US3853645A - Composite propellant containing polytetrafluoroethylene powder and butyl or ethylene-propylene rubber - Google Patents
Composite propellant containing polytetrafluoroethylene powder and butyl or ethylene-propylene rubber Download PDFInfo
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- US3853645A US3853645A US00090210A US9021070A US3853645A US 3853645 A US3853645 A US 3853645A US 00090210 A US00090210 A US 00090210A US 9021070 A US9021070 A US 9021070A US 3853645 A US3853645 A US 3853645A
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- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
- C06B45/04—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive
- C06B45/06—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component
- C06B45/10—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component the organic component containing a resin
Definitions
- the invention described herein may be manufactured and used by or for the Government of the United States of America for governmental purposes without the payment of any royalties thereon or therefor.
- the present invention relates to improved homogeneous propellant molding powder and to the process for preparation thereof. 1 5
- the present invention is for propellant powders which are highly homogeneous.
- the process eliminates a quality control problem, enhances reliability in regard to those features which are affected by homogeneity, and eliminates a potential safety hazard caused by free oxidizer.
- inorganic oxidizer and 10 to 20 percent by weight metal fuel were incorporated into a matrix comprising from about 2 to 10 percent by weight polytetrafluoroethylene (Teflon) and from of warm air or inert gas was circulated by blowing means and the strands collected on conveyor belts or other means, followed by complete drying or curing under ambient conditions.
- Teflon polytetrafluoroethylene
- the matrix is prepared by mixing the selected rubber,
- butyl and/or ethylene-propylene in a solvent such as petroleum ether which is preferred.
- a solvent such as petroleum ether which is preferred.
- hexane works satisfactorily with the ethylene-propylene rubbers.
- Butyl rubber is highly impermeable (a very desirable feature) and holds tenaciously to the solvent.
- Propellant strands prepared by this process are highly homogeneous.
- the strands show no oxidizer on the surface and no material is segrated. None is selectively lost by adherence to the mixing kettle, as often occurs in the well known shock-precipitation method of producing molding powders.
- the present process eliminates a quality control problem, enhances reliability in regard to those features which are affected by homogeneity, and eliminates a potential safety hazard caused by free oxidizer.
- This process contrasts with the old, but frequently used process for compounding propellant powders which involves preparing a solution of the soluble binder material, suspending the solid components in the solution, and precipitating the binder by quenching with a nonsolvent.
- the agglomerated mixture of ingreclients is separated from the supernatant liquids, and then dried, and sometimes screened.
- this is often called a coating process, it is in fact a simple agglomeration with solid particles randomly and mechanically held in a matrix of binder material.
- ammonium perchlorate the most widely used oxidizer, dissolves or recrystallizes in polar solvents which contain water resulting in changes in oxidizer particle size distribution in the final product.
- Teflon is used as a reinforcing agent. Teflon will, during a shearing procedure, coalesce and cold draw into fibers. Thus, with the Teflon powder-rubber mixture, the conventional extrusion procedure results in the formation of reinforcing fibers in situ. All the fibers are never really completely straight, for there is a certain amount of sideways drift of particles during extrusion. Teflon content as low as /q% effectively improves the tensile strength and elongation of propellants containing it. The strength increases as the Teflon content is increased.
- the tensile strengths were generally in the range 300 to 800 psi and the percent elongations in the range of 20 to 35%.
- the burning rates of these propellants measured with 0.125-inch diameter strands are about 0.5 in/sec at 1000 psi and ambient temperature.
- Slopes vary from 0.45 to 0.70 with butyl rubber, and from 0.6 to 0.8 with ethylene propylene rubber.
- Teflon 16 Ammonium perchlorate 77 Strand burning rates at 77 F. and 1,000 psi of three of the present new formulations are given below:
- cuprous oxide cupric 0x ide
- copper chromate copper chromate
- ferric oxide was used.
