US4740258A - Process for embossing flexible sheets of foam material - Google Patents

Process for embossing flexible sheets of foam material Download PDF

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Publication number
US4740258A
US4740258A US06/728,868 US72886885A US4740258A US 4740258 A US4740258 A US 4740258A US 72886885 A US72886885 A US 72886885A US 4740258 A US4740258 A US 4740258A
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US
United States
Prior art keywords
embossing
foam sheet
belt
process according
foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
US06/728,868
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English (en)
Inventor
Hans-Ulrich Breitscheidel
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HT Troplast AG
Original Assignee
Dynamit Nobel AG
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Publication date
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Publication of US4740258A publication Critical patent/US4740258A/en
Assigned to HULS TROISDORF AKTIENGESELLSCHAFT reassignment HULS TROISDORF AKTIENGESELLSCHAFT CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: DYNAMIT NOBEL AKTIENGESELLSCHAFT
Assigned to HT TROPLAST AG reassignment HT TROPLAST AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: HULS TROISDORF AKTIENGESELLSCHAFT
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/04—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10—Methods of surface bonding and/or assembly therefor
    • Y10T156/1002—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1007—Running or continuous length work
    • Y10T156/1023—Surface deformation only [e.g., embossing]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10—Methods of surface bonding and/or assembly therefor
    • Y10T156/1002—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1039—Surface deformation only of sandwich or lamina [e.g., embossed panels]
    • Y10T156/1041—Subsequent to lamination

