US3922306A - Process for refining amines - Google Patents
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- US3922306A US3922306A US435086A US43508674A US3922306A US 3922306 A US3922306 A US 3922306A US 435086 A US435086 A US 435086A US 43508674 A US43508674 A US 43508674A US 3922306 A US3922306 A US 3922306A
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
- C07C213/10—Separation; Purification; Stabilisation; Use of additives
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/60—Preparation of compounds containing amino groups bound to a carbon skeleton by condensation or addition reactions, e.g. Mannich reaction, addition of ammonia or amines to alkenes or to alkynes or addition of compounds containing an active hydrogen atom to Schiff's bases, quinone imines, or aziranes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/62—Preparation of compounds containing amino groups bound to a carbon skeleton by cleaving carbon-to-nitrogen, sulfur-to-nitrogen, or phosphorus-to-nitrogen bonds, e.g. hydrolysis of amides, N-dealkylation of amines or quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/82—Purification; Separation; Stabilisation; Use of additives
- C07C209/84—Purification
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/82—Purification; Separation; Stabilisation; Use of additives
- C07C209/86—Separation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/03—Monoamines
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/03—Monoamines
- C07C211/08—Monoamines containing alkyl groups having a different number of carbon atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/09—Diamines
- C07C211/10—Diaminoethanes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/14—Amines containing amino groups bound to at least two aminoalkyl groups, e.g. diethylenetriamines
Definitions
- This invention relates to a process for refining amines. More precisely, it relates to a process comprising refining aliphatic amines by treating them with herohydride compounds, and thereby preventing colorization of amine salts, quaternary ammonium salts or aminebetaine derived from the refined amines.
- Long-chain alkyl amines are widely used as cationic surfactants and as ampholytic surfactants such as amine salts, quaternary ammonium salts, or alkyl betaine, or they are converted to known useful long-chain alkylamine oxides.
- the products are undesirably colored yellow or pale red. Colorization is marked when the surfactants are derived from long-chain alkyl amines obtained from ethylene low polymers or derived from alkylamine mixtures containing said long-chain alkylamines as a constituent, and the commercial value of the products are reduced greatly.
- the present invention provides an improved process for refining aliphatic amines by treating said amines with hydrogenated boron compounds.
- the invention is a method of refining aliphatic hydrocarbon amines having at least one alkyl group of 9 to 22 carbon atoms attached to the amino nitrogen, said amines being derived from polymerized ethylene by known methods and having a tendency to form colored amine salts, which comprises suppressing said tendency "by reacting said aliphatic amine with 0.01 to 5% by weight based on the amine of a borohydride compound selected from the group consisting of an alkali metal borohydride, amine borohydrides, quaternary ammonium borohydrides and mixtures thereof, and recovering refined aliphatic amine from the reaction mixture.
- the amine material to which the refining process of the invention can be applied are generally aliphatic primary, secondary and tertiary amines, and mixtures of such amines.
- the amines have the formulas RNH RRNH and RRR"N, wherein R is alkyl havingifrom 9 the amine material is a mixture of primary, secondary or tertiary amines in which R has various values within the range of carbon atom number for R set forth above.
- the amine material can be a mixture of primary and/or secondary and/or tertiary amines.
- amine materials with which the process of the invention is particularly effective there are enumerated amine materials derived from ethylene low polymers such as a-olefins and Ziegler alcohols or amine mixtures containing said amines as a constituent. These amine materials derived from ethylene low polymers have the tendency of forming undesired color substances when converted to aminesalts, quaternary ammonium salts and/or betaines, apparently owing to a minor amount of impurities therein. Examples of such amines and their preparation are described in (l) M. T. Atwood, .IAOCS. 40, 64 (1963); (2) T. Clarke et al., .IAOCS. 41, 78 (1964); (3) Onyx Corp. U.S. Pat. No. 3,471,562 (Oct. 7, 1969); and (4) Sun Chemical Corp. U.S. Pat. No. 3,401,203 (Sept. 10, 1968).
