US3615909A - Method of producing a steel packing strip - Google Patents

Method of producing a steel packing strip Download PDF

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US3615909A
US3615909A US778074A US3615909DA US3615909A US 3615909 A US3615909 A US 3615909A US 778074 A US778074 A US 778074A US 3615909D A US3615909D A US 3615909DA US 3615909 A US3615909 A US 3615909A
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quenching
process according
steel
strip
tensile strength
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US778074A
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Hans-Wilhelm Grasshoff
Horst Turck
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HOESCH AG HAUPTVERWALTUNG
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HOESCH AG HAUPTVERWALTUNG
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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/54—Furnaces for treating strips or wire
    • C21D9/56—Continuous furnaces for strip or wire
    • C21D9/60—Continuous furnaces for strip or wire with induction heating
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273—Final recrystallisation annealing
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0252—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment with application of tension
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/25—Process efficiency

Definitions

  • ABSTRACT A steel packing strip with a tensile strength of around 95 to 125 kp./mm. an elongation of 85 of 10 to 17 percent and a yield point ratio of 0.7 to 0.9 is produced from rolled steel strip with a thickness of 0.30 to 1.3 mm. and a composition of about 0.10 to 0.20% C, at most 0.50% Si, possibly as much as 0.060% of P and S, 0.3% to 1% Mn, and the balance substantially all iron which is subjected to a continuous austenitizing annealing at a temperature of more than 820 C. and thereafter quenched in water to produce a structure with discrete particles of stress-laden ferrite.
  • the invention relates to a process for producing a steel packing strip of high strength with a tensile strength of about 95 to 125 kp./mm. an elongation 85 of to 17 percent and a yield point ratio of 0.7 to 0.9.
  • the Prior Art It is known to produce packing strip with a tensile strength of less than 95 kp./mm. by the relaxation and recovery annealing of cold rolled strip of a steel of the type of DIN 1624, as well as undeoxiclized, half-deoxidized, or completely deoxidized structural steel with additives corresponding to DIN 17100 with the desired tensile strength value.
  • the relaxation and recovery annealing can be carried out in continuous, pot or cupola annealing ovens.
  • a disadvantage of packing strips with a tensile strength of less than 95 kp./mm. is that they require a quite large cross section and for the same reason also are of substantial weight, in order to have adequate packing characteristics.
  • the disadvantage in the production of packing strips with a tensile strength of more than 95 kp./mm. is that two heat treatments are required.
  • the purpose of the present invention is to overcome these disadvantages in the known process for the production of packing strips and to produce a packing strip which has a tensile strength of 95 to 125 kp./mm. an elongation85 of 10 to 17 percent and a yield point ratio of 0.70 to 0.90 and to provide a simple procedure by which this can be done with only one heat treatment.
  • the quenching can advantageously be carried out also by means of cooled, for example, water-cooled, quenching plates, or by quenching rolls, because in this way an especially flat and strain-free product is obtained.
  • cooled for example, water-cooled, quenching plates, or by quenching rolls, because in this way an especially flat and strain-free product is obtained.
  • a protective gas in the heating zone it is further possible to obtain a completely scaleand tarnish-free surface.
  • the austenitizing annealing In order to avoid the formation of a thicker scale layer on the steel band by the austenitizing annealing, according to the invention it is proposed to carry out the annealing by direct current heating, inductive or resistance heating in as short as possible a space of time.
  • the layer of scale produced by the heating on the band can then be completely cracked off by the subsequent quenching.
  • the thickness of the scale layer By changing the length of the passage of the band being annealed through air, the thickness of the scale layer can be so controlled that upon dipping in water it cracks completely off and a clean contact surface for example by resistance heating is assured.
  • gas or electrically heated annealing ovens as well as when using induction or resistance heating it is advantageous to use a neutral protective gas for the austenitizing annealing.
  • it is proposed to carry out the quenching operation under tension which is accomplished by the use of plain or S-shaped rolls arranged in a water bath.
  • the procedure of the invention is carried out advantageously by quenching or produce a higher tensile strength than is required and thereafter allowing the band to dry. In this way, the required tensile strength of the band at the end of the treatment can be kept exact.
  • the quenching in water can be carried out in a single width or in several widths.
  • a subsequent splitting of arrow strips is made possible by the mechanical characteristics set out above.
  • several narrow strips can be produced simultaneously by the provision of corresponding reels.
  • the aforesaid mechanical characteristics of the packing strip are achieved through the production of a structure of stress-laden ferrite.
  • the relation of the carbon content to the manganese content is determined depending on the speed of quenching.
  • a carbon content of 0.10 to 0.12 percent with a manganese content of 0.40 to 0.60 percent is enough to produce drastically stress-laden ferrite in the steel band, If the quenching is carried out in more or less cold water between room temperature and 100 C., that is, with a correspondingly reduced quenching intensity, the carbon content must lie at about 0.20 percent and the manganese about 1 percent.
  • the mechanical characteristics can be kept in the desired ranges through an exchange of manganese through the carbon or of carbon through the manganese.
  • the advantages gained with the process according to the invention lie particularly in the fact that in contrast to the known packing bands with a tensile strength of less than kp./mm., the new packing band can be loaded more highly and besides in contrast to the packing band of the intermediate stage structure the same mechanical characteristics are obtained with only one heat treatment.
  • a cold rolled steel strip 2 of about 0.30 to 1.30 mm. thickness which is welded to the preceding steel strip 3 by means of a welding machine 4 for continuous operation, is rolled off and is passed through an austenitizing arrangement 5 over bending roller 6 through a water bath 7 and the reel 8. It is further advantageous between the outlet of the water bath and the wound-up reel 8 to provide an arrangement 10 for drying and/or annealing of the band and a lacquerring arrangement ll.
  • composition includes up to 0.60 percent P and S.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Abstract

