US4859544A - Weld filter material for fusion welding of high strength aluminum alloys - Google Patents

Weld filter material for fusion welding of high strength aluminum alloys Download PDF

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Publication number
US4859544A
US4859544A US07/217,680 US21768088A US4859544A US 4859544 A US4859544 A US 4859544A US 21768088 A US21768088 A US 21768088A US 4859544 A US4859544 A US 4859544A
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US
United States
Prior art keywords
wire according
filler wire
zinc
magnesium
manganese
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
US07/217,680
Inventor
Pius Schwellinger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alcan Holdings Switzerland AG
Original Assignee
Schweizerische Aluminium AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Schweizerische Aluminium AG filed Critical Schweizerische Aluminium AG
Assigned to SWISS ALUMINIUM LTD. reassignment SWISS ALUMINIUM LTD. ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: SCHWELLINGER, PIUS
Application granted granted Critical
Publication of US4859544A publication Critical patent/US4859544A/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/28Selection of soldering or welding materials proper with the principal constituent melting at less than 950 degrees C
    • B23K35/286Al as the principal constituent
    • B23K35/288Al as the principal constituent with Sn or Zn
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12736Al-base component
    • Y10T428/12764Next to Al-base component

Definitions

  • the invention relates to a weld filler material for fusion welding of high strength aluminum alloys, in particular alloys of the AlZnMgCu type.
  • welded components of high strength aluminum alloys must meet stringent demands with respect to mechanical strength. Apart from qualitatively good welding, the composition of the weld filler material is also a determining factor. On the one hand, the filler wire materials hitherto used tend to cause heat cracks in the weld metal and, on the other hand, they also cause cracks in the base material immediately adjoining the weld seam, because of their relatively high melting point and the associated large amount of heat introduced. Both types of cracks cause a deterioration of the properties of the welded joint to such an extent that use in load-bearing welded structures is not possible.
  • German Patent Specification No. 2,736,484 has disclosed a weld filler material consisting essentially of
  • weld filler material of the following composition:
  • An alloy which is especially suitable as a weld filler material for fusion welding of AlZnMgCu alloys has the following composition:
  • the weld filler material according to the invention is normally used in the form of wire and is suitable for all types of fusion welding processes.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Arc Welding In General (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

A weld filler material for fusion welding of high strength aluminum alloys, especially alloys of the AlZnMgCu type, contains
4.1-6.5% of zinc,
4.0-6.0% of magnesium,
0.3-0.6% of copper,
0.3-0.5% of manganese,
at most 0.1% of titanium,
at most 0.3% of chromium,
at most 0.3% of zirconium,
at most 0.1% of silicon and
at most 0.3% of iron,
the remainder being aluminum of commercial purity. The formation of cracks in the region of the weld seam can be prevented by means of the weld filler material.

