US3834529A - Device and method of density measurement and control of flotation systems - Google Patents

Device and method of density measurement and control of flotation systems Download PDF

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US3834529A
US3834529A US00219221A US21922172A US3834529A US 3834529 A US3834529 A US 3834529A US 00219221 A US00219221 A US 00219221A US 21922172 A US21922172 A US 21922172A US 3834529 A US3834529 A US 3834529A
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density
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ore
flotation
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P Hart
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Dow Chemical Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B13/00—Control arrangements specially adapted for wet-separating apparatus or for dressing plant, using physical effects
    • B03B13/005—Methods or arrangements for controlling the physical properties of heavy media, e.g. density, concentration or viscosity

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  • ABSTRACT Two open-end tubes are vertically immersed, openend down at substantially the same level, one near the place of entrance of a liquid in process in a series of treating vessels and the other near the outlet of the liquid whereby densities of the liquid at the respective locations are measured by means of a suitable pneumatic assembly, the density values are translated to and recorded as a pneumatic pressure differential and the pneumatic pressure differential is either (1) automatically converted to and recorded in meaningful values and the indicated adjustments manually made to restore and tend to maintain the optimum density differential, or (2) directed to an optimizer whereby optimum adjustments are automatically made to restore and tend to maintain a maximum density differential. Where a fluctuating level of liquid exists, two probes immersed at different depths to define a fixed stratum may be used in cooperation to obtain one density value.
  • Illustrative of the latter are ore flotation systems wherein a mineral is separated by passing an aqueous slurry of finely ground ore containing conditioning agents through a series of open-top chambers or vessels (usually called cells), psitioned substantially horizontally to each other, each provided with an upwardly directed air supply and troughs or trays along the upper edges thereof to collect and drain away the desired mineral which is frothed off, sometimes aided by additional water supplied to the collection system, and usually thereafter thickened and dried.
  • aqueous slurry of finely ground ore containing conditioning agents through a series of open-top chambers or vessels (usually called cells), psitioned substantially horizontally to each other, each provided with an upwardly directed air supply and troughs or trays along the upper edges thereof to collect and drain away the desired mineral which is frothed off, sometimes aided by additional water supplied to the collection system, and usually thereafter thickened and dried.
  • fluorite which term will herein be used interchangeably with substantially pure
  • the efficiency of the system is indicated by the difference in density of the slurry in the successive cells and particularly between the first and last cells of a series. In general, the greater the difference in density, the more of the desired heavier mineral is being floated off.
  • the invention fulfills this need to a most gratifying extent.
  • the invention is a method of continuously measuring density, and particularly the concurrent measurement of density values at two stages of progress in a liquid system to ascertain the density differential, and the apparatus necessary for performing such method.
  • the preferred mode of practicing the invention consists of a method and apparatus which measures such densities and density differential and promptly and automatically corrects the density differential to provide optimum conditions.
  • the invention is a method and apparatus which continuously measures the differential between density values, converts such values instantly to a pressure differential, optionally relates the density differential to a calibrated recording instrument, to guide manual changes if desired, and/or simultaneously makes proper changes in one or more components of the source material being introduced into the system, whereby the density differential is optimized to maintain maximum recovery of product of improved quality.
  • pH which strictly means only the reciprocal of the logarithm of the hydrogen ion concentration
  • electric potential produced in the slurry
  • the invention is an improvement in flotation processes generally, and apparatus necessary for the practice thereof.
  • conventional flotation applicable to the recovery of CaF product from fluorspar, is set out below.
  • Ore is pulverized, as by passing it through a rockcrusher, grizzly, or the like and then, after admixture with water to produce a slurry, some or all of the following treating agents are admixed therewith: a surface tension improving agent (known sometimes as a collector) to increase surface tension and to encourage bubble formation and stabilized froth, a suppressant to lessen the tendency of undesirable minerals present in the ore to rise in the froth, and an alkalinity-control agent to maintain desirable ionic potential in the slurry, and passing the so treated slurry in sequence: through a ball mill to reduce particle size; from the ball mill to a conditioning tank (conditioner) for thorough mixing and usually admixture of additional treating agents to attain a desired slurry composition for processing conditions; from the conditioner to a series of rougher cells wherein the slurry is agitated and into which are fed upwardly directed air to produce a mass of bubbles or froth, to which the desired mineral is attracted and adheres
  • the improvement, in broad terms, of the above conventional general procedure and equipment which is the instant invention comprises a method and means of continuous measurement of density differential of a mineral slurry at selected successive stages in a flotation system which differential is continuously recorded and serves as a basis for judicious adjustment of at least one component or condition of the process and provides for prompt adjustment thereof, e. g., a component of the feed composition in accordance with the density differential, to provide optimum recovery and improved quality of product.
  • This is attained inherently in the novel system by converting the density differential to a pressure differential which is transferred as a pneumatic impulse. This may be done by directing the impulse to a recording instrument which is observed and acted on.
  • the impulse preferably, however, is directed to an optimizer which automatically directly adjusts an ingredient in the feed to that proportion which results in the highest per cent recovery which is consistent with good quality.
  • This is a peak-seeking optimizer which continuously changes the selected ingredient to result in optimum density differential.
  • novel aspects and mode of operation of the improved process of the invention include cooperating mechanisms (the most critical of which are identified immediately below by small letters) for obtaining continuous density values converted to pressure differential employing (a) open-bottomed tubes (called hereafter density probes) positioned substantially vertically in the slurry at selected successive stages of the process, which connect at the top with tubing filled with dead air which terminate in (b) a two-chambered density cell, against a flexible diaphragm therein, which forms the density cells where, by density variations, the densities are converted to corresponding pressure variations in each chamber, called herein D and D respectively, for the selected stages.
  • density probes open-bottomed tubes
  • the differential between D, and D is either calculated and a pneumatic impulse sent to a recording meter for quick reading and manual adjustment made or an impulse is sent directly to (c) an optimizer which optimizer continuously seeks the greatest D,D or peak value possible and automatically relays this directly to a control which adjusts a component or condition so as to maintain the highest D,D value.
  • the pneumatic impulse from the density pressure cell may go both to the recording meter and to the optimizer whereby the potential difference in the slurry (which as aforesaid for practical purposes may be thought of as the pH value) is made of record but wherein the change is promptly made automatically by the peak-seeking optimizer.
  • an electric line or pneumatic conduit leads from the optimizer (or continues from the meter) to an electric motor which actuates the valves that control that component of the feed which must be changed to result in the desired optimum condition, viz. optimum electric potential in the slurry being processed which in turn maintains a large density differential which results in increased product recovery.
  • the optimizer is available from instrument specialists e.g., Model 571 Syncro Optimizer MS-27670l, as described and illustrated in Operating Instructions for said model published by Moore products Co., Spring House, Pennsylvania.
  • FIG. 1 shows the various parts of the assembled apparatus and the working relationship of a flotation system for carrying out the process of the invention.
  • FIG. 2 is a schematic view of an embodiment of the density measuring instrument of the invention wherein a fixed level is established between the lower ends of two cooperative probes which constitute one instrument to obtain a single reading. It is used where the surface level of the liquid under control fluctuates.
  • FIG. 3 is a schematic view of two instruments from which D and U and the differential thereof, of successive stages of a flotation operation, including the instrumentation referred to as (a) to (0) above, are shown.
  • FIG. 4 is a graph whereon the AD, i.e. D' -D' density differential as read on the recorder and guided by the optimizer, is curve (1) and as obtained manually is curve (2); and the pH values as established by automatic adjustment according to the invention is curve (3); and the pH values as taken manually are curve (4).
  • AD i.e. D' -D' density differential as read on the recorder and guided by the optimizer
  • FIGS. 5 and 6 are percent recovery values plotted against pH values of the slurry.
  • conduit is used for tube connections filled with air which effectuate desired changes by pneumatic impulses.
  • the word line refers to flow lines for liquids. Electric connections are referred to as wires or wiring.
  • Item 2 is a moving endless apron for conveying crushed ore from a mine or storage pile.
  • Item 3 supplies water (which need be neither deionized nor softened for use in the invention).
  • Line 4 supplies a suppressant, e.g., an aqueous solution of quebracho. Both 3 and 4 lead into line 5 which bifurcates, through control valves (a) and (b), into lines 6 and 7, respectively.
