USH1512H - Viscous coupling plate hardening and flattening method - Google Patents

Viscous coupling plate hardening and flattening method Download PDF

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Publication number
USH1512H
USH1512H US08/203,016 US20301694A USH1512H US H1512 H USH1512 H US H1512H US 20301694 A US20301694 A US 20301694A US H1512 H USH1512 H US H1512H
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United States
Prior art keywords
plates
viscous coupling
coupling plates
heat treatment
inches
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Abandoned
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US08/203,016
Inventor
Thomas W. Cowan
Sankar K. Mohan
Carl F. Stephens
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New Venture Gear Inc
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New Venture Gear Inc
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Priority to US08/203,016 priority Critical patent/USH1512H/en
Assigned to NEW VENTURE GEAR, INC. reassignment NEW VENTURE GEAR, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: COWAN, THOMAS W., MOHAN, SANKAR K., STEPHENS, CARL F.
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/80After-treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/28Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases more than one element being applied in one step
    • C23C8/30Carbo-nitriding
    • C23C8/32Carbo-nitriding of ferrous surfaces

Definitions

  • the present invention relates generally to the plates employed in a viscous coupling apparatus of the type used in motor vehicles and, more particularly, to a method for manufacturing a viscous coupling plate exhibiting improved wear resistance and improved resistance to permanent deformation under operating conditions.
  • Viscous couplings are used in various applications within the drivetrain of a motor vehicle.
  • viscous couplings include a rotatable input member and a rotatable output member, both members being rotatable about a common axis.
  • the output member is a hub and the input member is a housing that creates a hermetically sealed chamber around the hub.
  • Contained within the chamber are two sets of viscous coupling plates that are interleaved with one another. The first set of plates, the inner viscous coupling plates, are splined to the hub and rotatable with the hub.
  • a second set of plates, the outer viscous coupling plates are splined to the housing and rotatable with the housing. Filling the remaining space within the chamber is a high viscosity fluid, such as silicone oil, and a small amount of a gas or air.
  • Viscous coupling plates are generally manufactured from a thin plate stock, such as a carbon steel plate material, that is formed by a series of dies in a stamping operation of a machine press. Subsequent to forming operations, the viscous coupling plates are subjected to heat treatment processes in an effort to achieve the desired mechanical and physical properties, such as strength, hardness, toughness and wear resistance, that are required in the finished product.
  • the present invention provides for a method of hardening and flattening a viscous coupling plate generally combining a heat treatment process followed by a mechanical forming operation.
  • the heat treatment process of the present invention generally comprises the steps of first surface hardening a viscous coupling plate by ferritic nitrocarburizing to produce an epsilon iron nitride surface layer on the plate. The plates are then quenched. Next, the plate is tempered without requiring that several plates be clamped together or otherwise touching during this step. Finally, each plate is worked in a mechanical forming operation comprising a flattening process. This is contrary to the accepted teachings in the prior art which discount the effectiveness of such individualized, workpiece-flattening efforts.
  • the flattening process comprises passing the plates through a series of leveling rolls which cause the plates to flex in opposite directions to produce a sufficiently flat plate.
  • the flattening process can incorporate a single pass or multiple passes through the leveling rolls.
  • the flattening process eliminates any distortion in the plates and brings them within any required flatness specifications. Also, the flat rolling process serves to more uniformly redistribute any residual stresses that remain in the plates.
  • the resulting viscous coupling plates exhibit superior performance characteristics than prior plates. Most notably, the plates of the present invention resist the permanent deformation that has been experienced by prior viscous coupling plates under identical operating conditions.
  • the present invention provides a method of hardening and flattening a viscous coupling plate generally combining a heat treatment process followed by a mechanical forming operation.
  • a viscous coupling plate generally combining a heat treatment process followed by a mechanical forming operation.
