substances.
- the composition is applied to the hair in such a way 4 t as to saturate it thoroughly therewith. This may conveniently be accomplished by combing or brushing out the hair and by saturating it with a comb wet with the composition, and by like means known .to those skilled in the art.
- the intensity of shade of color obtained primarily depends upon the dye concentration and the dyeing temperature. Best results are obtained at a temperature within the range from 20 to 30 C. and when the dye concentration does not exceed 5 For most purposes, a dye concentration within the range from 1 to 4% is preferable, but much less than 1% may be adequate under certain circumstances.
- composition and process of the invention is applicable primarily to human hair, but may also be employed with animal fibers of all types, including wool.
- compositions according to the present invention are given by way of illustration.
- a transparent thickened hair dye composition is obtained which, developed with oxidizing agents in the usual Way, dyes even hair of low absorptive capacity a uniform dark blonde color without pretreatment.
- the pH of the hair dyeing composition made in this way is 8.7.
- EXAMPLE 2 To a hair dye charge according to Example 1 there are added 931 parts of 2.4% sodium carboxymethyl cellulose paste heated to 50 C. and containing 5.0% triethanolamine, 3.3% ammonium chloride, 2.2% pentaerythritol and 1.2% paraflin sulfonate. A transparent thickened hair dye with properties equal to those described in Example 1 is obtained. The pH of this hair dyeing composition is 8.6.
- EXAMPLE 3 To a hair dye charge according to Example 1 there are added 931 parts of a 2.4% sodium carboxymethyl cellulose paste containing 3.8% diethanolamine, 2.4% ammonium tartrate, 2.0% ethylene glycol, 1.0% of a condensation product of wool wax with polyhydroxyalkylene sorbitol and 1.0% paraflin sulfonate. A transparent thickened hair dye composition is obtained which absorbs and equalizes Well. The pH of-the hair dyeing composition is 8.9.
- compositions according to the present invention allow hair to be dyed with advantage at a pH substantially below that used at present, thus doing away with the harmful efiects of high alkalinity.
- the compositions are particularly suitable for the dyeing of coarse hair, of low absorptive power, which hitherto has required either an alkaline pro-treatment or a high alkalinity, in most cases a pH of about 10, in order to produce satisfactory results. If conventional ingredients are added, transparent pastes are obtained which can be packed in tubes and applied with ease.
- alkanolamine and oxidation dye as used in the claims include the salts thereof.
- a hair dyeing composition comprising an amount up to about 5% of an oxidation hair dye; an alcoholic, non-dyeing absorptionand dye-promoting polyhydroxyl compound containing from about 2 to about 12 carbon atoms and from about 2 to about 12 hydroxyl groups in an amount within the range from about 2% to about 6%; a dye-equalizing alkanolamine having at least one alkylol chain of low molecular weight up to about 12 carbon atoms and from [6] 1 to [9] 3 hydroxyl groups in an amount within the range from about 3% to about and a compound capable of supplying ammonium ions in an amount within the range from about 3% to about 5%; the said composition having a pH from 7 to 9.
- composition in accordance with claim 1 in which the polyhydroxyl compound is ethylene glycol is ethylene glycol.
- composition in accordance with claim 1 in which the polyhydroxyl compound is pentaerythritol.
- composition in accordance with claim 1 in which the polyhydroxyl compound is sorbitol is sorbitol.
- composition in accordance with claim 9 in which the aminophenol is p-aminophenol.
- a hair dyeing composition which comprises an oxidation hair dye in an amount within the range from about 1% 'to about 4%; an alcoholic, non-dyeing absorptionand dye-promoting polyhydroxyl compound containing from about 2 to about 12 carbon atoms and from about 2 to about 12 hydroxyl groups in an amount from about 2% to about 6%; a dye-equalizing alkanolamine having at least one alkylol chain of low molecular weight up to about 12 carbon atoms andfrom [6] 1 to [9] 3 hydroxyl groups in an amount within the range from about 4% to about 6%; and a compound capable of supplying ammonium ions in an amount within the range from about 3% to about 5%; the said composition having a pH from 7 to 9.
