US3865546A - Depilatory composition and method of use - Google Patents
Depilatory composition and method of use Download PDFInfo
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- US3865546A US3865546A US291305A US29130572A US3865546A US 3865546 A US3865546 A US 3865546A US 291305 A US291305 A US 291305A US 29130572 A US29130572 A US 29130572A US 3865546 A US3865546 A US 3865546A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q9/00—Preparations for removing hair or for aiding hair removal
- A61Q9/04—Depilatories
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
Definitions
- a means and method of removing hair from the skin of the body comprises applying a 1,4 dimercapto -2,3 butane diol to the hair at the skin at a pH of from 7 to 13.
- the 1,4 dimercapto -2,3 butane diol or substituted product thereof is permitted to react with the hair until depilatory action is carried out after which the hair and reaction products are removed from the skin.
- Preferably calcium ions are used in conjunction with the 1,4 dimercapto -2,3 butane diol or substituted product thereof to increase the speed of hair removal.
- An important object of this invention is to provide an advantageous means and method for removing human hair.
- Another important object of this invention is to provide a means and method in accordance with the preceding object which is highly efficient employing only a limited quantity of materials and which acts rapidly with minimized skin irritation problems.
- 1,4 dimercapto -2,3 butane diol or a substituted product thereof is applied to human hair at the skin of the body preferably in solution form in molar concentration of from 0.1 to 1.0M with a pH in the range of from 7 to 13.
- the solution is permitted to react with the hair until a depilatory action is carried out and then the reaction products, solution and hair are removed as by washing.
- the reaction is carried out at room temperature.
- the 1,4 dimercapto -2,3 butane diol or substituted product thereof is used in an aqueous solution which also incorporates a swelling agent to swell the hair thus enabling faster reaction times, a wetting agent to cause the solution to rapidly wet the hair and where a paste rather than a free flowing liquid is desired, a thickening agent.
- the 1,4 dimercapto -2,3 butane diol or substituted product thereof in aqueous solution preferably has added thereto calcium ions with the solution being alkaline and having a pH in the range of from 8 to 12.
- the alkaline pH is preferably obtained by adding the calcium to the solution in the form of calcium hydroxide.
- the present means and method is substantially non-irritating to the skin of users and carries out a depilatory action extremely rapidly.
- 1,4 dimercapto -2,3 butane diol having the formula:
- a and B are hydroxyl groups
- hair is exposed to a swelling agent and contacted with a solution of 1,4 dimercapto -2,3 butane diol preferably at room temperature.
- 1,4 dimercapto -2,3 butane diol preferably at room temperature.
- thiols and particularly thioglycolates such as calcium thioglycolate. Either the trans or cis form of the diol can be used.
- the efficiency of our compound is probably due to the formation of a stable ring compound after reaction with the disulfide linkages whereas thioglycolates participate in an equilibrium reaction where a substantial excess is required in order to have the reaction proceed.
- one or both of the hydroxyl groups can be removed and substituted with other water soluble polar groups including NH -PO H -COOH and -SO H.
- hydrogen may be used for the remaining A or B group although this is not preferred. In some cases either one of the hydroxyl groups can be removed and substituted with hydrogen.
- Examples of suitable compounds are: (1,4 dimercapto -2 hydroxy-n-butyl) 3-phosphate, (1,4 dimercapto -2 hydroxy-n-butyl) 3-sulfonate, 1,4 dimercapto -2-amino -3 hydroxy butane, 1,4 dimercapto -2 hydroxy-3-carboxy butane, (1,4 dimercapto-n-butyl) 3-su1fonate as well as their salts.
- These materials are solids at room temperature. Thus, they can easily be packaged in convenient dry packages and since they are highly soluble in water or conventional swelling agents for hair, they can easily be dissolved just prior to application in a depilatory procedure.
- the compounds of this invention are preferably used in aqueous solution at a concentration range of from 0.15 to 0.4 molar although the range may be 0.1 to 1.0 molar.
- the compounds are mixed in aqueous solution with swelling agents, wetting agents and in some cases thickening agents.