- boron hydride there can be employed an alkali metal salt of boron hydride such as sodium borohydride, potassium borohydride and lithium borohydride, an amine salt of boron hydride, a quaternaryammonium salt of boron hydride and mixtures thereof.
- the boron hydrides can be added in the form of dry powder or in alkaline aqueous solution.
- the amount of boron hydride to be added is dependent on the kind of amine to be treated, the process by which it was manufactured, and its properties.
- the amount of boron hydride used should be kept as low as possible in order to minimize expense, but the use of an excess amount of boron hydride does not cause any adverse effect.
- the boron hydride compound is added in an amount from about 0.01 to about 5% by weight, based on the weight of the starting amine material, preferably from 0.05 to 2% by weight.
- the alkali is preferably water-soluble and is added in an amount up to 50%, preferably in the range of 0.1 to 10%, based on the weight of the starting amine materials.
- the alkali it is preferred to use sodium hydroxide, potassium hydroxide and sodium carbonate. The amount thereof to be added is not critical.
- the boron hydride compound is effective even if no alkali at all is added.
- the preferred mode of performance of this invention consists of treating the starting amine material with boron hydride compound in an amount of from about 0.01 to about 5% by weight, based on the weight of the amine, in the presence of an alkali.
- a specific preferred process according to this invention comprises placing the starting amine material, boron hydride compound and an aqueous solution of caustic alkali in a reactor, and agitating the mixture for several (about 2 to about 10) hours at about 50 to C. It will be understood, however, that the treating temperature and the treating time are not critical.
- the present invention is carried out usually in a homogeneous or non-homogeneous phase of amine and water, but if necessary, alcohol such as methanol, ethano] or isopropanol can be added.
- the presence of inorganic salts in the starting amine material does not inhibit the desired effect of the boron hydride compound. Therefore, it is possible to employ as a starting amine material, a tertiary amine produced by reaction of an alkyl halide and a primary or secondary amine in the presence of an excess of alkali, followed by treatment of the resultant tertiary amine in place as it is, not isolated, with the boron hydride compound. This is an effective and simple process.
- the amine treated according to the process of this invention When the amine treated according to the process of this invention is isolated and converted to an amine salt, quaternary ammonium salt or amine betaine, by a known process, there is obtained a practically colorless product. Thus the colorization that occurs when an untreated product is similarly converted, is avoided by treating the amine material by the process of this invention.
- the amine material treated according to the process of this invention and the above-described compounds obtained from that amine material are quite similar to the corresponding products obtained from untreated amine material in the features, of chemical analysis, physical properties and chemical activity, but they are remarkably free of colorization.
- the treated and untreated tertiary amines were each i.
- EXAMPLE 2 The same conditions as in Example 1 were employed except that the amount of sodium borohydride was re- I quizd to 100 mg.
- the lauryl dimethylamine hydrochloride obtained by a conventional process as in Example l was, colorless and had a percent transmission of 93.6%. (The percent transmission was determined by the method used in Example 1. This applies also in the following examples.)
- EXAMPLE 3 The same conditions as in Example 1 were employed except that there was used 550mg. of potassium borohydride instead of sodium borohydride.
- the hydrochloride obtained by a conventional process as in Example 1 was colorless and had a percent transmission of 93.8%.
- lauryl benzyl dimethylammonium chorides were prepared by a conventional process.
- the chloride derived from the amine treated with sodium borohydride was colorless
- lauryl dimethylamine was prepared in the presence of an excess of caustic soda by a conventional process. 112 mg. of sodium borohydride were added to 152 grams of the unrefined crude amine reaction product, and the mixture was treated at 50 C for2 hours. Then, a 25% aqueous solution of lauryl dimethylamine hydrochloride was prepared by a conventional process as in Example 1. 1t was colorless andthe percent transmission thereof was 94.0%.
