US3849135A - Etch-bleaching treatment of exposed and developed photo plates and films - Google Patents

Etch-bleaching treatment of exposed and developed photo plates and films Download PDF

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US3849135A
US3849135A US00308112A US30811272A US3849135A US 3849135 A US3849135 A US 3849135A US 00308112 A US00308112 A US 00308112A US 30811272 A US30811272 A US 30811272A US 3849135 A US3849135 A US 3849135A
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photo
etch
article
bleaching
ultrasonic
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US00308112A
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J Karlikowski
H Michel
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Siemens AG
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Siemens AG
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
    • G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
    • G03C5/40—Chemically transforming developed images
    • G03C5/44—Bleaching; Bleach-fixing
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
    • G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
    • G03C5/40—Chemically transforming developed images
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/06—Silver salts

Definitions

  • the present invention is concerned with the etch- This invention relates to a methgd f r h h- 5 bleaching treatment of photo plates, films and the like.
  • the etch- 1 bleaching treatment provides for the bleaching of the silver images on the photo plates and films, and for the selective decomposition of the binding agents in the exposed areas of the photo plates and films.
  • the gelatin particles which are supposed to be removed during the process are not removed completely. Because of this, other means such as mechanical means are required to completely remove the gelatin particles from the treated photo plate or film.
  • the partially dissolved and unremoved gelatin particles are wiped away with asoft cloth. This procedure, although removing the gelatin particles provides undesired and different results than those required. That is, the removal of the gelatin may be uneven and not completely clean.
  • an etch-bleaching solution which is supposed to remove even the hardened gelatin from photo plates and films in a short period of time.
  • this etch-bleaching solution there is provided 1.1 mol of copper cupric cations per liter of solution and anions which form an insoluble silver salt.
  • the gelatin particles are not removed completely from the photo plates without applying additional mechanical means, e.g. wiping the gelatin particles off with a soft cloth.
  • an improved method for the etch-bleaching treatment of exposed and developed photo plates and films.
  • the method provides a means for completely removing the gelatin particles from photo plates and/or films during the etch-bleaching thereof.
  • the method comprises immersing the photo article in an etchbleaching solution containing copper cations, and applying an ultrasonic sound to the immersed photo article from an ultrasonic source for a sufficient period of time to completely remove the gelatin particles therefrom.
  • a more particular object of the present invention is to provide a method of etch-bleaching photo plates and/or films wherein the gelatin particles are completely removed from the treated photo article.
  • the silver images of the photo article are bleached and the binding agents remaining in the exposed areas of the photo article are selectively decomposed. Also, the partially decomposed gelatin particles of the treated photo article need to be removed and cleaned therefrom in order to provide a satisfactory and functionary photo plate or film.
  • the present method is primarily concerned with a means and method of removing completely the gelatin particles from photo plates and/or films during the etch-bleaching treatment thereof.
  • a photo plate or film is etch bleached by first being immersed into an etch-bleaching solution and then applying an ultrasonic sound to the immersed photo article for a sufficient period of time to completely remove the partially dissolved gelatin particles from the treated photo article.
  • the photo article being treated i.e. etch-bleached, such as a photo plate or film is initially suspended vertically within a suitable etch-bleaching solution.
  • an ultrasonic sound source which may be movably mounted in the etchbleaching bath, is moved back and forth in a reciprocating manner in a path which is parallel to the surface of the photo article being treated.
  • the etch-bleaching solution that can be used according to the present invention includes a mixture of cop per chloride, a mild acid, water and hydrogen peroxide.
  • the mild acid may be glacial acetic acid or citric acid.
  • the copper chloride may be a cupric copper solution.
  • the copper chloride may also be replaced with copper sulfate and/or sodium bromide.
  • the source for the ultrasonic or high frequency sound may be any conventional apparatus or device 'known in the art. According to the present invention,
  • the ultrasonic source is not firmly placed or mounted in front of the photo article.
  • the ultrasonic source is preferably arranged in the etchbleaching path to move in a path which is parallel to the surface of the photo plate or film being treated.
  • EXAMPLE 1 A photo plate was exposed in a conventional manner. Thereafter, the exposed photo plate was developed in a suitable liquid and then watered for approximately one minute and carefully flushed. An etch-bleaching solution was provided in a suitable bath. The solution consisted of a mixture of two parts:
  • an ultrasonic source was submerged in the solution.
  • the ultrasonic source was moved back and forth in a path parallel to the surface of the vertically suspended photo plate.
  • the photo plate was rotated 180 degrees and was treated with ultrasonic sound waves on its opposite side.
  • the ultrasonic etch-bleaching treatment lasted for a period of 8 minutes.
  • the photo plate was watered, developed a second time and once again watered for one or two minutes.
  • the photo plate was once more watered for a period of twenty to thirty seconds.
  • the photo plate was then dried for a period of about thirty minutes.
  • the etch-bleaching treatment with the ultrasonic sound being applied to the photo plate was done with red lighting and the subsequent steps in ordinary daylight.
  • gelatin particles were completely removed from the etch-bleach treated photo plate.
  • EXAMPLE 2 A similar photo plate was developed as in Example 1 and was treated in the same manner as in Example 1, except that the etch-bleaching solution included a Part A which instead of that provided in Example 1, consisted of:
  • Part A 5160 gms copper sulfate 2700 gms citric acid 135 gms sodium bromide l8 liters water (H O) This part A was mixed with a Part B consisting of 800 ccm of hydrogen peroxide (H a short period of time before it was used as the etch-bleaching bath for the photo plate. The photo plate was treated and washed in the same manner as set forth in Example 1.
  • the treatment resulted in completely removing the gelatin particles from the photo plate.
  • the present invention provides an improved means for etch-bleaching photo plate and films with the advantage that the gelatin particles are completely removed from the photo plate and/or film without the application of any additional mechanical means.
  • a method of physically removing gelatin particles during etch-bleaching of exposed and developed photo-plates, films and the like utilizing gelatin emulsions comprising:
  • an ultrasonic sound for at least a period of minutes to the immersed photo article from an ultrasonic source to apply mechanical force to the gelatin particles of the photo article, whereby and subsequently washing the photo article, preferably with a period of applied ultrasonic sound, such particles are thereby physically removed completely therefrom.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • ing And Chemical Polishing (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)