- Suitable swelling agents include water, organic or inorganic bases including potassium hydroxide, sodium ing clay, methyl cellulose, sodium carboxy methyl cellulose, ammonium polyacrylate, gum tragacanth, alginates, various emulsions such as combinations of lauryl sulfates with cetyl and stearyl alcohol,and others wellknown to the cosmetic formulator can be used. In most cases, it is preferred to form a viscous solution to prevent liquid run off during use. However, the thickener 55 no interaction precipitating out both the calcium and the agents. For example, if sodium laurate, a commonly used soap is used as the wetting agent, calcium ions should not be used since a precipitate would occur in the solution, thus, the swelling agents used must be selected without the use of calcium hydroxide.
- hydroxide calcium hydroxide, ammonium hydroxide, 5
- Known thickening agents such as gum tragacanth, monoethanolamine, triethanolamine, morpholine, urea various alginates, various emulsions such as combinaand others.
- These materials can also be employed to tions of lauryl sulfates with cetyl and stearyl alcohol maintain he nge of P mpl y Within the r g and the like which do not precipitate out are particuof from 7 to 13 and preferably 8 to 12.
- the swelling larly useful when calcium ions as in the form ofcalcium agents are used to swell the hair and permit faster reacl hydroxide are employed in the solutions of this invention times for hair removal. tion.
- Calcium ions are preferably used in the 1,4 dime
- the compound of this capto -2,3 butane diol or substituted products thereof invention is applied to the hair at the skin of the body in aqueous solutions at pl-ls of from 8 to 2.
- T e Ca preferably at room temperature although the temperacium is most conveniently added in the form ofcalcium ture can vary considerably and is preferably in the hydroxide thus simultaneously obtaining the desired range of from 60F to llOF. Higher temperatures inpH.
- the purpose of the calcium ions is to obtain faster crease the reaction rate.
- the only temperature limitareaction times at lower pH than other cations tested yet tion is that the temperature not cause discomfort to the without causing skin irritation.
- ions are used in the aqueous solutions of the 1,4 dimer- 20
- the reaction time necessary to have a depilatory accapto -2,3 butane diol or substituted products thereof tion will vary depending upon the concentration and when calcium ions are used. However, other cations temperature.
- depilatory action is accommay be present in minor amounts and preferably no plished in from 2 to 10 minutes although as much as 30 more than molar percent of the total cations presminutes may be employed. ent.
- the solution is permitted to react with clude sodium lauryl sulfates, Ethoxylated alkyl phenols, the hair until the depilatory action is carried out as evisulfated diethoxy alkyl phenol, soaps such as sodium denced by the hairs swollen appearance and loss of laurate, and other water soluble wetting agents which strength so that it is removed along with reaction prodhave well-known cosmetic use.
- the wetting agents are ucts as by washing the skin with water.
- the wetting agents preferably range atories in rapid and efficient processes. lt should be unin concentration from about 0.01 percent by weight up derstood that these examples are illustrative only and to 1 percent by weight of the solutions although higher are in no way limiting. concentrations can be used where particular effects are desired such as foaming, emulsification and the like.
- thickening agents such as inert fillers includ- 40 having the following formula:
- 1,4 dimercapto 2,3 butane diol 3.68 gms (to make the final solution 0.2 molar) Na HPO (buffer) 1.5 gms Sodium lauryl sulfate .17 gms 400 cps viscosity grade methyl cellulose .25 gms Water was used to bring the volume to mls and concentrated NaOH was then added until the pH was 12.0.
- 1,4-dimercapto-2,3 0.92 gms (to make the final butane diol solution 0.2 molar)
- Sodium lauryl sulfate 42.0 milligrams The sodium lauryl sulfate and 1,4 dimercapto 2,3 butane diol was added to water in an amount to form a final volume of 25 mls of solution.
- Calcium hydroxide was added to adjust the pH of the solution to 9.5.
- a small amount of the resultant solution was applied to a 2inch square area of a living human forearm which was profusely covered with growing hair. The time required for hair removal was noted. In 7 minutes at standard room temperature, all hair was completely removed from the treated area. No signs of irritation were observed.
- EXAMPLE 4 Example 3 is repeated but the amount of 1,4 dimercapto -2,3 butane diol is increased to 1.84 grams (to make the final solution 0.4 molar). Complete hair removal is obtained in 4 minutes.