Definitions

  • This invention relates to a process for embossing the surface of flexible sheets of foam material optionally laminated to a synthetic resin sheet or a flat textile form, wherein the sheet of foam material is superficially plasticized by heating and exposed to an embossing pressure by means of an embossing device in accordance with a desired embossing pattern.
  • Embossing of the surfaces of sheets of foam material to improve surface quality is conventional and is executed, in particular, with embossing rolls. Compacting of the surface occurs in the region of the embossing zone and, depending on the embossing pressure and depth of penetration, a variously embossed surface is obtained.
  • a disadvantageous factor in embossing foam materials by means of embossing rolls is that the flexible foam material does not completely enter into the relief texture or configuration of the embossing rolls and, thus, is not exactly molded, in part, since the air remaining in the relief texture elements cannot escape and a complete molding of the foam material in the embossing structure is prevented.
  • the invention is based on the object of providing a continuous process for embossing flexible foam material sheets and making it possible to effect fine as well as coarser embossings with a satisfactory and complete molding of the surface.
  • the process of this invention proposes to impress a perforated, metallic embossing belt into the surface of the sheet of foam material, and to remove the belt after cooling and solidification of the surface of the foam material sheet.
  • This perforated embossing belt has the advantage that venting is automatically afforded due to the perforations, and a desired, uniform molding of the foam is made possible without limitation due to dammed-up or trapped air.
  • the process of this invention provides that, although the foam is compressed during embossing, the foam expands again to its original thickness after termination of the embossing step and, due to the embossing, a minor increase in thickness may occur in dependence on the embossing pattern, on account of the free molding action, without confining means; i.e., counter surfaces, baffles or the like elements on the opposite side of the foam material.
  • An advantageous further development during the entire period of the embossing process provides that the impressed embossing belt is cooled during the impressing period.
  • the embossing belt is cooled during the impressing period.
  • An especially advantageous embodiment of the embossing belt to be utilized with the process of this invention is a wire mesh with open mesh widths of about 0.5-3 mm, constructed as an endlessly revolving belt, especially of stainless steel wire.
  • a wire mesh has the advantage that it easily enters the surface of the foam sheet and provides satisfactory venting and penetration of the foam material into the interstices of the mesh.
  • the embossing pattern can thus be selected within wide limits, by way of the chosen wire thicknesses and wire spacings; i.e., the so-called mesh numbers.
  • the wire mesh is welded into an endless embossing belt.
  • Medium and coarse wire mesh structures with mesh numbers of about 25 to 10 have proven themselves well.
  • Preferably soft elastic foam sheets which have a compression stress at 25% deflection measured according to DIN 53577 of 25 to 300 KN/m 2 according to a foam density of 25 to 130 kg/m 3 , prefered range 25 to 70 KN/m 2 according to a foam density of 25 to 50 kg/m 3 .
  • the foam sheets have preferably closed cells.
  • polyolefin foam sheets can be laminated with polyethylene films having a very small thickness of about 200-500 ⁇ m, resulting due to heating during embossing and the elastic recovery of the film effected during the subsequent cooling step in a smooth, profiled surface which has a very good handle and is soft.
  • the embossing belt with an ink application for printing the foam sheet so that the embossed surface is imprinted simultaneously with the embossing in the zone of the depressions, where the ink is protected.
  • the single FIGURE is a schematic view of a device and of the progression of steps for the embossing of a flexible foam sheet.
  • the process of this invention is conducted as an endless embossing procedure for flexible foam materials, especially crosslinked polyolefin foams, such as crosslinked polyethylene foam materials, which exhibit high elasticity.
  • the sheet 1 of foam material which--if it comes directly from manufacture--should no longer contain any residual heat, is reheated superficially by means of a heater 2, for example, a quartz radiator or ceramic radiator, until the exposed surface begins to become plasticized.
  • a heater 2 for example, a quartz radiator or ceramic radiator
  • This temperature lies, in case of crosslinked polyolefin foam sheets, at about 160°-170° C.
  • the pair of rolls 3a, 3b provide an inlet nip 4 for the foam, the spacing or size of this inlet nip being about 15-25% smaller than the thickness of the foam sheet 1.
  • the two rolls 3a, 3b are driven and are in a cold condition; i.e., at room temperature.
  • the roll 3b is fashioned as a pressure roll and can be further cooled, if it heats up too much due to the heated foam sheet 1 at very high speeds of revolution. Furthermore, the endlessly rotating embossing belt 5 is guided around the rolls 3b, 7b; this belt is constructed as a metallic, perforated band, preferably of wire mesh. In the spacing between the rolls 3b and 7b, the embossing belt 5, impressed into the surface of the foam sheet, revolves while contacting the foam sheet and is cooled along this air zone by the ambient air.
  • a cooling means 6 can be additionally provided, for example, means for providing additional air cooling (e.g., air jets) which acts in particular on the embossing belt 5.
  • additional air cooling e.g., air jets
  • heating of the roll 3b and of the embossing belt 5 to temperatures above 50° C. to 60° C. should be avoided in order to obtain a perfect, uniform embossed texture. Since the embossed foam sheet should be in a solidified state at the moment of leaving the belt, it is important, not to raise the processing temperature too high. Therefore, a low belt temperature serves for a quick cooling of the embossed foam sheet and surface and reduces the total length of the belt.
  • the roll 7b serves simultaneously as a tensioning roller for the revolving embossing belt 5 and is likewise driven. Furthermore, roll 7a can be driven or not and serves to deflect the foam sheet away from the belt (a take-up device, not shown, acts to take-up the sheet).
  • a take-up device not shown, acts to take-up the sheet.
  • the duration of heating and also the degree of plasticizing depend on the quality of the foam; higher weights per unit volume must be heated somewhat more vigorously.
  • the required amount of heat also depends on the color of the foam and on the fineness or coarseness of the desired embossed texture. Heating of the surface can be effected, as illustrated, for example by means of infrared radiators which can be varied in their spacing and heating power, but also, for example, directly by contact heating via rolls.
  • the embossing step takes place a laminating material downstream of the heating unit directly into the inlet nip 4 between the rolls 3a and 3b on top of the heated foam surface and subject this arrangement to embossing.
  • the laminating material for example, a synthetic resin film or a textile panel such as a mat or woven fabric, also printed fabrics of cotton or synthetic fibers, should, however, be capable of being shaped and should adhere, if at all possible, to the foam material without any additional adhesives.
  • the embossed texture attainable depends, on the one hand, on the quality of the flexible foam material which, in particular, is also determined by its weight per unit volume, and, on the other hand, on the type and structure of the perforated embossing belt.
  • the embossing belt 5 can be a punched metal sheet as well as a wire mesh.
  • the so-called profile factor is derived from the ratio of inside mesh width:wire diameter; in this connection, medium and coarser wire meshes yield good surface qualities in embossed texture.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)
US06/728,868 1982-12-15 1985-04-30 Process for embossing flexible sheets of foam material Expired - Fee Related US4740258A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3246368 1982-12-15
DE19823246368 DE3246368A1 (de) 1982-12-15 1982-12-15 Verfahren zum praegen von weichelastischen schaumstoffbahnen

