USRE15314E - Island - Google Patents
Island Download PDFInfo
- Publication number
- USRE15314E USRE15314E US15314DE USRE15314E US RE15314 E USRE15314 E US RE15314E US 15314D E US15314D E US 15314DE US RE15314 E USRE15314 E US RE15314E
- Authority
- US
- United States
- Prior art keywords
- hydrogen
- gas
- ammonia
- mixture
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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- 239000007789 gas Substances 0.000 description 36
- 229910052739 hydrogen Inorganic materials 0.000 description 30
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 27
- 239000001257 hydrogen Substances 0.000 description 27
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 26
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 239000000203 mixture Substances 0.000 description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 14
- 229910021529 ammonia Inorganic materials 0.000 description 13
- 235000017557 sodium bicarbonate Nutrition 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 12
- 239000012267 brine Substances 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 10
- 238000009621 Solvay process Methods 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 229960005419 nitrogen Drugs 0.000 description 8
- 239000008246 gaseous mixture Substances 0.000 description 7
- 230000006872 improvement Effects 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 241000220010 Rhode Species 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D7/00—Carbonates of sodium, potassium or alkali metals in general
- C01D7/18—Preparation by the ammonia-soda process
Definitions
- This invention in one of its aspects, relates to the ammonia soda process, and in another of its aspects, to the production of substantially pure or readily purifiable gas or gaseous mixtures, suitable for use in the synthesis of ammonia, from its elements.
- the CO, gas for producing the above're action is obtained from the burning of limestone in special lime kilns; in which case the CO gas is mixed with nitrogen,the mixed gases having approximately the fol-- lowing analysis:
- N2 65 /(7 to The Solvay towers were designed for the use of a carbonating gas containing approxima'tel 50% ()0 and 50% N and since their introduction by Solvay, they appear not to have been materially improved upon.
- a gas thus containing approximately 50% CO and 50% N has been found to be most suitable in the manufacture of bicarbonate of soda; because with such a mixture of gases, crystals of the bicarbonate salt have been found to form with ideal fineness, size, texture, etc.
- this discovery enables me to entirely eliminate, if desired, the quite costly step of burning limestone to produce tin-( 1.required for the ammonia soda process.
- This step is comparatively costly, is the great expense of installation and upkeep of the kilns in which the lime is burned; together, of course, with the cost of mining the stone.
- a second great advantage resides in the fact that the operation set'forth in equation (1), which has heretofore been conducted solely for the purpose of producing sodium bicarbonate; may, by effecting the herein described modification thereto, be caused to act in a dual capacity and yield not alone sodium bicarbonate, but also substantially pure hydrogen.
- the percentage of CO in this mixture may be made quite small"; the amount, of course, dqmnding upon the-nature of the catalyst and the temperature of the operation.
- TheCO content of the gaseous mixture is separated by the sodium bicarbonate forming reaction and nearly pure hydrogen passes off at the top of the carbonatirg tower.
- sulfur bearing gaseous impurities may be automatically eliminated in the Solvay towers, and, hence, the gas obtained is substantially pure hydrogen containing .more or less nitrogen, which is -unobjectionable; since a mixtur'e'of three parts by volume of nitrogen, to one of hydrogen, must be provided for the ammonia synthesisoperation.
- I may enrich my mixture of hydrogen and carbon dioxid gases, obtained from the water gas, by addingthereto pure CO from the calcining furnaces in which the bicarbonate of sodium is converted into sodium.
- amount of sulfur initially present in the water gas depends, used for making said gas.
- the process of producing sodium'b carb'onate and hydrogen which comprises treating a. gaseous mixture containing carbon monoxid, carbon dioxid. hydrogen and hydrogen sulfid, to free said mixture from said dioxid and sultid, by bubbling it through ammoniated brine in a receptacle the walls of which are of iron. treating the exit gases to convert said carbon monoxid into carbon dioxid, and bubbling the gaseous residues through amnioniated brine to produce sodium bicarbonate and hydrogen.
Description
UNITED STATES PATENT OFFICE.
ADRIAAN NAGELVOORT, OF PROVIDENCE, 'RHODE ISLAND, ASSIGNOR TO THE NITRO- GEN CORPORATION OF PROVIDENCE, RHODE ISLAND, A CORPORATION OF RHODE ISLAND.