- Example 3 is repeated but the amount of 1,4 dimercapto -2,3 butane diol is increased to 3.68 grams (to make the solution 0.8 molar). The time required for complete hair removal is 3.5 minutes.
- EXAMPLE 6 A 100 ml aqueous solution of this invention was formed in accordance with Example 3 containing 1,4 dimercapto -2,3 butane diol at 0.4 molar, polyethoxy isooctylphenol (Triton X-100) 0.5 percent by weight, gum tragacanth 1.0 percent by weight and calcium hydroxide to adjust the pH to 9.5.
- the resultant solution is extremely viscous and does not run off the arm when tested as in Example 3. Complete hair removal is obtained in 4 /2 minutes with no skin irritation observed or felt by the subject.
- Example 6 When Example 6 is repeated with variations in the calcium hydroxide used to adjust the pH to 8 and l 1.5 respectively, hair removal time is increased at the higher pH and decreased at the lower pH.
- Example 6 When the Triton X-100 and gum tragacanth are replaced in Example 6 by an emulsion of 4 percent by weight of the total solution of cetyl alcohol and onehalf percent by weight sodium lauryl sulfate prepared 65 in one-half of the total water used in the solution, similar results are obtained as in Example 6.
- a depilatory mixture can be formed in a dry package for sale to a user 5 who can form a solution or paste by addition of water or some other solvent.
- the dry packages can contain the swelling agents, wetting agents and/or thickening agents in separate packages.
- the amount of each material is predetermined to give sufficient depilatory action when mixed with a predetermined amount of water.
- the ratios of the various materials in solutions of this invention can vary greatly depending upon the times, temperatures and specific materials used.
- a method of removing hair from the skin of the body comprising,
- B is a water soluble polar group, said solution having said compound present in a concentration of from 0.1 to 1.0M with a pH of from 7 to 13, permitting said solution to react with said hair for a period of up to minutes until a depilatory action is carried out, and removing said solution from said skin along with reaction products and hair.
- said compound is 1,4 dimercapto 2,3 butane diol.
- each said water soluble, polar group is selected from the group consisting of OH, NH PO ',H-,, --COOH and SO -,H.
- An aqueous depilatory solution for use in removing hair from human skin
- B is a water soluble polar group, said compound present in a concentration of from 0.1 to 1.0M with a pH of from 7 to l3.
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Abstract
A means and method of removing hair from the skin of the body comprises applying a 1,4 dimercapto -2,3 butane diol to the hair at the skin at a pH of from 7 to 13. The 1,4 dimercapto -2,3 butane diol or substituted product thereof is permitted to react with the hair until depilatory action is carried out after which the hair and reaction products are removed from the skin. Preferably calcium ions are used in conjunction with the 1,4 dimercapto -2,3 butane diol or substituted product thereof to increase the speed of hair removal.
Description
United States Patent [191 Zemlin et al.
[ DEPILATORY COMPOSITION AND METHOD OF USE [75] Inventors: John C. Zemlin, Reading; Katherine A. Bowler, Acton, both of Mass.
[73] Assignee: Collaborative Research, Inc.,
Waltham, Mass.
[ Notice: The portion of the term of this patent subsequent to Aug. 5, 1986. has been disclaimed.
[22] Filed: Sept. 22, 1972 [21] Appl. No.: 291,305
Related US. Application Data [63] Continuation of Ser. No. 83,246, Oct. 22, 1970, abandoned, which is a continuation-in-part of Ser. No. 834,894, June 19, 1969, abandoned, which is a continuation-in-part of Ser. No. 533,236, March 10, 1966, Pat. No. 3,459,198.
[52] U.S. Cl. 8/161 [51] Int. Cl A61k 7/14 1 1*Feb. 11, 1975 [58] Field of Search 8/160, 161
[56] References Cited UNITED STATES PATENTS 3,459,198 8/1969 Zemiin et al 424/71 Primary Examiner-Sam Rosen Attorney, Agent, or Firm-W0lf, Greenfield & Sacks ABSTRACT A means and method of removing hair from the skin of the body comprises applying a 1,4 dimercapto -2,3 butane diol to the hair at the skin at a pH of from 7 to 13. The 1,4 dimercapto -2,3 butane diol or substituted product thereof is permitted to react with the hair until depilatory action is carried out after which the hair and reaction products are removed from the skin. Preferably calcium ions are used in conjunction with the 1,4 dimercapto -2,3 butane diol or substituted product thereof to increase the speed of hair removal.