- Butyl rubber used herein is a synthetic rubber produced by polymerizing isobutylene or alternatively by copolymerization of isobutylene (approximately 98%) with a small proportion (2%) of conjugated diene, for instance isoprene or butadiene, and is identified more specifically as isobutylene-isoprene rubber (HR).
- the ethylene-propylene rubber (EPR) is an elastomer made by the steriospecific copolymerization of ethylene and propylene and alternatively a small percent, 2 5%, of a conjugated diene is added to provide curing sites.
- a propellant molding powder comprising:
- inorganic oxidizer from about to percent by weight inorganic oxidizer; up to about 20 percent by weight polytetrafluoroethylene; and 5 from about 5 to about 15 percent by weight of a synthetic rubber selected from the group consisting of butyl rubber, ethylene propylene rubber and mixtures thereof.
Abstract
A process for the preparation of propellant molding powders having good ingredient quality control and good composition homogeneity comprising Teflon powder, butyl or ethylene-propylene rubber binder and an inorganic oxidizer. Metal fuels such as aluminum were also included, as were burning rate modifiers. The process comprises forming a homogeneous binder solution, adding the propellant ingredients and mixing to form a paste, extruding the paste through small cross-sectional orifices, blowing warm air or inert gas around the strands extruded from the orifices and collecting the strands by appropriate means.
Description
finite States tent n91 Kaufman et a1.
COMPOSITE PROPELLANT CONTAINING POLYTETRAFLUOROETHYLENE POWDER AND BUTYL 0R ETHYLENE-PROPYLENE RUBBER Inventors: Martin H. Kaufman; Edward M.
Roy, both of China Lake, Calif.
The United States of America as represented by the Secretary of the Navy, Washington, DC.
Filed: Oct. 30, 1970 Appl. No.: 90,210
Assignee:
US. Cl 149/19.3, 149/19.9l, 149/20, 149/44, 149/76 Int. Cl C06d 5/06 Field of Search..... 149/19, 76, 44, 19.3, 19.91, 149/20 References Cited UNITED STATES PATENTS 6/1966 Kaufman 149/2 X 4/1968 Hodgson 149/19 X 7/1968 Sparks et al. .i 149/19 X Bee. 10, 197
3,476,622 11/1969 Harada et a1. 149/19 3,513,043 5/1970 Burnside l 149/87 X 3,577,289 5/1971 Morrell 149/19 3,586,552 6/1971 Potts et al. 149/19 Primary Examiner-Benjamin R. Padgett Assistant ExaminerE. A. Miller Attorney, Agent, or Firm-R. S. Sciascia; Roy Miller; Lloyd E. K. Pohl [5 7] ABSTRACT 7 Claims, No Drawings l COMPOSITE PROPELLANT CONTAINING POLYTETRAFLUOROETHYLENE POWDER AND BUTYL OR ETHYLENE-PROPYLENE RUBBER STATEMENT OF GOVERNMENT INTEREST- The invention described herein may be manufactured and used by or for the Government of the United States of America for governmental purposes without the payment of any royalties thereon or therefor.
BACKGROUND OF THE INVENTION The present invention relates to improved homogeneous propellant molding powder and to the process for preparation thereof. 1 5
For some time in the propellant field work has been directed toward devising and providing a versatile family of propellants to meet the future needs of the rocket system developers. The hydrocarbon-rubber binder systems now in use'are highly unsaturated and are the major cause of chemical instability of the propellant grain. Chemical stability is important since chemical changes that affect the performance may occur during storage in uncontrolled environments, Moreover, the
techniques by which they are used may introduce various process variables which prevent ballistic reproducibility. The present invention is for propellant powders which are highly homogeneous. The process eliminates a quality control problem, enhances reliability in regard to those features which are affected by homogeneity, and eliminates a potential safety hazard caused by free oxidizer.
