US3601694A - Apparatus for electrically checking the continuity of a coating - Google Patents

Apparatus for electrically checking the continuity of a coating Download PDF

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US3601694A
US3601694A US782179A US3601694DA US3601694A US 3601694 A US3601694 A US 3601694A US 782179 A US782179 A US 782179A US 3601694D A US3601694D A US 3601694DA US 3601694 A US3601694 A US 3601694A
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web
coating
field
skips
signal
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Darrell A Checketts
David R Simonsen
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Eastman Kodak Co
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means

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  • Hodsdon ABSTRACT The aqueous coating on a triboelectrically chargeable web is employed, before such coating dries, to shield the charged web from a field meter, thereby to detect skips in the coating.
  • the invention is especially useful in the manufacture of photographic film such, for example, as that having a polyethylene terephthalate base.
  • subcoat is placed on the base to assure proper coating thereof with photographic emulsion. Discontinuities in the subcoat (hereinafter called subskips) will result in ruined, or at least low quality, film because the emulsion coat thereof will not securely adhere to the base in the region of such subskips; and therefore, when developingsuch film, the coated emulsion will wash off such base.
  • subskips Discontinuities in the subcoat
  • the invention takes into account that when a triboelectrically charged web is coated with a conductive layer (i.e., one having a resistance which is under approximately 150 megohms per square centimeter), the charge on such web is shielded, on its coated side, by means of such coat; and that therefore the coat is question may be used to detect skips in itself.
  • a conductive layer i.e., one having a resistance which is under approximately 150 megohms per square centimeter
  • the charge on such web is shielded, on its coated side, by means of such coat; and that therefore the coat is question may be used to detect skips in itself.
  • subskips it has been recognized that subskips almost always occur at any of three widthwise locations (either edge, or center) of such web; and so examination for subskips across an entire web is unnecessary.
  • the invention is employed to check for subskips in an aqueous gel which is coated on a web by means of a hopper.
  • the web By virtue of its being handled, the web becomes charged; and such charge is shielded "so long as the subcoat is fluid," i.e. electrolytically conductive.
  • the invention suggests the disposition fluid, three field meters-two edge and one center-to look for charge on the coated web, through its fluid coat, and before such coat dries.” Respective circuits are provided to respond to the field meter outputs, thereby to indicate the presence and locations of subskips.
  • An object of the invention is to provide improved apparatus and methods for use in conjunction with web handling.
  • Another object of the invention is to provide improved apparatus and methods for assuring the proper application of electrically conductive coatings to triboelectrically chargeable webs.
  • Another object of the invention is to provide improved apparatus and methods for detecting skips in an electrically conductive coating on an electrically chargeable web.
  • Another object of the invention is to provide apparatus for detecting skips in a coating on a web by examining the edges and center of such web.
  • Another object of the invention is to provide, in a system for, or in a process for, coating a solution having a resistance less than megohms per square centimeter on a triboelectrically chargeable web, the provision for checking for skips in such coating by examining the charge on such web as seen through such coating.
  • FIG. 1 is a diagram illustrating a basic concept according to the invention
  • FIG. 2 is a perspective view, partially in schematic block form, illustrating a presently preferred embodiment of the invention.
  • FIG. 3 is a diagram useful for illustrating how subskips occur, and how they are detected.
  • FIG. 1 has been presented to facilitate description of the preferred embodiment of the invention as in FIGS. 2, 3; and to indicate that the invention has wider implications and, as such, may find use in other processes.
  • FIG. 1 shows a web 10 being conveyed past an inspection station at which a probe 12 is located.
  • the web 10 may be a metal band; or it may be laminar bands of paper and metal as might be employed in the manufacture of capacitors, etc.
  • the probe 12 is disposed proximate the metal band and looks at an electric field emanating from an electrically conductive plate 14.
  • the plate is excited by means of a power source 16. So long as the metal band is continuous, the probe 12 is shielded from the plate 14, and as such cannot see the field.
  • a break such as that indicated at 18, passes beneath the probe 12, however, the shielding is interrupted, thereby causing the probe to apply a signal to a field meter 20 to register the web break.
  • a web 22 of polyethylene terephthalate material which is to be prepared for coating with a photographic emulsion is conveyed by means of a roller 23. past a hopper 24.
  • the hopper 24 applies an aqueous solution 26 to the web, and such aqueous solution serves as a subcoat for the photographic emulsion, thereby to assure adhesion of the emulsion to the web.