Description

DESCRIPTION
The invention relates to a weld filler material for fusion welding of high strength aluminum alloys, in particular alloys of the AlZnMgCu type.
Welded components of high strength aluminum alloys must meet stringent demands with respect to mechanical strength. Apart from qualitatively good welding, the composition of the weld filler material is also a determining factor. On the one hand, the filler wire materials hitherto used tend to cause heat cracks in the weld metal and, on the other hand, they also cause cracks in the base material immediately adjoining the weld seam, because of their relatively high melting point and the associated large amount of heat introduced. Both types of cracks cause a deterioration of the properties of the welded joint to such an extent that use in load-bearing welded structures is not possible.
German Patent Specification No. 2,736,484 has disclosed a weld filler material consisting essentially of
1-4% of zinc,
2-5% of magnesium
0.2-0.5% of copper and
0.3-0.5% of manganese,
the remainder being aluminum.
However, use of this material for fusion welding of high strength aluminum alloys cannot prevent the formation of cracks in the weld seam zone.
In the light of these facts, it was the object of the present invention to provide a weld filler material which is suitable for fusion welding of high strength aluminum alloys and by means of which the tendency to form cracks in the region of the weld seam can be suppressed.
According to the invention, the object is achieved by a weld filler material of the following composition:
4.1-6.5% of zinc,
4.0-6.0% of magnesium,
0.3-0.6% of copper,
0.3-0.5% of manganese,
at most 0.1% of titanium,
at most 0.3% of chromium,
at most 0.3% of zirconium,
at most 0.1% of silicon and
at most 0.3% of iron,
the remainder being aluminum of commercial purity.
For the individual elements, the following content ranges have proved to be preferred:
4.8-5.3% of zinc,
4.3-5.3% of magnesium,
0.45-0.55% of copper
0.35-0.45% of manganese,
at most 0.15% of chromium,
at most 0.15% of zirconium and
at most 0.10% of iron.
An alloy which is especially suitable as a weld filler material for fusion welding of AlZnMgCu alloys has the following composition:
4.9-5.3% of zinc,
4.5-5.1% of magnesium,
0.45-0.55% of copper,
0.35-0.45% of manganese,
at most 0.10% of titanium,
at most 0.15% of chromium,
at most 0.15% of zirconium,
at most 0.10% of silicon and
at most 0.10% of iron,
the remainder being aluminum of commercial purity.
All the content data concerning the composition of the weld filler material relates to percent by weight.
The weld filler material according to the invention is normally used in the form of wire and is suitable for all types of fusion welding processes.
The advantages of the weld filler material according to the invention is demonstrated below by reference to an illustrative example.
EXAMPLE
8 mm thick sheets of aluminum alloy with 5.6% of zinc, 2.6% of magnesium, 1.6% of copper, 0.16% of manganese, 0.18% of chromium, 0.01% of titanium, 0.20% of iron and 0.06% of silicon were welded by the TIG plasma keyhole welding method, using a filler wire having the composition of 5.2% of zinc, 4.8% of magnesium, 0.55% of copper, 0.40% of manganese, 0.10% of titanium, 0.10% of chromium, 0.04% of silicon and less than 0.10% of iron, the remainder being aluminum. The welded sheets were divided up and the individual weld specimens were subjected to different age-hardening conditions. The subsequent fracture test caused in none of the cases a fracture at the weld seam boundary or in the weld metal, but always gave a displacement of the position of fracture into the region of the base metal.
Metallographic examinations of the welded joints have confirmed that the formation of cracks in the region of the weld seam can be prevented by the weld filler material according to the invention.

Claims (11)

I claim:
1. A filler wire for fusion welding of high strength aluminum alloys, especially alloys of the AlZnMgCu type, said filler material consisting essentially of 4.1-6.5% of zinc, 4.0-6.0% of magnesium, 0.3-0.6% of copper, 0.3-0.5% of manganese, at most 0.1% of titanium, at most 0.3% of chromium, at most 0.3% of zirconium, at most 0.1% of silicon and at most 0.3% of iron, balance essentially aluminum wherein zinc is present in an amount greater than or equal to magnesium, said filler material characterized by the tendency to suppress cracks in the region of the weld seam.
2. A filler wire according to claim 1 containing 4.8-5.3% of zinc.
3. A filler wire according to claim 1 containing 4.3-5.3% of magnesium.
4. A filler wire according to claim 1 containing 0.45-0.55% of copper.
5. A filler wire according to claim 1 containing 0.35-0.45% of manganese.
6. A filler wire according to claim 1 containing at most 0.15% of chromium.
7. A filler wire according to claim 1 containing at most 0.15% of zirconium.
8. A filler wire according to claim 1 containing at most 0.10% of iron.
9. A filler wire according to claim 1 containing 4.9-5.3% of zinc, 4.5-5.1% of magnesium, 0.45-0.55% of copper, 0.35-0.45% of manganese, at most 0.10% of titanium, at most 0.15% of chromium, at most 0.15% of zirconium, at most 0.10% of silicon and at most 0.10% of iron, the remainder being aluminum of commercial purity.
10. A filler wire according to claim 1 in the form of wire.
11. A fusion welded assembly comprising alloys of the AlZnMgCu type and a filler material consisting essentially of 4.1-6.5% of zinc, 4.0-6.0% of magnesium, 0.3-0.6% of copper, 0.3-0.5% of manganese, at most 0.1% of titanium, at most 0.3% of chromium, at most 0.3% of zirconium, at most 0.1% of silicon and at most 0.3% of iron, balance essentially aluminum, said filler material characeterized by the tendency to suppress cracks in the region of the weld seam.
US07/217,680 1987-07-23 1988-07-11 Weld filter material for fusion welding of high strength aluminum alloys Expired - Fee Related US4859544A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH280787 1987-07-23
CH2807/87 1987-07-23

Publications (1)

Publication Number Publication Date
US4859544A true US4859544A (en) 1989-08-22

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Family Applications (1)

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US07/217,680 Expired - Fee Related US4859544A (en) 1987-07-23 1988-07-11 Weld filter material for fusion welding of high strength aluminum alloys

Country Status (3)