  • Tank 8 supplies an alkalinity control agent, e.g., an aqueous solution of soda ash, which connects with line 101.
  • Lines 6 and 10 supply water and conditioning agents to the ore as it enters, and line 7 as the ore leaves, ball mill 12 (i.e., a drum rotating on a substantially horizontal axis or inclined slightly towards the outlet end, and containing freely moving steel balls for grinding ore).
  • Item 13 is the outlet line from 12 which by means of pump (p) powered by motor (m) conveys slurry to 14 which is a cyclone separator of coarser and finer grind ore (in aqueous slurry containing the additives).
  • Item 16 is an outlet line for finer grind ore from 14 leading directly to further processing and line 18 is an outlet line for coarser grind ore from 14' leading back to 12 for regrinding.
  • Instrument 19 positioned in line 16 is a total ore volume measuring instrument which is connected by electric wire 20 to the first of two pens on recording instrument 21 which records hourly total ore volume thereon.
  • Line 16 terminates in conditioning tank 22 known as a conditioner for finely ground ore slurry from the ball mill, provided with a high speed agitator (A).
  • conditioning tank 22 known as a conditioner for finely ground ore slurry from the ball mill, provided with a high speed agitator (A).
  • electrodes T and S comprising electrode pair 24 made of erosion-resistant material (as described in co-pending application Ser. No.
  • Electrodes 24 are not essential to the practice of the invention but give an accurate slurry EMF (which for simplicity as indicated may be called pH value) at any time-and serve as an independent source of knowledge of the conditions of operation.
  • Feeding into 22 is a surface tension improver or col lector agent, e.g., oleic acid, by means of system 27.
  • a surface tension improver or col lector agent e.g., oleic acid
  • conditioner 22 there are shown a pair of cooperating vertical tubes 28, open at the bottom and containing air as shown in FIG. 2. They are, as shown on FIG. 2, immersed to different depths in the slurry, e.g., a difference in depth of about twenty to thirty inches between the open lower ends, thereby defining a fixed stratum or layer of slurry. upon which to calculate the slurry density.
  • conduits 29 and instrument 30 a pressure-density cell
  • conduit 31 This D value is conveyed through conduit 31 into three conduits, viz: 32, 33, 34: conduit 32 leads to computer 35 where the volume (V) value from meter 21 through conduit 36 is received and the calculation V X D, mass flow is made and the result sent by pneumatic signal through conduit 37 to a second pen on meter 21 for recording mass flow thereon.
  • Conduit 33 leads to computer 38 to provide the D, value to the computer.
  • Conduit 34 leads to a first pen on meter 39 which records the D value continuously.
  • Conduit 40 leads from meter 39 to valves (a) and (b): valve (a) provides automatic control of water containing quebracho into line 6 for entrance to ball mill 12 and valve (b) provides automatic control of water containing quebracho into line 7 as the slurry leaves ball mill 12. k
  • Line 41 leads conditioned ore from 22 to cell 01, the first of the series of rougher cells designated collectively item 42.
  • Density probe tube 44 (similar to the longer tube of 28 and described more fully hereinbelow), is submerged in cell C-l. Via air conduit 46.. the density D' of the slurry in cell C-l (converted to corresponding pressure) deflects a flexible diaphragm in accordance therewith, in two-chambered densitypressure instrument 48. Cell 06, the sixth.
  • Optimizer 56 continuously and automatically seeks the greatest density differential (D',D' since the greater differential in density indicates the greatest efficiency of the rougher cells.
  • An important condition for high recovery is the correct amount of alkalinity control agent (usually soda ash solution) added. Exact and quick adjustment of soda ash is accomplished by the optimizer passing optimum desired pH value signals, via conduit 59, to a pointer on meter 26 where they are continuously indicated for reference purposes and which the pH recording pen thereon tends to follow.
  • the optimizerguided pneumatic impulses are promptly passed on through branching conduits 62 and 63 to valves 0 and d, respectively which, by means of gap controller 64, control two branch flows from soda ash supply system, of the alkalinity control additive (e.g., an aqueous solution of soda ash).
  • Valve c regulates flow through line 10 to ball mill 12 and valve d regulates flow through line 65 to conditioner 22 in desired proportions, usually about twice as much being directed to 12 as to 22.
  • soda ash is used here for illustrative purposes. For some ores it is necessary that flotation be conducted in a neutral or acid medium, i.e., at a relatively low pH and an acidifying agent would be added.
  • An air supply system is represented by source 66, main conduit 67, and branches 68, 69, and 70, which system provides available pneumatic pressure as needed in the various conduits for automatic control.
  • a third density probe 72 (of the type designated 44 and 50) is immersed in cell C-8 whereby density D value is obtained by means of conduit 73 leading to pressure-density diaphragm cell 74.
  • the D value of C-8 is conveyed therefrom via conduit 76 to a second pen on meter 39 whereby D is recorded.
  • Branching off of conduit 76 is conduit 77 which feeds the D value into computer 38 for calculating D,D /D, percent recovery (percent R). This percent R value is conveyed by pneumatic signal via conduit 79 to a third pen on meter 39 whereby it is recorded.
  • the slurry which has not been frothed off in roughers 42 passes from a point near the bottom of cell C-8 through line 8ll and, by means of pump p and motor assembly m, is forced to a tailings pit or pile.
  • the high Cal content material, i.e., concentrates, from roughers 42 is frothed off into collecting trough system 82 from which it ultimately passes through line 83 to cleaners designated collectively 84, which are actually additional flotation cells (and not always necessary) and which are very similar to 42 but which are designed to accept the once-frothed off ore as feed which is of much higher CaF content than slurried fresh ore feed. That portion of the slurried concentrates which is not frothed off at cleaners 84 (similarly as from roughers 42) passes out from a point near the bottom of the last cleaner cell through line 85 into line 81 and thence to the tailings pile.
  • cleaners designated collectively 84 which are actually additional flotation cells (and not always necessary) and which are very similar to 42 but which are designed to accept the once-frothed off ore as feed which is of much higher CaF content than slurried fresh ore feed. That portion of the slurried concentrates which is not frothed
  • the recovered froth from cleaner cells 84 passes into collecting troughs 86 and ultimately into line 87 leading to thickener vessel 88 under slow agitation where a large percent of the water content thereof rises to the top and overflows to waste (or is recycled for reuse with fresh ore) as the concentrates settle toward the bottom and thickens.
  • the CaF is drawn off the bottom of 88 through line 89 into filter system 90 comprising envelopes which are subjected to interior vacuum, alternately being submerged in the thickened slurry which clings thereto to form a cake, and thence being brought out of the slurry into contact with fixed scraper blades that remove the cake (not shown in detail).
  • the rotating envelopes and stationary blades are identified schematically as items 91 and 92, respectively.
  • the so removed cake (now wet crumbles) is passed via conveyor 94 to dryer 96, which in practice customarily consists of a series of connected drying units, which produces a 97.4 percent or higher anhydrous CaF powder.
  • FIG. 2 shows two tubes in combination to define a fixed depth or stratum to obtain a single density value (where the level in the container varies) so that the volume at which density (D is measured remains the same. It is used, for example, when the density is obtained from conditioner 22. Since air must be provided to maintain adequate and substantially dead air in the probes, a metering valve, opening for admission of air without objectionable accompanying air currents, is provided in each of the two tubes comprising the probe.
  • FIG. 3 shows in some detail the assembly comprising density probes 44 and 50, conduit 46 leading from probe 44 and conduit 52 leading from probe 50 to opposing chambers D', and D g of density-pressure differential instrument 48.
  • the probes are elongated hollow cylinders which are open at the bottom and closed at the top to form dead-end systems terminating at the flexible diaphragm which separates 48 into D and D chambers.
  • the diaphragm responds to slight changes in pressure differential thereagainst which changes are promptly transferred from instrument 48 via conduit 54 to optimizer S6 and thence via conduit 59 to meter 26.
  • the pneumatic impulses recorded on meter 26 are passed on via conduit 61 to gap controller 64 and valves c and d.
  • Stirring and air supply assemblies are schematically represented and so labeled. Ample air is provided in tube probes 44 and 50 by air entering the cell bottoms for flotation.