- a method for refining aliphatic hydrocarbon amines having at least one alkyl group of 9 to 22 carbon atoms attached to the amino nitrogen, said amines being derived from polymerized ethylene and containing impurities which form coloring substances when the amines are converted to amine salts which comprises the steps of: reacting said amine with A. from 0.01 to 5 percent by weight, based on said amine, of a borohydride substance selected from the group consisting of alkali metal borohydrides,
- said amine is selected from the group consisting of compounds of the formulas RNl-l, RRNH and RR'R"H and mixtures thereof, wherein R is alkyl having 9 to 22 carbon atoms, and wherein R and R" are alkyls having 1 to 22 carbon atoms.
- R is alkyl having 10 to 18 carbon atoms and R and R are alkyls having 1 to 6 carbon atoms.
- R is lauryl and R and R" are methyl or ethyl.
- said borohydride substance is selected from the group consisting of sodium borohydride, potassium borohydride and lithium borohydride.
- said alkali is selected from the group consisting of sodium hydroxide, potassium hydroxide and sodium carbonate, and the amount of said alkali is from 0.1 to 10 percent by weight, based on said amine.
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- Chemical & Material Sciences (AREA)
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Abstract
Long chain alkyl amines produced from petrochemical methods are refined by treatment with 0.01 to 5 % by weight of a borohydride compound to eliminate the tendency to form colored compounds when further converted to amine salts.
Description
United States Patent 1 91 Takaku et al.
1 1 Nov. 25, 1975 i 1 PROCESS FOR REFlNlNG AMINES [75] Inventors: Masaaki Takaku; Shiro Kawahito,
both of Wakayama, Japan [30] Foreign Application Priority Data J:1n.24, l973 Japan 48-101 I6 [52] [1.8. Cl 260/583 N [51] Int. Cl. C07C 85/06; C07C 85/16 [58] Field of Search 260/583 N [56] References Cited UNITED STATES PATENTS 2,922,818 l/l960 Spiecberger et al. 260/583 N 3,468,954 9/1969 Conseiller et ul 260/583 N 3,594,421 7/1971 Kmiecik A 260/583 N 3,595.92l 7/1971 Pitts 4. 260/583 N Primary E.\'uminer-Paul F. Shaver Attorney. Agent, or Firm-Woodhams. Blanchard and Flynn [57] ABSTRACT Long chain alkyl amines produced from petrochemical methods are refined by treatment with 0.01 to 5 7! by weight of a borohydride compound to eliminate the tendency to form colored compounds when further converted to amine salts.
9 Claims, No Drawings PROCESS FOR REFINING AMINES BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to a process for refining amines. More precisely, it relates to a process comprising refining aliphatic amines by treating them with herohydride compounds, and thereby preventing colorization of amine salts, quaternary ammonium salts or aminebetaine derived from the refined amines.
2. Description of the Prior Art Long-chain alkyl amines have heretofore been produced from a starting material derived from natural animal or vegetable oils. But recently, following the development of the petrochemical industry, they are produced from an intermediate raw material derived from petroleum products, particularly low polymers of ethylene such as materials well known in the art as a-olefins and Ziegler alcohols.
Long-chain alkyl amines are widely used as cationic surfactants and as ampholytic surfactants such as amine salts, quaternary ammonium salts, or alkyl betaine, or they are converted to known useful long-chain alkylamine oxides.
However, when preparing these surfactants, sometimes the products are undesirably colored yellow or pale red. Colorization is marked when the surfactants are derived from long-chain alkyl amines obtained from ethylene low polymers or derived from alkylamine mixtures containing said long-chain alkylamines as a constituent, and the commercial value of the products are reduced greatly.
SUMMARY OF THE INVENTION We have discovered that the foregoing disadvantage can be overcome by treating the amines with a special class of reducing agents. We have discovered that hydrogenated boron compounds are superior in their effects, and in their safety and stability in an aqueous solution as a reducing agent for such amines. The present invention is an economic and simple industrial process for obtaining purified alkyl amines which are not apt to color during subsequent salt-forming reactions.
The present invention provides an improved process for refining aliphatic amines by treating said amines with hydrogenated boron compounds.