Country Link
US (1) US4859544A (en)
EP (1) EP0300962B1 (en)
DE (1) DE3866989D1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6579386B1 (en) 1999-03-15 2003-06-17 Lockheed Martin Corporation Filler wire for aluminum alloys and method of welding
US6840434B2 (en) 2002-04-09 2005-01-11 Ford Motor Company Tin-and zinc-based solder fillers for aluminum body parts and methods of applying the same
CN102699564A (en) * 2012-04-27 2012-10-03 浙江宇光铝材有限公司 High-performance aluminum alloy automatic welding wire
US20180243861A1 (en) * 2017-02-28 2018-08-30 GM Global Technology Operations LLC Avoiding hot cracks during laser welding of a workpiece stack-up assembly of aluminum alloy workpieces

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5599467A (en) * 1993-11-19 1997-02-04 Honda Giken Kogyo Kabushiki Kaisha Aluminum weldment and method of welding aluminum workpieces
CN103273214B (en) * 2013-05-17 2015-12-23 航天材料及工艺研究所 A kind of high-strength aluminium zinc-magnesium scandium alloy welding wire and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2245167A (en) * 1939-08-23 1941-06-10 Aluminum Co Of America Wrought aluminum base alloy and method of producing it
US3332773A (en) * 1965-05-12 1967-07-25 Aluminum Co Of America Welding aluminum
FR2191976A1 (en) * 1972-07-12 1974-02-08 Vaw Ver Aluminium Werke Ag
DE2736484A1 (en) * 1977-06-29 1979-01-04 Alusuisse WELDING MATERIAL FOR FUSION WELDING OF ALUMINUM ALLOYS
EP0206519A1 (en) * 1985-05-21 1986-12-30 Furukawa Aluminum Co., Ltd. An aluminium alloy and a magnetic disk substrate comprising the alloy

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2245167A (en) * 1939-08-23 1941-06-10 Aluminum Co Of America Wrought aluminum base alloy and method of producing it
US3332773A (en) * 1965-05-12 1967-07-25 Aluminum Co Of America Welding aluminum
FR2191976A1 (en) * 1972-07-12 1974-02-08 Vaw Ver Aluminium Werke Ag
DE2736484A1 (en) * 1977-06-29 1979-01-04 Alusuisse WELDING MATERIAL FOR FUSION WELDING OF ALUMINUM ALLOYS
GB2000806A (en) * 1977-06-29 1979-01-17 Alusuisse Filler metals
EP0206519A1 (en) * 1985-05-21 1986-12-30 Furukawa Aluminum Co., Ltd. An aluminium alloy and a magnetic disk substrate comprising the alloy

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
British Welding Journal, Jul. 1961. *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6579386B1 (en) 1999-03-15 2003-06-17 Lockheed Martin Corporation Filler wire for aluminum alloys and method of welding
US6840434B2 (en) 2002-04-09 2005-01-11 Ford Motor Company Tin-and zinc-based solder fillers for aluminum body parts and methods of applying the same
US20050109822A1 (en) * 2002-04-09 2005-05-26 Ford Motor Company Solder fillers for aluminum body parts and methods of applying the same
CN102699564A (en) * 2012-04-27 2012-10-03 浙江宇光铝材有限公司 High-performance aluminum alloy automatic welding wire
CN102699564B (en) * 2012-04-27 2015-04-22 浙江宇光铝材有限公司 High-performance aluminum alloy automatic welding wire
US20180243861A1 (en) * 2017-02-28 2018-08-30 GM Global Technology Operations LLC Avoiding hot cracks during laser welding of a workpiece stack-up assembly of aluminum alloy workpieces
US10888955B2 (en) * 2017-02-28 2021-01-12 GM Global Technology Operations LLC Avoiding hot cracks during laser welding of a workpiece stack-up assembly of aluminum alloy workpieces

Also Published As

Publication number Publication date
EP0300962A1 (en) 1989-01-25
DE3866989D1 (en) 1992-01-30
EP0300962B1 (en) 1991-12-18

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AS Assignment

Owner name: SWISS ALUMINIUM LTD., CHIPPIS, SWITZERLAND, A CORP

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:SCHWELLINGER, PIUS;REEL/FRAME:004907/0596

Effective date: 19880610

Owner name: SWISS ALUMINIUM LTD.,SWITZERLAND

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SCHWELLINGER, PIUS;REEL/FRAME:004907/0596

Effective date: 19880610

REMI Maintenance fee reminder mailed
LAPS Lapse for failure to pay maintenance fees
FP Expired due to failure to pay maintenance fee

Effective date: 19930822

STCH Information on status: patent discontinuation

Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362