US457488A - Alfred fischesser and joseph pokorny - Google Patents
Alfred fischesser and joseph pokorny Download PDFInfo
- Publication number
- US457488A US457488A US457488DA US457488A US 457488 A US457488 A US 457488A US 457488D A US457488D A US 457488DA US 457488 A US457488 A US 457488A
- Authority
- US
- United States
- Prior art keywords
- pokorny
- fischesser
- alfred
- joseph
- dyeing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004043 dyeing Methods 0.000 description 16
- 239000004744 fabric Substances 0.000 description 8
- JRBJSXQPQWSCCF-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine Chemical compound C1=C(N)C(OC)=CC(C=2C=C(OC)C(N)=CC=2)=C1 JRBJSXQPQWSCCF-UHFFFAOYSA-N 0.000 description 6
- ALKYHXVLJMQRLQ-UHFFFAOYSA-N 3-Hydroxy-2-naphthoate Chemical compound C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 ALKYHXVLJMQRLQ-UHFFFAOYSA-N 0.000 description 6
- NUIURNJTPRWVAP-UHFFFAOYSA-N Tolidine Chemical compound C1=C(N)C(C)=CC(C=2C=C(C)C(N)=CC=2)=C1 NUIURNJTPRWVAP-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-Naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 4
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-Naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 4
- HFACYLZERDEVSX-UHFFFAOYSA-N Benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 4
- VBEGHXKAFSLLGE-UHFFFAOYSA-N N-phenylnitramide Chemical class [O-][N+](=O)NC1=CC=CC=C1 VBEGHXKAFSLLGE-UHFFFAOYSA-N 0.000 description 4
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
- 229950011260 betanaphthol Drugs 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- -1 xylidine Chemical compound 0.000 description 4
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-Naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 2
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- 240000000491 Corchorus aestuans Species 0.000 description 2
- 235000011777 Corchorus aestuans Nutrition 0.000 description 2
- 235000010862 Corchorus capsularis Nutrition 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 229940097275 Indigo Drugs 0.000 description 2
- 240000007871 Indigofera tinctoria Species 0.000 description 2
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 2
- QFCSRGLEMDRBMN-UHFFFAOYSA-N N-(2-methylphenyl)nitramide Chemical class CC1=CC=CC=C1N[N+]([O-])=O QFCSRGLEMDRBMN-UHFFFAOYSA-N 0.000 description 2
- 210000002268 Wool Anatomy 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- LRTFPLFDLJYEKT-UHFFFAOYSA-N para-isopropylaniline Chemical compound CC(C)C1=CC=C(N)C=C1 LRTFPLFDLJYEKT-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 150000004992 toluidines Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/68—Preparing azo dyes on the material
Definitions
- This invention relates to the direct production of insoluble azo coloring-matters upon fabrics either by printing or by dyeing.
- One of the ingredients usually employed in carrying out such production of coloring-matters is alpha or beta naphthol.
- beta-oxynaphthoic acid the melting-point of which is 216 Celsius and the chemical formula is C H (CO,OH)3OH.
- a blue is obtained which resembles indigo and resists washing and soap.
- amido substances can be employed, viz: aniline, toluidine, xylidine, cumidine, amidoazo-Xylol, amidoazo-benzole, amidoazo-toluol, the various nitro-anilines and nitro-toluidines, alpha or beta naphthylaniines, benzidine, tolidine, diamidodiphenol ether, amido naphthols, acetparaphenylene diamine, thioparatoluidine, or mixtures of the same.
- Magenta can be employed as amine, and will also give good results.
- beta-naphthylamine gives a Bordeaux aniline a yellowish red, nitro-aniline a fiery red, tolidine a deep violet.
- the colors can also be produced by dyeing upon yarn and piece-ware.