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Description
United States Patent THICKENED HAIR DYEING COMPOSITION COM- PRISING POLYHYDROXYL COMPOUND AND ALKANOLAMINE Wolfgang Max Josef Eckardt and Siegfried Roland Preisinger, Bad Segeberg, Holstein, Germany, assignors to Lever Brothers Company, New York, N. Y., a corporation of Maine No Drawing. Original No. 2,769,748, dated November 6, 1956, Serial No. 273,352, February 25, 1952. Application for reissue July 1, 1957, Serial No. 669,915
Claims priority, application Germany February 26, 1951 11 Claims. (Cl. 167-88) Matter enclosed in heavy brackets appears in the original patent but forms no part of this reissue specification; matter printed in italics indicates the additions made by reissue.
. viously used, which hadthe great disadvantage of readily running from hair during use, redyeing parts of the hair which had already been dyed, and also staining the clothes and face of the user. However, these thickened compositions, being emulsions or suspensions, have not been transparent, so that it has been diflicult to observe the progress of the dyeing operation. Moreover, due to the use of the oxidation dyes there is an'increased risk of forming darker patches as a result of lack of uniformity of the hair, whilst originally white patches may not be dyed to a sufficient depth of shade, particularly in the case of coarse hair, which does not absorb dye easily.
In order to overcome the disadvantage of lack of absorption power in coarse hair, a pretreatment with am moniacal hydrogen peroxide has been required. This however due to the high alkalinity of the solution is not beneficial to the hair keratin. Another expedient has been the provision of an increased ammonia content in the thickened hair dyeing composition so as to increase the ability of the coarse hair to absorb the dye. Such hair dyeing preparations have, however, had a pH of about in order to achieve the desired effect. Here again the alkalinity is high enough to have a harmful effect on the hair keratin.
By the addition of hair-protecting substances, such as fatty acid-glycerides, higher fatty alcohols, cholesterol or wool wax, to thickened hair dyeing compositions, the harmful effect of excess free ammonia required to increase the absorption of the dye by the hair is to a certain degree overcome. In Swiss Patent No. 197,425, for example, it is proposed to add nonalkaline hair softening carriers, such as higher fatty alcohols and the like, and to abandon the addition of free ammonia. Although the hair is indeed protected from harmful effects, the dyeing is not satisfactory in all instances, and in the use of this composition a pretreatment with alkaline hydrogen peroxide cannot be avoided. When the treatment with alkaline hydrogen peroxide is effected, however, the whole dyeing process becomes troublesome and the. structure of the hair is injured by the alkaline hydrogen peroxide rather than by the hair dye.
, It has been proposed in German'Patent No. 582,521 that triethanolamine soaps be included in hair dyeing compositions. These substances, however, only increase the wetting action of the composition and do not enhance the dyeing elfect. The composition is not effective on coarse hair without an alkaline pretreatment.
Attempts have also been made to use triethanolamine in hair dyeing compbsitions, but satisfactory results have not been obtained, as is pointed out in French Patent No. 900,825, beginning at line 23.
Accordingly, it is an object of the present invention to provide a thickened hair dyeing composition'based on oxidation dyes which will dye hair in an unobjectionable manner without a pretreatment with alkaline hydrogen peroxide.
It is also an object of the invention to provide a thickened hair dyeing composition which has a relatively low pH, within the range from about 7 to about 9, so that the hair keratin is not affected during the dyeing process.
In accordance with the instant invention, a hair dyeing composition is provided containing as essential ingredicuts a polyhydroxyl compound which tends to promote absorption and dyeing and an alkanolamine having a carbon chain of low molecular weight which tends to equalize the dyeing. This combination of ingredients makes it possible to dispense with the alkaline peroxide pretreatment heretofore required, even in the case of coarse hair. Because this combination of components is effective at a pH below about 9, to which pH the composition can be adjusted by addition of an ammonium compound, the harmful effects of a high alkalinity in the hair dyeing composition also are reduced or eliminated. A further advantage of this composition is that hair can be dyed to a uniformly lighter shade than its natural color without pretreatment.
