US3528284A - Method for purifying penetrant waste liquors - Google Patents
Method for purifying penetrant waste liquors Download PDFInfo
- Publication number
- US3528284A US3528284A US846736A US3528284DA US3528284A US 3528284 A US3528284 A US 3528284A US 846736 A US846736 A US 846736A US 3528284D A US3528284D A US 3528284DA US 3528284 A US3528284 A US 3528284A
- Authority
- US
- United States
- Prior art keywords
- penetrant
- water
- layer
- emulsion
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
- G01N21/88—Investigating the presence of flaws or contamination
- G01N21/91—Investigating the presence of flaws or contamination using penetration of dyes, e.g. fluorescent ink
Definitions
- This invention is in the field of testing objects for surface discontinuities employing the oily-type dyed penetrant in which the penetrant is either self-emulsiable or is subsequently emulsied to produce a waste liquor which presents disposal problems.
- the penetrant method of flaw detection has been in use since the early 1940s. Basically, the method involves applying an oily penetrant containing either a visible or a fluorescent dye onto the surface of a test piece, removing excess penetrant while leaving the penetrant lodged in any surface flaws which may exist, applying a developer which is typically a particulated material or a suspension of nely divided absorptive particles in a volatile liquid, and then inspecting the part for the presence of flaws.
- the penetrant is drawn into the developer by capillary action whereupon the indication is enlarged and thereby rendered more readily visible to the inspector, using white light if a visible dye was used, or ultraviolet light where a fluorescent penetrant was used. Processes of this type are described in Switzer Pat. No. 2,259,400 issued Oct. 14, 1941.
- a penetrant waste liquor which contains an oil-inwater emulsion of the oily constituents of the penetrant, in combination with emulsier, water soluble components of the penetrant and the wash water.
- this type of disposal is objectionable for two reasons. For one, the presence of the oily materials in the waste liquor is objectionable from the standpoint of pollution of water courses into which the waste liquor is dumped. In addition, large amounts of water are used for washing purposes in large plants and with rising water costs, the water discharged into the sewer may represent a considerable sum.
- the present invention resides in a method for detecting surface discontinuities using an oily base penetrant wherein excess penetrant is removed by emulsication with wash water in a washing Zone to produce an oil-inwater emulsion, and the oily components are removed from the emulsion by adding an emulsion breaking electrolyte thereto in combination with an effective amount of a clay capable of forming a slurry with the oily components, agitating the resulting mixture thoroughly, stratifying the resulting admixture into a plurality of layers including a layer of a clay slurry containing oily components adsorbed by the clay and a layer of water containing water miscible penetrant components, and separating the layers.
- the water layer can be recycled back to the washing stage or it can be discharged directly into the sewage line since it is substantially free from non-biodegradable components.
- FIG. 1A is a schematic representation of the post emulsication process for penetrant inspection
- FIG. 1B is a schematic representation of another type of penetrant inspection process.
- FIG. 2 is a diagrammatic showing of an apparatus 0 for separating the water phase from Hthe oil-in-water emulsion produced by either of the processes shown in FIGS. 1A or 1B.
- reference numeral 10 has been applied to to a penetrant applicator station wherein an oily base penetrant containing either a visible dye or a fluorescent dye is applied to the article to be tested by means of spraying, dipping, painting, or other suitable means of application.
- the workpiece is passed to a washing station generally indicated at reference numeral 11 where it is subjected to the action of an emulsier introduced into the station 11 through a line 12 and wash water introduced into the washing station 11 through a line 13.
- the emulsifying composition is applied as a more or less static layer over the penetrant on the surface of the workpiece and migrates into the penetrant to assist in the removal of the excess penetrant.
- the wash Water is generally applied as a stream to displace the excess penetrant which has become emulsiiied ⁇ while leaving an emulsiiied penetrant entrapped in any flaws. After removal of the excess penetrant, the piece is ready for development and inspection in accordance with any of the well known development techniques.
- the oil-in-water emulsion which results from the interaction of the penetrant, emulsiiier and wash water in washing station 11 is withdrawn from that station and through a line 14 for treatment in accordance with the procedure to be described.
- the workpiece is treated with an emulsitiable penetrant in an applicator station 15.
- the penetrant treated workpiece is then passed to a washing station 16 where it is subjected to a spray of wash water entering that station through a line 17.
- the resulting oilin-water emulsion is periodically withdrawn from the washing station 16 through a line 18 for further processing in accordance with the present invention.