- the textile fibers whether cotton, wool, silk, or jute, are changeably impreg- 5o nated with the solution of the diazo or tetrazo compound and the beta-oxynaphthoic acid herein described in an alkaline solution, or vice versa. It is also advantageous to oil the fiber first, like with Turkey-red dyeing. Insoluble 5 5 metallic soaps may also be precipitated on it.
- the most vlauable shades produced by dyeing are greenish blue with dianisidine, reddish blue with tolidine, and dark violet (mauvine) with benzidine. A passage through weak acid after dyeing is useful in order to develop the color Well.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
UNITED STATES PATENT OFFICE.
ALFRED FISCHESSER AND JOSEPH POKORNY, OF LUT"ERBACH, GERMANY; SAID POKORNY ASSIGNOR TO SAID FISCHESSER.
PROCESS oF DYEING.
SPECIFICATION forming part of Letters Patent No. 457,488, dated August 11, 1891. Application filed April 20, 1891. Serial No. 389,593. (No specimens.)
To aZZ whom, it may concern.-
Be it known that we, ALFRED FISOI-IESSER and JOSEPH POKORNY, the first a subject of the Emperor of Germany and the second a subj ect of theEmperor of Austria,both residing at Lutterbach, Alsace, Germany, have invented a new and useful Improvement in Process of Dyeing and Printing Fibrous Materials and Fabrics, of which the followingis a specifica- [0 tion.
This invention relates to the direct production of insoluble azo coloring-matters upon fabrics either by printing or by dyeing. One of the ingredients usually employed in carrying out such production of coloring-matters is alpha or beta naphthol. According to our invention, by which We obtain very valuable new tints, we substitute for the ingredients above mentioned beta-oxynaphthoic acid, the melting-point of which is 216 Celsius and the chemical formula is C H (CO,OH)3OH. For instance, by preparinga fabric in an alkaline solution of the said beta-oxynaphthoic acid and printing upon the same a thickened solution of tetrazodized dianisidine a blue is obtained which resembles indigo and resists washing and soap.
Instead of dianisidine the following amido substances can be employed, viz: aniline, toluidine, xylidine, cumidine, amidoazo-Xylol, amidoazo-benzole, amidoazo-toluol, the various nitro-anilines and nitro-toluidines, alpha or beta naphthylaniines, benzidine, tolidine, diamidodiphenol ether, amido naphthols, acetparaphenylene diamine, thioparatoluidine, or mixtures of the same. Magenta can be employed as amine, and will also give good results.
It is evident that instead of the above-mentioned amines others can be used. however, scarcer, but they produce the same effects as those named. The tints obtained difier from those which the respective amines give with alpha or beta naphthol. Thus, for
They are, 4o
instance, beta-naphthylamine gives a Bordeaux aniline a yellowish red, nitro-aniline a fiery red, tolidine a deep violet. The colors can also be produced by dyeing upon yarn and piece-ware. The textile fibers, whether cotton, wool, silk, or jute, are changeably impreg- 5o nated with the solution of the diazo or tetrazo compound and the beta-oxynaphthoic acid herein described in an alkaline solution, or vice versa. It is also advantageous to oil the fiber first, like with Turkey-red dyeing. Insoluble 5 5 metallic soaps may also be precipitated on it. The most vlauable shades produced by dyeing are greenish blue with dianisidine, reddish blue with tolidine, and dark violet (mauvine) with benzidine. A passage through weak acid after dyeing is useful in order to develop the color Well.
We claim The improvement in the process of dyeing and printing fibers and fabrics, consisting in 6 5
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US457488A true US457488A (en) | 1891-08-11 |
Family
ID=2526364
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US457488D Expired - Lifetime US457488A (en) | Alfred fischesser and joseph pokorny |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US457488A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100891606B1 (en) * | 2001-01-26 | 2009-04-08 | 쎄코 툴스 에이비 | Cutting tool and cutting inserts |
-
0
- US US457488D patent/US457488A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100891606B1 (en) * | 2001-01-26 | 2009-04-08 | 쎄코 툴스 에이비 | Cutting tool and cutting inserts |
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