  • the web 22 moves past the hopper 24 in the direction of the bold arrows indicated on the web.
  • the level of the aqueous solution is maintained by means of a source 28 thereof.
  • an air knife 30 is employed to blow such excess back into the hopper 24.
  • the air knife 30, as is usual, has air under pressure applied to its opposite ends, thereby to provide as even an air-knife action as is possible.
  • a plurality of lamps 32 constitute a drying section for readying the subcoated polyethylene terephthalate web for emulsion coating.
  • three electric field sensing heads 34, 36, 38 Prior to the subcoat drying section (lamps 32), but after the air knife, in the direction of web travel, three electric field sensing heads 34, 36, 38 are supported by suitable means on a brace 40. As is best illustrated in the plan of FIG. 3, two sensing heads 34, 36 are situated at the respective edges of the web 22; and one sensing head 38 is situated about midway across the web 22. The sensing heads are preferably less than about 5 inches from the web 22.
  • a second disc 46 like the disc 44, is coaxial with the disc 44; is adapted to be stationary; and is thus periodically in the complete electrical shadow of the first disc 44 when the first disc rotates.
  • a field E falling upon the disc 44, as seen by the disc 46, is modulated at the frequency of the disc 44 rotation multiplied by the number of segments in the disc 44.
  • polyethylene terephthalate base is extremely susceptible to triboelectric charging; and voltages (between web and ground) well in excess of 500 volts are common.
  • the invention makes full use of this otherwise objectionable phenomenon by using the charge so produced for the same purpose that the plate 14 of FIG. 1 was employed. Going one step further, the invention employs the conductivity of the sub'coat-while such coat is fluidto shield the web field from the sensing heads 34, 36, 38, the ground path for such shield being via the coat and its source.
  • the impedance across which each field representative signal is developed is large; and so to detect, say, the signal from the field sensor 34, a field effect transistor 100, in a common emitter circuit, is employed for impedance matching purposes, thereby to avoid attenuating the field representative signal.
  • the signal is then amplified by an amplifier 101.
  • the field representative signal is of a frequency equal to the motor (42) speed multiplied by the number of disc (44) segments.
  • a filter 102 tuned to pass the field signal frequency, is employed; and the output of the filter 102 is applied to an amplifier 104. Since the field representative signal is an AC signal, it makes no difference, as far as the detection circuit is concerned, whether such signal results from modulating a positive or a negative web-produced field. This feature may be important if the invention is to be employed in other environments and/or with different kinds of webs.
  • a rectifier 105 is provided to convert the alternating field representative signal to its DC equivalent.
  • a meter relay 106 functionally representative within dashed lines, includes a dead zone portion 107 and a self-holding relay portion 108.
  • Meter relays of the type indicated are well known; and the unit known as Compact II, Model 371-K and supplied by API Instruments Company, Chesterland, Ohio 44026, is presently considered preferably.
  • the dead zone portion 107 of the meter relay produces no output signal so long as the signal applied thereto is within certain limits. Thus, if
  • the dead zone circuit would produce and apply a signal to actuate the relay 108.
  • the relay 108 Once the relay 108 is actuated, its self-holding contacts 109 close to assure that power is steadily applied from a source 110 through a relay operated switch 111 to an alarm 112 or similar type circuit.
  • Circuits 114 and 116 each like the circuit consisting of elements 100-112, may be connected to receive the signal from the field sensing heads 36 and 38 respectively, whereby the widthwise location of alarm-producing faults may be determined. It should be noted that if so locating faults is of no importance, the circuits 114, 116 may be eliminated, the sensing heads 34, 36, 38 output leads being all tied to the transistor 100 for alarm purposes.
  • a system for treating a light-transmissive triboelectrically char eable web of polyethylene terephthalate said system inc udlng, at least in part, means for applying an electrically conductive and light-transmissive aqueous fluid coating to one face of said web, means for drying said fluid coating, thereby making said coating electrically nonconductive, and means for use in moving said web past both said means for applying and said means for drying said coating,
  • said field responsive means being disposed, in the direction of web travel, after said means for applying said coating, and before said means for drying said coating, said field responsive means being further disposed proximate, but electrically insulated from, and without touching, the coated face of said web, whereby when a skip occurs in such coating, such skip is detected by said field responsive means which responds to the electric charge on said web which charge has been triboelectrically caused to exist in the web by its movement.
  • said means for applying a coating to said web is adapted to apply said coating to said web is adapted to apply said coating across the entire width of said web
  • said means responsive to electric fields includes at least three such means disposed, respectively, proximate thc opposite-edges of said web, and approximately midway across said web.