In a preferred embodiment, the composition also contains a thickening agent in an amount to increase its viscosity to a point at which the thickened composition will adhere to the hair for the time required to dye it.
The composition is effective with the usual oxidation dyes, i. e., aromatic diamines or aminophenols, such as p-toluylenediamine, p-aminophenol, and their salts. There is a large group of these useful dyes known to those skilled in this art and the few mentioned above are merely illustrative. p-Phenylenediamine is toxic and would not ordinarily be used.
Polyhydroxyl compounds which promote absorption and dyeing have from 2 to about 12 carbon atoms and from 2 to about 12 hydroxyl groups. The compound preferably is an aliphatic polyhydroxyl compound, such as'sorbitol, ethylene glycol, glycerine, pentaerythritol, xylitol, adonitol, diethylene glycol, mannitol, triethylene glycol, erythritol, dulcitol, propanediol-1,2, butyleneglycol-1,3 and propylene glycol. The above examples are all of saturated aliphatic compounds. Unsaturated aliphatic compounds can also be employed, if desired. Further, polyhydroxyl compounds containing aromatic and cycloaliphatic groups can also be utilized. The polyhydroxyl compound should be water-soluble or -dis persible.
Alkanolamines having at least one alkylol chain of low molecular weight, up to about 12 carbon atoms, and preferably from 6 to 9 carbon atoms and from [6] I to [9] 3 hydroxyl groups are effective dye equalizers. Typical alkylol groups, for example, are methylol, ethylol, and propylol. The amino nitrogen can be primary, secondary or tertiary, thus bearing at least one alkylol group, up to three alkylol groups, the remaining nitrogen valences being taken with hydrogen or alkyl groups of low molecular weight such as methyl, ethyl and propyl. These compounds can be used in the form of their acid salts. Triethanolarnine and its salts has been found to be very satisfactory and is preferred by reason of its availablity and cost. However, diethanolamine, tripropa-nolamine, monoethanolamine, monobutylolamine,
dipropanolamine, monopropanolamine, etc., and their salts, also can be used with advantage. Although the literature indicates that alkanolamines are capable of dyeing hair red, the present research has not been able to confirm this.
The pH of the thickened hair dyeing composition according to the invention should be between about 7 and about 9, which is below that of the alkaline thickened hair dyeing compositions used heretofore. The protection thus afforded to the hair is particularly noticeable in the gloss and firmness of the hair after treatment. If necessary, the pH can be adjusted by adding an ammonium compound, i. e., either free ammonia, ammonium hydroxide or an ammonium salt, such as ammonium carbonate, ammonium acetate, ammonium phosphate, ammonium chloride, ammonium tartrate, ammonium sulfate, ammonium nitrate, ammonium formate, and ammonium bromide. If alkanolamine salts are used, am monia or ammonium hydroxide would be used, but ammonium salts would be added if an alkanolamine is employed. The ammonium compound is employed in an amount to provide a pH within the stated range, and preferably approximating 8.5 to 9.0.
Taking into account the effect of the polyhydroxl compound to enhance the absorption and dyeing, and the effect of the alkanolamine to equalize the dyeing, it is usually desirable to employ from about 3 to about 15% of the alkanolamine, preferably from 4 to 6%, and be tween about 2 and about 6% of the polyhydroxyl compound by weight of the composition. The amount of ammonium compound required to buffer a composition containing these proportions of the polyhydroxyl compound and alkanolamine to a pH of from 7 to 9 usually will lie within the range from about 3 to about In addition to the above ingredients, the hair dye may contain a thickening agent, which may be a watersoluble cellulose derivative, such as hydroxyethyl cellulose, methyl cellulose and carboxymethylcellulose (glycolic acid cellulose ethers), usually used as the sodium salt, or a water-soluble alginate. These thickening agents are employed in an amount to transform the composition into a smooth cream or paste which will tend to adhere to the hair for as long a time as desired. The composition desirably flows only slowly, and preferably flows only under pressure. These thickening agents have the additional property of producing a. transparent or clear composition, thus facilitating the observation of the progress of the dyeing. Many of the compositions thickened with these agents in accordance with the invention have thixotropic properties. Where transparency is not required, however, it is possible to employ other thickening agents, such as starch, wheat flour. Usually from 1 to 10% of a thickening agent will produce a composition having the desired viscosity.