13 Claims, N0 Drawings .DEPILATORY COMPOSITION AND METHOD OF USE RELATED APPLICATIONS This is a continuation of application Ser. No. 83,246 filed Oct. 22, 1970 (now abandoned) which is a continuation-in-part application of Ser. No. 834,894 filed June 19, 1969 (now abandoned) which is a continuation-in-part of application Ser. No. 533,236 filed Mar. 10, 1966 which issued Aug. 5, 1969 as U.S. Pat. No. 3,459,198.
BACKGROUND OF THE INVENTION Human hair has been removed from the skin of the body for medical and cosmetic reasons by various means and methods throughout the ages. In recent times, depilatory means and methods involve a chemical approach for removing hair which often consists of applying strongly alkaline sulfides and sulfltydrates in solution form to the skin. Problems arise with these compounds in that the very high alkalinity normally used is often irritating to the skin and the solutions often have vapors that are extremely obnoxious and in some cases toxic.
Many newer chemical depilatory compositions today are mixtures based on calcium thioglycolate and calcium hydroxide. Practically all of these mixtures are also strongly alkaline, having pHs up to 13 and higher. The high alkalinity is needed with conventional materials to swell the hair so that the thioglycolate can penetrate the hair shaft and cause softening and dissolving of the hair by virtue of its reducing action on the disulfide cross links of the hair. This occurs since human hair is a high molecular weight protein consisting of long chains of protein cross linked by cystine disulfide bonds.
Although calcium thioglycolate preparations do have distinct advantages over older known sulfide and sulfhydrate solutions, they nevertheless are strongly alkaline and cause irritation to a high percentage of users. In addition, the depilatory action is relatively slow and the process of removing hair often become lengthy, sometimes involving waits of thirty minutes or over. The odor of the thioglycolates is extremely vile and difficult to eliminate or mask. Other known materials for use as depilatories have similar disadvantages.
An important object of this invention is to provide an advantageous means and method for removing human hair.
Another important object of this invention is to provide a means and method in accordance with the preceding object which is highly efficient employing only a limited quantity of materials and which acts rapidly with minimized skin irritation problems.
SUMMARY OF THE INVENTION According to the invention, 1,4 dimercapto -2,3 butane diol or a substituted product thereof is applied to human hair at the skin of the body preferably in solution form in molar concentration of from 0.1 to 1.0M with a pH in the range of from 7 to 13. The solution is permitted to react with the hair until a depilatory action is carried out and then the reaction products, solution and hair are removed as by washing. Preferably the reaction is carried out at room temperature.
Preferably the 1,4 dimercapto -2,3 butane diol or substituted product thereof is used in an aqueous solution which also incorporates a swelling agent to swell the hair thus enabling faster reaction times, a wetting agent to cause the solution to rapidly wet the hair and where a paste rather than a free flowing liquid is desired, a thickening agent.
In the preferred form of the invention, the 1,4 dimercapto -2,3 butane diol or substituted product thereof in aqueous solution preferably has added thereto calcium ions with the solution being alkaline and having a pH in the range of from 8 to 12. The alkaline pH is preferably obtained by adding the calcium to the solution in the form of calcium hydroxide.
It is a feature of this invention that the present means and method is substantially non-irritating to the skin of users and carries out a depilatory action extremely rapidly.
DESCRIPTION OF PREFERRED EMBODIMENTS According to the invention, 1,4 dimercapto -2,3 butane diol having the formula:
where A and B are hydroxyl groups, is used to reduce disulfide linkages of hair which hair can be easily washed from the skin. In the method of this invention hair is exposed to a swelling agent and contacted with a solution of 1,4 dimercapto -2,3 butane diol preferably at room temperature. It has been found that an unexpectedly small quantity of 1,4 dimercapto -2,3 butane diol is highly active to remove hair as compared with the previously used thiols and particularly thioglycolates such as calcium thioglycolate. Either the trans or cis form of the diol can be used. The efficiency of our compound is probably due to the formation of a stable ring compound after reaction with the disulfide linkages whereas thioglycolates participate in an equilibrium reaction where a substantial excess is required in order to have the reaction proceed.
