US3742192A - Electrical heating device and method - Google Patents

Electrical heating device and method Download PDF

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US3742192A
US3742192A US00222948A US3742192DA US3742192A US 3742192 A US3742192 A US 3742192A US 00222948 A US00222948 A US 00222948A US 3742192D A US3742192D A US 3742192DA US 3742192 A US3742192 A US 3742192A
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silicon
heating element
electrical
heating device
electric current
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J Brzuszek
E Brzuszek
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
    • H05B3/148Silicon, e.g. silicon carbide, magnesium silicide, heating transistors or diodes
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/68Heating arrangements specially adapted for cooking plates or analogous hot-plates
    • H05B3/74Non-metallic plates, e.g. vitroceramic, ceramic or glassceramic hobs, also including power or control circuits
    • H05B3/748Resistive heating elements, i.e. heating elements exposed to the air, e.g. coil wire heater
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S420/00Alloys or metallic compositions
    • Y10S420/903Semiconductive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9265Special properties
    • Y10S428/929Electrical contact feature
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12674Ge- or Si-base component

Definitions

  • an electrical heating device comprising a semiconductor body having bidirectional electric current conducting characteristics and having ohmic electrical contacts secured thereto at spaced points thereon for passing an electric current through at least a portion of said body, said body containing at least 99 percent by weight silicon and at least one other element uniformly dispersed therethrough.
  • This invention relates to a new and improved electrical heating device and method and has as its principal object the provision of an electrical resistance type heating device which is extremely efficient, inexpensive, and wherein the body functioning as the heating element has very high thermal conductivity such that heat generated by passing electric current through one portion of the body is rapidly transferred throughout the body.
  • the body functions as an extremely efficient electrical heating element, the high thermal conductivity of the silicon assuring rapid transfer of the generated heat to all surfaces of the body.
  • the body, as described, which functions as the heating element can take any of various shapes depending upon the particular application to be made. of the heating device and examples of such shapes are shown in the drawings wherein:
  • FIG. 1 is a perspective view of an electrical heating device embodying the invention
  • FIG. 2 is a side view showing another embodiment of v ments, and with the concentration of the other element varying from one surface of the. body to another, displays semiconductive properties.
  • a body with a .rectifying electrical contact, the body demonstrating unidirectional electric current conducting characteristics thereby to provide a rectifier.
  • Such doped silicon bodies as are used in rectifiers are quite expensive and have no practical use as electrical heating elements not only by reason of the expense but also by reason of the unidirectional current conducting characteristics.
  • the heating element for the electrical heating device is a body containing at least about 99% by weight silicon and at least one other element, the other element or elements being uniformly dispersed through the body and the body having bilateral electric current characteristics.
  • the element or elements other than silicon uniformly dispersed through the body are effective to provide a conductivity in the body higher than the conductivity of pure silicon.
  • Electric current is passed through the body through spaced ohmic electrical contacts on the body.
  • ohmic contact is meant an electrical contact wherein there is substantially no current rectification.
  • the body serves as an extremely efficient electrical resistance heating element. Further, because of the very high thermal conductivity of silicon, the heat generated is very rapidly conducted to all surfaces of the body, this being highly advantageous in the efficient utilization of the heat generated by the body.
  • the silicon containing the one or more other elements uniformly dispersed therethrough, such elements generally always being themselves electrically conductive (specifically, metals believed to be alloyed with the silicon) is commerically available on the market in the form of commerically pure silicon containing at least about 99 percent by weight silicon, and the remainder impurities, and is used as silicon additive for the manufacture of iron, aluminum, or other alloys containing silicon.
  • Commerically pure silicon of the type described is inherently polycrystalline in structure.
  • Preparation of this polycrystalline, commerically pure silicon for use in semiconductor devices such as transistors centers on refinement of the silicon to remove the impurities and transformation of such refined silicon to single crystal form by means of a crystal growing process.
  • the following is a table of such commerically pure silicon materials, all of which serve well, when fabri cated to the desired shape, as the electrical heating element for the practice of the present invention.
  • the ohmic electrical contacts can be provided by a brazing operation wherein the electrical leads are brazed, as by means of a silver brazing composition, to the heating element, or they can be accomplished simply by very tightly clamping the metal contact members to the heating element.