  • FIG. 4 clearly demonstrates the improved control leading to assured improved efflciency and higher percent recovery attained by the practice of the invention.
  • FIG. 5 shows the percent CaF recovered at increasing slurry pH values to show that recovery is substantially zero at too low or too high slurry EMF, herein referred to as pH values.
  • FIG. 6 shows that the percent CaF recovered remains high as the pH values are clustered about the optimum value as automatically set by the optimizer as it receives the signals from the pressure-density cell, the signals being in prompt response to the density differential based on densities measured by the probes in accordance with the invention.
  • the density probe for D need not be positioned in the cell selected in FIG. 1, although such is preferred. Any succeeding cell after cell C-l can be used. Since by far the major portion of the flotation has been consumated by the time the slurry has passed from cell C-6, that cell is selected for illustration. The remaining cells, viz. cells C-7 and C-8 of FIG. 1, often called scavenger cells, froth ofl very little additional CaF and sometimes none. However the D probe could be satisfactorily placed in cell 08 rather than cell C6 to provide for automatic adjustment of the additament required to maintain optimum conditions.
  • C-1 and G6 are selected for D, and D density values because a preponderance of the flotation is attained therebetween within a relatively short time and therefore automatic adjustments based thereon are made as promptly as possible.
  • D density i.e., the density of the unfrothed slurry
  • D is the density of the tailings. Both values are used for the calculation: D -D /D to give the overall percent CaF recovery.
  • Comparative This example was conducted to illustrate the recovery of CaF from fluorspar ore in accordance with conventional practice. Complete daily records were maintained for a prolonged period of continuous operation. The procedure followed consisted of feeding crushed fluorspar ore by way of conveyor 2 into ball mill 12 as shown in FIG. 1 into which were also fed 10 percent by weight aqueous solutions of quebracho and soda ash and sufficient water to provide the desired solids.
  • the procedure followed consisted of feeding crushed fluorspar ore by way of conveyor 2 into ball mill 12 as shown in FIG. 1 into which were also fed 10 percent by weight aqueous solutions of quebracho and soda ash and sufficient water to provide the desired solids.
  • Air was released into each cell near the bottom center by way of an annular opening about the shaft of a rotating stirrer-centrifugal pump assembly (illustrated in FIG. 3) vertically positioned in each cell to produce froth.
  • the CaF being attracted to the froth in the cells, rose to the top thereof, was caused to overflow, and was collected as a slurry in troughs positioned along the outer edges, where, aided by limited additional water flow, it was drained away, and thereafter subjected to a second flotation treatment in similar series of cells known as cleaners, e.g., 84 of FIG. 1 of the drawing.
  • the uncollected portion of the slurry in rougher cells 42 was drained away to a tailings pond as also was the uncollected portion of cleaner cells 84.
  • the recovered froth from the cleaners 84 was pumped to a relatively large moderately heated tank 88, called a thickener, provided with very slow agitation wherein an appreciable amount of the water present continued to rise and was separated by its overflowing.
  • the thickened paste-like slurry was flowed at a controlled rate from the bottom thereof to filter (dewatering) system 90 comprising exhausted envelopes, i.e., envelopes 91 having a vacuum applied to the interior causing the thickened slurry to cling to the exterior, whereby moisture was drawn inwardly from the slurry by the vacuum leaving a cake-like layer on the envelope exteriors.
  • This layer was removed by causing the envelopes to rotate against fixed scraper knives or blades 92 (or if more convenient the knives may be moved across the envelopes) causing the wet recovered mineral to fall in crumbles on a conveyor, e.g., 94, and be taken into the first of a series of dryers represented by 96.
  • the dryer produced an anhydrous CaF product.
  • positive-negative electrical potential any variation in electrode potential in a 7
  • the pair of density probe tubes 28 in conditioner 22 were positioned so that the vertical distance between their lower open ends was 25 inches, thus giving a fixed stratum or layer of slurry for measurement of density.
  • single density probe tubes 44 and 50 respectively, in rougher cells C-1 and 06, so that their open ends were 15 inches above the bottom of the cells, a fixed stratum of slurry was defined since the cellsware maintained full of liquid at all times during the flotation operation.
  • tubes 44 and 50 led into smaller flexible tubing lines 46 and 52, respectively, which dead-ended on opposite sides of the diaphragm in D,D meter 48 which converted the density values of the contents of cells C-1 and G6 to a pressure differential which was transmitted via conduit 54 to optimizer 56 which translated the pressure differential to the desired EMF potential (which may be considered pH value) corresponding to maximum pressure differential.
  • Conduit 59 carried the pneumatic impulse to 26 where it was indicated as the optimizer-guided desired pH value.
  • Conduit 61 further relayed the pneumatic impulses from optimizer 56 via conduit 62 and 63 to motor valves c and d .whereby adjustments were automatically made in soda ash feed, by means of gap controller 64, which tended continuously to maintain an optimum feed composition.
  • the cells 42, cleaners 80, thickener 88, filter assembly 90, and dryers 96 were employed as in the conventional examples.
  • the optimizer attains this objective by continuously adjusting the rate of aqueous soda ash solution flow toward maximum density, i.e., whenever increments in soda ash continue to increasetheA density, such increments continue to' be made but when such increments result in a decrease in A density, the optimizer immediately calls for a reduction in soda ash and continues to make such reductions until the A density again is not improved by such decreases.
  • the percent of SiO and CaCO in the CaF- product were less than in that produced conventionally.
  • EXAMPLE 2 Shortly after the optimizer-density probe assembly of the invention had been installed, calibrated, and conditions stabilized, it was employed to guide and control a production size operation for 24 hours. The analysis of the ore being processed showed 76.80 percent CaF 12.0 percent CaCO 7.68 percent Si0 and about 1,000 ppm Be. Simultaneously with the practice of the invention, the slurry in process was sampled, the pH value and D and D density values obtained according to conventional procedures, and indicated changes that normally would have been made (but in fact were not) recorded every hour. The pH values, D' D' and hence D, less D were automatically regulated in accordance with the invention. (Note that D is taken in conditioner 22 and D in cell C-8; D is taken in cell C-1 and D in cell 08).
  • the optimizer through its peak-seeking principle continued to change the rate of addition of the soda ash solution at pre-selected intervals of siz minutes, increasing the rate of flow thereof so long as the density differential increased, but when such increase in flow of soda ash ceased to increase the density differential, reversing direction and decreasing the rate of flow of soda ash so long as the density differential was not decreased by such decreased flow.
  • the percent CaF recovery based on the CaF content of the ore, is directly related to the D less D value and is calculated by D,D /D
  • the production unit was started at 8 a.m. and continued until 8 am. of the following morning, following the method of the invention. Manual tests were taken regularly and calculations made based thereon but such tests were not used to control the operation.
  • An apparatus for continuously measuring, recording and controlling an ore flotation process which comprises in combination:
  • a tube extending from the upper end of each of said probes leading to opposite sides of a closed bichambered pressure-sensitive instrument, the chambers being formed by a dividing flexible membrane, thereby providing entrapped substantially dead gas in each probe-tube chamber combination, the pressure of which increases or decreases directly in response to the density of the liquid at the level of the lower end of each of said probes and deflects said membrane in accordance with the pressure differential and therefore in accordance with the density differential;
  • a peak-seeking optimizer responsive to the pressure differential provided by said pressure-sensitive instrument and which adjusts the said electrical potential (EMF) of the slurry at said location prior to the first flotation stage at the optimum necessary to maintain the pressure differential (and thus the ore recovery) at a maximum.

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Abstract

Two open-end tubes are vertically immersed, open-end down at substantially the same level, one near the place of entrance of a liquid in process in a series of treating vessels and the other near the outlet of the liquid whereby densities of the liquid at the respective locations are measured by means of a suitable pneumatic assembly, the density values are translated to and recorded as a pneumatic pressure differential and the pneumatic pressure differential is either (1) automatically converted to and recorded in meaningful values and the indicated adjustments manually made to restore and tend to maintain the optimum density differential, or (2) directed to an optimizer whereby optimum adjustments are automatically made to restore and tend to maintain a maximum density differential. Where a fluctuating level of liquid exists, two probes immersed at different depths to define a fixed stratum may be used in cooperation to obtain one density value.