Abstract

This invention provides a method for the etch-bleaching treatment of exposed and developed photo plates, films and the like. The method comprises the immersing of the developed photo article in an etch-bleaching solution and applying an ultrasonic sound to the immersed article from an ultrasonic source, whereby the gelatin particles of the photo article are completely removed therefrom.

Description

United States Patent [191 Karlikowslki et al.
ETCH-BLEACHING TREATMENT OF EXPOSED AND DEVELOPED PHOTO PLATES AND FILMS Inventors: Jupp Karlikowski, Eurasburg; Hans Michel, Munich, both of Germany Siemens Aktiengesellschaft, Berlin and Munich, Germany Filed: Nov. 20, 1972 Appl. No.: 308,112
Assignee:
Foreign Application Priority Data Dec. 10, 1971 Germany 2161407 US. Cl. 96/36, 156/5 Int. Cl G03c 5/00 Field of Search 96/36, 36.2; 156/5; 134/1 References Cited UNITED STATES PATENTS 9/1958 Lyman et al 96/36 Primary Examiner-David Klein Attorney, Agent, or Firm-Hill, Gross, Simpson, Van Santen, Steadman, Chiara & Simpson 5 7] ABSTRACT This invention provides a method for the etchbleaching treatment of exposed and developed photo plates, films and the like. The method comprises the immersing of the developed photo article in an etchbleaching solution and applying an ultrasonic sound to the immersed article from an ultrasonic source,
whereby the gelatin particles of the photo article are completely removed therefrom.
6 Claims, N0 Drawings BACKGROUND OF THE INVENTION DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention is concerned with the etch- This invention relates to a methgd f r h h- 5 bleaching treatment of photo plates, films and the like.
bleaching treatment of exposed and developed photo plates, films and the like.
There are several known processes of etch-bleaching photo plates, films and the like. Generally, the etch- 1 bleaching treatment provides for the bleaching of the silver images on the photo plates and films, and for the selective decomposition of the binding agents in the exposed areas of the photo plates and films. However, it is common in the known etch-bleaching processes that the gelatin particles which are supposed to be removed during the process, are not removed completely. Because of this, other means such as mechanical means are required to completely remove the gelatin particles from the treated photo plate or film. Usually, the partially dissolved and unremoved gelatin particles are wiped away with asoft cloth. This procedure, although removing the gelatin particles provides undesired and different results than those required. That is, the removal of the gelatin may be uneven and not completely clean.
In one process of etch-bleaching photo plates and films, there is provided an etch-bleaching solution which is supposed to remove even the hardened gelatin from photo plates and films in a short period of time. In this etch-bleaching solution, there is provided 1.1 mol of copper cupric cations per liter of solution and anions which form an insoluble silver salt. However, even with this etch-bleaching solution, the gelatin particles are not removed completely from the photo plates without applying additional mechanical means, e.g. wiping the gelatin particles off with a soft cloth.
SUMMARY OF THE INVENTION In view of the disadvantages of the prior art and in accordance with the principles of the present invention an improved method is provided for the etch-bleaching treatment of exposed and developed photo plates and films. The method provides a means for completely removing the gelatin particles from photo plates and/or films during the etch-bleaching thereof. The method comprises immersing the photo article in an etchbleaching solution containing copper cations, and applying an ultrasonic sound to the immersed photo article from an ultrasonic source for a sufficient period of time to completely remove the gelatin particles therefrom.
Therefore, it is an object of the present invention to provide an improved method for etch-bleaching photo plates, films and the like.
A more particular object of the present invention is to provide a method of etch-bleaching photo plates and/or films wherein the gelatin particles are completely removed from the treated photo article.
Other objects, features and advantages of the invention will be readily apparent from the following description of the preferred embodiments thereof, although variations and modifications may be effected without departing from the spirit and scope of the novel concepts of the disclosure.
In the etch-bleaching treatment of exposed and developed photo plates and films, the silver images of the photo article are bleached and the binding agents remaining in the exposed areas of the photo article are selectively decomposed. Also, the partially decomposed gelatin particles of the treated photo article need to be removed and cleaned therefrom in order to provide a satisfactory and functionary photo plate or film.
The present method is primarily concerned with a means and method of removing completely the gelatin particles from photo plates and/or films during the etch-bleaching treatment thereof.