  • the metal used for forming the ohmic contact with the heating element should, of course, have a melting point higher than that of silicon, which is about l4l0C, or at least higher than the maximum temperature to be generated within the heating element during operationthereof.
  • One manner we have found quite successful for providing the ohmic electrical connections with the heating element is to form, for each of the connections, a blind hole in the heating element, as by a drilling operation, and then driving a short rod of hard electrical conductive material, for example tungsten carbide, stainless steel or other hard metal, into the blind hole so as to provide an. interference fit. Also, a silver brazing material can be used between the rod of the hard electrical conductive material and the walls of the opening in the heating element so as to attain a bond.
  • hard electrical conductive material for example tungsten carbide, stainless steel or other hard metal
  • FIG. 1 shows an embodiment of the invention wherein the electrical heating device is for use as the heating element for a household electric range.
  • the heating element 6 is a circular plate, about 5 inches diameter and three-eighths inches thickness, and is cast of molten silicon containing at least about 99 percent by weight silicon together with very small amounts of other metals uniformly dispersed therein for example, any of the materials set forth in the above table.
  • the ohmic electrical contacts are shown at 8 and 10, these contacts being connected by suitable metal wires from integral projections on the bottom of the cast plate to a source of direct or alternating current, preferably the former, diagrammatically shown at 14.
  • FIG. 2 shows an embodiment wherein the heating element, of the composition described, is in the form of a rod 16 having integral spaced parallel disc shaped fins 18 extending radially therefrom.
  • the heating element of the composition described, is in the form of a rod 16 having integral spaced parallel disc shaped fins 18 extending radially therefrom.
  • the heating element 24, of the composition described is in the form of a sheet or slab embedded in and slightly below the surface of a concrete sidewalk, driveway or other surface.
  • the heat generated within the rod is conducted to the surface of the concrete thereby to melt snow or ice or prevent the formation of accumulation thereof.
  • it will generally be desired to generate temperatures only on the order of about 200 to 250F, and it will be understood, of course, that the amount of current used will depend on the length of the heating element and the precise temperature desired to be generated.
  • the FIG. 4 embodiment shows a soldering iron, partially in section, incorporating an electrical heating element made in accordance with the present invention. That is, the heating element 32 is a rod of the silicon containing another element or elements uniformly dispersed therethrough, as aforesaid, the electrical connections being shown at 40 and 34.
  • An insulated wire 36 extends from the contact back through a handle (not shown) which is secured to a metal casing 38 to which the contact 40 is secured.
  • the second of the ohmic contacts (the first of the ohmic controls being shown at 34) is actually the contact between the heating element 32 and the metal casing 38 at the location shown at 40.
  • the tapered end 42 of the heating element very rapidly becomes heated because of the extremely high thermal conductivity of the silicon.
  • temperatures of about 1000F can be rapidly generated at the tapered end of the heating element.
  • the invention has an additional advantage in that conventional soldering materials do not adhere to the silicon heating element thereby simplifying soldering operations.
  • the amount of heat generated is dependent upon the electrical current passed through the heating element, and it will be manifest that in no instance should the amount of current applied be such as to generate a temperature within the heating element in excess of the melting temperature of the heating element and, to be on the safe side, it is preferable that the temperature generated not exceed about 1000C. Such a temperature is more than ample for an extremely wide range of end-uses for the heating device.
  • An electrical heating device comprising a polycrystalline semiconductor body having a bilateral current conducting characteristic and having ohmic electrical terminal contacts directly secured thereto at spaced points thereon for passing an electric current through at least a portion of said body, said body containing at least about 99 percent by weight silicon and containing metal uniformly dispersed therethrough and alloyed with the silicon, said metal comprising at least about 0.5 percent by weight of said body thereby being effective to provide a conductivity in said body higher than the conductivity of pure silicon.
  • a method for generating heat at a rate on the order of about 20 watts or greater comprising passing an electric current through a solid body having bilateral current conducting characteristics thereby to cause the generation of heat in said body, said body containing at least about 99 percent by weight polycrystalline silicon and containing metal uniformly dispersed therethrough and alloyed with the silicon, said metal comprising at least about 0.5 percent by weight of said body thereby being effective to provide a conductivity in said body higher than the conductivity of pure silicon.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Resistance Heating (AREA)