DESCRIPTION OF THE INVENTION In accordance with the present invention from about. 50 to 70 percent by weight inorganic oxidizer and 10 to 20 percent by weight metal fuel were incorporated into a matrix comprising from about 2 to 10 percent by weight polytetrafluoroethylene (Teflon) and from of warm air or inert gas was circulated by blowing means and the strands collected on conveyor belts or other means, followed by complete drying or curing under ambient conditions.
The matrix is prepared by mixing the selected rubber,
butyl and/or ethylene-propylene, in a solvent such as petroleum ether which is preferred. However, hexane works satisfactorily with the ethylene-propylene rubbers. Butyl rubber is highly impermeable (a very desirable feature) and holds tenaciously to the solvent.
Propellant strands prepared by this process are highly homogeneous. The strands show no oxidizer on the surface and no material is segrated. Nothing is selectively lost by adherence to the mixing kettle, as often occurs in the well known shock-precipitation method of producing molding powders. The present process eliminates a quality control problem, enhances reliability in regard to those features which are affected by homogeneity, and eliminates a potential safety hazard caused by free oxidizer.
This process contrasts with the old, but frequently used process for compounding propellant powders which involves preparing a solution of the soluble binder material, suspending the solid components in the solution, and precipitating the binder by quenching with a nonsolvent. The agglomerated mixture of ingreclients is separated from the supernatant liquids, and then dried, and sometimes screened. Although this is often called a coating process, it is in fact a simple agglomeration with solid particles randomly and mechanically held in a matrix of binder material. Often by this process, old in the art, ammonium perchlorate, the most widely used oxidizer, dissolves or recrystallizes in polar solvents which contain water resulting in changes in oxidizer particle size distribution in the final product.
In the present invention with the rubber based propellant formulations Teflon is used as a reinforcing agent. Teflon will, during a shearing procedure, coalesce and cold draw into fibers. Thus, with the Teflon powder-rubber mixture, the conventional extrusion procedure results in the formation of reinforcing fibers in situ. All the fibers are never really completely straight, for there is a certain amount of sideways drift of particles during extrusion. Teflon content as low as /q% effectively improves the tensile strength and elongation of propellants containing it. The strength increases as the Teflon content is increased.
Several hundred measurements have been made on 0.125-inch diameter strands of the extruded mixedbinder (i.e., Teflon/rubber) propellants. The tensile strengths were generally in the range 300 to 800 psi and the percent elongations in the range of 20 to 35%.
In general the burning rates of these propellants measured with 0.125-inch diameter strands are about 0.5 in/sec at 1000 psi and ambient temperature. Slopes vary from 0.45 to 0.70 with butyl rubber, and from 0.6 to 0.8 with ethylene propylene rubber.
The following examples in Table l below present motor firing data for the mixed binder extruded propellants formulated as follows:
TABLE l (ominucd 'Iheorctical 4 Measured Propcllant Formulation 1 Density 1... Density Efficiency Ex. Ingredients Wt. sec lb/in" sec lb/in-' 4 Butyl rubber 7 242.0 0.066 227.0 0.065 93.8
Teflon 16 Ammonium perchlorate 77 Strand burning rates at 77 F. and 1,000 psi of three of the present new formulations are given below:
TABLE 11 Propellant Composition Rate Slope by weight) (in/sec) A rate/ A pressure Butvl Teflon Al AP 8.0 .0 19.0 70.0 0.48 0.49 Ethylenepropylene In Table III hereinbelow the theoretical performance is given of a number of propellants prepared as herein disclosed:
TABLE III THEORETlCAL PERFORMANCE OF NEW PROPELLANTS Composition, Ballistics Butyl Teflon A1 AP 1,, p p1 Chamber Temp, F
12 0 88 248 1.72 427 4,813 12 0 2 86 251 1.73 433 4,928 12 0 8 80 258 1.75 452 5,269 12 0 1O 78 260 1.76 458 5,376 12 73 256 1.77 454 5,197 10 0 0 90 252 1.75 442 4,968 10 5 2 83 251 1.77 444 5,026 10 5 4 81 253 1.78 450 5,150 10 0 6 84 258 1.78 460 5,381 10 5 6 79 255 1.79 456 5,268 10 5 10 75 259 1.80 467 5,490 10 3 72 263 1.83 480 5,796 10 3 17 70 264 1.84 484 5.880 9 3 15 73 263 1.85 485 5,915 9 4 17 70 263 1.86 488 5,975 9 3 19 69 264 1.87 493 6,084 9 4 67 264 1.87 494 6,079 8 15 0 77 243 1.82 441 4,857 8 5 2 85 253 1.81 457 5,097 8 10 2 80 ,250 1.82 454 5,072 8 5 4 83 255 1.82 463 5,270 8 5 6 81 257 1.83 469 5,422 8 4 15 73 262 1.87 489 5,992 8 4 17 71 263 1.88 493 6.088 8 3 17 72 263 1.88 493 6,113 8 3 19 70 264 1.89 497 6,202 8 2 2O 70 264 1.89 499 6,271 8 4 20 68 264 1.89 499 6,208 7 5 15 73 261 1.90 497 6,055 7 6 17 70 261 1.90 497 6,137 7 15 19 59 257 1.93 496 5,888 6 15 2 77 248 1.86 462 5,033 6 1O 6 78 254 1.87 476 5,405 6 7 17 70 261 1.93 501 6,201 5 7 17 71 259 1.95 505 6,262
from the group consisting of cuprous oxide, cupric 0x ide, copper chromate and ferric oxide were used. The
following is a typical example:
Percent by weight Copper chromate 3 Butyl rubber was mixed into the solvent, petroleum ether, to which Teflon, aluminum and ammonium perchlorate crystals (in a ratio of 1:1 as received, 190a average diameter, and ground 8y. average diameter) were blended to form a paste. The paste was extruded into burning rate strands from which the following data was derived: burning rate, 0.98 in/sec, slope A rate/A pressure 0.53.
Butyl rubber used herein is a synthetic rubber produced by polymerizing isobutylene or alternatively by copolymerization of isobutylene (approximately 98%) with a small proportion (2%) of conjugated diene, for instance isoprene or butadiene, and is identified more specifically as isobutylene-isoprene rubber (HR). The ethylene-propylene rubber (EPR) is an elastomer made by the steriospecific copolymerization of ethylene and propylene and alternatively a small percent, 2 5%, of a conjugated diene is added to provide curing sites.
What is claimed is:
l. A propellant molding powder comprising:
from about to percent by weight inorganic oxidizer; up to about 20 percent by weight polytetrafluoroethylene; and 5 from about 5 to about 15 percent by weight of a synthetic rubber selected from the group consisting of butyl rubber, ethylene propylene rubber and mixtures thereof.
2. The powder in accordance with claim 1 wherein the oxidizer is ammonium perchlorate.
3. The powder in accordance with claim 1 containing additionally up to about 20 percent by weight metallic fuel.
4. The powder in accordance with claim 3 containing additionally up to about 3 percent burning rate moditier.
5. The powder in accordance with claim 3 wherein the fuel is aluminum.
6. The powder in accordance with claim 5 wherein the oxidizer is ammonium perchlorate.
7. The powder in accordance with claim 4 wherein the oxidizer is ammonium perchlorate, the fuel is aluminum and the burning rate modifier is copper chromate.
Claims (7)
1. A PROPELLANT MOLDING POWDER COMPRISING: FROM ABOUT 70 TO 90 PERCENT BY WEIGHT INORGANIC OXIDIZER; UP TO ABOUT 20 PERCENT BY WEIGHT POLYTETRAFLHOROETHYLENE; AND FROM ABOUT 5 TO ABOUT 15 PERCENT BY WEIGHT OF A SYNTHETIC RUBBER SELECTED FROM THE GROUP CONSISTING OF BUTYL RUBBER, ETHYLENE PROPGLENE RUBBER AND MIXTURES THEREOFF.