Description

United States Patent 1 Hart [ Sept. 10, 1974 1 DEVICE AND METHOD OF DENSITY MEASUREMENT AND CONTROL OF FLOTATION SYSTEMS [75] Inventor: Porter Hart, Lake Jackson, Tex.
[73] Assignee: The Dow Chemical Company,
Midland, Mich.
22 Filed: Jan.20, 1972 211 App]. No.: 219,221
[52] us. c1 209/1, 209/166, 210/96 [56] References Cited UNITED STATES PATENTS 2,115,520 4/1938 Decker 73/438 2,125,663 8/1938 Wuensch 209/l72.5 X
2,765,219 10/1956 Shawhan 235/1501 X 3,031,267 4/1962 Martin 235/1501 X 3,094,484 6/1963 Rizo-Patron.. 209/164 X 3,207,305 9/1965 Custred 209/166 X 3,333,695 8/1967 Van Note 210/96 X 3,427,198 2/1969 Hill 73/439 X 3,460,394 8/1969 Cryer 73/439 3,462,364 8/1969 Carlson 210/42 OTHER PUBLICATIONS Chem. Abst., 64, 1966, 15444c.
Quelvra c/io so /u for) Chem. Abst., 68, 1968, 89182K.
Chem. Abst., 69, 1968, 37996e.
Primary ExaminerRobert l-lalper Attorney, Agent, or Firm-A. Cooper Ancona [57] ABSTRACT Two open-end tubes are vertically immersed, openend down at substantially the same level, one near the place of entrance of a liquid in process in a series of treating vessels and the other near the outlet of the liquid whereby densities of the liquid at the respective locations are measured by means of a suitable pneumatic assembly, the density values are translated to and recorded as a pneumatic pressure differential and the pneumatic pressure differential is either (1) automatically converted to and recorded in meaningful values and the indicated adjustments manually made to restore and tend to maintain the optimum density differential, or (2) directed to an optimizer whereby optimum adjustments are automatically made to restore and tend to maintain a maximum density differential. Where a fluctuating level of liquid exists, two probes immersed at different depths to define a fixed stratum may be used in cooperation to obtain one density value.
8 Claims, 6 Drawing Figures 7 L1 (070/0 (llflc/ua al-l (0 0, 'v A (em/ e 1 2 0 (EfTo/a/ 21 .9 mass 26 (3%,? 54 Prod 41c? -l-**'i l 7.9Jl L I J 1 Ro/arg 81 Roz/96ers o T fiickener W0 fer recyc/e or lo wasfe PAIENTEB SEN 0:914
sum 1 via INVENTOR. fiorrer Horf QO Q 0% TTQRNEY DEVICE AND METHOD OF DENSITY MEASUREMENT AND CONTROL OF FLOTATION SYSTEMS BACKGROUND OF THE'INVENTION In many processes conducted in liquid phase, it is essential for control thereof to ascertain and-control the density at various stages. Density differential very often is also indicative and sometimes an accurate measurement of the efficiency of the process. Illustrative of the latter are ore flotation systems wherein a mineral is separated by passing an aqueous slurry of finely ground ore containing conditioning agents through a series of open-top chambers or vessels (usually called cells), psitioned substantially horizontally to each other, each provided with an upwardly directed air supply and troughs or trays along the upper edges thereof to collect and drain away the desired mineral which is frothed off, sometimes aided by additional water supplied to the collection system, and usually thereafter thickened and dried. For specific consideration the separation of fluorite (which term will herein be used interchangeably with substantially pure CaF from fluorspar ore is illustrative. Fluorite which is the principal component of the ore and which is of greatest density, is frothed off as the slurry moves through the vessels, commonly called rougher cells. Accordingly, the density of the slurry is lessened as it passes from cell to cell. The efficiency of the system is indicated by the difference in density of the slurry in the successive cells and particularly between the first and last cells of a series. In general, the greater the difference in density, the more of the desired heavier mineral is being floated off.
Heretofore, density values have been obtained by manually taking samples of the slurry as it enters the first cell and again as it leaves a subsequent cell, weighing the samples, and calculating the density differential. Although this has long been done by a convenient liter vessel attached to one end of a balance arm and having a calibrated spring scale attached to the other, such measurements are only roughly accurate, and also provide only periodic values; they do not provide adequate information for satisfactory control of the system. Not only is such method of measurement done only at intervals so that conditions between measurements are unknown, but the time lag between the time that awareness of an undesirable change in density is known and a correction is made and becomes effective leads to erratic results.
A need, therefore, exists for a method of continuous density differential measurement and for prompt correction and particularly for automatic correction to effectuate the greatest differential conducive to frothing off a high quality product. The invention fulfills this need to a most gratifying extent.
SUMMARY OF THE INVENTION Broadly, the invention is a method of continuously measuring density, and particularly the concurrent measurement of density values at two stages of progress in a liquid system to ascertain the density differential, and the apparatus necessary for performing such method. The preferred mode of practicing the invention consists of a method and apparatus which measures such densities and density differential and promptly and automatically corrects the density differential to provide optimum conditions. Particularly the invention is a method and apparatus which continuously measures the differential between density values, converts such values instantly to a pressure differential, optionally relates the density differential to a calibrated recording instrument, to guide manual changes if desired, and/or simultaneously makes proper changes in one or more components of the source material being introduced into the system, whereby the density differential is optimized to maintain maximum recovery of product of improved quality.
Although the term pH (which strictly means only the reciprocal of the logarithm of the hydrogen ion concentration) is used herein to designate E.M.F. or electric potential produced in the slurry, it is to be borne in mind that such potential may be due in part to other contributing causes.
DESCRIPTION OF THE INVENTION The invention is an improvement in flotation processes generally, and apparatus necessary for the practice thereof. To better understand the invention, conventional flotation, applicable to the recovery of CaF product from fluorspar, is set out below.
Ore is pulverized, as by passing it through a rockcrusher, grizzly, or the like and then, after admixture with water to produce a slurry, some or all of the following treating agents are admixed therewith: a surface tension improving agent (known sometimes as a collector) to increase surface tension and to encourage bubble formation and stabilized froth, a suppressant to lessen the tendency of undesirable minerals present in the ore to rise in the froth, and an alkalinity-control agent to maintain desirable ionic potential in the slurry, and passing the so treated slurry in sequence: through a ball mill to reduce particle size; from the ball mill to a conditioning tank (conditioner) for thorough mixing and usually admixture of additional treating agents to attain a desired slurry composition for processing conditions; from the conditioner to a series of rougher cells wherein the slurry is agitated and into which are fed upwardly directed air to produce a mass of bubbles or froth, to which the desired mineral is attracted and adheres and which is caused to overflow out into collecting troughs positioned along the outer edges of the cells; from the collecting troughs (usually some additional water being admixed with the froth at this point) optionally into a second series of similarly designed cells (often called cleaners) by which the so collected foam is again subjected to air flotation and refined to a higher content of desired mineral; from the cleaners (or directly from the roughers) into a slowly agitated moderately heated tank (usually called a thickener) during which entrapped air escapes and considerable water separates as an upper layer and overflows to waste (or is recycled back to the ball mill to be used to slurry additional ore) leaving in the thickener a high viscosity but easily pumpable slurry; from the thickener the so thickened slurry of recovered mineral passes from the bottom thereof to a filter system which is preferably a vacuum dewatering type which comprises envelopes connected to an internal vacuum system to provide interior low pressure, arranged on a wheel which rotates on a horizontal axis so as to define an arc passing below the upper surface of the body of the thickened mineral slurry, causing slurry to adhere to the outside as a wet cake and water to be removed therefrom through the internal vacuum system, and to rotate through a second are above the surface of the slurry where the envelopes scrape against fixed blades which remove the cake as wet crumbles; from thence the cake crumbles drop onto a conveyor and are conveyed to dryers which produce a dehydrated commercially acceptable CaF product.
All necessary crushers, ball mills, conveyors, treating compound inlet and feed lines, transfer lines, control valves and pumps, rougher cells equipped for mechanical agitation, aerating and collection means, conditioning and thickener tanks, vacuum dehydration means, and dryers (all of which are known in the art) are located in accordance with a recommended lay-out suggested by advanced technology of ore treatment processing.