Related Parent Applications (1)

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US06559699 Continuation 1983-12-09

Publications (1)

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US4740258A true US4740258A (en) 1988-04-26

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US (1) US4740258A (de)
DE (1) DE3246368A1 (de)

Cited By (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4929303A (en) * 1987-03-11 1990-05-29 Exxon Chemical Patents Inc. Composite breathable housewrap films
US5183672A (en) * 1991-04-16 1993-02-02 Gary W. Fetterhoff Apparatus for forming at least one fold line pattern in a rigid plastic material
US5268138A (en) * 1991-04-16 1993-12-07 Gary W. Fetterhoff Method for forming at least one fold line pattern in a rigid plastic material
US5350544A (en) * 1992-03-06 1994-09-27 Earth & Ocean Sports, Inc. Method of preparing a cross-linked, polyethylene foam product by surface expansion of a foam
US5356696A (en) * 1991-04-16 1994-10-18 Fetterhoff Gary W Apparatus and method for sealing edges of corrugated plastic material
US5460757A (en) * 1993-12-29 1995-10-24 Topstamp, Inc. Method for manufacturing pre-inked stamps
US5653166A (en) * 1994-03-29 1997-08-05 Winning Image, Inc. Method for molding a design in low relief in an ink printed on fabric
US5698153A (en) * 1994-04-29 1997-12-16 The Boeing Co. Method of prescoring foam board
US5765688A (en) * 1996-11-25 1998-06-16 Sealed Air Corporation Embossed foam in bag cushions
US5776510A (en) * 1996-11-01 1998-07-07 Sealed Air Corporation On-demand production of foam cushions with defined three-dimensional geometry
WO1999004939A1 (en) 1997-07-23 1999-02-04 Foamex L.P. Continuous platform cutting apparatus
US6024907A (en) * 1998-02-02 2000-02-15 Bruce Jagunich Embossing with an endless belt composed of a shape memory alloy
US6085627A (en) * 1997-07-23 2000-07-11 Foamex L.P. Apparatus for cutting a cellular polymer surface with multiple continuous platforms
US6142053A (en) * 1997-07-23 2000-11-07 Foamex L.P. Method of cutting a cellular polymer surface with a continous platform cutting apparatus
US6173638B1 (en) 1997-07-23 2001-01-16 Foamex L.P. Method for cutting a cellular polymer surface with multiple continuous platforms
EP1090950A1 (de) * 1998-06-25 2001-04-11 NHK Spring Co., Ltd. Oberflächenverzierte schaumhaut von vernetztem weichem kautschukartigem olefinharz
US6258308B1 (en) 1996-07-31 2001-07-10 Exxon Chemical Patents Inc. Process for adjusting WVTR and other properties of a polyolefin film
US6264864B1 (en) 1998-10-16 2001-07-24 Exxon Chemical Patents Inc. Process for producing polyolefin microporous breathable film
US6668698B1 (en) 1997-07-23 2003-12-30 Foamex L.P. Continuous platform cutting method
US6675691B1 (en) 1997-07-23 2004-01-13 Foamex L.P. Continuous platform cutting apparatus
US20040028870A1 (en) * 2002-02-05 2004-02-12 Lehr Gregory S. Laminate inlay process for sports boards
US20040151875A1 (en) * 2003-02-04 2004-08-05 Lehr Gregory S. Laminate inlay process for sports boards
US20040266289A1 (en) * 2003-06-24 2004-12-30 Scott Burke Expanded polystyrene core sports board
US6966815B2 (en) * 2002-06-14 2005-11-22 Invists North America S.R.R.L. Shaped anti-roll supports and garments incorporating such supports
US20080185092A1 (en) * 2007-02-02 2008-08-07 S.D. Warren Company Tip printing embossed surfaces
US20080305714A1 (en) * 2007-03-30 2008-12-11 Sobah-Wilhelm Mary C Bra and/or bra pad for providing the appearance of symmetry to asymmetrical breasts
US20090050129A1 (en) * 2007-08-24 2009-02-26 Catalytic Combustion Corporation Catalytic converter unit and method for treating cooking emissions
US20090133909A1 (en) * 2007-11-26 2009-05-28 Blenkhorn Gary P Tip Printing and Scrape Coating Systems and Methods for Manufacturing Electronic Devices
US20090247047A1 (en) * 2008-03-28 2009-10-01 Roxana Avalos-Dessner Brassiere cup and brassiere for women having unevenly sized breasts
US20110024938A1 (en) * 2009-08-03 2011-02-03 S.D. Warren Company Imparting texture to cured powder coatings
US20110186712A1 (en) * 2007-04-30 2011-08-04 S.D. Warren Company Materials Having a Textured Surface and Methods for Producing Same
US20110223831A1 (en) * 2007-03-30 2011-09-15 Sobah-Wilhelm Mary C Bra and/or bra pad for providing the appearance of symmetry to asymmetrical breasts
US20120017663A1 (en) * 2010-07-23 2012-01-26 Formtech Gmbh Method for the manufacture of a workpiece with defined surface
WO2013082290A1 (en) * 2011-12-02 2013-06-06 Palziv Group Embossed polymer sheet
WO2017212292A1 (en) * 2016-06-10 2017-12-14 Sentient Foams Limited Absorbent aliphatic polyurethane foam product
US10334890B2 (en) 2007-03-30 2019-07-02 Mary C. Sobah Bra and/or bra pad for providing the appearance of symmetry to asymmetrical breasts
US10675794B2 (en) 2011-02-24 2020-06-09 3M Innovative Properties Company Coated abrasive article with foam backing and method of making
US11285642B2 (en) * 2016-04-29 2022-03-29 Aplix Moulding apparatus for forming a fastening device