According to the present invention a photo plate or film is etch bleached by first being immersed into an etch-bleaching solution and then applying an ultrasonic sound to the immersed photo article for a sufficient period of time to completely remove the partially dissolved gelatin particles from the treated photo article. Generally, in the present process, the photo article being treated, i.e. etch-bleached, such as a photo plate or film is initially suspended vertically within a suitable etch-bleaching solution. Then, an ultrasonic sound source which may be movably mounted in the etchbleaching bath, is moved back and forth in a reciprocating manner in a path which is parallel to the surface of the photo article being treated. By this procedure, it has been found that the gelatin particles of a photo plate or film are completely removed therefrom during the etch-bleaching treatment.
The etch-bleaching solution that can be used according to the present invention, includes a mixture of cop per chloride, a mild acid, water and hydrogen peroxide. The mild acid may be glacial acetic acid or citric acid. The copper chloride may be a cupric copper solution. The copper chloride may also be replaced with copper sulfate and/or sodium bromide.
The source for the ultrasonic or high frequency sound may be any conventional apparatus or device 'known in the art. According to the present invention,
it is preferred that the ultrasonic source is not firmly placed or mounted in front of the photo article. The ultrasonic source is preferably arranged in the etchbleaching path to move in a path which is parallel to the surface of the photo plate or film being treated.
The following examples will further illustrate the advantages of the etch-bleaching process of the present invention.
EXAMPLE 1 A photo plate was exposed in a conventional manner. Thereafter, the exposed photo plate was developed in a suitable liquid and then watered for approximately one minute and carefully flushed. An etch-bleaching solution was provided in a suitable bath. The solution consisted of a mixture of two parts:
Part A 200 gms. copper chloride I000 ccm glacial acetic acid l8 liters water (IMO);
-Continued Part B 1800 ccm hydrogen peroxide (H202).
The parts, A and B, were mixed shortly before they were placed in the bath. After the photo plate was suspended vertically in the etch-bleaching solution, an ultrasonic source was submerged in the solution. The ultrasonic source was moved back and forth in a path parallel to the surface of the vertically suspended photo plate. After a sufficient period of time, the photo plate was rotated 180 degrees and was treated with ultrasonic sound waves on its opposite side. The ultrasonic etch-bleaching treatment lasted for a period of 8 minutes. Thereafter, the photo plate was watered, developed a second time and once again watered for one or two minutes. Finally, while the ultrasonic sound was applied to it, the photo plate was once more watered for a period of twenty to thirty seconds. The photo plate was then dried for a period of about thirty minutes.
The etch-bleaching treatment with the ultrasonic sound being applied to the photo plate was done with red lighting and the subsequent steps in ordinary daylight.
The gelatin particles were completely removed from the etch-bleach treated photo plate.
EXAMPLE 2 A similar photo plate was developed as in Example 1 and was treated in the same manner as in Example 1, except that the etch-bleaching solution included a Part A which instead of that provided in Example 1, consisted of:
Part A 5160 gms copper sulfate 2700 gms citric acid 135 gms sodium bromide l8 liters water (H O) This part A was mixed with a Part B consisting of 800 ccm of hydrogen peroxide (H a short period of time before it was used as the etch-bleaching bath for the photo plate. The photo plate was treated and washed in the same manner as set forth in Example 1.
The treatment resulted in completely removing the gelatin particles from the photo plate.
From the above it is apparent that the present invention provides an improved means for etch-bleaching photo plate and films with the advantage that the gelatin particles are completely removed from the photo plate and/or film without the application of any additional mechanical means.
Although minor modifications might be suggested by those versed in the art, it should be understood that we wish to embody within the scope of the patent warranted hereon all such modifications as might reasonably and properly come within the scope of our contribution to the art as defined in the appended claims.
We claim as our invention:
1. A method of physically removing gelatin particles during etch-bleaching of exposed and developed photo-plates, films and the like utilizing gelatin emulsions, said method comprising:
immersing the developed photo article in an etchbleaching solution; and
applying an ultrasonic sound, for at least a period of minutes to the immersed photo article from an ultrasonic source to apply mechanical force to the gelatin particles of the photo article, whereby and subsequently washing the photo article, preferably with a period of applied ultrasonic sound, such particles are thereby physically removed completely therefrom.
2. The method of claim 1, wherein the ultrasonic source is moved in a path parallel to the surface of said photo article.
3. The method of claim 2, wherein the ultrasonic source is moved in a reciprocating manner in said parallel path.
4. The method of claim 1, wherein the ultrasonic sound is applied for a period of about eight minutes.
5. The method of claim 1, wherein there are several ultrasonic sources applying sounds to the photo article in said etch-bleaching solution.
6. The method of claim 1, wherein said etchbleaching solution includes copper cations.