While 1,4 dimercapto -2,3 butane diol in either of its isomer forms is preferred for use in this invention, one or both of the hydroxyl groups can be removed and substituted with other water soluble polar groups including NH -PO H -COOH and -SO H. When one of the hydroxyl groups is so substituted, hydrogen may be used for the remaining A or B group although this is not preferred. In some cases either one of the hydroxyl groups can be removed and substituted with hydrogen. Examples of suitable compounds are: (1,4 dimercapto -2 hydroxy-n-butyl) 3-phosphate, (1,4 dimercapto -2 hydroxy-n-butyl) 3-sulfonate, 1,4 dimercapto -2-amino -3 hydroxy butane, 1,4 dimercapto -2 hydroxy-3-carboxy butane, (1,4 dimercapto-n-butyl) 3-su1fonate as well as their salts. These materials are solids at room temperature. Thus, they can easily be packaged in convenient dry packages and since they are highly soluble in water or conventional swelling agents for hair, they can easily be dissolved just prior to application in a depilatory procedure.
The compounds of this invention are preferably used in aqueous solution at a concentration range of from 0.15 to 0.4 molar although the range may be 0.1 to 1.0 molar. Preferably the compounds are mixed in aqueous solution with swelling agents, wetting agents and in some cases thickening agents.
Suitable swelling agents include water, organic or inorganic bases including potassium hydroxide, sodium ing clay, methyl cellulose, sodium carboxy methyl cellulose, ammonium polyacrylate, gum tragacanth, alginates, various emulsions such as combinations of lauryl sulfates with cetyl and stearyl alcohol,and others wellknown to the cosmetic formulator can be used. In most cases, it is preferred to form a viscous solution to prevent liquid run off during use. However, the thickener 55 no interaction precipitating out both the calcium and the agents. For example, if sodium laurate, a commonly used soap is used as the wetting agent, calcium ions should not be used since a precipitate would occur in the solution, thus, the swelling agents used must be selected without the use of calcium hydroxide.
hydroxide, calcium hydroxide, ammonium hydroxide, 5 Known thickening agents such as gum tragacanth, monoethanolamine, triethanolamine, morpholine, urea various alginates, various emulsions such as combinaand others. These materials can also be employed to tions of lauryl sulfates with cetyl and stearyl alcohol maintain he nge of P mpl y Within the r g and the like which do not precipitate out are particuof from 7 to 13 and preferably 8 to 12. The swelling larly useful when calcium ions as in the form ofcalcium agents are used to swell the hair and permit faster reacl hydroxide are employed in the solutions of this invention times for hair removal. tion.
Calcium ions are preferably used in the 1,4 dime In the method of this invention, the compound of this capto -2,3 butane diol or substituted products thereof invention is applied to the hair at the skin of the body in aqueous solutions at pl-ls of from 8 to 2. T e Ca preferably at room temperature although the temperacium is most conveniently added in the form ofcalcium ture can vary considerably and is preferably in the hydroxide thus simultaneously obtaining the desired range of from 60F to llOF. Higher temperatures inpH. The purpose of the calcium ions is to obtain faster crease the reaction rate. The only temperature limitareaction times at lower pH than other cations tested yet tion is that the temperature not cause discomfort to the without causing skin irritation. Preferably no other catski of a ser, ions are used in the aqueous solutions of the 1,4 dimer- 20 The reaction time necessary to have a depilatory accapto -2,3 butane diol or substituted products thereof tion will vary depending upon the concentration and when calcium ions are used. However, other cations temperature. Preferably depilatory action is accommay be present in minor amounts and preferably no plished in from 2 to 10 minutes although as much as 30 more than molar percent of the total cations presminutes may be employed. ent. After application of the compound preferably in an Suitable wetting agents for use in this invention inaqueous solution, the solution is permitted to react with clude sodium lauryl sulfates, Ethoxylated alkyl phenols, the hair until the depilatory action is carried out as evisulfated diethoxy alkyl phenol, soaps such as sodium denced by the hairs swollen appearance and loss of laurate, and other water soluble wetting agents which strength so that it is removed along with reaction prodhave well-known cosmetic use. The wetting agents are ucts as by washing the skin with water. preferably used to lower surface tension and permit The following illustrative examples indicate the efgood wetting of the hair fibers by the aqueous solutions fectiveness of the compounds of this invention as depilof this invention. The wetting agents preferably range atories in rapid and efficient processes. lt should be unin concentration from about 0.01 percent by weight up derstood that these examples are illustrative only and to 1 percent by weight of the solutions although higher are in no way limiting. concentrations can be used where particular effects are desired such as foaming, emulsification and the like. EXAMPLE 1 In cases where a paste is desired rather than a liquid 100 milliliters of a depilatory solution was prepared solution, thickening agents such as inert fillers includ- 40 having the following formula:
1,4 dimercapto 2,3 butane diol 3.68 gms (to make the final solution 0.2 molar) Na HPO (buffer) 1.5 gms Sodium lauryl sulfate .17 gms 400 cps viscosity grade methyl cellulose .25 gms Water was used to bring the volume to mls and concentrated NaOH was then added until the pH was 12.0.