Families Citing this family (1)

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Publication number Priority date Publication date Assignee Title
DE102016114933A1 (de) * 2016-08-11 2018-02-15 Bikoma Gmbh Spezialmaschinen Verfahren zum Erzeugen einer Prägung und entsprechende Vorrichtung

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GB1095290A (de) *
US2681612A (en) * 1951-01-31 1954-06-22 Kurt P Reimann Means for embossing and printing
US2776451A (en) * 1952-02-16 1957-01-08 Chavannes Ind Synthetics Inc Apparatus for method for producing embossed thermoplastic film
US2783175A (en) * 1952-11-07 1957-02-26 Decora Corp Method for forming three dimensional patterns in textile material
US2915787A (en) * 1954-04-12 1959-12-08 British Celanese Embossing
US3305419A (en) * 1962-03-28 1967-02-21 Allied Chem Method of producing an embossed panel
US3496043A (en) * 1966-04-07 1970-02-17 Robert O Ragan Method of manufacturing an embossed laminated foam
US3608006A (en) * 1966-10-01 1971-09-21 Furukawa Electric Co Ltd Production of foamed polyolefin composite sheet
US3657036A (en) * 1969-10-02 1972-04-18 Nat Gypsum Co Method for production of rigid polyurethane articles
US3966383A (en) * 1974-12-30 1976-06-29 Ethyl Corporation Apparatus for embossing film
US4022643A (en) * 1975-12-24 1977-05-10 Congoleum Corporation Methods of manufacturing embossed resinous products
JPS54149779A (en) * 1978-05-17 1979-11-24 Sekisui Plastics Production of polyolefinic laminated resin sheet
US4229406A (en) * 1974-11-21 1980-10-21 Borg-Warner Corporation Method for preparing an embossed foamed latex sheet
US4364892A (en) * 1978-07-25 1982-12-21 Helmut Rehlen Process for surface treatment of foamed sheets

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FR1505153A (fr) * 1965-12-18 1967-12-08 Procédé et moyen pour mettre en forme des substances thermoplastiques moussées ou expansées et articles ou objets ainsi obtenus
DE1704813A1 (de) * 1966-09-20 1972-03-02 Alcide Mora Verfahren zur Herstellung reliefartig gemusterter Schaumstoffbahnen und zur Verbindung solcher Bahnen mit einer Auflagebahn sowie Vorrichtung zur Ausuebung des Verfahrens