  • Viscous coupling plates are generally manufactured from a thin plate stock, such as a carbon steel plate material, that is formed by a series of dies in a stamping operation of a machine press. The resulting plates are generally ring-shaped.
  • multiple viscous coupling plates are fixtured on racks in a manner such that individual plates are not in any contact with one another. Also, the plates are spaced as is necessary to ensure the adequate flow of the nitriding media over the entire surface of the plates. In a similar manner, multiple plates can alternatively be suspended or hung on rails.
  • the plates are then surface hardened in a ferritic nitrocarburizing process to create an epsilon iron nitride surface layer on the plates that is on the order of about 0.0003 inches to about 0.0015 inches thick, and preferably 0.0010 inches to about 0.0015 inches thick.
  • the ferritic nitrocarburizing process is performed in a suitable nitriding media, which is preferably either a gaseous atmosphere, such as an atmosphere of ammonia and an endothermic gas, or a molten salt bath, such as one providing a source of nitrogen and carbon.
  • the ferritic nitrocarburizing process is preferably performed at a temperature ranging from about 1050° F. to about 1200° F.
  • the plates are then quenched to room temperature.
  • the parts are either oil quenched or salt quenched followed by air cooling to room temperature.
  • the plates are next tempered.
  • the tempering occurs while the plates are fixtured on the identical apparatus that was used during the preceding ferritic nitrocarburizing process. Consequently, refixturing or rearrangement of the plates prior to the tempering cycle is not required, nor is it necessary that the plates be clamped together or otherwise touching one another during this step.
  • significant cost savings are achievable over conventional techniques which necessitate refixturing of the workpieces prior to tempering.
  • refixturing of the plates could be performed, if desired, provided that the plates are not clamped together or otherwise touching one another.
  • the plates are tempered for at least approximately two (2) hours at a temperature of at least approximately 350° F.
  • the plates are then allowed to air cool to room temperature. It should be understood that the term "air cool" is intended to mean slow cooling, as distinguished from quenching.
  • the viscous coupling plates are removed from their fixturing and are individually processed in a mechanical forming operation.
  • the mechanical forming operation is a flattening process well-known in the art as roller leveling.
  • the roller leveling eliminates any waviness or distortion in the plates without degrading the performance of the hardened surface layer of the plates.
  • the roller leveling allows the plates to be made flat within about 0.002 inches to about 0.013 inches. This easily meets or exceeds any required flatness specifications for the plates.
  • the flat rolling process serves to more uniformly redistribute any residual stresses that remain in the plates.
  • the leveling rolls act to flex the plates simultaneously in opposite directions to flatten the plate.
  • the roller leveling can be accomplished by a single pass or though multiple passes of the viscous coupling plates through the leveling rolls.
  • the resulting viscous coupling plate exhibits ample surface wear resistance properties as well as superior resistance to dishing or permanent deformation when exposed to the operating environment of the viscous coupling apparatus.
  • the surface hardness of the plate meets or exceeds a value of Rockwell C62.
  • the method of hardening and flattening viscous coupling plates of the present invention provides an improved method for hardening and flattening a viscous coupling plate in spite of the contradictory teachings of the prior art. Further, the present invention provides a method for producing a viscous coupling plate which exhibits improved properties and which is cost effective to manufacture in a high volume production environment.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

A method of hardening and flattening a viscous coupling plate generally combining a heat treatment process followed by roller leveling is disclosed. The heat treatment process produces an epsilon iron nitride surface layer of the desired hardness on the plate. Subsequent to the heat treatment, the plates are passed through a series of leveling rolls to produce a sufficiently flat plate. The flat rolling process can incorporate a single pass or multiple passes through the leveling rolls. The method of the present invention eliminates any distortion in the plates and brings them within any required flatness specifications, as well as producing viscous coupling plates that exhibit improved resistance to permanent deformation under operating conditions.