A small amount of the resulting slightly viscous solution was applied to a 2 inch square area of human forearm which was profusely covered with hair and the time required for hair removal was noted. In 5 minutes substantial softening of the hair and partial solution was observed. In 10 minutes the hair was completely removed from the treated area. No signs of irritation was observed.
EXAMPLE 2 In a similar fashion 100 mls of solution were prepared using the following amounts of material:
Urea
solution Continued Sodium lauryl sulfate .17 gms 4000 cps viscosity grade methyl cellulose .25 gms Water was added to bring the volume to 100 mls and then concentrated ammonium hydroxide was added drop-wise until the pH was 9.5.
This solution on the same human skin as in Example 1 gave slight hair removal in minutes, considerable hair removal in minutes, and complete hair removal in minutes. No signs of irritation were noted.
EXAMPLE 3 25 mls solution of this invention were prepared using the following materials in the amounts noted:
1,4-dimercapto-2,3 0.92 gms (to make the final butane diol solution 0.2 molar) Sodium lauryl sulfate 42.0 milligrams The sodium lauryl sulfate and 1,4 dimercapto 2,3 butane diol was added to water in an amount to form a final volume of 25 mls of solution. Calcium hydroxide was added to adjust the pH of the solution to 9.5. A small amount of the resultant solution was applied to a 2inch square area of a living human forearm which was profusely covered with growing hair. The time required for hair removal was noted. In 7 minutes at standard room temperature, all hair was completely removed from the treated area. No signs of irritation were observed.
EXAMPLE 4 Example 3 is repeated but the amount of 1,4 dimercapto -2,3 butane diol is increased to 1.84 grams (to make the final solution 0.4 molar). Complete hair removal is obtained in 4 minutes.
EXAMPLE 5 Example 3 is repeated but the amount of 1,4 dimercapto -2,3 butane diol is increased to 3.68 grams (to make the solution 0.8 molar). The time required for complete hair removal is 3.5 minutes.
EXAMPLE 6 A 100 ml aqueous solution of this invention was formed in accordance with Example 3 containing 1,4 dimercapto -2,3 butane diol at 0.4 molar, polyethoxy isooctylphenol (Triton X-100) 0.5 percent by weight, gum tragacanth 1.0 percent by weight and calcium hydroxide to adjust the pH to 9.5. The resultant solution is extremely viscous and does not run off the arm when tested as in Example 3. Complete hair removal is obtained in 4 /2 minutes with no skin irritation observed or felt by the subject.
When Example 6 is repeated with variations in the calcium hydroxide used to adjust the pH to 8 and l 1.5 respectively, hair removal time is increased at the higher pH and decreased at the lower pH.
When the Triton X-100 and gum tragacanth are replaced in Example 6 by an emulsion of 4 percent by weight of the total solution of cetyl alcohol and onehalf percent by weight sodium lauryl sulfate prepared 65 in one-half of the total water used in the solution, similar results are obtained as in Example 6.
It is a feature of this invention that a depilatory mixture can be formed in a dry package for sale to a user 5 who can form a solution or paste by addition of water or some other solvent. In some cases, the dry packages can contain the swelling agents, wetting agents and/or thickening agents in separate packages. The amount of each material is predetermined to give sufficient depilatory action when mixed with a predetermined amount of water. The ratios of the various materials in solutions of this invention can vary greatly depending upon the times, temperatures and specific materials used.