A steel packing strip with a tensile strength of around 95 to 125 kp./mm.2, an elongation of delta 5 of 10 to 17 percent and a yield point ratio of 0.7 to 0.9 is produced from rolled steel strip with a thickness of 0.30 to 1.3 mm. and a composition of about 0.10 to 0.20% C, at most 0.50% Si, possibly as much as 0.060% of P and S, 0.3% to 1% Mn, and the balance substantially all iron which is subjected to a continuous austenitizing annealing at a temperature of more than 820* C. and thereafter quenched in water to produce a structure with discrete particles of stress-laden ferrite.

Description

United States Patent METHOD OF PRODUCING A STEEL PACKING STRIP 8 Claims, 1 Drawing Fig.
US. Cl l48/16.7, 148/12.1,148/12.4,148/127,l48/131,148/143, 148/153 Int. Cl C21d 1/00, C21d 9/46 Field ofSearch 148/16.7,
Metals Handbook, 1948 Ed. pages 631- 633 Primary Examiner-Charles N. Lovell Att0rney.lennings Bailey, Jr.
ABSTRACT: A steel packing strip with a tensile strength of around 95 to 125 kp./mm. an elongation of 85 of 10 to 17 percent and a yield point ratio of 0.7 to 0.9 is produced from rolled steel strip with a thickness of 0.30 to 1.3 mm. and a composition of about 0.10 to 0.20% C, at most 0.50% Si, possibly as much as 0.060% of P and S, 0.3% to 1% Mn, and the balance substantially all iron which is subjected to a continuous austenitizing annealing at a temperature of more than 820 C. and thereafter quenched in water to produce a structure with discrete particles of stress-laden ferrite.
1 METHOD OF PRODUCING A STEEL PACKING STRIP BACKGROUND OF THE INVENTION 1. Field of the Invention The invention relates to a process for producing a steel packing strip of high strength with a tensile strength of about 95 to 125 kp./mm. an elongation 85 of to 17 percent and a yield point ratio of 0.7 to 0.9.
2. The Prior Art It is known to produce packing strip with a tensile strength of less than 95 kp./mm. by the relaxation and recovery annealing of cold rolled strip of a steel of the type of DIN 1624, as well as undeoxiclized, half-deoxidized, or completely deoxidized structural steel with additives corresponding to DIN 17100 with the desired tensile strength value. The relaxation and recovery annealing can be carried out in continuous, pot or cupola annealing ovens. The high-strength packing strip with a tensile strength of more than 95 kp./mm. has been produced in a known way through a continuous or intermittent tempering in two heat treatments from a steel with a composition of about 0.20 to 0.40%C, 0.15 to 0.35%Si, up to 1.5% Mn and, at times, as much as 0.035% P and S.
A disadvantage of packing strips with a tensile strength of less than 95 kp./mm., is that they require a quite large cross section and for the same reason also are of substantial weight, in order to have adequate packing characteristics. The disadvantage in the production of packing strips with a tensile strength of more than 95 kp./mm. is that two heat treatments are required.
SUMMARY OF THE DISCLOSURE The purpose of the present invention is to overcome these disadvantages in the known process for the production of packing strips and to produce a packing strip which has a tensile strength of 95 to 125 kp./mm. an elongation85 of 10 to 17 percent and a yield point ratio of 0.70 to 0.90 and to provide a simple procedure by which this can be done with only one heat treatment.
This is achieved according to the invention by starting with a steel strip with a thickness of 0.3 to 1.3 mm. and a composition of about 0.10 to 0.20% C at most 0.50% Si possibly up to 0.060% P and S 0.30 to 1.0% Mn balance substantially all iron which is subjected to a continuous austenitizing annealing at temperatures of more than 820 C. and a subsequent quenching in water for the production of a structure with discreet particles of stress-laden ferrite.
The quenching can advantageously be carried out also by means of cooled, for example, water-cooled, quenching plates, or by quenching rolls, because in this way an especially flat and strain-free product is obtained. By using a protective gas in the heating zone it is further possible to obtain a completely scaleand tarnish-free surface.
In a similar way as with the steel band with the specified components it is also possible in general to use a steel deoxidized with the addition of aluminum.
In order to avoid the formation of a thicker scale layer on the steel band by the austenitizing annealing, according to the invention it is proposed to carry out the annealing by direct current heating, inductive or resistance heating in as short as possible a space of time. The layer of scale produced by the heating on the band can then be completely cracked off by the subsequent quenching. By changing the length of the passage of the band being annealed through air, the thickness of the scale layer can be so controlled that upon dipping in water it cracks completely off and a clean contact surface for example by resistance heating is assured. In gas or electrically heated annealing ovens as well as when using induction or resistance heating it is advantageous to use a neutral protective gas for the austenitizing annealing. In order also to avoid a wavy and rough-edged band, to be produced after the treatment, it is proposed to carry out the quenching operation under tension, which is accomplished by the use of plain or S-shaped rolls arranged in a water bath.