Abstract

In accordance with the invention there is provided an electrical heating device comprising a semiconductor body having bidirectional electric current conducting characteristics and having ohmic electrical contacts secured thereto at spaced points thereon for passing an electric current through at least a portion of said body, said body containing at least 99 percent by weight silicon and at least one other element uniformly dispersed therethrough.

Description

United States Patent 1191 Brzuszek et al.
1 ELECTRICAL HEATING DEVICE AND METHOD [76] Inventors: John T. Brzuszek, 26741 Woodmont, Centerline, Mich. 48066; Emil J. Brzuszek, 7122 Jenerous, Roseville, Mich. 48015 221 Filed: Feb. 2, 1972 211 Appl. No.: 222,948
[52] US. Cl 219/553, 29/195, 75/148,
148/33, 219/540, 338/22 SD, 338/330 [51] Int. Cl. H051) 3/10 [58] Field of Search 219/523, 213, 530,
[56] References Cited UNITED STATES PATENTS 3,013,192 12/1961 Starr 338/22 SD 3,051,924 8/1962 Amberg et a1 3,189,973 6/1965 Edwards et a1. 338/22 SD 1 June 26, 1973 3,375,774 4/1968 Fujimura et al. 219/441 X 3,291,129 12/1966 Sanchez et a1 338/22 SD 2,871,330 1/1959 Collins 338/22 SD 1,906,963 5/1933 Heyroth 338/330 3,226,269 12/1965 Allegrettiet a1 l48/33.5 3,240,571 3/1966 Michelitsch.... 148/33 X 3,321,727 5/1967 Schrewelius 219/553 Primary ExaminerVolodymyr Y. Mayewsky Attorney-Gerald E. McGlynn, Jr., Paul J. Reising et a1.
[57] ABSTRACT In accordance with the invention there is provided an electrical heating device comprising a semiconductor body having bidirectional electric current conducting characteristics and having ohmic electrical contacts secured thereto at spaced points thereon for passing an electric current through at least a portion of said body, said body containing at least 99 percent by weight silicon and at least one other element uniformly dispersed therethrough.
2 Claims, 4 Drawing Figures PAIENIEDJUNZB x915 3.742.192
CURRENT SOURCE I ELECTRICAL HEATING DEVICE AND METHOD This invention relates to a new and improved electrical heating device and method and has as its principal object the provision of an electrical resistance type heating device which is extremely efficient, inexpensive, and wherein the body functioning as the heating element has very high thermal conductivity such that heat generated by passing electric current through one portion of the body is rapidly transferred throughout the body.
Briefly, what we have discovered is that if a body containing at least 99 percent by weight silicon and at least one other .element uniformly dispersed therethrough and having bidirectional electric current conducting characteristics is provided with spaced ohmic electrical connections and electric current is then passed through said body between said connections,
the body functions as an extremely efficient electrical heating element, the high thermal conductivity of the silicon assuring rapid transfer of the generated heat to all surfaces of the body.
The body, as described, which functions as the heating element can take any of various shapes depending upon the particular application to be made. of the heating device and examples of such shapes are shown in the drawings wherein:
FIG. 1 is a perspective view of an electrical heating device embodying the invention;
FIG. 2 is a side view showing another embodiment of v ments, and with the concentration of the other element varying from one surface of the. body to another, displays semiconductive properties. Hence, it is common practice to provide such a body with a .rectifying electrical contact, the body demonstrating unidirectional electric current conducting characteristics thereby to provide a rectifier. Such doped silicon bodies as are used in rectifiers are quite expensive and have no practical use as electrical heating elements not only by reason of the expense but also by reason of the unidirectional current conducting characteristics.
In accordance with the present invention the heating element for the electrical heating device is a body containing at least about 99% by weight silicon and at least one other element, the other element or elements being uniformly dispersed through the body and the body having bilateral electric current characteristics. The element or elements other than silicon uniformly dispersed through the body are effective to provide a conductivity in the body higher than the conductivity of pure silicon. Electric current is passed through the body through spaced ohmic electrical contacts on the body. By ohmic contact is meant an electrical contact wherein there is substantially no current rectification. By reason-of the semiconductive properties imparted to the body by the uniformly dispersed small amount of another element or other elements, the body serves as an extremely efficient electrical resistance heating element. Further, because of the very high thermal conductivity of silicon, the heat generated is very rapidly conducted to all surfaces of the body, this being highly advantageous in the efficient utilization of the heat generated by the body.
