US566673A - Electrolytic apparatus - Google Patents

Electrolytic apparatus Download PDF

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US566673A
US566673A US566673DA US566673A US 566673 A US566673 A US 566673A US 566673D A US566673D A US 566673DA US 566673 A US566673 A US 566673A
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blocks
plates
anode
cathode
electrolytic apparatus
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes

Definitions

  • This invention relates to improvements in electrolytic apparatus, and the object is to facilitate the separation of precious metals from base metals or materials, and also to separate from metals generally such foreign metals or materials as may be incorporated with them.
  • Figure 1 is a plan view of an apparatus embodying our invention.
  • Fig. 2 is a sectional elevation of the same, and
  • Fig. 3 is a perspective view of an anode and cathode employed.
  • A designates an electrolytic tank of any suitable material, such, for instance, as wood.
  • B indicates the anodes, and B the cathodes.
  • These anodes and cathodes are supported vertically in the tank A with their lower ends resting on strips of glass or other non-conducting material a, secured within the tank at the lower portion of the opposite side walls. These strips serve to support the anodes and cathodes sufficiently above the bottom of the tank to prevent bridging or short-circuiting through byproducts that may fall to the bottom of the tank.
  • the anodes B may be made of either cast or rolled metal and of any desired thickness, but preferably they will be made of cast metal, for the sake of economy, and as thin as possible.
  • the cathodes B may be made of any desired metal or material which is a good conductor 0" electricity, either similar to or different from the anodes, but preferably of a diiferent mate- $eria1No. 591,054. (No model.)
  • Each cathode is placed in close contact with an anode, so that no electrolyte in the tank can pass between them.
  • the plates may be secured together by any suitable means, such, for instance, as by clamps. We find, however, that it is better to first make the cathode in the form of a paste and spread it over the face of the anode, where it is allowed to dry and harden before being used.
  • spherical blocks a a of non-conducting substance, such, for instance, as fictile material. These blocks are arranged to bear at one side against an anode and at the other side against an adjacent cathode, the blocks a being at the upper portion and near the ends of the plates and the blocks a at the lower portion and near the ends of the plates.
  • the upper blocks a at each end of the plates are connected in pairs by a cord or similar flexible connection a and are suspended over alternate plates, and the lower blocks a are suspended by cords or other flexible connections from the upper blocks.
  • the parts 0, a may consist of a single cord with the four blocks strung upon it.
  • spherical blocks instead of square or angular blocks are because they oppose less bearing-surface to the plates and thus cause less unfinished product that would have to be again treated. It is to be understood, however, that we do not confine our invention to spherical ball or blocks, as it is obvious that they may be of any other shape, suclnfor instance,as rectan gular,without departing from the spirit of our invention.
  • the initial anode B is a single plate of the material to be refined, and the terminal cathode B is a single plate of the finished product.
  • one pole of an electric source here indicated as a dynamo A, has a connection .2 with the ini- -tial anode 13 and the other pole of the electric source has a connection 1 with the terminal cathode B so that the current will pass through the whole series of anodes and cathodes and the electrolyte within the tank.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)