The improvement, in broad terms, of the above conventional general procedure and equipment which is the instant invention, comprises a method and means of continuous measurement of density differential of a mineral slurry at selected successive stages in a flotation system which differential is continuously recorded and serves as a basis for judicious adjustment of at least one component or condition of the process and provides for prompt adjustment thereof, e. g., a component of the feed composition in accordance with the density differential, to provide optimum recovery and improved quality of product. This is attained inherently in the novel system by converting the density differential to a pressure differential which is transferred as a pneumatic impulse. This may be done by directing the impulse to a recording instrument which is observed and acted on. The impulse preferably, however, is directed to an optimizer which automatically directly adjusts an ingredient in the feed to that proportion which results in the highest per cent recovery which is consistent with good quality. This is a peak-seeking optimizer which continuously changes the selected ingredient to result in optimum density differential.
The novel aspects and mode of operation of the improved process of the invention include cooperating mechanisms (the most critical of which are identified immediately below by small letters) for obtaining continuous density values converted to pressure differential employing (a) open-bottomed tubes (called hereafter density probes) positioned substantially vertically in the slurry at selected successive stages of the process, which connect at the top with tubing filled with dead air which terminate in (b) a two-chambered density cell, against a flexible diaphragm therein, which forms the density cells where, by density variations, the densities are converted to corresponding pressure variations in each chamber, called herein D and D respectively, for the selected stages. The differential between D, and D is either calculated and a pneumatic impulse sent to a recording meter for quick reading and manual adjustment made or an impulse is sent directly to (c) an optimizer which optimizer continuously seeks the greatest D,D or peak value possible and automatically relays this directly to a control which adjusts a component or condition so as to maintain the highest D,D value.
If desired, the pneumatic impulse from the density pressure cell may go both to the recording meter and to the optimizer whereby the potential difference in the slurry (which as aforesaid for practical purposes may be thought of as the pH value) is made of record but wherein the change is promptly made automatically by the peak-seeking optimizer. To attain this latter end, an electric line or pneumatic conduit leads from the optimizer (or continues from the meter) to an electric motor which actuates the valves that control that component of the feed which must be changed to result in the desired optimum condition, viz. optimum electric potential in the slurry being processed which in turn maintains a large density differential which results in increased product recovery.
It is to be understood that the invention may be practiced by employing variations and modifications of the above procedure so long as the concept of density measurement and automatic optimum adjustment of density, in accordance with the invention, is practiced.
The optimizer is available from instrument specialists e.g., Model 571 Syncro Optimizer MS-27670l, as described and illustrated in Operating Instructions for said model published by Moore products Co., Spring House, Pennsylvania.
DESCRIPTION OF THE DRAWING The drawing schematically illustrates an embodiment of the apparatus of the invention and that used to practice the method of the invention.
FIG. 1 shows the various parts of the assembled apparatus and the working relationship of a flotation system for carrying out the process of the invention.
FIG. 2 is a schematic view of an embodiment of the density measuring instrument of the invention wherein a fixed level is established between the lower ends of two cooperative probes which constitute one instrument to obtain a single reading. It is used where the surface level of the liquid under control fluctuates.
FIG. 3 is a schematic view of two instruments from which D and U and the differential thereof, of successive stages of a flotation operation, including the instrumentation referred to as (a) to (0) above, are shown.
FIG. 4 is a graph whereon the AD, i.e. D' -D' density differential as read on the recorder and guided by the optimizer, is curve (1) and as obtained manually is curve (2); and the pH values as established by automatic adjustment according to the invention is curve (3); and the pH values as taken manually are curve (4).
FIGS. 5 and 6 are percent recovery values plotted against pH values of the slurry.
In the drawing the word conduit is used for tube connections filled with air which effectuate desired changes by pneumatic impulses. The word line refers to flow lines for liquids. Electric connections are referred to as wires or wiring.
In more detail, the significant members of the assembled flotation system of FIG. 1 are represented by the following designations:
Item 2 is a moving endless apron for conveying crushed ore from a mine or storage pile. Item 3 supplies water (which need be neither deionized nor softened for use in the invention). Line 4 supplies a suppressant, e.g., an aqueous solution of quebracho. Both 3 and 4 lead into line 5 which bifurcates, through control valves (a) and (b), into lines 6 and 7, respectively. Tank 8 supplies an alkalinity control agent, e.g., an aqueous solution of soda ash, which connects with line 101. Lines 6 and 10 supply water and conditioning agents to the ore as it enters, and line 7 as the ore leaves, ball mill 12 (i.e., a drum rotating on a substantially horizontal axis or inclined slightly towards the outlet end, and containing freely moving steel balls for grinding ore). Item 13 is the outlet line from 12 which by means of pump (p) powered by motor (m) conveys slurry to 14 which is a cyclone separator of coarser and finer grind ore (in aqueous slurry containing the additives). Item 16 is an outlet line for finer grind ore from 14 leading directly to further processing and line 18 is an outlet line for coarser grind ore from 14' leading back to 12 for regrinding. Instrument 19 positioned in line 16 is a total ore volume measuring instrument which is connected by electric wire 20 to the first of two pens on recording instrument 21 which records hourly total ore volume thereon. Line 16 terminates in conditioning tank 22 known as a conditioner for finely ground ore slurry from the ball mill, provided with a high speed agitator (A). Positioned in 22 are electrodes T and S comprising electrode pair 24 made of erosion-resistant material (as described in co-pending application Ser. No. 219,230, entitled METHOD OF CONTINUOUS MEASUREMENT AND CONTROL OF FLOTATION CONDITIONS", of Porter Hart, filed concurrently herewith) which are provided with electric wiring 25 connected thereto and leading to a first recording pen which records continuously the electrode potential, which for simplicity may be considered to be the alkalinity of the slurry, on meter 26 (which for practical purposes may be considered a pH meter). Electrodes 24 are not essential to the practice of the invention but give an accurate slurry EMF (which for simplicity as indicated may be called pH value) at any time-and serve as an independent source of knowledge of the conditions of operation.
Feeding into 22 is a surface tension improver or col lector agent, e.g., oleic acid, by means of system 27.
Also in conditioner 22 there are shown a pair of cooperating vertical tubes 28, open at the bottom and containing air as shown in FIG. 2. They are, as shown on FIG. 2, immersed to different depths in the slurry, e.g., a difference in depth of about twenty to thirty inches between the open lower ends, thereby defining a fixed stratum or layer of slurry. upon which to calculate the slurry density. By means of conduits 29 and instrument 30 (a pressure-density cell) there is provided an accurate density reading D by reason of corresponding pressure changes. This D value is conveyed through conduit 31 into three conduits, viz: 32, 33, 34: conduit 32 leads to computer 35 where the volume (V) value from meter 21 through conduit 36 is received and the calculation V X D, mass flow is made and the result sent by pneumatic signal through conduit 37 to a second pen on meter 21 for recording mass flow thereon. Conduit 33 leads to computer 38 to provide the D, value to the computer. Conduit 34 leads to a first pen on meter 39 which records the D value continuously. Conduit 40 leads from meter 39 to valves (a) and (b): valve (a) provides automatic control of water containing quebracho into line 6 for entrance to ball mill 12 and valve (b) provides automatic control of water containing quebracho into line 7 as the slurry leaves ball mill 12. k
Line 41 leads conditioned ore from 22 to cell 01, the first of the series of rougher cells designated collectively item 42. Density probe tube 44 (similar to the longer tube of 28 and described more fully hereinbelow), is submerged in cell C-l. Via air conduit 46.. the density D' of the slurry in cell C-l (converted to corresponding pressure) deflects a flexible diaphragm in accordance therewith, in two-chambered densitypressure instrument 48. Cell 06, the sixth. of rougher cells 42, is provided with density probe 50 (similar to probe 44 of cell C-l) which by way of conduit 52 converts the density D' of the slurry in cell C-6 to pressure which also tends to deflect the flexible diaphragm in density-pressure instrument 48 (against the opposing pressure responsive to the density of O1), in accordance with the pressure changes. By means of the pressure-activated diaphragm positioned between the two chambers in 48, a pneumatic impulse, responsive to the pressure differential, is passed along conduit 54, sending one signal into optimizer 56 and a second signal through conduit 58 to a second pen on meter 26 which continuously registers the actual, i.e., existing, D -D, or AD value for purposes of record.