The silicon containing the one or more other elements uniformly dispersed therethrough, such elements generally always being themselves electrically conductive (specifically, metals believed to be alloyed with the silicon) is commerically available on the market in the form of commerically pure silicon containing at least about 99 percent by weight silicon, and the remainder impurities, and is used as silicon additive for the manufacture of iron, aluminum, or other alloys containing silicon. Commerically pure silicon of the type described is inherently polycrystalline in structure. Preparation of this polycrystalline, commerically pure silicon for use in semiconductor devices such as transistors centers on refinement of the silicon to remove the impurities and transformation of such refined silicon to single crystal form by means of a crystal growing process. The following is a table of such commerically pure silicon materials, all of which serve well, when fabri cated to the desired shape, as the electrical heating element for the practice of the present invention.
Silicon Iron Calcium Aluminum Manganese Chromium The best manner of farbicating the heating element from such commercially pure silicon will, of course, depend upon the precise shape desired for the heating element. In some cases this involves a casting operation, in others, machining operations and in still others extrusion or drawing operations.
The ohmic electrical contacts can be provided by a brazing operation wherein the electrical leads are brazed, as by means of a silver brazing composition, to the heating element, or they can be accomplished simply by very tightly clamping the metal contact members to the heating element. The metal used for forming the ohmic contact with the heating element should, of course, have a melting point higher than that of silicon, which is about l4l0C, or at least higher than the maximum temperature to be generated within the heating element during operationthereof. One manner we have found quite successful for providing the ohmic electrical connections with the heating element is to form, for each of the connections, a blind hole in the heating element, as by a drilling operation, and then driving a short rod of hard electrical conductive material, for example tungsten carbide, stainless steel or other hard metal, into the blind hole so as to provide an. interference fit. Also, a silver brazing material can be used between the rod of the hard electrical conductive material and the walls of the opening in the heating element so as to attain a bond.
FIG. 1 shows an embodiment of the invention wherein the electrical heating device is for use as the heating element for a household electric range. In this embodiment the heating element 6 is a circular plate, about 5 inches diameter and three-eighths inches thickness, and is cast of molten silicon containing at least about 99 percent by weight silicon together with very small amounts of other metals uniformly dispersed therein for example, any of the materials set forth in the above table. The ohmic electrical contacts are shown at 8 and 10, these contacts being connected by suitable metal wires from integral projections on the bottom of the cast plate to a source of direct or alternating current, preferably the former, diagrammatically shown at 14. Upon passage of current through the element 8, heat is generated in the portion of the element between the electrical contacts, and this heat is very rapidly conducted throughout the heating element and hence relatively uniformly over the entire upper area of the element. With the contacts spaced about 3 inches and using a DC source of about volts and 4 amps, a plate temperature of 1000F can be attained with the temperature being relatively uniform across the plate. Of course by reducing the current, there can be controlled lower plate temperatures.