Description

BACKGROUND AND SUMMARY OF THE INVENTION
1. Field of the Invention
The present invention relates generally to the plates employed in a viscous coupling apparatus of the type used in motor vehicles and, more particularly, to a method for manufacturing a viscous coupling plate exhibiting improved wear resistance and improved resistance to permanent deformation under operating conditions.
2. Discussion
Viscous couplings are used in various applications within the drivetrain of a motor vehicle. In general, viscous couplings include a rotatable input member and a rotatable output member, both members being rotatable about a common axis. Typically, the output member is a hub and the input member is a housing that creates a hermetically sealed chamber around the hub. Contained within the chamber are two sets of viscous coupling plates that are interleaved with one another. The first set of plates, the inner viscous coupling plates, are splined to the hub and rotatable with the hub. Similarly, a second set of plates, the outer viscous coupling plates, are splined to the housing and rotatable with the housing. Filling the remaining space within the chamber is a high viscosity fluid, such as silicone oil, and a small amount of a gas or air.
In operation, a slight difference in the rotational speed between the input and output members of the viscous coupling (i.e. slip) is permitted due to the relatively low viscous shear rate within the fluid. However, as the speed differential between the input and output members increases, the viscous shear rate of the fluid also increases. As this occurs, the fluid works to transmit torque from the input member to the output member. Eventually, a pressure increase occurs within the chamber and forces adjacent inner and outer plates into contact with one another, resulting in torque being transferred by friction between the mating plates in addition to the viscous shear rate of the fluid. Once frictional contact has been established between the plates, torque transmission is suddenly and significantly amplified.
Viscous coupling plates are generally manufactured from a thin plate stock, such as a carbon steel plate material, that is formed by a series of dies in a stamping operation of a machine press. Subsequent to forming operations, the viscous coupling plates are subjected to heat treatment processes in an effort to achieve the desired mechanical and physical properties, such as strength, hardness, toughness and wear resistance, that are required in the finished product.
However, it has been learned through experience that conventional heat treatment techniques create distortion in the shape of the viscous coupling plates, causing the plates to be wavy and to fail to meet established requirements for flatness. Further, it is believed that heat treatment generally tends to create a non-uniform distribution of any residual stresses that remain in the plate as a result of the manufacturing operations which formed the plate. The combination of these heat treatment side effects causes the plates to be susceptible to "dishing", a phenomenon of permanent deformation that results from the operating conditions that are experienced by the plates in the viscous coupling apparatus. As a consequence of dishing, the performance of the viscous coupling apparatus is seriously degraded.
Previous attempts have been made to solve the problem of distortion that occurs in thin flat workpieces during heat treatment. Generally, these prior efforts have concentrated on methods involving subjecting a plurality of the distorted workpieces to a second heat treatment while the workpieces are placed under a compression force. Thus, each workpiece, having already undergone a first heat treatment to enhance its material properties, is processed in a second heat treatment that is aimed at reducing or eliminating the distortion. In the subsequent heat treatment, a plurality of the workpieces are fixtured so as to be stacked upon one another and clamped together under a compression force. These prior methods to reduce distortion in thin, flat workpieces, however, require strict controls on the second heat treatment process or result in negating the positive effects of the first heat treatment.
It is therefore an object of the present invention to overcome the disadvantages associated with conventional viscous coupling plates and to provide a method for manufacturing a viscous coupling plate which exhibits resistance to wear and to permanent deformation under operating conditions.
It is another object of the present invention to provide an improved method for hardening and flattening a viscous coupling plate. It is also an object of this invention is to produce a viscous coupling plate which exhibits the above advantages and which is cost effective to manufacture in a high volume production environment.
In achieving the above objects, the present invention provides for a method of hardening and flattening a viscous coupling plate generally combining a heat treatment process followed by a mechanical forming operation. The heat treatment process of the present invention generally comprises the steps of first surface hardening a viscous coupling plate by ferritic nitrocarburizing to produce an epsilon iron nitride surface layer on the plate. The plates are then quenched. Next, the plate is tempered without requiring that several plates be clamped together or otherwise touching during this step. Finally, each plate is worked in a mechanical forming operation comprising a flattening process. This is contrary to the accepted teachings in the prior art which discount the effectiveness of such individualized, workpiece-flattening efforts. The flattening process comprises passing the plates through a series of leveling rolls which cause the plates to flex in opposite directions to produce a sufficiently flat plate. The flattening process can incorporate a single pass or multiple passes through the leveling rolls. The flattening process eliminates any distortion in the plates and brings them within any required flatness specifications. Also, the flat rolling process serves to more uniformly redistribute any residual stresses that remain in the plates.