A small amount of a surface active agent, such as a synthetic detergent, can also be included, usually about 1%, in order to facilitate wetting of the hair by the dye and do away with a subsequent soap shampoo to remove excess dye. As exemplary of such agents, paraflin sulfonates, sulfonated alcohols,'sulfonated fatty acids, fatty alcohol sulfates and fatty acid sulfates can be mentioned. For example, sulfonated coconut oil fatty acids, lauryl sulfate, myristyl sulfate, and sodium palmitic methyl tauride can be employed.
Small quantities of fatty alcohols or colloidally soluble wool wax derivatives, in particular, condensation products of these substances with polyhydroxyalkylene sorbitol, can be added for the care of the hair.
The addition of hydrocarbons, such as paraffin oil, in a small amount, usually less than 1%, will facilitate combing of the dyed hair.
The transparency of the thickened hair dyeing composition of the invention is not affected by the addition of the above-mentioned substances.
The composition is applied to the hair in such a way 4 t as to saturate it thoroughly therewith. This may conveniently be accomplished by combing or brushing out the hair and by saturating it with a comb wet with the composition, and by like means known .to those skilled in the art.
The intensity of shade of color obtained primarily depends upon the dye concentration and the dyeing temperature. Best results are obtained at a temperature within the range from 20 to 30 C. and when the dye concentration does not exceed 5 For most purposes, a dye concentration within the range from 1 to 4% is preferable, but much less than 1% may be adequate under certain circumstances.
It will be appreciated by those skilled in the art that the intensity of shade will also be dependent to some extent upon the dyeing temperature and upon the nature of the dye. For this reason, specific conditions adapted for every dyeing cannot be given, but those skilled in the art will know from the above disclosure and the following examples what conditions to employ in a given case.
The composition and process of the invention is applicable primarily to human hair, but may also be employed with animal fibers of all types, including wool.
The following examples of compositions according to the present invention are given by way of illustration.
EXAMPLE 1 Parts p-Toluylene diamine sulfate 6.0 p-Aminophenol hydrochloride 0.5 Resorcinol 2.5 Isopropyl alcohol 60.0
The above are mixed together, and to this mixture are added 931 parts of 2.4%, sodium carboxymethyl cellulose paste heated to 50 C. and containing 4.2% triethanolamine, 2.0% ethylene glycol, 2.4% ammonium tartrate and 1.0% paraffin sulfonate. A transparent thickened hair dye composition is obtained which, developed with oxidizing agents in the usual Way, dyes even hair of low absorptive capacity a uniform dark blonde color without pretreatment. The pH of the hair dyeing composition made in this way is 8.7.
EXAMPLE 2 To a hair dye charge according to Example 1 there are added 931 parts of 2.4% sodium carboxymethyl cellulose paste heated to 50 C. and containing 5.0% triethanolamine, 3.3% ammonium chloride, 2.2% pentaerythritol and 1.2% paraflin sulfonate. A transparent thickened hair dye with properties equal to those described in Example 1 is obtained. The pH of this hair dyeing composition is 8.6.
EXAMPLE 3 EXAMPLE 4 To a hair dye charge according to Example 1 there are added 931 parts of a 2.4% sodium carboxymethyl cellulose paste containing 3.8% diethanolamine, 2.4% ammonium tartrate, 2.0% ethylene glycol, 1.0% of a condensation product of wool wax with polyhydroxyalkylene sorbitol and 1.0% paraflin sulfonate. A transparent thickened hair dye composition is obtained which absorbs and equalizes Well. The pH of-the hair dyeing composition is 8.9.