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  • Chemical & Material Sciences (AREA)
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Abstract

The aqueous coating on a triboelectrically chargeable web is employed, before such coating dries, to shield the charged web from a field meter, thereby to detect skips in the coating.

Description

United States Patent Darrell A. Checketts;
David R. Simonsen, both of Rochester, N.Y. [2]] App]. No. 782,179
[22] Filed Dec. 9, 1968 [45] Patented Aug. 24, 1971 [73] Assignee Eastman Kodak Company Rochester, N.Y.
[72] Inventors [54] APPARATUS FOR ELECI'RICALLY CHECKING THE CONTINUITY OF A COATING 3 Claims, 3 Drawing Figs.
[52] US. Cl 324/32, 340/260 [51] Int. Cl ..G0lr 29/12, G08b 21/00 [50] Field of Search 324/32; 73/150; 340/259,'260
POWER [56] References Cited UNITED STATES PATENTS 2,189,352 2/1940 Siegenheim 324/32 2,532,010 ll/l950 Courvoisier.... 324/32X 3,234,462 2/1966 Holdsworth 324/71 OTHER REFERENCES Susskind, C.; The Encyclopedia of Electronics; Reinhold Publishing Co; 1962; pages 782 and 783 Primary ExaminerRudolph V. Rolinec Assistant Examiner Ernest F. Karlsen AttorneysPaul R. Holmes, Robert F. Cody and Walter O.
Hodsdon ABSTRACT: The aqueous coating on a triboelectrically chargeable web is employed, before such coating dries, to shield the charged web from a field meter, thereby to detect skips in the coating.
FIELD METER PATENTED AUG24I9YI 3,601,694
SHEET 1 [IF 2 FIELD I 1% METER POWER 20 DARRELL A. CHECKETTS DAVID R. SIMO/VSEN INVE TORS Arron EYS APPARATUS FOR ELECTRICALLY CHECKING THE CONTINUIT Y OF A COATING BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates in general to web handling and checking apparatus; and in particular the invention provides apparatus and methods for inspecting and examining webs which may become electrically charged, and which webs are thereafter coated with a layer which is, at least sometimes,
electrically conductive.
The invention is especially useful in the manufacture of photographic film such, for example, as that having a polyethylene terephthalate base.
2. Description Relative to the Prior Art In the manufacture of polyethylene terephthalate based photographic film, a subcoat is placed on the base to assure proper coating thereof with photographic emulsion. Discontinuities in the subcoat (hereinafter called subskips) will result in ruined, or at least low quality, film because the emulsion coat thereof will not securely adhere to the base in the region of such subskips; and therefore, when developingsuch film, the coated emulsion will wash off such base.
To assure against subskip-type film defects and thereby provide high quality products, it has been the prior practice to direct a widthwise ribbon of light, through the subcoated polyethylene terephthalate base, onto an array of photocells which are shifted, widthwise of the web, back and forth a certain frequency. On occurrence of a subskip, the light ribbon is modulated, thereby to produce an alarm signal for indicating the subskip. Subskip detection by this procedure leaves something to be desired, primarily because it is directed to examination of the whole of a coated web, and not to the coat itself in particular. lnnocuous specks and streaks, or the like, in an otherwise good polyethylene terephthalate web base will modulate the above indicated light ribbon just as easily as will a subskip; and so there is much false alarming with prior art subskip detector apparatus. False alarms, while being objectionable from the standpoint that they cause wasted effort and attendantly higher products costs, are-especially undesirable because they create nonreliance, on the part of machine attendants, in their subskip detector apparatus. So, as will happen, attendants will often ignore legitimate subskip-produced alarms simply because they have been too frequently fooled by false alarms. This is perhaps the most serious indictment of the prior practice since it serves to diminish the assurance of finished products which are of the highest possible quality.
SUMMARY OF THE INVENTION The invention takes into account that when a triboelectrically charged web is coated with a conductive layer (i.e., one having a resistance which is under approximately 150 megohms per square centimeter), the charge on such web is shielded, on its coated side, by means of such coat; and that therefore the coat is question may be used to detect skips in itself. In implementing the invention, it has been recognized that subskips almost always occur at any of three widthwise locations (either edge, or center) of such web; and so examination for subskips across an entire web is unnecessary. As presently preferred, the invention is employed to check for subskips in an aqueous gel which is coated on a web by means of a hopper. By virtue of its being handled, the web becomes charged; and such charge is shielded "so long as the subcoat is fluid," i.e. electrolytically conductive. The invention suggests the disposition fluid, three field meters-two edge and one center-to look for charge on the coated web, through its fluid coat, and before such coat dries." Respective circuits are provided to respond to the field meter outputs, thereby to indicate the presence and locations of subskips.