The invention is a method of refining aliphatic hydrocarbon amines having at least one alkyl group of 9 to 22 carbon atoms attached to the amino nitrogen, said amines being derived from polymerized ethylene by known methods and having a tendency to form colored amine salts, which comprises suppressing said tendency "by reacting said aliphatic amine with 0.01 to 5% by weight based on the amine of a borohydride compound selected from the group consisting of an alkali metal borohydride, amine borohydrides, quaternary ammonium borohydrides and mixtures thereof, and recovering refined aliphatic amine from the reaction mixture.
The amine material to which the refining process of the invention can be applied are generally aliphatic primary, secondary and tertiary amines, and mixtures of such amines. The amines have the formulas RNH RRNH and RRR"N, wherein R is alkyl havingifrom 9 the amine material is a mixture of primary, secondary or tertiary amines in which R has various values within the range of carbon atom number for R set forth above. The amine material can be a mixture of primary and/or secondary and/or tertiary amines. As amine materials with which the process of the invention is particularly effective, there are enumerated amine materials derived from ethylene low polymers such as a-olefins and Ziegler alcohols or amine mixtures containing said amines as a constituent. These amine materials derived from ethylene low polymers have the tendency of forming undesired color substances when converted to aminesalts, quaternary ammonium salts and/or betaines, apparently owing to a minor amount of impurities therein. Examples of such amines and their preparation are described in (l) M. T. Atwood, .IAOCS. 40, 64 (1963); (2) T. Clarke et al., .IAOCS. 41, 78 (1964); (3) Onyx Corp. U.S. Pat. No. 3,471,562 (Oct. 7, 1969); and (4) Sun Chemical Corp. U.S. Pat. No. 3,401,203 (Sept. 10, 1968).
As the boron hydride, there can be employed an alkali metal salt of boron hydride such as sodium borohydride, potassium borohydride and lithium borohydride, an amine salt of boron hydride, a quaternaryammonium salt of boron hydride and mixtures thereof.
The boron hydrides can be added in the form of dry powder or in alkaline aqueous solution. The amount of boron hydride to be added is dependent on the kind of amine to be treated, the process by which it was manufactured, and its properties. The amount of boron hydride used should be kept as low as possible in order to minimize expense, but the use of an excess amount of boron hydride does not cause any adverse effect. Generally, the boron hydride compound is added in an amount from about 0.01 to about 5% by weight, based on the weight of the starting amine material, preferably from 0.05 to 2% by weight.
If a small amount of alkali is added to the starting amine material together with the boron hydride compound, the effect of the boron hydride compound is greatly enhanced and the properties of the amines are further improved. The alkali is preferably water-soluble and is added in an amount up to 50%, preferably in the range of 0.1 to 10%, based on the weight of the starting amine materials. As the alkali, it is preferred to use sodium hydroxide, potassium hydroxide and sodium carbonate. The amount thereof to be added is not critical. The boron hydride compound is effective even if no alkali at all is added.
The preferred mode of performance of this invention consists of treating the starting amine material with boron hydride compound in an amount of from about 0.01 to about 5% by weight, based on the weight of the amine, in the presence of an alkali.
A specific preferred process according to this invention comprises placing the starting amine material, boron hydride compound and an aqueous solution of caustic alkali in a reactor, and agitating the mixture for several (about 2 to about 10) hours at about 50 to C. It will be understood, however, that the treating temperature and the treating time are not critical.
The present invention is carried out usually in a homogeneous or non-homogeneous phase of amine and water, but if necessary, alcohol such as methanol, ethano] or isopropanol can be added.
The presence of inorganic salts in the starting amine material, such as sodium chloride, sodium bromide, and potassium chloride, does not inhibit the desired effect of the boron hydride compound. Therefore, it is possible to employ as a starting amine material, a tertiary amine produced by reaction of an alkyl halide and a primary or secondary amine in the presence of an excess of alkali, followed by treatment of the resultant tertiary amine in place as it is, not isolated, with the boron hydride compound. This is an effective and simple process.
When the amine treated according to the process of this invention is isolated and converted to an amine salt, quaternary ammonium salt or amine betaine, by a known process, there is obtained a practically colorless product. Thus the colorization that occurs when an untreated product is similarly converted, is avoided by treating the amine material by the process of this invention. The amine material treated according to the process of this invention and the above-described compounds obtained from that amine material are quite similar to the corresponding products obtained from untreated amine material in the features, of chemical analysis, physical properties and chemical activity, but they are remarkably free of colorization.