- the oil-in-water emulsion, of whatever source is introduced into a treating vessel 20, together with an electrolyte, such as sodium nitrite, which is added by means of a line 21.
- An adsorbent clay material, such as bentonite is added to the vessel 20 through a line 22.
- the resulting contents of the vessel 20 are then thoroughly agitated by means of compressed air introduced near the bottom through a header 23 and through upwardly directed discharge nozzles 24 spaced along the length of the header.
- the vessel 20 is also provided with a bottom discharge outlet 25 from which a pump 26 pumps settled material for discharge through piping 27.
- the vessel 20 is further provided near its top with a swivel draw-off pipe 28, swiveled at its upper end, as at 29, to permit the lower end 36 thereof to be raised or lowered.
- the draw-off pipe 28 is connected through a pipe to a pump 31 which serves to draw off supernatant liquid from the vessel 20 by means of a pump 31.
- the oil-free water which is thus withdrawn can be pumped back into the washing station or it can be discharged directly into the sewer since it is quite innocuous.
- the air is shut off and the contents of the vessel are allowed to remain quiescent for a number of hours, usually overnight or for an equivalent length of time.
- a lower layer 33 which is a relatively heavy pumpable slurry of adsorbent material and of the material adsorbed thereon, including oily materials and coloring matter, and a relatively thin supernatant layer 34 which may be in the nature of a scum ⁇ of foreign oatable solids and contaminants brought to the surface with air bubbles from the header 23.
- This layer of scum may be easily skimmed off.
- a main body layer 35 which is of considerable depth, consists largely of water containing water soluble organic materials from the penetrant referred to herein as water miscible organic solvents. The water in the layer 35 is of sucient purity for reuse at the Washing station.
- the water containing water miscible organic solvents is drawn off through the swivel draw-off pipe 28 until a level of the water reaches about that of the level of the slurry, or the free flowing slurry may be pumped out in advance of drawing otf the water layer 35.
- the pump 31 serves to draw the water out through the swivel draw-off pipe 28 from the various depths to which the open end 36 of the draw-olf pipe is lowered (as indicated by the pipe 28 in dotted lines) into the pipe 32 for further disposition.
- the purpose of the electrolyte is to aid in causing the adsorbent material to settle out as completely as possible and leave a main layer 35 of clear liquid.
- Sodium nitrite is the preferred electrolyte because it is also a corrosion inhibitor, but any highly ionizable inorganic salt can be used that will aid in causing an effective settling out of the adsorbent material.
- the adsorbent material it is preferable to use bentonite, but any equivalent oil-adsorbent material having adsorbent properties toward water-immiscible contaminants, such as oil, can be used.
- the adsorbent material during air agitation is thoroughly dispersed and becomes coated with the water-immiscible componentsand with the coloring matter of the penetrant waste liquor.
- the layer 35 has little or no uorescence in cases where uorescent dye is used in the penetrant.
- suicient quantities of sodium nitrite and bentonite are added to give a solution of about 2.5 grams of sodium nitrite per liter, and l0 grams of bentonite per liter of the liquid contents of the vessel 20.
- these respective concentrations of sodium nitrite and bentonite result in a separate layer 35 of water and water-miscible organic solvents of suicient purity so that the resulting water solution can be reused in the washing station, or discharged into water courses.
- the invention provides a closed system wherein a finite volume of water is recycled to the washing station of a penetrant inspection operation from the zone in which, by means of agitation followed by sedimentation, purification is effected through the use of an electrolyte and an adsorbent material to provide a separable layer of water containing organic water-miscible solvents from the penetrant.
- the so separated and recycled water component effects a very considerable economy in the overall operation by reducing the amount of fresh Water required. As much as 60% of the penetrant introduced into the closed system may remain in solution in the system during continued recycling.
- the volume of the slurry of oil and color-contaminated adsorbent material that is removed to waste each time after overnight settling and stratication is somewhere between about 2.5 and 35%, or about 32% of the total volume of the contents of the sedimentation vessel. It is this volume that is replaced at the beginning of the day with a fresh mixture of adsorbent material and electrolyte plus a sufficient volume of water to make up the original volume.
- the make-up volume will vary somewhat depending upon the particular penetrant involved and upon the specic electrolyte and the specic adsorbent material used, but the above gures are illustrative when sodium nitrite and bentonite are employed.
- Other suitable electrolytes are sodium or potassium nitrate, chloride, sulfate, and the like.