An object of the invention is to provide improved apparatus and methods for use in conjunction with web handling.
Another object of the invention is to provide improved apparatus and methods for assuring the proper application of electrically conductive coatings to triboelectrically chargeable webs.
Another object of the invention is to provide improved apparatus and methods for detecting skips in an electrically conductive coating on an electrically chargeable web.
Another object of the invention is to provide apparatus for detecting skips in a coating on a web by examining the edges and center of such web.
Another object of the invention is to provide, in a system for, or in a process for, coating a solution having a resistance less than megohms per square centimeter on a triboelectrically chargeable web, the provision for checking for skips in such coating by examining the charge on such web as seen through such coating.
The invention will be described with reference to the figures wherein:
FIG. 1 is a diagram illustrating a basic concept according to the invention,
FIG. 2 is a perspective view, partially in schematic block form, illustrating a presently preferred embodiment of the invention, and
FIG. 3 is a diagram useful for illustrating how subskips occur, and how they are detected.
FIG. 1 has been presented to facilitate description of the preferred embodiment of the invention as in FIGS. 2, 3; and to indicate that the invention has wider implications and, as such, may find use in other processes. FIG. 1 shows a web 10 being conveyed past an inspection station at which a probe 12 is located. The web 10 may be a metal band; or it may be laminar bands of paper and metal as might be employed in the manufacture of capacitors, etc. The probe 12 is disposed proximate the metal band and looks at an electric field emanating from an electrically conductive plate 14. The plate is excited by means of a power source 16. So long as the metal band is continuous, the probe 12 is shielded from the plate 14, and as such cannot see the field. When a break, such as that indicated at 18, passes beneath the probe 12, however, the shielding is interrupted, thereby causing the probe to apply a signal to a field meter 20 to register the web break.
With the above as background, reference should now be had to FIG. 2. A web 22 of polyethylene terephthalate material which is to be prepared for coating with a photographic emulsion is conveyed by means of a roller 23. past a hopper 24. The hopper 24 applies an aqueous solution 26 to the web, and such aqueous solution serves as a subcoat for the photographic emulsion, thereby to assure adhesion of the emulsion to the web. The web 22 moves past the hopper 24 in the direction of the bold arrows indicated on the web. As in common practice, the level of the aqueous solution is maintained by means of a source 28 thereof. To eliminate excess subcoat from the web 22, an air knife 30 is employed to blow such excess back into the hopper 24. The air knife 30, as is usual, has air under pressure applied to its opposite ends, thereby to provide as even an air-knife action as is possible. A plurality of lamps 32 constitute a drying section for readying the subcoated polyethylene terephthalate web for emulsion coating.
It has been found that skips in the subcoat practically always originate and/or reside at the edges of the web 22, or at about the center of such web. Edge subskips usually occur, it is believed, as a result of fluid-surface tension; centrally disposed skips in the web subcoat usually result from the air turbulence which is created as a result of oppositely charging the air knife 30 with air.
Prior to the subcoat drying section (lamps 32), but after the air knife, in the direction of web travel, three electric field sensing heads 34, 36, 38 are supported by suitable means on a brace 40. As is best illustrated in the plan of FIG. 3, two sensing heads 34, 36 are situated at the respective edges of the web 22; and one sensing head 38 is situated about midway across the web 22. The sensing heads are preferably less than about 5 inches from the web 22.
Though the particular form of sensing head constitutes no' others. A second disc 46, like the disc 44, is coaxial with the disc 44; is adapted to be stationary; and is thus periodically in the complete electrical shadow of the first disc 44 when the first disc rotates. A field E falling upon the disc 44, as seen by the disc 46, is modulated at the frequency of the disc 44 rotation multiplied by the number of segments in the disc 44.