Because the exact reaching of the required tensile strength value by a simple quenching with water can be attended with difficulty, the procedure of the invention is carried out advantageously by quenching or produce a higher tensile strength than is required and thereafter allowing the band to dry. In this way, the required tensile strength of the band at the end of the treatment can be kept exact.
In general the quenching in water can be carried out in a single width or in several widths. A subsequent splitting of arrow strips is made possible by the mechanical characteristics set out above. In addition several narrow strips can be produced simultaneously by the provision of corresponding reels.
It is an important feature of the invention that the aforesaid mechanical characteristics of the packing strip are achieved through the production of a structure of stress-laden ferrite. In order for a partial or even a complete conversion of the structure to stress-laden ferrite, to attain the desired mechanical characteristics of the packing strip, the relation of the carbon content to the manganese content is determined depending on the speed of quenching. By quenching in flowing water, for example with a very high quenching intensity, a carbon content of 0.10 to 0.12 percent with a manganese content of 0.40 to 0.60 percent is enough to produce drastically stress-laden ferrite in the steel band, If the quenching is carried out in more or less cold water between room temperature and 100 C., that is, with a correspondingly reduced quenching intensity, the carbon content must lie at about 0.20 percent and the manganese about 1 percent. The mechanical characteristics can be kept in the desired ranges through an exchange of manganese through the carbon or of carbon through the manganese.
The advantages gained with the process according to the invention lie particularly in the fact that in contrast to the known packing bands with a tensile strength of less than kp./mm., the new packing band can be loaded more highly and besides in contrast to the packing band of the intermediate stage structure the same mechanical characteristics are obtained with only one heat treatment.
Further objects and advantages of the invention will appear more fully from the following description particularly when taken in conjunction with the drawing which is a part thereof.
BRIEF DESCRIPTION OF THE DRAWING The drawing shows diagrammatically an apparatus for carrying out the process according to the invention.
From a feeding reel 1 a cold rolled steel strip 2 of about 0.30 to 1.30 mm. thickness, which is welded to the preceding steel strip 3 by means of a welding machine 4 for continuous operation, is rolled off and is passed through an austenitizing arrangement 5 over bending roller 6 through a water bath 7 and the reel 8. It is further advantageous between the outlet of the water bath and the wound-up reel 8 to provide an arrangement 10 for drying and/or annealing of the band and a lacquerring arrangement ll. With a steel band which has the following composition which is austenitized for 5 minutes and quenched in a water bath at 20 C., it is possible at various thicknesses and austenitizing temperatures (TAU n (0 am the lollowlla characlerbflclz Thickness T,C. in v8 65 rrsloB cs 08 55 0.8 sec 86.5 102.2 12.: us
:2: :2: '22-: :1: :1: wwaim:
1. Process for the production of steel packing strip with a 10 tensile strength of 95-]25 kp./mm. an elongation 65 of with an 0.5 mm. thickness steel band with a composition of Si Mn P S A1 0.20% 0.04% 0.56% 0.021% 0.017% 0.0%
N Fe
0.004% Balance 2 which is subjected to austemtlztng annealing for 5 minutes at 820 C. and a water quenching at C. the following results were found:
as 013 55 KpJmn. KpJrnm. a's/o-B A further steel band of 0.5 mm. thickness with an analysis of is subjected to an austenitizing annealing at 800 C. and water quenched at 20 C. and shows the following characteristics:
10-17 percent and a yield point ratio of 0.70 to 0.90, in which a steel strip with a thickness of 0.30 to 1.3 mm. and a composition of about at most 0.50%Si balance substantially all iron is subjected first to a continuous austenitizing annealing at more than 820 C. followed directly by quenching with water to obtain a structure with discrete particles of stress-laden fer- 0 rite.
2. Process according to claim I in which the composition includes up to 0.60 percent P and S.
3. Process according to claim 1 in which the quenching is accomplished by the use of water-cooled quenching surfaces.
4. Process according to claim 1 in which the steel has been deoxidized by the addition of aluminum.
5. Process according to claim I in which the austenitizing annealing is carried out in the shortest possible time.
6. Process according to claim 1 in which annealing is carried out in a neutral gas.
the austenitizing protecting atmosphere of a 7. Process according to claim 1 in which the strip is stretched during quenching.
i =8 0 i t