2. The powder in accordance with claim 1 wherein the oxidizer is ammonium perchlorate.
3. The powder in accordance with claim 1 containing additionally up to about 20 percent by weight metallic fuel.
4. The powder in accordance with claim 3 containing additionally up to about 3 percent burning rate modifier.
5. The powder in accordance with claim 3 wherein the fuel is aluminum.
6. The powder in accordance with claim 5 wherein the oxidizer is ammonium perchlorate.
7. The powder in accordance with claim 4 wherein the oxidizer is ammonium perchlorate, the fuel is aluminum and the burning rate modifier is copper chromate.
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US00090210A US3853645A (en) | 1970-10-30 | 1970-10-30 | Composite propellant containing polytetrafluoroethylene powder and butyl or ethylene-propylene rubber |
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US00090210A US3853645A (en) | 1970-10-30 | 1970-10-30 | Composite propellant containing polytetrafluoroethylene powder and butyl or ethylene-propylene rubber |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3981756A (en) * | 1975-09-09 | 1976-09-21 | The United States Of America As Represented By The Secretary Of The Navy | Process for preparing high density solid propellants |
US4001135A (en) * | 1974-12-30 | 1977-01-04 | The United States Of America As Represented By The Secretary Of The Air Force | Fluorine generating solid formulation for use in chemical lasers |
WO1994017014A1 (en) * | 1991-12-06 | 1994-08-04 | E.I. Du Pont De Nemours And Company | Fibrillatable ptfe in plastic-bonded explosives |
WO1997030954A1 (en) * | 1996-02-22 | 1997-08-28 | John Douglas Michael Wraige | Energetic compositions |
US6132536A (en) * | 1997-08-20 | 2000-10-17 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Automated propellant blending |
US6427599B1 (en) | 1997-08-29 | 2002-08-06 | Bae Systems Integrated Defense Solutions Inc. | Pyrotechnic compositions and uses therefore |
US7363861B2 (en) | 2004-08-13 | 2008-04-29 | Armtec Defense Products Co. | Pyrotechnic systems and associated methods |
US7913625B2 (en) | 2006-04-07 | 2011-03-29 | Armtec Defense Products Co. | Ammunition assembly with alternate load path |
US8146502B2 (en) | 2006-01-06 | 2012-04-03 | Armtec Defense Products Co. | Combustible cartridge cased ammunition assembly |
CN104849312A (en) * | 2015-06-04 | 2015-08-19 | 西安近代化学研究所 | Standard substance for calibrating pressure of thermal explosion system |
RU2637330C1 (en) * | 2016-07-07 | 2017-12-04 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ КАЗЕННОЕ ВОЕННОЕ ОБРАЗОВАТЕЛЬНОЕ УЧРЕЖДЕНИЕ ВЫСШЕГО ОБРАЗОВАНИЯ "Военная академия Ракетных войск стратегического назначения имени Петра Великого" МИНИСТЕРСТВА ОБОРОНЫ РОССИЙСКОЙ ФЕДЕРАЦИИ | Method for preparing colloid paste |
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US3257802A (en) * | 1964-03-13 | 1966-06-28 | Martin H Kaufman | Method of hybrid high specific impulse propulsion using lithium-polyethylene solid with chlorine containing oxidizers |
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US3476622A (en) * | 1966-12-20 | 1969-11-04 | Asahi Chemical Ind | Carboxy-terminated composite rocket propellant and process for producing using an amide additive |
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US3577289A (en) * | 1968-02-12 | 1971-05-04 | Jacque C Morrell | Composite high energy solid rocket propellants and process for same |
US3586552A (en) * | 1968-05-23 | 1971-06-22 | Union Carbide Corp | Propellant composition having a curable ethylene interpolymer binder |