The effect of the boron hydride compounds in this acid.
The invention is further described by reference to the following illustrative and non-limiting Examples.
EXAMPLE 1 Lauryl alcohol consisting of 70 wt. Ziegleralcohol and 30 wt. coconut alcohol was converted to the corresponding chloride, and the lauryl dimethylamine produced from the chloride in known manner was em ployed as the starting amine material. To a mixture of 115 grams of said lauryl dimethylamine, 100 grams of water and 12 grams of isopropyl alcohol, there were added 2 grams of caustic soda and 390 mg. of sodium borohydride. The mixture was agitated at 50-60C for 2 hours. After the end of this period, the product was allowed to separate into phases, and the upper layer, i.e., the amine layer, was washed with 100 ml of warm water twice to obtain refined lauryl dimethylamine. The analytical values of the lauryl dimethylamine were as follows:
Untreated starting material: total amine value: 250.9 tertiary amine value: 249.7 Treated product: total amine value: 250.7 tertiary amine value: 248.2
To 55 gram samples of each of said treated and untreated amine, there were added 100 grams of water and 101 grams of 3N hydrochloric acid, and the mixtures were agitated at 50 60C for 2 hours. Then, the degree of colorization of aqueous solutions of the produced lauryl dimethylamine hydrochlorides was observed. The hydrochloride of the untreated amine material was pale red, while the hydrochloride of the amine material treated with boron hydride compound according to this invention was colorless. The percent transmission of the respective hydrochlorides was determined, based on that of distilled water as being 100%, by a colorimeter at a wave length of 500mu. The percent transmission was 89.5% with the hydrochloride of the untreated amine, whereas hydrochloride of the treated amine product of this invention had a percent transmission of 94.8%. I
The treated and untreated tertiary amines were each i.
EXAMPLE 2 The same conditions as in Example 1 were employed except that the amount of sodium borohydride was re- I duced to 100 mg. The lauryl dimethylamine hydrochloride obtained by a conventional process as in Example l was, colorless and had a percent transmission of 93.6%. (The percent transmission was determined by the method used in Example 1. This applies also in the following examples.)
EXAMPLE 3 The same conditions as in Example 1 were employed except that there was used 550mg. of potassium borohydride instead of sodium borohydride. The hydrochloride obtained by a conventional process as in Example 1 was colorless and had a percent transmission of 93.8%.
EXAMPLE 4 Lauryl dimethylamine, produced by the reaction of lauryl bromide prepared by the radical addition reac-.
tion of dodecene with hydrogen bromide and dimethyl-' I amine, was treated with sodium borohydride under the same conditions as in Example 1. The 25% aqueous solution of lauryl dimethylamine hydrochloride prepared from the treated amine was colorless and the percent transmission thereof was 94.0%. The corresponding hydrochloride of the untreated amine was pale red, and
the percent transmissionthereof was 86.8%.
From the treated and untreated amines, lauryl benzyl dimethylammonium chorides were prepared by a conventional process. The chloride derived from the amine treated with sodium borohydride was colorless,
whereas the chloride derived from the untreated amine was pale red at pH less than 3.
EXAMPLE 5 Lauryl amine, produced by the reaction of lauryl bro mide used in Example 4 and ammonia, was treated with sodium borohydride under the same conditions as in Example 1, and then a 25% aqueous solution of lauryl amine hydrochloride was prepared by a conventional process. The solution was colorless. The lauryl amine hydrochloride prepared from the untreated amine was 9 slightly red.
EXAMPLE 6 From the lauryl bromide used in Example 4 anddimethylamine, lauryl dimethylamine was prepared in the presence of an excess of caustic soda by a conventional process. 112 mg. of sodium borohydride were added to 152 grams of the unrefined crude amine reaction product, and the mixture was treated at 50 C for2 hours. Then, a 25% aqueous solution of lauryl dimethylamine hydrochloride was prepared by a conventional process as in Example 1. 1t was colorless andthe percent transmission thereof was 94.0%.