Optimizer 56 continuously and automatically seeks the greatest density differential (D',D' since the greater differential in density indicates the greatest efficiency of the rougher cells. An important condition for high recovery is the correct amount of alkalinity control agent (usually soda ash solution) added. Exact and quick adjustment of soda ash is accomplished by the optimizer passing optimum desired pH value signals, via conduit 59, to a pointer on meter 26 where they are continuously indicated for reference purposes and which the pH recording pen thereon tends to follow. However, by means of conduit 61, the optimizerguided pneumatic impulses are promptly passed on through branching conduits 62 and 63 to valves 0 and d, respectively which, by means of gap controller 64, control two branch flows from soda ash supply system, of the alkalinity control additive (e.g., an aqueous solution of soda ash). Valve c regulates flow through line 10 to ball mill 12 and valve d regulates flow through line 65 to conditioner 22 in desired proportions, usually about twice as much being directed to 12 as to 22. It should be understood that soda ash is used here for illustrative purposes. For some ores it is necessary that flotation be conducted in a neutral or acid medium, i.e., at a relatively low pH and an acidifying agent would be added.
An air supply system is represented by source 66, main conduit 67, and branches 68, 69, and 70, which system provides available pneumatic pressure as needed in the various conduits for automatic control.
As the slurry is moved from cell to cell in roughers 42, leaving each preceding cell and entering the next succeeding cell, while being agitated and while air is blown upwardly therethrough foam is produced which carries CaF to the top of the cells and froths it off into the collecting troughs 82.
A third density probe 72 (of the type designated 44 and 50) is immersed in cell C-8 whereby density D value is obtained by means of conduit 73 leading to pressure-density diaphragm cell 74. The D value of C-8 is conveyed therefrom via conduit 76 to a second pen on meter 39 whereby D is recorded. Branching off of conduit 76 is conduit 77 which feeds the D value into computer 38 for calculating D,D /D, percent recovery (percent R). This percent R value is conveyed by pneumatic signal via conduit 79 to a third pen on meter 39 whereby it is recorded.
The slurry which has not been frothed off in roughers 42 passes from a point near the bottom of cell C-8 through line 8ll and, by means of pump p and motor assembly m, is forced to a tailings pit or pile.
The high Cal content material, i.e., concentrates, from roughers 42 is frothed off into collecting trough system 82 from which it ultimately passes through line 83 to cleaners designated collectively 84, which are actually additional flotation cells (and not always necessary) and which are very similar to 42 but which are designed to accept the once-frothed off ore as feed which is of much higher CaF content than slurried fresh ore feed. That portion of the slurried concentrates which is not frothed off at cleaners 84 (similarly as from roughers 42) passes out from a point near the bottom of the last cleaner cell through line 85 into line 81 and thence to the tailings pile. The recovered froth from cleaner cells 84 passes into collecting troughs 86 and ultimately into line 87 leading to thickener vessel 88 under slow agitation where a large percent of the water content thereof rises to the top and overflows to waste (or is recycled for reuse with fresh ore) as the concentrates settle toward the bottom and thickens. From thickener 88, as a high viscosity fluid, the CaF is drawn off the bottom of 88 through line 89 into filter system 90 comprising envelopes which are subjected to interior vacuum, alternately being submerged in the thickened slurry which clings thereto to form a cake, and thence being brought out of the slurry into contact with fixed scraper blades that remove the cake (not shown in detail). The rotating envelopes and stationary blades are identified schematically as items 91 and 92, respectively.
The so removed cake (now wet crumbles) is passed via conveyor 94 to dryer 96, which in practice customarily consists of a series of connected drying units, which produces a 97.4 percent or higher anhydrous CaF powder.
Although pneumatically operated controls are shown in the illustration, it should be understood that, other than the pressure impulses received from the density probes by the pressure cells, all signals may be transferred and measured by means of an electric system.
FIG. 2 shows two tubes in combination to define a fixed depth or stratum to obtain a single density value (where the level in the container varies) so that the volume at which density (D is measured remains the same. It is used, for example, when the density is obtained from conditioner 22. Since air must be provided to maintain adequate and substantially dead air in the probes, a metering valve, opening for admission of air without objectionable accompanying air currents, is provided in each of the two tubes comprising the probe.
FIG. 3 shows in some detail the assembly comprising density probes 44 and 50, conduit 46 leading from probe 44 and conduit 52 leading from probe 50 to opposing chambers D', and D g of density-pressure differential instrument 48. The probes, as aforesaid, are elongated hollow cylinders which are open at the bottom and closed at the top to form dead-end systems terminating at the flexible diaphragm which separates 48 into D and D chambers. The diaphragm responds to slight changes in pressure differential thereagainst which changes are promptly transferred from instrument 48 via conduit 54 to optimizer S6 and thence via conduit 59 to meter 26. The pneumatic impulses recorded on meter 26 are passed on via conduit 61 to gap controller 64 and valves c and d. Stirring and air supply assemblies are schematically represented and so labeled. Ample air is provided in tube probes 44 and 50 by air entering the cell bottoms for flotation.
FIG. 4 clearly demonstrates the improved control leading to assured improved efflciency and higher percent recovery attained by the practice of the invention.
FIG. 5 shows the percent CaF recovered at increasing slurry pH values to show that recovery is substantially zero at too low or too high slurry EMF, herein referred to as pH values.
FIG. 6 shows that the percent CaF recovered remains high as the pH values are clustered about the optimum value as automatically set by the optimizer as it receives the signals from the pressure-density cell, the signals being in prompt response to the density differential based on densities measured by the probes in accordance with the invention.
The density probe for D need not be positioned in the cell selected in FIG. 1, although such is preferred. Any succeeding cell after cell C-l can be used. Since by far the major portion of the flotation has been consumated by the time the slurry has passed from cell C-6, that cell is selected for illustration. The remaining cells, viz. cells C-7 and C-8 of FIG. 1, often called scavenger cells, froth ofl very little additional CaF and sometimes none. However the D probe could be satisfactorily placed in cell 08 rather than cell C6 to provide for automatic adjustment of the additament required to maintain optimum conditions. C-1 and G6 are selected for D, and D density values because a preponderance of the flotation is attained therebetween within a relatively short time and therefore automatic adjustments based thereon are made as promptly as possible.
The principal use of D density, i.e., the density of the unfrothed slurry, is for the purpose of controlling the total solids, (i.e., amount of water added to the ore) in the ball mill. D is the density of the tailings. Both values are used for the calculation: D -D /D to give the overall percent CaF recovery.
EXAMPLES To illustrate the practice of the invention in comparison with conventional practice employing as nearly as possible the same mill lay-out, ore, and processing techniques except that, in the practice of the invention, the hereinafter claimed density-pressure probes and optimizer control of soda ash were employed whereas control was exercised in the conventional or comparative example in accordance with the most efficient techniques known prior to the instant invention.
The most significant operating conditions and results obtained for illustrative and comparative examples are shown in Table I.
Comparative This example was conducted to illustrate the recovery of CaF from fluorspar ore in accordance with conventional practice. Complete daily records were maintained for a prolonged period of continuous operation. The procedure followed consisted of feeding crushed fluorspar ore by way of conveyor 2 into ball mill 12 as shown in FIG. 1 into which were also fed 10 percent by weight aqueous solutions of quebracho and soda ash and sufficient water to provide the desired solids. The
ples are shown in Table I.
ore was thereby converted to a conditioned slurry of fine particle ore. From 12 the slurry was passed into a cyclone separator of the type designated 14 in FIG. 1. Therein particles coarser than 200 mesh size were returned to the ball mill and the finer particles were pumped to a highly agitated conditioning tank (e.g., conditioner 22) into which concurrently were fed oleic acid and additional aqueous soda ash solution controlled as needed.
From the conditioner the substantially uniformly mixed treated ore slurry was caused to flow to the se ries of flotation (rougher) cells as represented by 42 of the drawing.