What is claimed is: 1. A method of removing hair from the skin of the body comprising,
applying to the hair at the skin an aqueous solution of a compound having the formula wherein A is selected from the group consisting of hydrogen and a water soluble polar group,
B is a water soluble polar group, said solution having said compound present in a concentration of from 0.1 to 1.0M with a pH of from 7 to 13, permitting said solution to react with said hair for a period of up to minutes until a depilatory action is carried out, and removing said solution from said skin along with reaction products and hair. 2. A method in accordance with the method of claim 1 wherein said compound is 1,4 dimercapto 2,3 butane diol.
3. A method in accordance with the method of claim 1 wherein each said water soluble, polar group is selected from the group consisting of OH, NH PO ',H-,, --COOH and SO -,H.
4. A method in accordance with the method of claim 1 wherein in addition said solution contains calcium ions in an amount sufficient to obtain rapid depilatory reactions at a pH in the range of from 7 to 13.
5. A method in accordance with the method of claim 1 wherein said solution comprises calcium hydroxide in an amount sufficient to form the pH of the solution to a value of from 8 to 12.
6. A method in accordance with the method of claim 2 wherein in addition said solution contains calcium ions in an amount sufficient to obtain rapid depilatory reactions at a pH in the range of from 7 to 13.
7. A method in accordance with the method of claim 2 wherein said solution comprises calcium hydroxide in an amount sufficient to form the pH of the solution to a value of from 8 to 12.
8. A method in accordance with the method of claim 2 wherein said solution is permitted to react for a period of from 2 to 15 minutes.
9. An aqueous depilatory solution for use in removing hair from human skin,
said solution comprising,
an effective amount of a compatible swelling agent and wetting agent, and a compound having the formula ll ll PI l 1!; RAB-Ii wherein A is selected from the group consisting of hydrogen and a water soluble polar group,
B is a water soluble polar group, said compound present in a concentration of from 0.1 to 1.0M with a pH of from 7 to l3.
agent.
UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. ,546 Dated 5 Inventor) John C. Zemlln and Katherine A. Bowler It is certified that error appears in the above-identified patent and that said Letters Patentare hereby corrected as shown below:
Column 3; line 59, change "1,1" to -1,4--.
Column 4, line 58, cancel "was" and substitute --were-.
Signed and sealed this 15th day of April 1975.
fattest:
? W I C. MARSHALL DEIIJN may? commissioner 0L :atents attesting utrlcer and Trademarks FORM PO-1050 (10-69) USCOMM-DC 50376-P69 U.5. GOVERNMENT PRINTING OFFICE 2 I959 0-J55-334,
Claims (13)
1. A METHOD OF REMOVING HAIR FROM THE SKIN OF THE BODY COMPRISING, APPLYING TO THE HAIR AT THE SKIN AN AQUEOUS SOLUTION OF A COMPOUND HAVING THE FORMULA
2. A method in accordance with the method of claim 1 wherein said compound is 1,4 dimercapto -2,3 butane diol.
3. A method in accordance with the method of claim 1 wherein each said water soluble, polar group is selected from the group consisting of -OH, -NH2, -PO3H2, -COOH and -SO3H.
4. A method in accordance with the method of claim 1 wherein in addition said solution contains calcium ions in an amount sufficient to obtain rapid depilatory reactions at a pH in the range of from 7 to 13.
5. A method in accordance with the method of claim 1 wherein said solution comprises calcium hydroxide in an amount sufficient to form the pH of the solution to a value of from 8 to 12.
6. A method in accordance with the method of claim 2 wherein in addition said solution contains calcium ions in an amount sufficient to obtain rapid depilatory reactions at a pH in the range of from 7 to 13.
7. A method in accordance with the method of claim 2 wherein said solution comprises calcium hydroxide in an amount sufficient to form the pH of the solution to a value of from 8 to 12.
8. A method in accordance with the method of claim 2 wherein said solution is permitted to react for a period of from 2 to 15 minutes.