- bentonite other oil adsorbent clays and silicates, oil adsorbent aluminas, such as Alon-C, a product of Degaussa Inc., Pigment Division, Kearney, NJ., and oil adsorbent silicas, such as Cab-O-Sil, a pyrogenic silica product of Cabot Corporation can be used.
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Materials By The Use Of Optical Means Adapted For Particular Applications (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Description
H. N. SKOGLUND ET AL. 3,528,284
METHOD FOR PURIFYING PENETRANT WASTE LIQUORS Filed Aug. l, 1969 Sept. 15, 1970 410m PH M o 7- @JMA/@WSH United States Patet ABSTRACT OF THE DISCLOSURE Method for detecting surface discontinuities in objects employing the penetrant-type inspection process wherein the penetrant waste liquor, containing oily penetrant materials, an emulsier and wash water are introduced into an agitation zone where the waste liquor is combined with an electrolyte emulsion breaker and a clay, the mixture is thoroughly agitated, and then stratified to produce a plurality of layers one of which is essentially an oil free layer of water which can be reused in the lwashing zone or disposed of without causing pollution.
CROSS-REFERENCE TO RELATED APPLICATION This application is a continuation-in-part of our Ser.
No. 609,883 filed Jan. 17, 1967, now abandoned.
BACKGROUND OF THE INVENTION Field of the invention This invention is in the field of testing objects for surface discontinuities employing the oily-type dyed penetrant in which the penetrant is either self-emulsiable or is subsequently emulsied to produce a waste liquor which presents disposal problems.
DESCRIPTION OF THE PRIOR ART The penetrant method of flaw detection has been in use since the early 1940s. Basically, the method involves applying an oily penetrant containing either a visible or a fluorescent dye onto the surface of a test piece, removing excess penetrant while leaving the penetrant lodged in any surface flaws which may exist, applying a developer which is typically a particulated material or a suspension of nely divided absorptive particles in a volatile liquid, and then inspecting the part for the presence of flaws. The penetrant is drawn into the developer by capillary action whereupon the indication is enlarged and thereby rendered more readily visible to the inspector, using white light if a visible dye was used, or ultraviolet light where a fluorescent penetrant was used. Processes of this type are described in Switzer Pat. No. 2,259,400 issued Oct. 14, 1941.
Improvements in rendering the penetrants removable by water were effected during the commercialization of this type of process. U.S. Pat. No. 2,405,078 to Ward describes penetrant compositions which contain water emulsiable materials therein so that water alone could be used to effect their removal.
Further improvements in the art were made by De Forest and Parker when, in U.S. Pat. No. 2,806,959 they described a more sensitive system wherein an oily penetrant devoid of emulsifier was employed in combination with a wash water which contained an emulsifier. `Using this system, the emulsier diffused into a superficial portion of the penetrant coating and was thereupon washed away leaving an emulsier free penetrant trapped in the discontinuities which could bleed out to the surface and be detected by the developer.
Whether the emulsifying agent is included in the penetrant, per se, or added as part of the wash water, a penetrant waste liquor is produced which contains an oil-inwater emulsion of the oily constituents of the penetrant, in combination with emulsier, water soluble components of the penetrant and the wash water. Heretofore it has been customary to discharge this penetrant waste liquor from the washing zone in which the emulsion is formed to a sewage system without making any attempt to recover the water content of the waste liquor or to eliminate its oily content. This type of disposal is objectionable for two reasons. For one, the presence of the oily materials in the waste liquor is objectionable from the standpoint of pollution of water courses into which the waste liquor is dumped. In addition, large amounts of water are used for washing purposes in large plants and with rising water costs, the water discharged into the sewer may represent a considerable sum.
It has been proposed to treat the effluent from the washing station to break the oil and water emulsion and thereafter separate the oil from the water by sedimentation or froth flotation techniques. However, such treatments are predicated on the assumption that penetrant wastes can be completely broken down into two non-miscible liquid phases, one water and the other oil. This, however, is not a valid assumption, since most penetrant waste liquors contain organic emulsifiers, such as petroleum sulfonates which are water soluble, or organic solvents that are water miscible. Consequently, penetrant waste liquors as heretofore treated may result in a waste water component that still contains oil and organic materials as contaminants in sucient quantity to strain local sewage treatment facilities.