Air was released into each cell near the bottom center by way of an annular opening about the shaft of a rotating stirrer-centrifugal pump assembly (illustrated in FIG. 3) vertically positioned in each cell to produce froth. The CaF being attracted to the froth in the cells, rose to the top thereof, was caused to overflow, and was collected as a slurry in troughs positioned along the outer edges, where, aided by limited additional water flow, it was drained away, and thereafter subjected to a second flotation treatment in similar series of cells known as cleaners, e.g., 84 of FIG. 1 of the drawing. The uncollected portion of the slurry in rougher cells 42 was drained away to a tailings pond as also was the uncollected portion of cleaner cells 84. The recovered froth from the cleaners 84, usually aided by more additional water for satisfactory flow, was pumped to a relatively large moderately heated tank 88, called a thickener, provided with very slow agitation wherein an appreciable amount of the water present continued to rise and was separated by its overflowing. From 88 the thickened paste-like slurry was flowed at a controlled rate from the bottom thereof to filter (dewatering) system 90 comprising exhausted envelopes, i.e., envelopes 91 having a vacuum applied to the interior causing the thickened slurry to cling to the exterior, whereby moisture was drawn inwardly from the slurry by the vacuum leaving a cake-like layer on the envelope exteriors. This layer was removed by causing the envelopes to rotate against fixed scraper knives or blades 92 (or if more convenient the knives may be moved across the envelopes) causing the wet recovered mineral to fall in crumbles on a conveyor, e.g., 94, and be taken into the first of a series of dryers represented by 96. The dryer produced an anhydrous CaF product.
The only process control practiced in the above'conventional operation, other than observation and hand feel consisted essentially of ore analyses, periodic sampling for manual determinations of both .pH and density, and laboratory analyses of the periodic sami The conditions and results of the conventional exam- Example of the Invention The following example is illustrative of the practice 7 of the invention. As aforesaid,'the rate of feed of ore,
the additives, and flotation principles applied and the general flow pattern were substantially the same as in the above comparative example except that the techniques applied tothe control of the process were those of the invention.
By the term positive-negative electrical potential as used herein is meant any variation in electrode potential in a 7 In accordance with the invention the pair of density probe tubes 28 in conditioner 22 were positioned so that the vertical distance between their lower open ends was 25 inches, thus giving a fixed stratum or layer of slurry for measurement of density. Likewise, by inserting single density probe tubes 44 and 50, respectively, in rougher cells C-1 and 06, so that their open ends were 15 inches above the bottom of the cells, a fixed stratum of slurry was defined since the cellsware maintained full of liquid at all times during the flotation operation. The top of tubes 44 and 50 led into smaller flexible tubing lines 46 and 52, respectively, which dead-ended on opposite sides of the diaphragm in D,D meter 48 which converted the density values of the contents of cells C-1 and G6 to a pressure differential which was transmitted via conduit 54 to optimizer 56 which translated the pressure differential to the desired EMF potential (which may be considered pH value) corresponding to maximum pressure differential. Conduit 59 carried the pneumatic impulse to 26 where it was indicated as the optimizer-guided desired pH value. Conduit 61 further relayed the pneumatic impulses from optimizer 56 via conduit 62 and 63 to motor valves c and d .whereby adjustments were automatically made in soda ash feed, by means of gap controller 64, which tended continuously to maintain an optimum feed composition. The cells 42, cleaners 80, thickener 88, filter assembly 90, and dryers 96, were employed as in the conventional examples.
By means of the peak-seeking optimizer 56, that pH was maintained which caused the A density, and hence percent CaF recovered, to remain at the top of the curve shown in FIG. 6. The optimizer attains this objective by continuously adjusting the rate of aqueous soda ash solution flow toward maximum density, i.e., whenever increments in soda ash continue to increasetheA density, such increments continue to' be made but when such increments result in a decrease in A density, the optimizer immediately calls for a reduction in soda ash and continues to make such reductions until the A density again is not improved by such decreases.
TABLE I Kgm/ min. aq. 10%
of sol. aq. CaF,
CaF of soda CaF Product Ore availqueash Oleic probased CaF Feed CaF, able bracho soln. acid duct on CaF, in [(gm/ in in mi] ml/ ml/ Conditioner Kgm/ ore CaF, Min. Ore Ore min min. min. T.S. Ternp.C. min. Content Product Comparative (conventional) Examples 140.28 58.0 81.4 500-900 12004300 3-5 32-33 110-130 5000 61.5 97.4 130.50 67.3 87.7 5001000 1100-4500 3-5 32-33 1 10130 55.50 63.3 97.4
Examplg 1 of the Invention ra Total solids Reference to Table I clearly shows a number of significant advantages due to the practice of the invention. Although exactly the same mill was employed for all examples, except for the use of the instrumentation of the invention, the following benefits of the invention are clearly realized:
I. the amount of ore, i.e., the rate of feed, that can be put through the mill is far greater;
2. the amount of quebracho (suppressant) required was steady;
3. the amount of soda ash was controlled within narrower limits;
4. the amount of oleic acid (collector agent) required was less;
5. the temperature in the conditioner was held more steady;
6. the percent of CaF product (of the same purity) recovered, based upon the CaF available in the ore, was considerably higher. (It is estimated that 1 percent greater recovery has a money value of about $500 per 100 tons of ore processed).
Although not specifically shown on the table, operation according to the invention was much more steady: the pH reading fluctuated over a much narrower range; the rate of ore feed and the periodic analyses of the recovered product showed less variation. The elimination of the man hours required for sampling the slurry and taking the pH and density by conventional methods released operators for other duties.
The percent of SiO and CaCO in the CaF- product were less than in that produced conventionally.
EXAMPLE 2 Shortly after the optimizer-density probe assembly of the invention had been installed, calibrated, and conditions stabilized, it was employed to guide and control a production size operation for 24 hours. The analysis of the ore being processed showed 76.80 percent CaF 12.0 percent CaCO 7.68 percent Si0 and about 1,000 ppm Be. Simultaneously with the practice of the invention, the slurry in process was sampled, the pH value and D and D density values obtained according to conventional procedures, and indicated changes that normally would have been made (but in fact were not) recorded every hour. The pH values, D' D' and hence D, less D were automatically regulated in accordance with the invention. (Note that D is taken in conditioner 22 and D in cell C-8; D is taken in cell C-1 and D in cell 08).
The optimizer through its peak-seeking principle continued to change the rate of addition of the soda ash solution at pre-selected intervals of siz minutes, increasing the rate of flow thereof so long as the density differential increased, but when such increase in flow of soda ash ceased to increase the density differential, reversing direction and decreasing the rate of flow of soda ash so long as the density differential was not decreased by such decreased flow.
The percent CaF recovery, based on the CaF content of the ore, is directly related to the D less D value and is calculated by D,D /D
The production unit was started at 8 a.m. and continued until 8 am. of the following morning, following the method of the invention. Manual tests were taken regularly and calculations made based thereon but such tests were not used to control the operation.
TABLE 11 Percent Cal- Product Recovered Based on Cal- Content of Ore Actual p fi \m calculated Recovery From Recovery if Based on Optimizer Operation Optimizer Density Had been Density Manually Probe Guided by Probe Time Taken Control Manual Tests Control 8 9.7 9.35 52.2 59.6 9 9.4 9.35 64.2 72.6 I 10 9.5 9.35 60.8 68.5 11 9.3 9.30 64.2 70.3 12 9.2 9.30 74.0 71.6 RM.
Reference to Table II evinces convincingly the more reliable control promptly and effectively made by the practice of the invention.
Below is a summary showing the real recovery ac- 1 cording to the invention and the recovery that would have been made had conventional practices been followed, i.e., had the manual sampling and the pH and density values which were thereby obtained been used to adjust the rate of flow of ore, water, and soda ash solution. The summary shows the superior performance of the method of the invention employing the required apparatus of the invention.