Claims (7)

  1. 2. Process according to claim 1 in which the composition includes up to 0.60 percent P and S.
  2. 3. Process according to claim 1 in which the quenching is accomplished by the use of water-cooled quenching surfaces.
  3. 4. Process according to claim 1 in which the steel has been deoxidized by the addition of aluminum.
  4. 5. Process according to claim 1 in which the austenitizing annealing is carried out in the shortest possible time.
  5. 6. Process according to claim 1 in which the austenitizing annealing is carried out in a protecting atmosphere of a neutral gas.
  6. 7. Process according to claim 1 in which the strip is stretched during quenching.
  7. 8. Process according to claim 1 in which during the quenching the band is given a higher tensile Strength than is required and is thereafter relaxed during drying.
US778074A 1967-11-23 1968-11-22 Method of producing a steel packing strip Expired - Lifetime US3615909A (en)

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DE (1) DE1608164B1 (en)
FR (1) FR1592914A (en)
GB (1) GB1223766A (en)
SE (1) SE352106B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5830291A (en) * 1996-04-19 1998-11-03 J&L Specialty Steel, Inc. Method for producing bright stainless steel
WO2000052965A2 (en) * 1999-03-01 2000-09-08 Avestapolarit Aktiebolag (Publ) A method of heating metal strip and apparatus therefor
CN106566992A (en) * 2016-10-27 2017-04-19 唐山钢铁集团有限责任公司 950Mpa-grade high-strength cold-rolled strapping steel and preparation method thereof
CN108570592A (en) * 2018-04-27 2018-09-25 唐山不锈钢有限责任公司 TKDC ties hot-strip and its production method
CN114645187A (en) * 2022-01-29 2022-06-21 安阳钢铁股份有限公司 Non-quenched and tempered 950 MPa-grade high-strength strapping steel and production method thereof

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5551410B2 (en) * 1974-01-31 1980-12-24
AU530384B2 (en) * 1979-06-28 1983-07-14 Nippon Kokan Kabushiki Kaisha Controlled cooling of steel strip to effect continuous annealing
AU671246B2 (en) * 1994-04-28 1996-08-15 Illinois Tool Works Inc. Method and apparatus for an improved steel strap
DE102016000576A1 (en) * 2016-01-22 2017-07-27 Wsp Gmbh Method for the continuous annealing and quenching of strips of metallic materials and apparatus for carrying out the method

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE412852C (en) * 1923-06-26 1925-05-01 Friedrich Boecker Ph S Sohn Process for hardening and tempering steel wire, steel strip and the like like
GB1148912A (en) * 1965-05-10 1969-04-16 Ass Elect Ind Improvements relating to the heat treatment of steel sheet and strip

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5830291A (en) * 1996-04-19 1998-11-03 J&L Specialty Steel, Inc. Method for producing bright stainless steel
WO2000052965A2 (en) * 1999-03-01 2000-09-08 Avestapolarit Aktiebolag (Publ) A method of heating metal strip and apparatus therefor
WO2000052965A3 (en) * 1999-03-01 2000-12-28 Avesta Sheffield Aktiebolag Pu A method of heating metal strip and apparatus therefor
US6608290B1 (en) 1999-03-01 2003-08-19 Avesta Sheffield Aktiebolag Method of heating metal strip and apparatus thereof
CN106566992A (en) * 2016-10-27 2017-04-19 唐山钢铁集团有限责任公司 950Mpa-grade high-strength cold-rolled strapping steel and preparation method thereof
CN108570592A (en) * 2018-04-27 2018-09-25 唐山不锈钢有限责任公司 TKDC ties hot-strip and its production method
CN108570592B (en) * 2018-04-27 2019-08-09 唐山不锈钢有限责任公司 TKDC banding hot-strip and its production method
CN114645187A (en) * 2022-01-29 2022-06-21 安阳钢铁股份有限公司 Non-quenched and tempered 950 MPa-grade high-strength strapping steel and production method thereof

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FR1592914A (en) 1970-05-19
GB1223766A (en) 1971-03-03
BE724161A (en) 1969-05-20
DE1608164B1 (en) 1971-11-11
SE352106B (en) 1972-12-18

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