METHOD or rno-noomo son'rom BICARBONATE AND mmauum.
Specification of Reissued Letters Patent. Reissue-d lvlar, 21, 1922,
No Drawing. Original No. 1,352,211, dated September 7, 1920, Serial No. 357,042, med February 7, 1920. Application for reissue filed July 16, 1921. SeriaLNo. 485,287.
To all whom it may concern:
Be 1t known that I, ADRIAAN NAoELvooRT,
'a citizen of the United States, residing at Providence, in the county of Providence and State of Rhode Island, have invented certain new and useful Improvements in Methods of Producing Sodium Bicarbonate and Hydrogen, of which the following is a specification.
This invention, in one of its aspects, relates to the ammonia soda process, and in another of its aspects, to the production of substantially pure or readily purifiable gas or gaseous mixtures, suitable for use in the synthesis of ammonia, from its elements.
In the ammonia soda process, for the production of sodium bicarbonate and carbonate of sodium, the following reaction is utilized:
The CO, gas for producing the above're action is obtained from the burning of limestone in special lime kilns; in which case the CO gas is mixed with nitrogen,the mixed gases having approximately the fol-- lowing analysis:
00., 435% to 407;. N2 65 /(7 to The Solvay towers were designed for the use of a carbonating gas containing approxima'tel 50% ()0 and 50% N and since their introduction by Solvay, they appear not to have been materially improved upon. In practice, a gas thus containing approximately 50% CO and 50% N has been found to be most suitable in the manufacture of bicarbonate of soda; because with such a mixture of gases, crystals of the bicarbonate salt have been found to form with ideal fineness, size, texture, etc.
I have discovered that hydrogen may be substituted for nitrogen as a dilutent of the carbon dioxid, without impairment to theproeess in any way; while on the other hand certain very important advantages are obtained by this substitution.
To begin with, this discovery enables me to entirely eliminate, if desired, the quite costly step of burning limestone to produce tin-( 1.required for the ammonia soda process. One reason why this step is comparatively costly, is the great expense of installation and upkeep of the kilns in which the lime is burned; together, of course, with the cost of mining the stone.
A second great advantage resides in the fact that the operation set'forth in equation (1), which has heretofore been conducted solely for the purpose of producing sodium bicarbonate; may, by effecting the herein described modification thereto, be caused to act in a dual capacity and yield not alone sodium bicarbonate, but also substantially pure hydrogen.
The foregoing may be accomplished, desirably, by using water gas as a source of the C(),,which becomes possible by virtue of my aforesaid discovery. \Vater gas. may be considered as having approximately the following analysis:
I1 49; CO, 40%; G(). 5%; N 5%; II S, and about of (3H,, or the like, etc.
To obtain hydrogen gas from such a gaseous mixture, it hasheretofore been necessary to remove the other gases eitherby ll'}lll(liltl()ll 0l absorption by suitable absorbers, with or without pressure.
B converting the CO in the water gas,
- into CO and H, by-means, for example, of
some one of the known metal-oxid catalytic masses,mixin steam with the water gas preparatory to of ecting contact of the so formed, gaseous mixture with the contact body,-it is possible to obtain a mixture of hydrogen and carbon dioxid, associated" with varying amounts of carbon monoxid and nitrogen, and In somecascs, with other nnpurltu-s such as hydrogen sulfid; care being taken in the contact prbcess, to avoid methane or like hydrocarbon formation dun ing the steam treatment.
The percentage of CO in this mixture may be made quite small"; the amount, of course, dqmnding upon the-nature of the catalyst and the temperature of the operation.
Such a small percentage of CO and other impurities, in the gases emerging from the contact chamber, will not be harmful in the manufacture of bicarbonate of sodium in ammonia soda process. Accordingly, I now cause the said mixture to pass up through usual a Solvay carbonating tower, in lieu of the mixture of carbon dioxid and nitrogen.
TheCO content of the gaseous mixture is separated by the sodium bicarbonate forming reaction and nearly pure hydrogen passes off at the top of the carbonatirg tower.
The remaining tracesof CO 'in this exit gas may be eliminated by known treatment, such as by using cuprous .chlorid solution as an absorbent for the CO.