The resulting viscous coupling plates exhibit superior performance characteristics than prior plates. Most notably, the plates of the present invention resist the permanent deformation that has been experienced by prior viscous coupling plates under identical operating conditions.
Various other features and advantages of the present invention will become apparent to those skilled in the art to which this invention relates after having the benefit of studying the teachings of the specification and the claims.
DESCRIPTION OF THE PREFERRED EMBODIMENT
It should be understood from the outset that while the following discussion relates to a particular embodiment of the present invention, this embodiment merely represents what is presently regarded as the best mode of practicing the invention and other modifications may be made to the particular embodiment without departing from the spirit and scope of the invention.
The present invention provides a method of hardening and flattening a viscous coupling plate generally combining a heat treatment process followed by a mechanical forming operation. Although the following discussion is specifically addressing the hardening and flattening of viscous coupling plates, it should be readily appreciated by those in the art that the method of the present invention is equally suitable for other thin, disc-like workpieces such as clutch plates, thrust washers, shims, and the like.
Viscous coupling plates are generally manufactured from a thin plate stock, such as a carbon steel plate material, that is formed by a series of dies in a stamping operation of a machine press. The resulting plates are generally ring-shaped.
In preparation for the heat treatment process of the present invention, multiple viscous coupling plates are fixtured on racks in a manner such that individual plates are not in any contact with one another. Also, the plates are spaced as is necessary to ensure the adequate flow of the nitriding media over the entire surface of the plates. In a similar manner, multiple plates can alternatively be suspended or hung on rails.
The plates are then surface hardened in a ferritic nitrocarburizing process to create an epsilon iron nitride surface layer on the plates that is on the order of about 0.0003 inches to about 0.0015 inches thick, and preferably 0.0010 inches to about 0.0015 inches thick. The ferritic nitrocarburizing process is performed in a suitable nitriding media, which is preferably either a gaseous atmosphere, such as an atmosphere of ammonia and an endothermic gas, or a molten salt bath, such as one providing a source of nitrogen and carbon. The ferritic nitrocarburizing process is preferably performed at a temperature ranging from about 1050° F. to about 1200° F. for a time period of about one (1) to six (6) hours, and preferably for about three (3) to about three and one-half (31/2) hours. After nitrocarburizing, the plates are then quenched to room temperature. Preferably the parts are either oil quenched or salt quenched followed by air cooling to room temperature.
To achieve metallurgical stability, the plates are next tempered. The tempering occurs while the plates are fixtured on the identical apparatus that was used during the preceding ferritic nitrocarburizing process. Consequently, refixturing or rearrangement of the plates prior to the tempering cycle is not required, nor is it necessary that the plates be clamped together or otherwise touching one another during this step. Thus, significant cost savings are achievable over conventional techniques which necessitate refixturing of the workpieces prior to tempering. However, refixturing of the plates could be performed, if desired, provided that the plates are not clamped together or otherwise touching one another. The plates are tempered for at least approximately two (2) hours at a temperature of at least approximately 350° F. The plates are then allowed to air cool to room temperature. It should be understood that the term "air cool" is intended to mean slow cooling, as distinguished from quenching.
Subsequent to the heat treatment, the viscous coupling plates are removed from their fixturing and are individually processed in a mechanical forming operation. The mechanical forming operation is a flattening process well-known in the art as roller leveling. The roller leveling eliminates any waviness or distortion in the plates without degrading the performance of the hardened surface layer of the plates. The roller leveling allows the plates to be made flat within about 0.002 inches to about 0.013 inches. This easily meets or exceeds any required flatness specifications for the plates. In addition, the flat rolling process serves to more uniformly redistribute any residual stresses that remain in the plates.
As the plates are passed through the leveling rolls, the leveling rolls act to flex the plates simultaneously in opposite directions to flatten the plate. The roller leveling can be accomplished by a single pass or though multiple passes of the viscous coupling plates through the leveling rolls.
The resulting viscous coupling plate exhibits ample surface wear resistance properties as well as superior resistance to dishing or permanent deformation when exposed to the operating environment of the viscous coupling apparatus. The surface hardness of the plate meets or exceeds a value of Rockwell C62.
The method of hardening and flattening viscous coupling plates of the present invention provides an improved method for hardening and flattening a viscous coupling plate in spite of the contradictory teachings of the prior art. Further, the present invention provides a method for producing a viscous coupling plate which exhibits improved properties and which is cost effective to manufacture in a high volume production environment.
The present invention has been described in an illustrative manner. It should be understood that the terminology which has been used is intended to be in the nature of words of description rather than of limitation. Many modifications or variations to the present invention are possible in light of the above teachings. Therefore, within the scope of the following claims, the present invention may be practiced otherwise than as specifically described.