Claims (6)

1. A METHOD OF PHYSICALLY REMOVING GELATIN PARTICLES DURING ETCH-BLEACHING OF EXPOSED AND DEVELOPED PHOTO-PLATES, FILMS AND THE LIKE UTILIZING GELATIN EMULSIONS, SAID METHOD COMPRISING: IMMERSING THE DEVELOPED PHOTO ARTICLE IN AN ETCH-BLEACHING SOLUTION; AND APPLYING AN ULTRASONIC SOUND, FOR AT LEAST A PERIOD OF MINUTES TO THE IMMERSED PHOTO ARTICLE FROM AN ULTRASONIC SOURCE TO APPLY MECHANICAL FORCE TO THE GELATIN PARTICLES OF THE PHOTO ARTICLE, WHEREBY AND SUBSEQUENTLY WASHING THE PHOTO ARTICLE, PREFERABLY WITH A PERIOD OF APPLIED ULTRASONIC SOUND, SUCH PARTICLES ARE THEREBY PHYSICALLY REMOVED COMPLETELY THEREFROM.
2. The method of claim 1, wherein the ultrasonic source is moved in a path parallel to the surface of said photo article.
3. The method of claim 2, wherein the ultrasonic source is moved in a reciprocating manner in said parallel path.
4. The method of claim 1, wherein the ultrasonic sound is applied for a period of about eight minutes.
5. The method of claim 1, wherein there are several ultrasonic sources applying sounds to the photo article in said etch-bleaching solution.
6. The method of claim 1, wherein said etch-bleaching solution includes copper cations.
US00308112A 1971-12-10 1972-11-20 Etch-bleaching treatment of exposed and developed photo plates and films Expired - Lifetime US3849135A (en)