As will be hereinafter pointed out, the
sulfur bearing gaseous impurities may be automatically eliminated in the Solvay towers, and, hence, the gas obtained is substantially pure hydrogen containing .more or less nitrogen, which is -unobjectionable; since a mixtur'e'of three parts by volume of nitrogen, to one of hydrogen, must be provided for the ammonia synthesisoperation.
I may enrich my mixture of hydrogen and carbon dioxid gases, obtained from the water gas, by addingthereto pure CO from the calcining furnaces in which the bicarbonate of sodium is converted into sodium.
carbonate-An which operation CO and H 0 are produced; the H 0 being separated from the CO by suitable condensers. pref erably before said carbon dioxid is thus added to the hydrogen-carbon-dioxid mixture. a
I shall 'now consider the third great advantage of the present improvement in the ammonia soda process. usually conducted, a small amount of sulfur is regularly introduced into the carbonating towers in the form of H S or (NTL). ,S to form a coating of Fes on the interior walls of these carbonating towers, which are made of iron.
This prevents the corrosion of the iron walls. and keeps the precipitated bicarbonate free from iron rust, which, otherwise would color and spot and make unsalaliile the sodium bicarbonate.
In water gas there is always more or less H S which, especially if'present in any material amount, should be removed before the (X) of the water gas can be elliciently eonrerted into CO by the catalyst or catalysts used as contact bodies to'eil'ect the reaction:
In order to prolong the life of the C0 and Ill forming catalyst, l'have found it of advantage to'lirst pass the water gas directly througlione or more Solvay carbonatiug towers to eliminate the hydrogen sulfid and the CO incidentto the production of the water gas hefore passing the exit gases through the contactapparatus for conversion of the CD into (fo The S content of the water gas isjust about enough to keeptheeai'lmnating towers In said process,
coated with FeS, for the step of the operation in which the CO is utilized in the formation of sodium bicarbonate. When said H 8 content is insufficient for this purpose, a small quantityof H S can be added directly to the water gas. In general, the
amount of sulfur initially present in the water gas depends, used for making said gas.
The preferred mode of conducting the entire operation is hence briefly as follows:
I'bubble the water gas coming from the generators, up through ammonia brine solution in one or more carbonating towers of of course,
upon the fuel a an ammonia soda process plant,-to remove sulfur compounds together with any CO present in said gas,-then take the gases from said tower or towers, which are now substantially C0 and H and add steam preparatory to passing the mixture, at an elevated temperature, over a heated catalyst. to convert all CO into"CO by'the reaction expressed b equation (2). #Fiirallyg'l pass the prefera ly so produced mixture (if CO and H through the ammonia brine solution in a second carbonating tower, or series of towers, for the precipitation of sodium bi carbonate and simultaneous purification of hydrogen gas for use in the synthesis of ammonia, the hydrogen content of the Illikllll'l.
I passed through this second tower. preferably utilizing the hydrogen gas thus freed from the carbon dioxid in the production of ammonia and utilizing the reaction with amnioniated brine for the double purpose of forming sodium bicarbonate and effecting a preliminary purification of the hydrogen gas to adapt the same for use in the synthesis of ammonia.
By using each carbonating tower of an ammonia soda plant in turn, for the removal of sulfur compounds from water gas, hlkeep the interior of my towerscoated with ms.
Having thus described my inventiomyvhat I claim 15:
1. The improvement in the etfectuation of the ammonia soda process which comprises.
reacting upon ammoniated brine with carbon dioxid diluted with hydrogen to prevent undue development of heat and favor the formation of relatively large crystals of sodium bicarbonate, while simultaneously separatlng said carbon dioxld from said hydrogen, and collecting said hydrogen "preparatory to using the same in an ammonia synthesizing operation.
2. The improvement in the efl'ectuation of the ammonia soda process which comprises reacting upon ammoniated brine with car bon dioxid diluted with hydrogen and which mixture of carbon dioxid and hydrogen is substantially free from carbon monoxid, to simultaneously produce sodium bicarbonate and hydrogen substantially free from gaseous impurities other than nitrogen.
3. The process of producing sodium'b carb'onate and hydrogen, which comprises treating a. gaseous mixture containing carbon monoxid, carbon dioxid. hydrogen and hydrogen sulfid, to free said mixture from said dioxid and sultid, by bubbling it through ammoniated brine in a receptacle the walls of which are of iron. treating the exit gases to convert said carbon monoxid into carbon dioxid, and bubbling the gaseous residues through amnioniated brine to produce sodium bicarbonate and hydrogen.
