US801489A - Protecting metal surfaces. - Google Patents

Protecting metal surfaces. Download PDF

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Publication number
US801489A
US801489A US22764304A US1904227643A US801489A US 801489 A US801489 A US 801489A US 22764304 A US22764304 A US 22764304A US 1904227643 A US1904227643 A US 1904227643A US 801489 A US801489 A US 801489A
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metal
metal surfaces
copper
electropositive
iron
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US22764304A
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Friedrich Uthemann
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • C23F13/02Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions

Definitions

  • the present invention relates to the protection of bodies having surfaces containing copper or other corrodible metal-for instance, copper pipes-from the action of sea-Water or other corroding Huid. j
  • the surface of the metal is covered at as uniformlyrecurring distances as possible with a more electroposltve metal-for example, iron-in such form as to leave spaces between the portions of the applied metal.
  • a more electroposltve metal-for example, iron-in such form as to leave spaces between the portions of the applied metal.
  • Wire-netting, helically-wound wire, perforated sheets, or other suitable forms of the electropositive-metal may he used.
  • 'Such metal is brought into electrical contact with the surface to be protected.
  • the electrolytic action taking place on salt water having access to the corrodible surface brings about a destruction of the electropositive metal, a firmly-adhering uniform layer of iron oxid being simultaneously formed on the copper or other surface.
  • Copper or other pipes which are used to conduct the salt Water are preferably provided internally with a helically-Wound resilient iron or steelY wire, the wire being of such thickness as to amount to about a one hundred and fiftieth part of the surface of the pipe to be protected.
  • the Wire helix or spring is contracted diametrically and introduced into the pipe, and when released its elasticity causes it to lie so tightly against the inner wall of the pipe that an ordinary current of water cannot drag the helix with it. In long pipes and those having many bends the helices may be introduced from both ends.
  • the protective oxid layer ' is deposited even on those places which are not directly reached by the wire, so that such places are protected from corrosion.
  • Other corrodible metals which are exposed to corroding fluids may be treated in a similar manner to that in which the surfaces containing copper are treated.
  • Figure 1 shows a surface of copper-for instance, a
  • Fig. 2 shows a pipe d in longitudinal section ⁇ which pipe is covered on its interior with helicall ywound wire f of iron or steel.
  • electropositive material s'hould be applied in such manner as to leave spaces between its parts through which the water may reach the surface to be protected, and any form, whether of netted wires, perforated plates, helices, or otherwise, which permits this action is included within the term .network, which I have used in the claims to designate such form of the electropositive metal.
  • What I claim is-' 1.
  • the method of protecting a surface containing a metal which is liable to be attacked by a corroding fluid which consists in depositing upon such surface a coating from a more electropositive metal by distributing it at intervals over said surface, supportingv it in electrical contact with said surface and permitting such uid to act upon such metals.
  • a body for use in contact with a corroding Huid having a surface containing a corrodible metal and having a more electropositive metal distributed at intervals over said IOO surface and supported in electrical Contact electropositive material in Contact; with said .IO with said surface. i interior surface.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • ing And Chemical Polishing (AREA)