Description

(H0 Madel.)
a. w. PIELDING & L. B. WALKER. ELEGTROLYTIG APPARATUS.
No; 566,673. Patented Aug. 25, 1896.
A TTOHNEIS.
UNITED STATES PATENT Oiwrcn.
CHARLES TV. FIELDING, OF LONDON, ENGLAND, AND LOUIS B. WALKER, OF ELIZABETH, NEW JERSEY.
ELECTROLYTlC APPARATUS.
SPECIFICATION formingpart of Letters Patent No. 566,673, dated August 25, 1896.
Application filed May 11, 1896.
To all whom it may concern.-
Be it known that we, CHARLES XV. FIELD- ING, of London, England, and LOUIS B. \VALKER, of Elizabeth, in the county of Union and State of New Jersey, have invented a new and Improved Electrolytic Apparatus, of which the following is a full, clear, and exact description.
This invention relates to improvements in electrolytic apparatus, and the object is to facilitate the separation of precious metals from base metals or materials, and also to separate from metals generally such foreign metals or materials as may be incorporated with them.
"We will describe an apparatus embodying our invention, and then point out the novel features in the appended claims.
Reference is to be had to the accompanying drawings, forming a part of this specification, in which similar characters of reference indicate corresponding parts in all the figures.
Figure 1 is a plan view of an apparatus embodying our invention. Fig. 2 is a sectional elevation of the same, and Fig. 3 is a perspective view of an anode and cathode employed.
Referring to the drawings, A designates an electrolytic tank of any suitable material, such, for instance, as wood. B indicates the anodes, and B the cathodes. These anodes and cathodes are supported vertically in the tank A with their lower ends resting on strips of glass or other non-conducting material a, secured within the tank at the lower portion of the opposite side walls. These strips serve to support the anodes and cathodes sufficiently above the bottom of the tank to prevent bridging or short-circuiting through byproducts that may fall to the bottom of the tank.
The anodes B may be made of either cast or rolled metal and of any desired thickness, but preferably they will be made of cast metal, for the sake of economy, and as thin as possible.
The cathodes B may be made of any desired metal or material which is a good conductor 0" electricity, either similar to or different from the anodes, but preferably of a diiferent mate- $eria1No. 591,054. (No model.)
rial. Each cathode is placed in close contact with an anode, so that no electrolyte in the tank can pass between them. The plates may be secured together by any suitable means, such, for instance, as by clamps. We find, however, that it is better to first make the cathode in the form of a paste and spread it over the face of the anode, where it is allowed to dry and harden before being used.
Vithout regard to the means for securing an anode and cathode together, it is to be understood that there is to be no insulationbetween them.
As a means for separating and supporting the plates vertically in the tank, we employ spherical blocks a a of non-conducting substance, such, for instance, as fictile material. These blocks are arranged to bear at one side against an anode and at the other side against an adjacent cathode, the blocks a being at the upper portion and near the ends of the plates and the blocks a at the lower portion and near the ends of the plates.
The upper blocks a at each end of the plates are connected in pairs by a cord or similar flexible connection a and are suspended over alternate plates, and the lower blocks a are suspended by cords or other flexible connections from the upper blocks.
It is to be understood that the parts 0, a may consist of a single cord with the four blocks strung upon it.
The object in employing spherical blocks instead of square or angular blocks is because they oppose less bearing-surface to the plates and thus cause less unfinished product that would have to be again treated. It is to be understood, however, that we do not confine our invention to spherical ball or blocks, as it is obvious that they may be of any other shape, suclnfor instance,as rectan gular,without departing from the spirit of our invention.
The initial anode B is a single plate of the material to be refined, and the terminal cathode B is a single plate of the finished product.
In refining copper or other material one pole of an electric source, here indicated as a dynamo A, has a connection .2 with the ini- -tial anode 13 and the other pole of the electric source has a connection 1 with the terminal cathode B so that the current will pass through the whole series of anodes and cathodes and the electrolyte within the tank.
Having thus described our invention, we claim as new and desire to secure by Letters Patent 1. In an electrolytic apparatus, the combination with anodes and cathodes, of separating and supporting blocks of insulating material suspended between plates at points between their ends, substantially as specified.
2. In an electrolytic apparatus, the combination with anode and cathode plates, of separating and supporting blocks of non-conducting material suspended from the plates,
substantially as specified.
3. In an electrolytic apparatus, the combination with anode and cathode plates, of separating and supporting blocks of insulating material having cords or flexible connections as a support, substantially as specified.
4. In an electrolytic apparatus, the combination with anode and cathode plates, 01": separating and supporting blocks of insulating material, and a flexible connection between 1 specified.
GHARLESW. FIELDING. LOUIS B. WALKER.
Witnesses to the signature of Charles V.
Fielding:
W. O. FALLON, T. G. WATERS.
Witnesses to the signature of Louis B. Valker:
THos. P. SHERIDAN, W. P. LAVERTY.
US566673D Electrolytic apparatus Expired - Lifetime US566673A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3451906A (en) * 1965-10-29 1969-06-24 Electric Reduction Co Respacing of electrodes in electrolytic cells for the production of the halates,perhalates or hypohalites of alkali metals
US3864237A (en) * 1972-01-26 1975-02-04 Diamond Shamrock Corp Bipolar diaphragmless electrolytic cells
US4288309A (en) * 1978-12-20 1981-09-08 Ecopol Electrolytic device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3451906A (en) * 1965-10-29 1969-06-24 Electric Reduction Co Respacing of electrodes in electrolytic cells for the production of the halates,perhalates or hypohalites of alkali metals
US3864237A (en) * 1972-01-26 1975-02-04 Diamond Shamrock Corp Bipolar diaphragmless electrolytic cells
US4288309A (en) * 1978-12-20 1981-09-08 Ecopol Electrolytic device

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