4. The improvement in the etl'ectuatiim oi" the ammonia. soda process which comprises treating carbonaceous matter, at an elevated temperature, with steam, to form carbon dioxid and hydrogen, and separating said hydrogen from said carbon dioxid through the intermediary of ammoniated brine.
The improvement in the efi'ectuation of: the annnonia soda process, as conducted in carbonating towers the walls of which are of iron, which comprises converting the surfaces of said walls into iron sullid. to providejt'oatings of said sullid upon said walls, v-; assing through said towers the gaseous reaction products resulting from the conversion of sulfur bearing fuel and steam.
into hydrogen. hydrogen sullid. carbon monoxid and arbon dioxid. treating the gases e 'rging lrom said-tower to convert said "I c rbon inonoxld into carbon (bond, and
separating said carbon dioxid from said hydrogen by reacting upon said dioxid with ammoniated brine in a carbonating tower the walls of which are coated with iron sulfid to prevent discoloration of the sodium bicarbonate crystals formed by said last mentioned reaction. a
G. The improvement in the etfectuation of the ammonia soda process, as conducted in carbonating towers the walls of which are of iron, which comprises converting the surfaces of said walls into iron sulfid, to provide coatings of said sultid upon said walls, by passing through said towers the gaseous reaction products resulting from the conversion of sulfur bearing fuel and steam, into hydrogen, hydrogen suliid, carbon monoxid and carbon dioxid.
7. The process of producing sodium bicarbonate and synthetic annnonia by interrelated operations which comprises the formation of a gaseous mixture and the utilization of said mixture to effect the first of said operations and at the same time eliminate from said mixture gases which are adapted to injurious'ly affect the second operation.
8. lhe 'n'ocess oi producing sodium birarbonate and an'nnonia which comprises the formation o'l" a gaseous mixture including carbon dioxid and an ammonia forming gas, utilizing said mixture. in the production of sodium bicarbonate whereby said ammonia forming gas serves as a dilutent tor the carbon dioxid. and recovering the ammonia forinin gas thus freed from carbon dioXid.
9. The process of obtaining pure or substantially pure hydrogen by reacting upon ammoniated brine with a mixture of carbon dioxid and hydrogen. I
In testimony whereof I have atiixed my signature.
ADRIAAN N AGIGIJVOUK-T.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US158863XA | 1920-02-07 | 1920-02-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
USRE15314E true USRE15314E (en) | 1922-03-21 |
Family
ID=21774180
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15314D Expired USRE15314E (en) | 1920-02-07 | Island | |
US1352211D Expired - Lifetime US1352211A (en) | 1920-02-07 | Island |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US1352211D Expired - Lifetime US1352211A (en) | 1920-02-07 | Island |
Country Status (3)
Country | Link |
---|---|
US (2) | US1352211A (en) |
FR (1) | FR524370A (en) |
GB (1) | GB158863A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2787521A (en) * | 1951-06-02 | 1957-04-02 | Chemical Construction Corp | Method of continuously conducting a liquid-gas exothermic reaction |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE756844C (en) * | 1940-12-10 | 1953-01-05 | Kalk Chemische Fabrik Gmbh | Process for the production of acetylene and ammonia soda |
US3329479A (en) * | 1964-04-21 | 1967-07-04 | Hustinx Edmond | Process for recovering calcium chloride from the ammonium chloride waste liquor of the ammonia soda process |
-
0
- US US15314D patent/USRE15314E/en not_active Expired
- US US1352211D patent/US1352211A/en not_active Expired - Lifetime
-
1920
- 1920-09-02 GB GB25359/20A patent/GB158863A/en not_active Expired
- 1920-09-18 FR FR524370A patent/FR524370A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2787521A (en) * | 1951-06-02 | 1957-04-02 | Chemical Construction Corp | Method of continuously conducting a liquid-gas exothermic reaction |
Also Published As
Publication number | Publication date |
---|---|
FR524370A (en) | 1921-09-02 |
GB158863A (en) | 1922-02-02 |
US1352211A (en) | 1920-09-07 |
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