As is well-known, polyethylene terephthalate base is extremely susceptible to triboelectric charging; and voltages (between web and ground) well in excess of 500 volts are common. The invention makes full use of this otherwise objectionable phenomenon by using the charge so produced for the same purpose that the plate 14 of FIG. 1 was employed. Going one step further, the invention employs the conductivity of the sub'coat-while such coat is fluidto shield the web field from the sensing heads 34, 36, 38, the ground path for such shield being via the coat and its source.
As will be apparent from FIG. 3, the impedance across which each field representative signal is developed is large; and so to detect, say, the signal from the field sensor 34, a field effect transistor 100, in a common emitter circuit, is employed for impedance matching purposes, thereby to avoid attenuating the field representative signal. The signal is then amplified by an amplifier 101.
It was above indicated that the field representative signal is of a frequency equal to the motor (42) speed multiplied by the number of disc (44) segments. To prevent spurious signals such as the 60 cycle line frequency from adversely affecting subskip detection, a filter 102, tuned to pass the field signal frequency, is employed; and the output of the filter 102 is applied to an amplifier 104. Since the field representative signal is an AC signal, it makes no difference, as far as the detection circuit is concerned, whether such signal results from modulating a positive or a negative web-produced field. This feature may be important if the invention is to be employed in other environments and/or with different kinds of webs. A rectifier 105 is provided to convert the alternating field representative signal to its DC equivalent.
A meter relay 106, functionally representative within dashed lines, includes a dead zone portion 107 and a self-holding relay portion 108. Meter relays of the type indicated are well known; and the unit known as Compact II, Model 371-K and supplied by API Instruments Company, Chesterland, Ohio 44026, is presently considered preferably. The dead zone portion 107 of the meter relay produces no output signal so long as the signal applied thereto is within certain limits. Thus, if
any component to were to fail for any reason; or if the sensor 34 were to produce a field representative signal, the dead zone circuit would produce and apply a signal to actuate the relay 108. Once the relay 108 is actuated, its self-holding contacts 109 close to assure that power is steadily applied from a source 110 through a relay operated switch 111 to an alarm 112 or similar type circuit. I
Circuits 114 and 116, each like the circuit consisting of elements 100-112, may be connected to receive the signal from the field sensing heads 36 and 38 respectively, whereby the widthwise location of alarm-producing faults may be determined. It should be noted that if so locating faults is of no importance, the circuits 114, 116 may be eliminated, the sensing heads 34, 36, 38 output leads being all tied to the transistor 100 for alarm purposes.
The invention has been described in detail with particular reference to preferred embodiments thereof, but it will be understood that variations and modifications can be effected with the spirit and scope of the invention.
We claim:
1. In a system for treating a light-transmissive triboelectrically char eable web of polyethylene terephthalate, said system inc udlng, at least in part, means for applying an electrically conductive and light-transmissive aqueous fluid coating to one face of said web, means for drying said fluid coating, thereby making said coating electrically nonconductive, and means for use in moving said web past both said means for applying and said means for drying said coating,
means responsive to electric fields, said field responsive means being disposed, in the direction of web travel, after said means for applying said coating, and before said means for drying said coating, said field responsive means being further disposed proximate, but electrically insulated from, and without touching, the coated face of said web, whereby when a skip occurs in such coating, such skip is detected by said field responsive means which responds to the electric charge on said web which charge has been triboelectrically caused to exist in the web by its movement.
2. The system of claim 1 wherein said means for applying a coating to said web is adapted to apply said coating to said web is adapted to apply said coating across the entire width of said web, and wherein said means responsive to electric fields includes at least three such means disposed, respectively, proximate thc opposite-edges of said web, and approximately midway across said web.
3. The system of claim 2 including respective alarm means cooperative with said three field responsive means, thereby to indicate not only the occurrence of coating skips, but their general locations as well.