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- 1970-10-30 US US00090210A patent/US3853645A/en not_active Expired - Lifetime
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US3513043A (en) * | 1958-11-04 | 1970-05-19 | Phillips Petroleum Co | Composite solid propellants containing a perfluoroethylene resin,metal and a fluoroelastomer |
US3395055A (en) * | 1959-03-26 | 1968-07-30 | Exxon Research Engineering Co | Method of making a hybrid liquid-solid propellant system with encapsulated oxidizingagent and metallic fuel |
US3377955A (en) * | 1961-06-07 | 1968-04-16 | Solid Fuels Corp | Coated tablets and other fuel cores of exotic reactive fuels and method of making same |
US3257802A (en) * | 1964-03-13 | 1966-06-28 | Martin H Kaufman | Method of hybrid high specific impulse propulsion using lithium-polyethylene solid with chlorine containing oxidizers |
US3476622A (en) * | 1966-12-20 | 1969-11-04 | Asahi Chemical Ind | Carboxy-terminated composite rocket propellant and process for producing using an amide additive |
US3577289A (en) * | 1968-02-12 | 1971-05-04 | Jacque C Morrell | Composite high energy solid rocket propellants and process for same |
US3586552A (en) * | 1968-05-23 | 1971-06-22 | Union Carbide Corp | Propellant composition having a curable ethylene interpolymer binder |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4001135A (en) * | 1974-12-30 | 1977-01-04 | The United States Of America As Represented By The Secretary Of The Air Force | Fluorine generating solid formulation for use in chemical lasers |
US3981756A (en) * | 1975-09-09 | 1976-09-21 | The United States Of America As Represented By The Secretary Of The Navy | Process for preparing high density solid propellants |
WO1994017014A1 (en) * | 1991-12-06 | 1994-08-04 | E.I. Du Pont De Nemours And Company | Fibrillatable ptfe in plastic-bonded explosives |
WO1997030954A1 (en) * | 1996-02-22 | 1997-08-28 | John Douglas Michael Wraige | Energetic compositions |
US6132536A (en) * | 1997-08-20 | 2000-10-17 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Automated propellant blending |
US6427599B1 (en) | 1997-08-29 | 2002-08-06 | Bae Systems Integrated Defense Solutions Inc. | Pyrotechnic compositions and uses therefore |
US7363861B2 (en) | 2004-08-13 | 2008-04-29 | Armtec Defense Products Co. | Pyrotechnic systems and associated methods |
US8146502B2 (en) | 2006-01-06 | 2012-04-03 | Armtec Defense Products Co. | Combustible cartridge cased ammunition assembly |
US8807038B1 (en) | 2006-01-06 | 2014-08-19 | Armtec Defense Products Co. | Combustible cartridge cased ammunition assembly |
US7913625B2 (en) | 2006-04-07 | 2011-03-29 | Armtec Defense Products Co. | Ammunition assembly with alternate load path |
US8136451B2 (en) | 2006-04-07 | 2012-03-20 | Armtec Defense Products Co. | Ammunition assembly with alternate load path |
US20120291652A1 (en) * | 2006-04-07 | 2012-11-22 | Armtec Defense Products Co. | Ammunition assembly with alternate load path |
US8430033B2 (en) * | 2006-04-07 | 2013-04-30 | Armtec Defense Products Co. | Ammunition assembly with alternate load path |
CN104849312A (en) * | 2015-06-04 | 2015-08-19 | 西安近代化学研究所 | Standard substance for calibrating pressure of thermal explosion system |
RU2637330C1 (en) * | 2016-07-07 | 2017-12-04 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ КАЗЕННОЕ ВОЕННОЕ ОБРАЗОВАТЕЛЬНОЕ УЧРЕЖДЕНИЕ ВЫСШЕГО ОБРАЗОВАНИЯ "Военная академия Ракетных войск стратегического назначения имени Петра Великого" МИНИСТЕРСТВА ОБОРОНЫ РОССИЙСКОЙ ФЕДЕРАЦИИ | Method for preparing colloid paste |
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