FIG. 2 shows an embodiment wherein the heating element, of the composition described, is in the form of a rod 16 having integral spaced parallel disc shaped fins 18 extending radially therefrom. Upon passage of current through the rod, by way of the ohmic electrical contacts 20 and 22 heat is generated within the rod and this heat is very rapidly conducted to the fins. By circulating air between the fins the air becomes heated and this embodiment can be effectively used, therefore, as a space heater for heating dwellings.
In the FIG. 3 embodiment, the heating element 24, of the composition described, is in the form of a sheet or slab embedded in and slightly below the surface of a concrete sidewalk, driveway or other surface. When current is passed through the heating element, by way of the electrical contacts 28 and 30 at the ends of the heating element, the heat generated within the rod is conducted to the surface of the concrete thereby to melt snow or ice or prevent the formation of accumulation thereof. For the FIG. 2 and 3 embodiments, it will generally be desired to generate temperatures only on the order of about 200 to 250F, and it will be understood, of course, that the amount of current used will depend on the length of the heating element and the precise temperature desired to be generated.
The FIG. 4 embodiment shows a soldering iron, partially in section, incorporating an electrical heating element made in accordance with the present invention. That is, the heating element 32 is a rod of the silicon containing another element or elements uniformly dispersed therethrough, as aforesaid, the electrical connections being shown at 40 and 34. An insulated wire 36 extends from the contact back through a handle (not shown) which is secured to a metal casing 38 to which the contact 40 is secured. Hence, the second of the ohmic contacts (the first of the ohmic controls being shown at 34) is actually the contact between the heating element 32 and the metal casing 38 at the location shown at 40. Despite the short current path through the heating element, between the contacts 34 and 40, the tapered end 42 of the heating element very rapidly becomes heated because of the extremely high thermal conductivity of the silicon. Using a heating element of about 2% inches length and '9 inches diameter and a DC source similar to that described with reference to FIG. 1, temperatures of about 1000F can be rapidly generated at the tapered end of the heating element. In connection with this particular embodiment, the invention has an additional advantage in that conventional soldering materials do not adhere to the silicon heating element thereby simplifying soldering operations.
Of course the amount of heat generated is dependent upon the electrical current passed through the heating element, and it will be manifest that in no instance should the amount of current applied be such as to generate a temperature within the heating element in excess of the melting temperature of the heating element and, to be on the safe side, it is preferable that the temperature generated not exceed about 1000C. Such a temperature is more than ample for an extremely wide range of end-uses for the heating device.
It will be understood that while the invention has been described with reference to certain embodiments thereof, various changes and modifications may be made all within the full and intended scope of the claims which follow.
The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. An electrical heating device comprising a polycrystalline semiconductor body having a bilateral current conducting characteristic and having ohmic electrical terminal contacts directly secured thereto at spaced points thereon for passing an electric current through at least a portion of said body, said body containing at least about 99 percent by weight silicon and containing metal uniformly dispersed therethrough and alloyed with the silicon, said metal comprising at least about 0.5 percent by weight of said body thereby being effective to provide a conductivity in said body higher than the conductivity of pure silicon.
2. A method for generating heat at a rate on the order of about 20 watts or greater comprising passing an electric current through a solid body having bilateral current conducting characteristics thereby to cause the generation of heat in said body, said body containing at least about 99 percent by weight polycrystalline silicon and containing metal uniformly dispersed therethrough and alloyed with the silicon, said metal comprising at least about 0.5 percent by weight of said body thereby being effective to provide a conductivity in said body higher than the conductivity of pure silicon.