Claims (1)

What is claimed is:
1. A method for hardening and flattening viscous coupling plates used in drivetrains of motor vehicles and subjected to frictional contact with one another for torque transmission to provide wear resistance and improved resistance to plastic deformation during use, said method comprising the steps of:
(a) placing a plurality of viscous coupling plates spaced apart from one another in a fixture and while in said fixture sequentially:
(1) ferritic nitrocarburizing said viscous coupling plates from step (a) above at a temperature of about 1050° F. to about 1200° F. in a nitriding media for a time period of about three to about three and one-half hours and producing an epsilon iron nitride surface layer on said viscous coupling plates that is about 0.0010 inches to about 0.0015 inches thick and has a hardness of about Rockwell C62;
(2) oil quenching said viscous coupling plates from step (a)(1) to room temperature;
(3) tempering said viscous coupling plates from step (a)(2) for at least about two hours at a temperature of at least about 350° F.;
(4) air cooling said viscous coupling plates from step (a)(3) to room temperature;
(b) removing said viscous coupling plates from step (a)(4) from said fixture; and
(c) passing said viscous coupling plates from step (b) through a series of leveling rolls at least once to bring said plates to within about 0.002 inches to about 0.013 inches flatness and to more uniformly redistribute any residual stresses that remain in said plates and to render said plates less susceptible to deformation during use in the drivetrain of a motor vehicle.
US08/203,016 1994-02-28 1994-02-28 Viscous coupling plate hardening and flattening method Abandoned USH1512H (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020134104A1 (en) * 2000-11-10 2002-09-26 James Stenhouse High efficiency discontinuous cryogenic mixed gas refrigeration system using coalescent (depth) membrane filters and plate heat exchangers and refrigerant therefore
US20030107751A1 (en) * 2001-12-12 2003-06-12 Sadahiro Tanaka Multi-mode print data processing
US6656293B2 (en) 2001-12-10 2003-12-02 Caterpillar Inc Surface treatment for ferrous components
US20080118763A1 (en) * 2006-11-20 2008-05-22 Balow Robert A Seasoned Ferrous Cookware
US20100242785A1 (en) * 2009-03-26 2010-09-30 Belanger, Inc. Car wash conveyor dolly and method of making same
US20110067788A1 (en) * 2009-09-24 2011-03-24 Swiatek Glenn J Processes for reducing flatness deviations in alloy articles