SUMMARY OF THE INVENTION The present invention resides in a method for detecting surface discontinuities using an oily base penetrant wherein excess penetrant is removed by emulsication with wash water in a washing Zone to produce an oil-inwater emulsion, and the oily components are removed from the emulsion by adding an emulsion breaking electrolyte thereto in combination with an effective amount of a clay capable of forming a slurry with the oily components, agitating the resulting mixture thoroughly, stratifying the resulting admixture into a plurality of layers including a layer of a clay slurry containing oily components adsorbed by the clay and a layer of water containing water miscible penetrant components, and separating the layers. The water layer can be recycled back to the washing stage or it can be discharged directly into the sewage line since it is substantially free from non-biodegradable components.
Other objects, features and advantages of the invention will be readily apparent from the following description of certain preferred embodiments thereof, taken in conjunction with the accompanying drawings, although variations and modifications may be effected without departing from the spirit and scope of the novel concepts of the disclosure, and in which:
FIG. 1A is a schematic representation of the post emulsication process for penetrant inspection;
FIG. 1B is a schematic representation of another type of penetrant inspection process; and
FIG. 2 is a diagrammatic showing of an apparatus 0 for separating the water phase from Hthe oil-in-water emulsion produced by either of the processes shown in FIGS. 1A or 1B.
3 DESCRIPTION OF THE PREFERRED EMBODIMENTS In FIG. 1A reference numeral 10 has been applied to to a penetrant applicator station wherein an oily base penetrant containing either a visible dye or a fluorescent dye is applied to the article to be tested by means of spraying, dipping, painting, or other suitable means of application. After application of the penetrant, the workpiece is passed to a washing station generally indicated at reference numeral 11 where it is subjected to the action of an emulsier introduced into the station 11 through a line 12 and wash water introduced into the washing station 11 through a line 13. The emulsifying composition is applied as a more or less static layer over the penetrant on the surface of the workpiece and migrates into the penetrant to assist in the removal of the excess penetrant. The wash Water is generally applied as a stream to displace the excess penetrant which has become emulsiiied `while leaving an emulsiiied penetrant entrapped in any flaws. After removal of the excess penetrant, the piece is ready for development and inspection in accordance with any of the well known development techniques. The oil-in-water emulsion which results from the interaction of the penetrant, emulsiiier and wash water in washing station 11 is withdrawn from that station and through a line 14 for treatment in accordance with the procedure to be described.
In another form of penetrant inspection process, that shown in FIG. 1B, the workpiece is treated with an emulsitiable penetrant in an applicator station 15. The penetrant treated workpiece is then passed to a washing station 16 where it is subjected to a spray of wash water entering that station through a line 17. The resulting oilin-water emulsion is periodically withdrawn from the washing station 16 through a line 18 for further processing in accordance with the present invention.
The oil-in-water emulsion, of whatever source is introduced into a treating vessel 20, together with an electrolyte, such as sodium nitrite, which is added by means of a line 21. An adsorbent clay material, such as bentonite, is added to the vessel 20 through a line 22. The resulting contents of the vessel 20 are then thoroughly agitated by means of compressed air introduced near the bottom through a header 23 and through upwardly directed discharge nozzles 24 spaced along the length of the header. The vessel 20 is also provided with a bottom discharge outlet 25 from which a pump 26 pumps settled material for discharge through piping 27. The vessel 20 is further provided near its top with a swivel draw-off pipe 28, swiveled at its upper end, as at 29, to permit the lower end 36 thereof to be raised or lowered. The draw-off pipe 28 is connected through a pipe to a pump 31 which serves to draw off supernatant liquid from the vessel 20 by means of a pump 31. The oil-free water which is thus withdrawn can be pumped back into the washing station or it can be discharged directly into the sewer since it is quite innocuous.
After the air agitation and consequent mixing of the contents of the vessel 20, the air is shut off and the contents of the vessel are allowed to remain quiescent for a number of hours, usually overnight or for an equivalent length of time. While in its quiescent state, the mass within the sedimentation vessel 20 stratifies into a lower layer 33 which is a relatively heavy pumpable slurry of adsorbent material and of the material adsorbed thereon, including oily materials and coloring matter, and a relatively thin supernatant layer 34 which may be in the nature of a scum `of foreign oatable solids and contaminants brought to the surface with air bubbles from the header 23. This layer of scum may be easily skimmed off. A main body layer 35 which is of considerable depth, consists largely of water containing water soluble organic materials from the penetrant referred to herein as water miscible organic solvents. The water in the layer 35 is of sucient purity for reuse at the Washing station.