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DE2161407A DE2161407C3 (en) 1971-12-10 1971-12-10 Process for the bleaching treatment of exposed and developed photographic plates and films

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BE (1) BE792499A (en)
DE (1) DE2161407C3 (en)
FR (1) FR2162542B1 (en)
GB (1) GB1366816A (en)
IT (1) IT971384B (en)
LU (1) LU66615A1 (en)
NL (1) NL176980C (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4056395A (en) * 1974-11-19 1977-11-01 Fuji Photo Film Co., Ltd. Method for producing a relief pattern by ion-etching a photographic support
US4110114A (en) * 1974-10-11 1978-08-29 Fuji Photo Film Co., Ltd. Image forming method
US4207105A (en) * 1975-01-27 1980-06-10 Fuji Photo Film Co., Ltd. Plasma-etching image in exposed AgX emulsion
US4284713A (en) * 1975-03-14 1981-08-18 Fuji Photo Film Co., Ltd. Image forming method
US4447510A (en) * 1981-05-13 1984-05-08 Hoechst Aktiengesellschaft Process for producing relief copies in light hardenable materials with ultrasonic treatment
US4517267A (en) * 1983-01-13 1985-05-14 Archival Color Technologies Processing machine for printing
US4555302A (en) * 1984-08-24 1985-11-26 Urbanik John C Method and apparatus for ultrasonic etching of printing plates
US20180020551A1 (en) * 2014-11-28 2018-01-18 Zeon Corporation Desmear processing method and manufacturing method for multilayer printed wiring board

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2854386A (en) * 1955-02-07 1958-09-30 Aladdin Ind Inc Method of photographically printing conductive metallic patterns
US3489624A (en) * 1965-03-31 1970-01-13 Westinghouse Canada Ltd Etching techniques for glass
US3542550A (en) * 1966-09-30 1970-11-24 Ibm Photosensitive glass technique for forming contact holes in protective glass layers
US3661660A (en) * 1968-02-21 1972-05-09 Grace W R & Co Method for ultrasonic etching of polymeric printing plates

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2854386A (en) * 1955-02-07 1958-09-30 Aladdin Ind Inc Method of photographically printing conductive metallic patterns
US3489624A (en) * 1965-03-31 1970-01-13 Westinghouse Canada Ltd Etching techniques for glass
US3542550A (en) * 1966-09-30 1970-11-24 Ibm Photosensitive glass technique for forming contact holes in protective glass layers
US3661660A (en) * 1968-02-21 1972-05-09 Grace W R & Co Method for ultrasonic etching of polymeric printing plates

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4110114A (en) * 1974-10-11 1978-08-29 Fuji Photo Film Co., Ltd. Image forming method
US4056395A (en) * 1974-11-19 1977-11-01 Fuji Photo Film Co., Ltd. Method for producing a relief pattern by ion-etching a photographic support
US4207105A (en) * 1975-01-27 1980-06-10 Fuji Photo Film Co., Ltd. Plasma-etching image in exposed AgX emulsion
US4284713A (en) * 1975-03-14 1981-08-18 Fuji Photo Film Co., Ltd. Image forming method
US4447510A (en) * 1981-05-13 1984-05-08 Hoechst Aktiengesellschaft Process for producing relief copies in light hardenable materials with ultrasonic treatment
US4517267A (en) * 1983-01-13 1985-05-14 Archival Color Technologies Processing machine for printing
US4555302A (en) * 1984-08-24 1985-11-26 Urbanik John C Method and apparatus for ultrasonic etching of printing plates
US20180020551A1 (en) * 2014-11-28 2018-01-18 Zeon Corporation Desmear processing method and manufacturing method for multilayer printed wiring board

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Publication number Publication date
LU66615A1 (en) 1973-02-08
GB1366816A (en) 1974-09-11
BE792499A (en) 1973-03-30
DE2161407B2 (en) 1979-09-13
DE2161407C3 (en) 1980-05-22
IT971384B (en) 1974-04-30
FR2162542B1 (en) 1977-12-23
DE2161407A1 (en) 1973-06-20
FR2162542A1 (en) 1973-07-20
NL176980C (en) 1985-07-01
NL7209443A (en) 1973-06-13

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