COMPARISON EXAMPLE Table 1 Charged Amount Hydrochlorides (based on the Reducing Agent wt7 of amine) 71 Transmission color Sodium sulfite 5.57: 88.8% Pale red Sodium hydrosul- 9.| 88.5 Pale red fite Hydrazine 2.2 90.0 Pale red Hypophosphorous 2.9 9 l .0 Slightly acid red Untreated 85.2 Pale red As seen in Table 1, there was found a slight improvement effect in each case, in comparison with the untreated material. But in each case the improvement was greatly inferior to that of the product treated with boron hydride.
The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
l. A method for refining aliphatic hydrocarbon amines having at least one alkyl group of 9 to 22 carbon atoms attached to the amino nitrogen, said amines being derived from polymerized ethylene and containing impurities which form coloring substances when the amines are converted to amine salts, which comprises the steps of: reacting said amine with A. from 0.01 to 5 percent by weight, based on said amine, of a borohydride substance selected from the group consisting of alkali metal borohydrides,
6 amine borohydrides, quaternary ammonium borohydrides and mixtures thereof, and
B. up to 50 percent by weight, based on said aliphatic amine, of an alkali, and recovering from the reaction mixture a refined aliphatic amine which is not apt to color during salt-forming reactions.
2. A method according to claim 1 in which said amine is selected from the group consisting of compounds of the formulas RNl-l, RRNH and RR'R"H and mixtures thereof, wherein R is alkyl having 9 to 22 carbon atoms, and wherein R and R" are alkyls having 1 to 22 carbon atoms.
3. A method according to claim 2 wherein R is alkyl having 10 to 18 carbon atoms and R and R are alkyls having 1 to 6 carbon atoms.
4. A method according to claim 2 wherein R is lauryl and R and R" are methyl or ethyl.
5. A method according to claim 3 in which said borohydride substance is selected from the group consisting of sodium borohydride, potassium borohydride and lithium borohydride.
6. A method according to claim 5 in which the amount of said borohydride substance is from 0.05 to 2 percent by weight, based on said amine.
7. A method according to claim 6 in which said alkali is selected from the group consisting of sodium hydroxide, potassium hydroxide and sodium carbonate, and the amount of said alkali is from 0.1 to 10 percent by weight, based on said amine.
8. A method according to claim 7 in which said amine, said borohydride substance and an aqueous solution of said alkali are placed in a reactor and are mixed therein, at about 50 to C, for from 2 to 10 hours, and the refined amine is recovered by allowing the liquid reaction mixture to separate into layers and the layer containing the refined amine is removed from the remainder of the reaction mixture.
9. A method according to claim 1 in which the reaction is carried out in water.
Claims (9)
1. A METHOD FOR REFINING ALIPHATIC HYDROCARBON AMINES HAVING AT LEAST ONE ALKYL GROUP OF 9 TO 22 CARBON ATOMS ATTACHED TO THE AMINO NITROGEN, SAID AMINES BEING DERIVED FROM POLYMERIZED ETHYLENE AND CONTAINING IMPURITIES WHICH FORM COLORING SUBSTANCE WHEN THE AMINES ARE CONVERTED TO AMINE SALTS, WHICH COMPRISES THE STEPS OF: A. FROM 0.01 TO 5 PERCENT BY WEIGHT, BASED ON SAID AMINE WITH A BOROHYDRIDE SUBSTANCE SELECTED FROM THE GROUP CONSISTING OF ALKALI METAL BOROHYDRIDES AND MIXTURES THEREOF, AND AMMONIUM BOROHYDRIDES AND MIXTURES THEREOF, AND B. UP TO 50 PERCENT BY WEIGHT, BASED ON SAID ALIPHATIC AMINE, OF AN ALKALI, AND RECOVERING FROM THE REACTION MIXTURE A REFINED ALIPHATIC AMINE WHICH IS NOT APT TO COLOR DURING SALT-FORMING REACTIONS.