9. An aqueous depilatory solution for use in removing hair from human skin, said solution comprising, an effective amount of a compatible swelling agent and wetting agent, and a compound having the formula
10. An aqueous depilatory solution in accordance with claim 9 wherein said compound is 1,4 dimercapto -2,3 butane diol.
11. An aqueous depilatory solution in accordance with claim 10 wherein said swelling agent is calcium hydroxide.
12. An aqueous depilatory solution in accordance with claim 9 and further comprising calcium ions in an amount sufficient to Obtain rapid depilatory reactions at a pH in the range of from 7 to 13.
13. The aqueous depilatory composition of claim 10 converted into a paste consistency by incorporating therein an effective amount of a compatible thickening agent.
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US291305A US3865546A (en) | 1970-10-22 | 1972-09-22 | Depilatory composition and method of use |
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Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8324670A | 1970-10-22 | 1970-10-22 | |
US291305A US3865546A (en) | 1970-10-22 | 1972-09-22 | Depilatory composition and method of use |
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US3865546A true US3865546A (en) | 1975-02-11 |
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ID=26769094
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US291305A Expired - Lifetime US3865546A (en) | 1970-10-22 | 1972-09-22 | Depilatory composition and method of use |
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Cited By (17)
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US5402697A (en) * | 1993-11-18 | 1995-04-04 | Brooks; Shirley E. | Depilatory applicating razor |
WO1995033440A1 (en) * | 1994-06-09 | 1995-12-14 | The Procter & Gamble Company | Depilatory compositions comprising sulfhydryl compounds |
US5645825A (en) * | 1995-06-07 | 1997-07-08 | The Procter & Gamble Company | Depilatory compositions comprising sulfhydryl compounds |
EP0801570A1 (en) * | 1994-12-21 | 1997-10-22 | Cosmederm Technologies | Formulations and methods for reducing skin irritation |
US5840765A (en) * | 1997-08-04 | 1998-11-24 | Miller; Ethel | Depilating method |
US20030031727A1 (en) * | 1994-12-21 | 2003-02-13 | Cosmederm Technologies, Llc | Topical product formulations containing strontium for reducing skin irritation |
US20030124202A1 (en) * | 1994-12-21 | 2003-07-03 | Hahn Gary S. | Formulations and methods for reducing skin irritation |
WO2003097880A1 (en) * | 2002-05-22 | 2003-11-27 | Basf Aktiengesellschaft | Method for removing horn substance from skins, pelts, or furs |
US20040063392A1 (en) * | 1998-02-23 | 2004-04-01 | Monfort, Inc. | Method and system for processing waste streams derived from the dehairing of animals |
WO2004038046A1 (en) * | 2002-10-21 | 2004-05-06 | Basf Aktiengesellschaft | Method for removing horn substances from animal skin |
FR2854568A1 (en) * | 2003-05-06 | 2004-11-12 | Oreal | Use of water-soluble dithiols in a reducing composition for deformation of keratinic fibers, especially hair, at a defined pH |
WO2005049870A1 (en) * | 2003-11-17 | 2005-06-02 | Basf Aktiengesellschaft | Method for the extraction of keratin from dead animal skins |
US20090049619A1 (en) * | 2006-01-16 | 2009-02-26 | Farid Moussouni | Composition, Process For Preparation and Method of Use |
US20110197374A1 (en) * | 2010-02-17 | 2011-08-18 | Paul James Smith | Efficacious Depilatory Article |
US20110238086A1 (en) * | 2010-03-26 | 2011-09-29 | Charles Robert Smith | Method of Depilation and Depilatory Kit |
US20110232006A1 (en) * | 2010-03-26 | 2011-09-29 | Charles Robert Smith | Kit and Method for Removing Hair |
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US3459198A (en) * | 1966-03-10 | 1969-08-05 | Collaborative Res Inc | Waving and straightening human hair with 1,4-dimercapto-2,3-butane diol and substituted products thereof |
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US7404826B2 (en) * | 2002-05-22 | 2008-07-29 | Basf Se | Method for removing horn substance from skins, pelts or furs |
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US7250062B2 (en) | 2002-10-21 | 2007-07-31 | Basf Aktienegesellschaft | Method for removing horn substances from animal skin |
US20070143930A1 (en) * | 2002-10-21 | 2007-06-28 | Basfaktiengesellschaft | Method for removing horn substances from animal skin |
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