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1095290A (de) *
US2681612A (en) * 1951-01-31 1954-06-22 Kurt P Reimann Means for embossing and printing
US2776451A (en) * 1952-02-16 1957-01-08 Chavannes Ind Synthetics Inc Apparatus for method for producing embossed thermoplastic film
US2783175A (en) * 1952-11-07 1957-02-26 Decora Corp Method for forming three dimensional patterns in textile material
US2915787A (en) * 1954-04-12 1959-12-08 British Celanese Embossing
US3305419A (en) * 1962-03-28 1967-02-21 Allied Chem Method of producing an embossed panel
US3496043A (en) * 1966-04-07 1970-02-17 Robert O Ragan Method of manufacturing an embossed laminated foam
US3608006A (en) * 1966-10-01 1971-09-21 Furukawa Electric Co Ltd Production of foamed polyolefin composite sheet
US3657036A (en) * 1969-10-02 1972-04-18 Nat Gypsum Co Method for production of rigid polyurethane articles
US4229406A (en) * 1974-11-21 1980-10-21 Borg-Warner Corporation Method for preparing an embossed foamed latex sheet
US3966383A (en) * 1974-12-30 1976-06-29 Ethyl Corporation Apparatus for embossing film
US4022643A (en) * 1975-12-24 1977-05-10 Congoleum Corporation Methods of manufacturing embossed resinous products
JPS54149779A (en) * 1978-05-17 1979-11-24 Sekisui Plastics Production of polyolefinic laminated resin sheet
US4364892A (en) * 1978-07-25 1982-12-21 Helmut Rehlen Process for surface treatment of foamed sheets