2. A method according to claim 1 in which said amine is selected from the group consisting of compounds of the formulas RNH, RR''NH and RR''R''''H and mixtures thereof, wherein R is alkyl having 9 to 22 carbon atoms, and wherein R'' and R'''' are alkyls having 1 to 22 carbon atoms.
3. A method according to claim 2 wherein R is alkyl having 10 to 18 carbon atoms and R'' and R'''' are alkyls having 1 to 6 carbon atoms.
4. A method according to claim 2 wherein R is lauryl and R'' and R'''' are methyl or ethyl.
5. A method according to claim 3 in which said borohydride substance is selected from the group consisting of sodium borohydride, potassium borohydride and lithium borohydride.
6. A method according to claim 5 in which the amount of said borohydride substance is from 0.05 to 2 percent by weight, based on said amine.
7. A method according to claim 6 in which said alkali is selected from the group consisting of sodium hydroxide, potassium hydroxide and sodium carbonate, and the amount of said alkali is from 0.1 to 10 percent by weight, based on said amine.
8. A method according to claim 7 in which said amine, said borohydride substance and an aqueous solution of said alkali are placed in a reactor and are mixed therein, at about 50* to 70*C, for from 2 to 10 hours, and the refined amine is recovered by allowing the liquid reaction mixture to separate into layers and the layer containing the refined amine is removed from the remainder of the reaction mixture.
9. A method according to claim 1 in which the reaction is carried out in water.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP1011673A JPS5522465B2 (en) | 1973-01-24 | 1973-01-24 |
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US3922306A true US3922306A (en) | 1975-11-25 |
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ID=11741322
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US435086A Expired - Lifetime US3922306A (en) | 1973-01-24 | 1974-01-21 | Process for refining amines |
Country Status (3)
Country | Link |
---|---|
US (1) | US3922306A (en) |
JP (1) | JPS5522465B2 (en) |
ES (1) | ES422539A1 (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5103053A (en) * | 1991-03-18 | 1992-04-07 | Ethyl Corporation | Process for treating tert-amines |
US5103052A (en) * | 1991-03-18 | 1992-04-07 | Ethyl Corporation | Tertiary amine treatment |
US5107028A (en) * | 1991-03-18 | 1992-04-21 | Ethyl Corporation | Process for treating tert-amines |
US5113017A (en) * | 1991-03-18 | 1992-05-12 | Ethyl Corporation | Process for treating tertiary amines |
US5118852A (en) * | 1991-03-18 | 1992-06-02 | Ethyl Corporation | Tert-amine treatment |
US5136092A (en) * | 1991-03-18 | 1992-08-04 | Ethyl Corporation | Process for treating tertiary amines |
EP0504628A2 (en) * | 1991-03-18 | 1992-09-23 | Ethyl Corporation | Process for treating tertiary amines |
US5359139A (en) * | 1991-03-18 | 1994-10-25 | Albemarle Corporation | Tertiary amine treatment |
WO1997046529A1 (en) * | 1996-06-03 | 1997-12-11 | Basf Aktiengesellschaft | Process for purifying sterically hindered 4-amino piperidines |
WO2018099871A1 (en) | 2016-11-29 | 2018-06-07 | Basf Se | Method for stabilizing at least mono-alkyl-substituted diaminocyclohexanes |
CN113277949A (en) * | 2020-02-19 | 2021-08-20 | 科莱恩丰益脂肪胺(连云港)有限公司 | Method for processing, producing or refining aliphatic hydrocarbon amines or derivatives thereof |
US11203568B2 (en) | 2015-12-29 | 2021-12-21 | Sabic Global Technologies B.V. | Methods of reducing color in alkanolamine compositions and compositions produced thereby |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2922818A (en) * | 1955-12-29 | 1960-01-26 | Bayer Ag | Process for the production of ethylene diamine |
