US598096A - Theodor ieylev - Google Patents

Description

Substances,

,Pnrsnr @l hifillg THEODQR ZEVLEV, OF ST. PETERSBURG, RUSSIA.

EXPLOSWE.

@PEUEFECl-L'JIIQBI forming part of Letters Fatent No. 598,096, dated February 1, 1898. Application filed May 28, 1897- Seriel No. 638,618x (No specimens.)

To caZZ 10. 10722 it rim/7, concern.-

Bllil1OWTib113 1,THEODORIEVLEV,#lSilbjeet of the Elnperorof Russia, residing at St. Petershurg, Russia, have invented certain new and useful Improvements in Explosible of which the following is a specificetion.

My invention has relation to explosives; and it has for its object a compound that is neither explosive nor inflammable per se,l1ut which when ininregusted or saturated with a. combustible liquid rich in carbon becomes explosive, not in the open air, but when confined and subjected to concussion or percussion or when ignited, or both.

The further object of my invention is to avoid the use of nitrogen-hearing substances, notwithstanding the great energy of nitrogen in explos es, on account of the unstable neture of theeompouuds of this element.

The nonf-Texplos'ive and non-inflammable compou ed referred to consists, in accordance with this invention, of oxygenheeriug substances or asubstenocs capable of evolving oxygen in the presence of heat, together with oxygeirheering substances, as e chlorate of e metal of the alkelies and a metallic oxid or oxide. uch a com iouud when impregnated with an inflammable or combustible liquid, as a hydrocarbon or an essential hydrocarbon oil, or both, becomes highly explosive when sul j ected to percussion or concussion or when ignited, or both, the explosive power being at least equal to that of dynamite or other like high explosives, while in the open an the compound is quiet-i producing an intense white 1 1 According to the uses made oi. the explosive 1 odd or may add whet is usually termed a moderator that to say, e substance capable of retarding combustion-stud to this end I use a slow-burning oil, as an oil of the fatty-acid series, such as oil of almonds; but that my invention may be fully understood 1 will describe the same in detail.

The non-inflammable and non-explosive compound consists or may consist of the following substances in or about in the proportions, by weight, set forth:

Chlorate of pot- $esquioxid or Oxid of mangu- Total 5 ash, (KCIOM iron, (1? e 0 nose, (llln(),.) 56 parts. 24 parts. 20 parts. 190 OI 76 parts. 24 parts. 100 or u SO'purts. 20, parts. 100

The impregnating liquid consists or may consist of the following, to which may be or is added a moderator iuthe proportions, by

' weight, stated:

on 0i en-018mm. on of tulpnti1ie. Oilofulmonds. Total.

50 parts. 40 parts. 10 parts. 100 or '50 parts. 50 parts. 190' 5 or y 80 parts. 15 parts. 5 parts. 100 or 100parts. 100 or 7 100 parts. 100

The proportions of inflammable liquid necesssry to convert the non-explosive and noninilammahle compound into an inflammable and explosive compound is about as of'thr'ee of the latter to oneof the liquid, or, in other words, it requires two hundred and fifty grams of the liquid to seven hundred and fifty grams of the compound.

The explosive may be used as such or made up into cartridges of any desired size and form, which cartridges can be provided with the percussion-firing devices or caps commonly used with explosives or they maybe fired by electricity.

' 'lhe impregnation of the non-explosive com.- pouud with the liquid may be effected at once or after being made up into cartridges, the latter method being of course preferred be cause. all danger of premature explosion is thereby avoided, and in order that the impregnation may be readily eflected I make the certridgecases of a. material that will readily absorb the liquid, the compound itself dynamite,

- an explosion will not taking up or absorbing such liquid very readily, and, according to the material used for the cartridge-cases, from ten to fifteen minutes will be required for the absorption,

of the liquid.

The non-inflammable and non-explosive compound-21 e., the non-impregnated compound-possesses the following properties: It is, as inferred, non-inflammable and nonexplosivewhen subjected to concussion or percussion, whether in the open air or confined. It is therefore absolutely safe, not only in its manufacture and in the handling thereof otherwise, as in packing or storing, but also in transportation on land or water. It is not affected by atmospheric influences, nor does it umlergo either physical or ehemical changes under such influences, however sudden or great in the degree of their variations these changes may be.

The impregnating liquid possesses the following properties, to wit: It does not ignite very readily, burns quietly when ignited, and produces during combustion relatively large quantities of carbon, while if ignited it can be readily extinguished by water and possesses besides this the properties of the nonexplosive compound. It follows that so long as the compound is not impregnated with the liquid an explosion is not to be feared, so that the laws relating to the storage of high explosives do not apply and the usual expenses in providing special storage are avoided.

The explosivei. 6., the compound-when impregnated with the liquid possesses the following properties: It will burn quietly in the open air, producing an intense white light and evolving comparatively enormous quantities of gas. When confined either within solid Walls or in water and ignited or subjectedto concussion or percussion it explodes with an energy equally as great as that of the combustion being apparently perfect in that there is no discoloration (unconsumed carbon) noticeable on the surfaces in contact with the explosive, nor will the explosive or a cartridge of such when exploded in the vicinity of another result in the explosion of the latter, which clearly shows that result unless the impregnated powder is subjected to the direct action of percussion or concussion br to fire, or both.

Inasmuch as the impregnating liquid is 5 5 more or less volatile, should a cartridge have been impregnated and not used it can be exposed to sufficient heat to evaporate the liquid, whereby its explosive properties will be destroyed, and such cartridge can atany time 69 thereafter be again impregnated for use.

Inasmuch as-it takes some time to impregnate a cartridge with the liquid, as above stated, the compound does not become explosive until the absorption is complete, so that ample time is afforded for the introduction of the cartridge into the blast-hole and for the attendants to move to a safe distance or place.-

It will also be observed that the explosive is 70 free from ,nitrogen-bearing substances, hence free from nitrogen, which element although Very energetic in explosive compounds is not desirable, because its combinations are-very unstable.

In view of the properties of the explosive it can he used without the least danger in an atmosphere of explosible gases, as in an at mosphere of fire-damp.

Finally, it will be obvious to any one cou- 8o versant with the manufacture of high explosives that, irrespective of the advantages possessed by the explosive forming thesubjectmatter of this invention and hereinabove described, there is a further and very great advantage in the extremely'low cost of the explosive as compared with the cost of explosives of like power heretofore used.

Having thus described my invention, what I claim as new therein, and desire to secure by 0 Letters Patent, is-

1. 'An explosive consisting of chlorate of potash, a metallic oxid or oxids, petroleum and turpentine,-in about the proportions set forth.

2..An explosive compound consisting of chlorate of potash, sesquioxid of iron, oxidof manganese, petroleum, turpentine and an oil of the fatty-acid series, asoil of almonds, in about the proportions set forth.

In testimony whereof I have signed my: name tothis specification in the presence of two subscribing witnesses.

THEODOR IE VLEV.

\Vitncsses:

N. TSCHEKALOFF, J. BLAU.