I Average Per Cent Recovery Manual Optimizer-Density Shifts Operation Cell Control 8 am. to 4 pm. 65.0% 68.6% D P)M) TO AB P)M) 61.3% 66.5% 12 pm. to 8 am. 63.5% 69.8%
Having described my invention, what I claim and desire to protect by Letters Patent is:
1. In the recovery of mineral values from an ore slurry employing flotation principles wherein conditioning agents are admixed with water and pulverulent ore to make a treated slurry and said slurry is subjected to flotation by passing air upwardly through the agitated slurry in successive connected cells whereby the mineral sought to be recovered is collected in a froth which is overflowed and recovered from the thus provided overflow, the improvement comprising:
continuously measuring the density values of at least two of said cells, continuously converting the density values to a pressure differential which is proportional to the differential of density values;
causing a pneumatic impulse in accordance with variations in the pressure differential to be relayed to a continuous registering instrument to provide a continuous pressure differential record which is calibrated to show density differential;
adjusting at least one additive of the flotation process in accordance with the recorded density differential to tend to maintain said differential at a maximum.
2. The method according to claim 1 wherein the electrical potential (EMF) value of the slurry prior to its tential can be adjusted in accordance with changes in said density differential.
3. The method according to claim 2 wherein the electrical potential (EMF) is calibrated into pH values.
4. The method according to claim 1 wherein a pneumatic impulse in accordance with said pressure differential, as controlled and determined by said density differential, is continuously sent to an optimizer which automatically seeks the maximum density differential which is continuously recorded.
5. The method according to claim 4 wherein said maximum density differential is continuously converted to pH values and such values used to guide the amount of an ingredient which, when admixed with the slurry, modifies the electrical potential (EMF) thereof.
6. The method according to claim 4 wherein a series of pneumatic impulses provided by said optimizer are sent to the feed control of an ingredient which modifies the electrical potential (EMF) in the slurry and increases or decreases the rate of said feed to cause the potential to trend at predetermined time intervals in the direction of maximum density differential in the slurry bath in the two cells being measured.
7. The method according to claim 6 wherein the optimum positive-negative potential differential in the slurry bath is recorded as well as automaticadjustment made of the rate of feed of a positive-negative modifying ingredient to continue to modify that rate to one which gives maximum density differential between the density of the slurry at or near the beginning and that at or near the end of the flotation operation.
8. An apparatus for continuously measuring, recording and controlling an ore flotation process which comprises in combination:
1. at least two independently operating vertically positioned elongated hollow probes, open at the lower end, each immersed to substantially the same depth in a body of ore slurry, each probe being located at one of selected successive flotation stages and filled with a non-turbulent gas, substantially chemically unreactive with the slurry;
2. a tube extending from the upper end of each of said probes leading to opposite sides of a closed bichambered pressure-sensitive instrument, the chambers being formed by a dividing flexible membrane, thereby providing entrapped substantially dead gas in each probe-tube chamber combination, the pressure of which increases or decreases directly in response to the density of the liquid at the level of the lower end of each of said probes and deflects said membrane in accordance with the pressure differential and therefore in accordance with the density differential;
3. means for continuously measuring the electrical potential (EMF) of the ore slurry at a location prior to the first flotation stage and means for recording and adjusting said electrical potential; and
4. a peak-seeking optimizer responsive to the pressure differential provided by said pressure-sensitive instrument and which adjusts the said electrical potential (EMF) of the slurry at said location prior to the first flotation stage at the optimum necessary to maintain the pressure differential (and thus the ore recovery) at a maximum.
UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION PATENT NO. 3,834,529 Q DATED September 10, 1974 INVENTOR(S) I Porter Hart it is certified that error appears in the ab0ve-identified patent and that said Letters Patent are hereby corrected as shown below:
Column 13, line 19, "DP)M) TO ABP)M)" should be changed to 4 p.m. to 12 p.m.
O Signed andfiealed this second Day Of September 1975 [SEAL] Arrest.
RUTH c. MASON c. MARSHALL DANN ilrzsn'ng Officer (ummissr'mrcr uj'lulcntx and Trademarks

Claims (11)

1. In the recovery of mineral values from an ore slurry employing flotation principles wherein conditioning agents are admixed with water and pulverulent ore to make a treated slurry and said slurry is subjected to flotation by passing air upwardly through the agitated slurry in successive connected cells whereby the mineral sOught to be recovered is collected in a froth which is overflowed and recovered from the thus provided overflow, the improvement comprising: continuously measuring the density values of at least two of said cells, continuously converting the density values to a pressure differential which is proportional to the differential of density values; causing a pneumatic impulse in accordance with variations in the pressure differential to be relayed to a continuous registering instrument to provide a continuous pressure differential record which is calibrated to show density differential; adjusting at least one additive of the flotation process in accordance with the recorded density differential to tend to maintain said differential at a maximum.
2. The method according to claim 1 wherein the electrical potential (EMF) value of the slurry prior to its being subjected to flotation is continuously recorded so that, for purposes of process control, said electrical potential can be adjusted in accordance with changes in said density differential.
2. a tube extending from the upper end of each of said probes leading to opposite sides of a closed bi-chambered pressure-sensitive instrument, the chambers being formed by a dividing flexible membrane, thereby providing entrapped substantially dead gas in each probe-tube chamber combination, the pressure of which increases or decreases directly in response to the density of the liquid at the level of the lower end of each of said probes and deflects said membrane in accordance with the pressure differential and therefore in accordance with the density differential;
3. means for continuously measuring the electrical potential (EMF) of the ore slurry at a location prior to the first flotation stage and means for recording and adjusting said electrical potential; and
3. The method according to claim 2 wherein the electrical potential (EMF) is calibrated into pH values.
4. a peak-seeking optimizer responsive to the pressure differential provided by said pressure-sensitive instrument and which adjusts the said eleCtrical potential (EMF) of the slurry at said location prior to the first flotation stage at the optimum necessary to maintain the pressure differential (and thus the ore recovery) at a maximum.
4. The method according to claim 1 wherein a pneumatic impulse in accordance with said pressure differential, as controlled and determined by said density differential, is continuously sent to an optimizer which automatically seeks the maximum density differential which is continuously recorded.
5. The method according to claim 4 wherein said maximum density differential is continuously converted to pH values and such values used to guide the amount of an ingredient which, when admixed with the slurry, modifies the electrical potential (EMF) thereof.
6. The method according to claim 4 wherein a series of pneumatic impulses provided by said optimizer are sent to the feed control of an ingredient which modifies the electrical potential (EMF) in the slurry and increases or decreases the rate of said feed to cause the potential to trend at predetermined time intervals in the direction of maximum density differential in the slurry bath in the two cells being measured.
7. The method according to claim 6 wherein the optimum positive-negative potential differential in the slurry bath is recorded as well as automatic adjustment made of the rate of feed of a positive-negative modifying ingredient to continue to modify that rate to one which gives maximum density differential between the density of the slurry at or near the beginning and that at or near the end of the flotation operation.
8. An apparatus for continuously measuring, recording and controlling an ore flotation process which comprises in combination:
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US4005008A (en) * 1974-08-08 1977-01-25 J. M. Huber Corporation Apparatus for magnetic beneficiation of particle dispersion
US4193791A (en) * 1976-10-28 1980-03-18 Reynolds Metals Company Concentration of hydrated aluminum oxide minerals by flotation
US4226714A (en) * 1978-12-27 1980-10-07 The Anaconda Company Thickener control system
US4273658A (en) * 1977-10-19 1981-06-16 Exxon Production Research Company Thickener control process
US4279742A (en) * 1976-12-20 1981-07-21 Institute Po Physikochimia Method of and apparatus for the flotation of mineral raw materials
US5307937A (en) * 1993-02-17 1994-05-03 North Carolina State University High throughput flotation column process
CN103941701A (en) * 2014-04-29 2014-07-23 东北大学 System and method for controlling operation of flotation industrial process under dual-network environment

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3985646A (en) * 1974-08-08 1976-10-12 J. M. Huber Corporation Method for magnetic beneficiation of particle dispersions
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US4273658A (en) * 1977-10-19 1981-06-16 Exxon Production Research Company Thickener control process
US4226714A (en) * 1978-12-27 1980-10-07 The Anaconda Company Thickener control system
US5307937A (en) * 1993-02-17 1994-05-03 North Carolina State University High throughput flotation column process
CN103941701A (en) * 2014-04-29 2014-07-23 东北大学 System and method for controlling operation of flotation industrial process under dual-network environment
CN103941701B (en) * 2014-04-29 2016-05-11 东北大学 Flotation industrial process operation control system and method under a kind of two net environment

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