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1535191A (en) * 1924-02-15 1925-04-28 Ernest E Wemp Method of constructing clutch disks
US2814580A (en) * 1955-09-02 1957-11-26 Int Harvester Co Heat treated agricultural implement disks having non-directional fracture characteristics
US3510367A (en) * 1967-10-20 1970-05-05 Kent Moore Corp Method of heat treating ferrous alloy sheets
US3806379A (en) * 1972-03-13 1974-04-23 Crucible Inc Method for heat treating coulter blades
US4210843A (en) * 1979-04-03 1980-07-01 Zenith Radio Corporation Color CRT shadow mask and method of making same
US4496401A (en) * 1981-10-15 1985-01-29 Lucas Industries Corrosion resistant steel components and method of manufacture thereof
US4713122A (en) * 1985-03-20 1987-12-15 Lucas Industries Public Limited Company Production of thin flat articles with hardened surfaces
US4793871A (en) * 1986-04-10 1988-12-27 Lucas Industries Public Limited Company Method of improving surface wear qualities of metal components

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1535191A (en) * 1924-02-15 1925-04-28 Ernest E Wemp Method of constructing clutch disks
US2814580A (en) * 1955-09-02 1957-11-26 Int Harvester Co Heat treated agricultural implement disks having non-directional fracture characteristics
US3510367A (en) * 1967-10-20 1970-05-05 Kent Moore Corp Method of heat treating ferrous alloy sheets
US3806379A (en) * 1972-03-13 1974-04-23 Crucible Inc Method for heat treating coulter blades
US4210843A (en) * 1979-04-03 1980-07-01 Zenith Radio Corporation Color CRT shadow mask and method of making same
US4496401A (en) * 1981-10-15 1985-01-29 Lucas Industries Corrosion resistant steel components and method of manufacture thereof
US4713122A (en) * 1985-03-20 1987-12-15 Lucas Industries Public Limited Company Production of thin flat articles with hardened surfaces
US4793871A (en) * 1986-04-10 1988-12-27 Lucas Industries Public Limited Company Method of improving surface wear qualities of metal components

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Metals Handbook, "Nitriding", 1948 Edition, The American Society for Metals, 1948, pp. 697-702.
Metals Handbook, Nitriding , 1948 Edition, The American Society for Metals, 1948, pp. 697 702. *
New Venture Gear Process Standard No. 632 Rev. A, Dec. 5, 1991 2 pages. *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020134104A1 (en) * 2000-11-10 2002-09-26 James Stenhouse High efficiency discontinuous cryogenic mixed gas refrigeration system using coalescent (depth) membrane filters and plate heat exchangers and refrigerant therefore
US6656293B2 (en) 2001-12-10 2003-12-02 Caterpillar Inc Surface treatment for ferrous components
US20030107751A1 (en) * 2001-12-12 2003-06-12 Sadahiro Tanaka Multi-mode print data processing
US20080118763A1 (en) * 2006-11-20 2008-05-22 Balow Robert A Seasoned Ferrous Cookware
US7622197B2 (en) * 2006-11-20 2009-11-24 Ferroxy-Aled, Llc Seasoned ferrous cookware
US20100242785A1 (en) * 2009-03-26 2010-09-30 Belanger, Inc. Car wash conveyor dolly and method of making same
US8985029B2 (en) * 2009-03-26 2015-03-24 Belanger, Inc. Car wash conveyor dolly and method of making same
US20110067788A1 (en) * 2009-09-24 2011-03-24 Swiatek Glenn J Processes for reducing flatness deviations in alloy articles
US9822422B2 (en) * 2009-09-24 2017-11-21 Ati Properties Llc Processes for reducing flatness deviations in alloy articles
US10260120B2 (en) 2009-09-24 2019-04-16 Ati Properties Llc Processes for reducing flatness deviations in alloy articles

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