US3468954A (en) * | 1965-03-26 | 1969-09-23 | Rhone Poulenc Sa | Stabilized dinitroso-pentamethylene tetramine |
US3594421A (en) * | 1968-10-31 | 1971-07-20 | Jefferson Chem Co Inc | Recovery of primary amines |
US3595921A (en) * | 1969-06-16 | 1971-07-27 | Jefferson Chem Co Inc | Reducing the color content of polyethylene polyamines prepared by the reaction of ammonia with ethylene dichloride |
-
1973
- 1973-01-24 JP JP1011673A patent/JPS5522465B2/ja not_active Expired
-
1974
- 1974-01-21 US US435086A patent/US3922306A/en not_active Expired - Lifetime
- 1974-01-23 ES ES422539A patent/ES422539A1/en not_active Expired
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2922818A (en) * | 1955-12-29 | 1960-01-26 | Bayer Ag | Process for the production of ethylene diamine |
US3468954A (en) * | 1965-03-26 | 1969-09-23 | Rhone Poulenc Sa | Stabilized dinitroso-pentamethylene tetramine |
US3594421A (en) * | 1968-10-31 | 1971-07-20 | Jefferson Chem Co Inc | Recovery of primary amines |
US3595921A (en) * | 1969-06-16 | 1971-07-27 | Jefferson Chem Co Inc | Reducing the color content of polyethylene polyamines prepared by the reaction of ammonia with ethylene dichloride |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5359139A (en) * | 1991-03-18 | 1994-10-25 | Albemarle Corporation | Tertiary amine treatment |
US5118852A (en) * | 1991-03-18 | 1992-06-02 | Ethyl Corporation | Tert-amine treatment |
US5103053A (en) * | 1991-03-18 | 1992-04-07 | Ethyl Corporation | Process for treating tert-amines |
US5113017A (en) * | 1991-03-18 | 1992-05-12 | Ethyl Corporation | Process for treating tertiary amines |
EP0504628A3 (en) * | 1991-03-18 | 1993-01-27 | Ethyl Corporation | Process for treating tertiary amines |
US5136092A (en) * | 1991-03-18 | 1992-08-04 | Ethyl Corporation | Process for treating tertiary amines |
EP0504628A2 (en) * | 1991-03-18 | 1992-09-23 | Ethyl Corporation | Process for treating tertiary amines |
US5103052A (en) * | 1991-03-18 | 1992-04-07 | Ethyl Corporation | Tertiary amine treatment |
US5107028A (en) * | 1991-03-18 | 1992-04-21 | Ethyl Corporation | Process for treating tert-amines |
US6011157A (en) * | 1996-06-03 | 2000-01-04 | Basf Aktiengesellschaft | Process for purifying sterically hindered 4-amino piperidines |
WO1997046529A1 (en) * | 1996-06-03 | 1997-12-11 | Basf Aktiengesellschaft | Process for purifying sterically hindered 4-amino piperidines |
US11203568B2 (en) | 2015-12-29 | 2021-12-21 | Sabic Global Technologies B.V. | Methods of reducing color in alkanolamine compositions and compositions produced thereby |
US11702382B2 (en) | 2015-12-29 | 2023-07-18 | Sabic Global Technologies B.V. | Methods of reducing color in alkanolamine compositions and compositions produced thereby |
WO2018099871A1 (en) | 2016-11-29 | 2018-06-07 | Basf Se | Method for stabilizing at least mono-alkyl-substituted diaminocyclohexanes |
CN109996784A (en) * | 2016-11-29 | 2019-07-09 | 巴斯夫欧洲公司 | Method for stablizing the diaminocyclohexane that at least monoalkyl replaces |
CN113277949A (en) * | 2020-02-19 | 2021-08-20 | 科莱恩丰益脂肪胺(连云港)有限公司 | Method for processing, producing or refining aliphatic hydrocarbon amines or derivatives thereof |
CN113277949B (en) * | 2020-02-19 | 2023-03-14 | 科莱恩丰益脂肪胺(连云港)有限公司 | Method for processing, producing or refining aliphatic hydrocarbon amines or derivatives thereof |
Also Published As
Publication number | Publication date |
---|---|
ES422539A1 (en) | 1976-05-01 |
JPS5522465B2 (en) | 1980-06-17 |
JPS4995907A (en) | 1974-09-11 |
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