Claims (1)

  1. 2. A method for generating heat at a rate on the order of about 20 watts or greater comprising passing an electric current through a solid body having bilateral current conducting characteristics thereby to cause the generation of heat in said body, said body containing at least about 99 percent by weight polycrystalline silicon and containing metal uniformly dispersed therethrough and alloyed with the silicon, said metal comprising at least about 0.5 percent by weight of said body thereby being effective to provide a conductivity in said body higher than the conductivity of pure silicon.
US00222948A 1972-02-02 1972-02-02 Electrical heating device and method Expired - Lifetime US3742192A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991010336A1 (en) * 1989-12-27 1991-07-11 Ing Biro Establishment Silicon heating element
USD428135S (en) * 1999-04-26 2000-07-11 Potchen Robert T Adhesive melter heater element
WO2002009868A2 (en) * 2000-08-01 2002-02-07 Regents Of The University Of Minnesota Apparatus for generating a temperature gradient and methods for using the gradient to characterize molecular interactions
US10912154B1 (en) 2020-08-06 2021-02-02 Michael E. Brown Concrete heating system

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2111809B (en) * 1981-12-14 1985-08-21 Atomic Energy Authority Uk An improved fluid permeable porous electric heating element

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US1906963A (en) * 1930-04-28 1933-05-02 Globar Corp Impregnated silicon carbide article and the manufacture thereof
US2871330A (en) * 1954-12-22 1959-01-27 Gen Electric Silicon current controlling devices
US3013192A (en) * 1958-01-03 1961-12-12 Int Standard Electric Corp Semiconductor devices
US3051924A (en) * 1958-07-05 1962-08-28 Kanthal Ab Sintered electric resistance heating elements and methods of producing such elements
US3189973A (en) * 1961-11-27 1965-06-22 Bell Telephone Labor Inc Method of fabricating a semiconductor device
US3226269A (en) * 1960-03-31 1965-12-28 Merck & Co Inc Monocrystalline elongate polyhedral semiconductor material
US3240571A (en) * 1960-12-22 1966-03-15 Int Standard Electric Corp Semiconductor device and method of producing it
US3291129A (en) * 1962-08-10 1966-12-13 Burelle Pierre Laurent Raymond Scarificator for use in vaccination, skin tests, or the like
US3321727A (en) * 1964-12-09 1967-05-23 Kanthal Ab Heat-resistant and oxidationproof materials
US3375774A (en) * 1967-01-05 1968-04-02 Matsushita Electric Ind Co Ltd Fully automatic electric coffee pot

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1906963A (en) * 1930-04-28 1933-05-02 Globar Corp Impregnated silicon carbide article and the manufacture thereof
US2871330A (en) * 1954-12-22 1959-01-27 Gen Electric Silicon current controlling devices
US3013192A (en) * 1958-01-03 1961-12-12 Int Standard Electric Corp Semiconductor devices
US3051924A (en) * 1958-07-05 1962-08-28 Kanthal Ab Sintered electric resistance heating elements and methods of producing such elements
US3226269A (en) * 1960-03-31 1965-12-28 Merck & Co Inc Monocrystalline elongate polyhedral semiconductor material
US3240571A (en) * 1960-12-22 1966-03-15 Int Standard Electric Corp Semiconductor device and method of producing it
US3189973A (en) * 1961-11-27 1965-06-22 Bell Telephone Labor Inc Method of fabricating a semiconductor device
US3291129A (en) * 1962-08-10 1966-12-13 Burelle Pierre Laurent Raymond Scarificator for use in vaccination, skin tests, or the like
US3321727A (en) * 1964-12-09 1967-05-23 Kanthal Ab Heat-resistant and oxidationproof materials
US3375774A (en) * 1967-01-05 1968-04-02 Matsushita Electric Ind Co Ltd Fully automatic electric coffee pot

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991010336A1 (en) * 1989-12-27 1991-07-11 Ing Biro Establishment Silicon heating element
USD428135S (en) * 1999-04-26 2000-07-11 Potchen Robert T Adhesive melter heater element
WO2002009868A2 (en) * 2000-08-01 2002-02-07 Regents Of The University Of Minnesota Apparatus for generating a temperature gradient and methods for using the gradient to characterize molecular interactions
WO2002009868A3 (en) * 2000-08-01 2002-06-27 Univ Minnesota Apparatus for generating a temperature gradient and methods for using the gradient to characterize molecular interactions
US6544477B1 (en) 2000-08-01 2003-04-08 Regents Of The University Of Minnesota Apparatus for generating a temperature gradient
US6610470B2 (en) 2000-08-01 2003-08-26 Regents Of The University Of Minnesota Apparatus for generating a temperature gradient and methods for using the gradient to characterize molecular interactions
US6733729B2 (en) 2000-08-01 2004-05-11 Regents Of The University Of Minnesota Apparatus for generating a temperature gradient and methods for using the gradient to characterize molecular interactions
US10912154B1 (en) 2020-08-06 2021-02-02 Michael E. Brown Concrete heating system
US11683862B2 (en) 2020-08-06 2023-06-20 Michael E. Brown Concrete heating system

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