The compositions according to the present invention allow hair to be dyed with advantage at a pH substantially below that used at present, thus doing away with the harmful efiects of high alkalinity. The compositions are particularly suitable for the dyeing of coarse hair, of low absorptive power, which hitherto has required either an alkaline pro-treatment or a high alkalinity, in most cases a pH of about 10, in order to produce satisfactory results. If conventional ingredients are added, transparent pastes are obtained which can be packed in tubes and applied with ease.
All parts and percentages are by weight.
The terms alkanolamine and oxidation dye as used in the claims include the salts thereof.
We claim:
1. A hair dyeing composition comprising an amount up to about 5% of an oxidation hair dye; an alcoholic, non-dyeing absorptionand dye-promoting polyhydroxyl compound containing from about 2 to about 12 carbon atoms and from about 2 to about 12 hydroxyl groups in an amount within the range from about 2% to about 6%; a dye-equalizing alkanolamine having at least one alkylol chain of low molecular weight up to about 12 carbon atoms and from [6] 1 to [9] 3 hydroxyl groups in an amount within the range from about 3% to about and a compound capable of supplying ammonium ions in an amount within the range from about 3% to about 5%; the said composition having a pH from 7 to 9.
2. A composition in accordance with claim 1 in which the polyhydroxyl compound is ethylene glycol.
3. A composition in accordance with claim 1 in which the polyhydroxyl compound is pentaerythritol.
4. A composition in accordance with claim 1 in which the polyhydroxyl compound is sorbitol.
5. A composition in accordance with claim 1 in which the alkanolamine is triethanolamine.
6. A composition in accordance with claim 1 in which the alkanolamine is diethanolamine.
7. A composition in accordance with claim 1 in which the oxidation dye is an arylene diamine.
8. A composition in accordance with claim 7 in which the oxidation dye is a p-toluylene diamine.
9. A composition in accordance with claim 1 in which the dye is an aminophenol.
10. A composition in accordance with claim 9 in which the aminophenol is p-aminophenol.
11. A hair dyeing composition which comprises an oxidation hair dye in an amount within the range from about 1% 'to about 4%; an alcoholic, non-dyeing absorptionand dye-promoting polyhydroxyl compound containing from about 2 to about 12 carbon atoms and from about 2 to about 12 hydroxyl groups in an amount from about 2% to about 6%; a dye-equalizing alkanolamine having at least one alkylol chain of low molecular weight up to about 12 carbon atoms andfrom [6] 1 to [9] 3 hydroxyl groups in an amount within the range from about 4% to about 6%; and a compound capable of supplying ammonium ions in an amount within the range from about 3% to about 5%; the said composition having a pH from 7 to 9.
References Cited in the file of this patent 1 or the original patent UNITED STATES PATENTS 1,663,202 Kritchevsky Mar. 20, 1928 1,705,818 Kern Mar. 29, 1929 1,923,178 Ulrich Aug. 22, 19 33 2,042,698 Basch June 2, 1936 2,126,964 Kerth Aug. 16, 1938 2,236,970 Goldfarb Apr. 1, 1941 2,305,356 Luckenbach Dec. 15, 1942 FOREIGN PATENTS 307,948 Great Britain Mar. 14, 1929 27,781 Australia Dec. 9, 1930 366,961 Great Britain Feb. 9, 1932 466,172 Great Britain May 19, 1937 107,057 Australia Apr. 20, 1939 OTHER REFERENCES Cox: Hair Dyes, II," The Analyst, July 1940, pp. 393-398, esp. at p. 393.
Evans: Progress in Hair Coloring, Drug and Cosmetic Industry, January 1949, pp. 37, 38 and 117-121.
Janistyn: Riechstofie, Seifen, Kosmetika, vol. II, Huthig', Heidelberg, 1950, pp. 451-455.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4092102A (en) | 1973-10-15 | 1978-05-30 | Clairol Incorporated | Dyeing keratin fibers with 2-substituted m-toluenediamines |
-
0
- US US24373D patent/USRE24373E/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4092102A (en) | 1973-10-15 | 1978-05-30 | Clairol Incorporated | Dyeing keratin fibers with 2-substituted m-toluenediamines |
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