Cited By (63)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4929303A (en) * 1987-03-11 1990-05-29 Exxon Chemical Patents Inc. Composite breathable housewrap films
US5183672A (en) * 1991-04-16 1993-02-02 Gary W. Fetterhoff Apparatus for forming at least one fold line pattern in a rigid plastic material
US5268138A (en) * 1991-04-16 1993-12-07 Gary W. Fetterhoff Method for forming at least one fold line pattern in a rigid plastic material
US5304056A (en) * 1991-04-16 1994-04-19 James M. Park Apparatus for sealing edges of corrugated plastic material
US5356696A (en) * 1991-04-16 1994-10-18 Fetterhoff Gary W Apparatus and method for sealing edges of corrugated plastic material
US5350544A (en) * 1992-03-06 1994-09-27 Earth & Ocean Sports, Inc. Method of preparing a cross-linked, polyethylene foam product by surface expansion of a foam
US5460757A (en) * 1993-12-29 1995-10-24 Topstamp, Inc. Method for manufacturing pre-inked stamps
US5653166A (en) * 1994-03-29 1997-08-05 Winning Image, Inc. Method for molding a design in low relief in an ink printed on fabric
US5698153A (en) * 1994-04-29 1997-12-16 The Boeing Co. Method of prescoring foam board
US6419776B1 (en) * 1994-04-29 2002-07-16 The Boeing Company Method of prescoring foam board
US6258308B1 (en) 1996-07-31 2001-07-10 Exxon Chemical Patents Inc. Process for adjusting WVTR and other properties of a polyolefin film
US5776510A (en) * 1996-11-01 1998-07-07 Sealed Air Corporation On-demand production of foam cushions with defined three-dimensional geometry
US5765688A (en) * 1996-11-25 1998-06-16 Sealed Air Corporation Embossed foam in bag cushions
US6142053A (en) * 1997-07-23 2000-11-07 Foamex L.P. Method of cutting a cellular polymer surface with a continous platform cutting apparatus
US6675691B1 (en) 1997-07-23 2004-01-13 Foamex L.P. Continuous platform cutting apparatus
US6173638B1 (en) 1997-07-23 2001-01-16 Foamex L.P. Method for cutting a cellular polymer surface with multiple continuous platforms
US6085627A (en) * 1997-07-23 2000-07-11 Foamex L.P. Apparatus for cutting a cellular polymer surface with multiple continuous platforms
WO1999004939A1 (en) 1997-07-23 1999-02-04 Foamex L.P. Continuous platform cutting apparatus
US6467386B1 (en) 1997-07-23 2002-10-22 Foamex L.P. Multiple continuous platform cutting apparatus
US6513414B1 (en) 1997-07-23 2003-02-04 Foamex L.P. Method of cutting a cellular polymer surface with a continuous platform cutting apparatus
US6546836B1 (en) 1997-07-23 2003-04-15 Foamex L.P. Continuous platform cutting apparatus for cutting a cellular polymer surface
US6668698B1 (en) 1997-07-23 2003-12-30 Foamex L.P. Continuous platform cutting method
US6024907A (en) * 1998-02-02 2000-02-15 Bruce Jagunich Embossing with an endless belt composed of a shape memory alloy
EP1090950A1 (de) * 1998-06-25 2001-04-11 NHK Spring Co., Ltd. Oberflächenverzierte schaumhaut von vernetztem weichem kautschukartigem olefinharz
EP1090950A4 (de) * 1998-06-25 2003-07-09 Nhk Spring Co Ltd Oberflächenverzierte schaumhaut von vernetztem weichem kautschukartigem olefinharz
US6264864B1 (en) 1998-10-16 2001-07-24 Exxon Chemical Patents Inc. Process for producing polyolefin microporous breathable film
US6706228B2 (en) 1998-10-16 2004-03-16 Exxonmobil Chemical Company Process for producing polyolefin microporous breathable film
US20040028870A1 (en) * 2002-02-05 2004-02-12 Lehr Gregory S. Laminate inlay process for sports boards
US6966815B2 (en) * 2002-06-14 2005-11-22 Invists North America S.R.R.L. Shaped anti-roll supports and garments incorporating such supports
US20040151875A1 (en) * 2003-02-04 2004-08-05 Lehr Gregory S. Laminate inlay process for sports boards
US7368031B2 (en) 2003-02-04 2008-05-06 Wham-O, Inc. Laminate inlay process for sports boards
US20040266289A1 (en) * 2003-06-24 2004-12-30 Scott Burke Expanded polystyrene core sports board
US6908351B2 (en) 2003-06-24 2005-06-21 Wham-O, Inc. Expanded polystyrene core sports board
US20080185092A1 (en) * 2007-02-02 2008-08-07 S.D. Warren Company Tip printing embossed surfaces
US20080305714A1 (en) * 2007-03-30 2008-12-11 Sobah-Wilhelm Mary C Bra and/or bra pad for providing the appearance of symmetry to asymmetrical breasts
US10334890B2 (en) 2007-03-30 2019-07-02 Mary C. Sobah Bra and/or bra pad for providing the appearance of symmetry to asymmetrical breasts
US8506349B2 (en) 2007-03-30 2013-08-13 Mary C. Sobah-Wilhelm Bra and/or bra pad for providing the appearance of symmetry to asymmetrical breasts
US7833083B2 (en) 2007-03-30 2010-11-16 Sobah-Wilhelm Mary C Bra and/or bra pad for providing the appearance of symmetry to asymmetrical breasts
US20110223831A1 (en) * 2007-03-30 2011-09-15 Sobah-Wilhelm Mary C Bra and/or bra pad for providing the appearance of symmetry to asymmetrical breasts
US20110186712A1 (en) * 2007-04-30 2011-08-04 S.D. Warren Company Materials Having a Textured Surface and Methods for Producing Same
US8192830B2 (en) 2007-04-30 2012-06-05 S.D. Warren Company Materials having a textured surface and methods for producing same
US8418684B2 (en) 2007-08-24 2013-04-16 Catalytic Combustion Corporation Catalytic converter unit and method for treating cooking emissions
US20090050129A1 (en) * 2007-08-24 2009-02-26 Catalytic Combustion Corporation Catalytic converter unit and method for treating cooking emissions
US8286342B2 (en) 2007-11-26 2012-10-16 S.D. Warren Company Methods for manufacturing electronic devices
US20090133909A1 (en) * 2007-11-26 2009-05-28 Blenkhorn Gary P Tip Printing and Scrape Coating Systems and Methods for Manufacturing Electronic Devices
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