Description

UNrrED STATES PATENT OFFICE.
PnoTEcTINe mE-TAL SURFACES.
Specification of Letters Patent.
Patented Oct. 10, 1905.
Application mea october a, 1904. serial No. 227.643.
To all whom, it may concern:
Be it known that I, FRIEDRICH UTHEMANN, a subject of the King of Prussia, German Emperor, residing at Heiligenbrunner Weg 6, Langfuhr, near Dantzie, Germany, have inventedcertain new and useful Improvements in Protecting Metal Surfaces, of which the following is a specification.
The present invention relates to the protection of bodies having surfaces containing copper or other corrodible metal-for instance, copper pipes-from the action of sea-Water or other corroding Huid. j
According to the preferred form of the present invention as applied to the' protection of copper or surfaces containing copper against corrosion due to the action of salt water the surface of the metal is covered at as uniformlyrecurring distances as possible with a more electroposltve metal-for example, iron-in such form as to leave spaces between the portions of the applied metal. Wire-netting, helically-wound wire, perforated sheets, or other suitable forms of the electropositive-metal may he used. 'Such metal is brought into electrical contact with the surface to be protected. The electrolytic action taking place on salt water having access to the corrodible surface brings about a destruction of the electropositive metal, a firmly-adhering uniform layer of iron oxid being simultaneously formed on the copper or other surface. This deposit is not acted upon by the salt water-that is to say, it is proof against the latter-so that even after the complete consumption of the more electropositive metal ample protection is afforded. Copper or other pipes which are used to conduct the salt Water are preferably provided internally with a helically-Wound resilient iron or steelY wire, the wire being of such thickness as to amount to about a one hundred and fiftieth part of the surface of the pipe to be protected. The Wire helix or spring is contracted diametrically and introduced into the pipe, and when released its elasticity causes it to lie so tightly against the inner wall of the pipe that an ordinary current of water cannot drag the helix with it. In long pipes and those having many bends the helices may be introduced from both ends. The protective oxid layer 'is deposited even on those places which are not directly reached by the wire, so that such places are protected from corrosion. Other corrodible metals which are exposed to corroding fluids may be treated in a similar manner to that in which the surfaces containing copper are treated.
In the accompanying drawings, Figure 1 shows a surface of copper-for instance, a
sheet a-which is covered with netted wires b of iron or steel on that side which comes in contact with the water. The netting may be fixed to the sheet in any suitable manner, as by clamping, riveting, or otherwise. Fig. 2 shows a pipe d in longitudinal section` which pipe is covered on its interior with helicall ywound wire f of iron or steel.
It will be noted that the electropositive material s'hould be applied in such manner as to leave spaces between its parts through which the water may reach the surface to be protected, and any form, whether of netted wires, perforated plates, helices, or otherwise, which permits this action is included within the term .network, which I have used in the claims to designate such form of the electropositive metal.
While I have specifically described my invention in its preferred form as applied to protecting surfaces containing copper from corrosion from salt water, it will be understood that I do'not wish to be limited thereto,
as my invention is susceptible of use with other materials and in other Ways than those thus described.
What I claim is-' 1. The method of protecting a surface containing a metal which is liable to be attacked by a corroding fluid, which consists in depositing upon such surface a coating from a more electropositive metal by distributing it at intervals over said surface, supportingv it in electrical contact with said surface and permitting such uid to act upon such metals.
2. The method of protecting the surface of a tube containing a metal which is liable to bel attacked by a uid, which consists in applying a helical strip of electropositive metal thereto, and permitting such fluid Ato act upon said metals.
3. The method of protecting a surface containing copper from the corroding action of salt water, which consists in depositing thereon a coating from iron, by supporting a network of iron in electrical contact with said surface, and permitting such fluid to act upon said metals.
4. A body for use in contact with a corroding Huid having a surface containing a corrodible metal and having a more electropositive metal distributed at intervals over said IOO surface and supported in electrical Contact electropositive material in Contact; with said .IO with said surface. i interior surface.
5. A tube for use in Contact with a coi'rod- In witness whereof I have hereunto signed ing fluid, having a surface containing a eormy name in the presence of two subscribing rodible metal and a helical strip of more eleewitnesses.
tropositive metal supported upon said surface. I FRIEDRICH U'IHEMANN.
6. A tube for use in conveyinga corroding Witnesses:
iuid having an interior surface containing a ERNST GRUMSKI,
corrodible metal, and a helical strip of more ERIK BLMNER.
US22764304A 1904-10-08 1904-10-08 Protecting metal surfaces. Expired - Lifetime US801489A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2861924A (en) * 1956-07-23 1958-11-25 Shell Dev Composition of matter and corrosion prevention process
US3373802A (en) * 1964-12-07 1968-03-19 Reymersholms Gamla Ind Ab Heat exchanger with removable tube groups of decreasing flow area
US3445370A (en) * 1965-05-07 1969-05-20 Roger M Sherman Corrosion prevention device for irrigation pipe
US3656545A (en) * 1968-05-21 1972-04-18 Varian Associates Fibrous vapor cooling means
US3724250A (en) * 1971-10-04 1973-04-03 A Molino Rolling and beading machine
US3891394A (en) * 1974-04-10 1975-06-24 Love Oil Company Inc Crystal generator to inhibit scale formation and corrosion in fluid handling systems
US4496444A (en) * 1973-04-19 1985-01-29 Caunned Aktiengesellschaft Method of corrosion protection

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2861924A (en) * 1956-07-23 1958-11-25 Shell Dev Composition of matter and corrosion prevention process
US3373802A (en) * 1964-12-07 1968-03-19 Reymersholms Gamla Ind Ab Heat exchanger with removable tube groups of decreasing flow area
US3445370A (en) * 1965-05-07 1969-05-20 Roger M Sherman Corrosion prevention device for irrigation pipe
US3656545A (en) * 1968-05-21 1972-04-18 Varian Associates Fibrous vapor cooling means
US3724250A (en) * 1971-10-04 1973-04-03 A Molino Rolling and beading machine
US4496444A (en) * 1973-04-19 1985-01-29 Caunned Aktiengesellschaft Method of corrosion protection
US3891394A (en) * 1974-04-10 1975-06-24 Love Oil Company Inc Crystal generator to inhibit scale formation and corrosion in fluid handling systems

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