Claims (2)

  1. 2. The system of claim 1 wherein said means for applying a coating to said web is adapted to apply said coating to said web is adapted to apply said coating across the entire width of said web, and wherein said means responsive to electric fields includes at least three such means disposed, respectively, proximate the opposite edges of said web, and approximately midway across said web.
  2. 3. The system of claim 2 including respective alarm means cooperative with said three field responsive means, thereby to indicate not only the occurrence of coating skips, but their general locations as well.
US782179A 1968-12-09 1968-12-09 Apparatus for electrically checking the continuity of a coating Expired - Lifetime US3601694A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE28394E (en) * 1971-05-21 1975-04-15 Point apparatus for testing electrical contact between metallic objects
US4041375A (en) * 1974-04-18 1977-08-09 Ljudmila Alexeevna Polukhina Apparatus for measuring content of moving dielectric materials moisture
US4479090A (en) * 1982-09-30 1984-10-23 International Business Machines Corporation Circuitry for measuring magnetic head flying characteristics
US4724392A (en) * 1985-05-10 1988-02-09 International Business Machines Corporation System for testing magnetic head/disk interfaces
US4857853A (en) * 1987-07-23 1989-08-15 E. I. Du Pont De Nemours And Company On-line electrostatic defect detector for polyester base
US5604438A (en) * 1995-03-06 1997-02-18 The United States Of America As Represented By The Secretary Of The Navy Controlled spark ignition testing apparatus

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5525145U (en) * 1978-08-07 1980-02-18

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2189352A (en) * 1936-03-17 1940-02-06 Firm M Rudolf Jahr Process and device for the determination and regulation of the moisture content of lengths of material
US2532010A (en) * 1944-04-17 1950-11-28 Courvoisier Frederic Determination of moisture contents
US3234462A (en) * 1961-08-16 1966-02-08 Comstock & Wescott Polymeric testing by dipole orientation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2189352A (en) * 1936-03-17 1940-02-06 Firm M Rudolf Jahr Process and device for the determination and regulation of the moisture content of lengths of material
US2532010A (en) * 1944-04-17 1950-11-28 Courvoisier Frederic Determination of moisture contents
US3234462A (en) * 1961-08-16 1966-02-08 Comstock & Wescott Polymeric testing by dipole orientation

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
3Susskind, C.; The Encyclopedia of Electronics; Reinhold Publishing Co; 1962; pages 782 and 783 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE28394E (en) * 1971-05-21 1975-04-15 Point apparatus for testing electrical contact between metallic objects
US4041375A (en) * 1974-04-18 1977-08-09 Ljudmila Alexeevna Polukhina Apparatus for measuring content of moving dielectric materials moisture
US4479090A (en) * 1982-09-30 1984-10-23 International Business Machines Corporation Circuitry for measuring magnetic head flying characteristics
US4724392A (en) * 1985-05-10 1988-02-09 International Business Machines Corporation System for testing magnetic head/disk interfaces
US4857853A (en) * 1987-07-23 1989-08-15 E. I. Du Pont De Nemours And Company On-line electrostatic defect detector for polyester base
US5604438A (en) * 1995-03-06 1997-02-18 The United States Of America As Represented By The Secretary Of The Navy Controlled spark ignition testing apparatus

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