After skimming 0E the layer 34, the water containing water miscible organic solvents is drawn off through the swivel draw-off pipe 28 until a level of the water reaches about that of the level of the slurry, or the free flowing slurry may be pumped out in advance of drawing otf the water layer 35. The pump 31 serves to draw the water out through the swivel draw-off pipe 28 from the various depths to which the open end 36 of the draw-olf pipe is lowered (as indicated by the pipe 28 in dotted lines) into the pipe 32 for further disposition.
The purpose of the electrolyte is to aid in causing the adsorbent material to settle out as completely as possible and leave a main layer 35 of clear liquid. Sodium nitrite is the preferred electrolyte because it is also a corrosion inhibitor, but any highly ionizable inorganic salt can be used that will aid in causing an effective settling out of the adsorbent material. As the adsorbent material, it is preferable to use bentonite, but any equivalent oil-adsorbent material having adsorbent properties toward water-immiscible contaminants, such as oil, can be used. The adsorbent material during air agitation is thoroughly dispersed and becomes coated with the water-immiscible componentsand with the coloring matter of the penetrant waste liquor. Upon settling, there is left a clear intermediate or body layer 35 of water containing water-miscible organic solvents. The layer 35 has little or no uorescence in cases where uorescent dye is used in the penetrant.
As to the concentrations that are employed, suicient quantities of sodium nitrite and bentonite are added to give a solution of about 2.5 grams of sodium nitrite per liter, and l0 grams of bentonite per liter of the liquid contents of the vessel 20. With a penetrant waste liquor containing about 0.1% by weight of total penetrant components, these respective concentrations of sodium nitrite and bentonite result in a separate layer 35 of water and water-miscible organic solvents of suicient purity so that the resulting water solution can be reused in the washing station, or discharged into water courses.
In a typical operation, after overnight sedimentation, the free-flowing slurry of bentonite contaminated with the oily and color constituents of the penetrant Waste liquor is drained or pumped off at the beginning of the day. Layer 35 may be returned to the washing station, together with fresh water equal to the combined volumes of layers 33 and 34, to make up the original volume of the system. The cycle is then repeated.
Where the reclaimed water is reused in the washing station, the invention provides a closed system wherein a finite volume of water is recycled to the washing station of a penetrant inspection operation from the zone in which, by means of agitation followed by sedimentation, purification is effected through the use of an electrolyte and an adsorbent material to provide a separable layer of water containing organic water-miscible solvents from the penetrant. The so separated and recycled water component effects a very considerable economy in the overall operation by reducing the amount of fresh Water required. As much as 60% of the penetrant introduced into the closed system may remain in solution in the system during continued recycling. During such recycling, the volume of the slurry of oil and color-contaminated adsorbent material that is removed to waste each time after overnight settling and stratication is somewhere between about 2.5 and 35%, or about 32% of the total volume of the contents of the sedimentation vessel. It is this volume that is replaced at the beginning of the day with a fresh mixture of adsorbent material and electrolyte plus a sufficient volume of water to make up the original volume.
The make-up volume will vary somewhat depending upon the particular penetrant involved and upon the specic electrolyte and the specic adsorbent material used, but the above gures are illustrative when sodium nitrite and bentonite are employed. Other suitable electrolytes are sodium or potassium nitrate, chloride, sulfate, and the like. Instead of bentonite, other oil adsorbent clays and silicates, oil adsorbent aluminas, such as Alon-C, a product of Degaussa Inc., Pigment Division, Kearney, NJ., and oil adsorbent silicas, such as Cab-O-Sil, a pyrogenic silica product of Cabot Corporation can be used.
We claim as our invention:
1. In the method of detecting surface discontinuities wherein an oily base penetrant is applied to a workpiece and excess penetrant is removed by emuls'ification with wash water in a washing zone to produce an oil-in-water emulsion, the steps of removing oily components from said emulsion which comprise charging said emulsion into an agitation zone, incorporating into said emulsion an effective amount of an electrolyte capable of breaking said emulsion and an effective amount of a clay capable of forming a slurry with the oily components of said penetrant in said emulsion, thoroughly mixing said emulsion, said electrolyte and said clay in said agitation zone, stratifying the resulting admixture into a plurality of layers including a layer of a clay slurry containing oily components adsorbed by said clay and a layer of water containing water miscible penetrant components, separating said layers and recirculating said layer of water back to said washing zone.
2. The method of claim 1 in which said electrolyte is an inorganic salt and said clay is bentonite.
3. The method of claim 1 in which said penetrant as applied to said workpiece contains anemulsifying agent.
4. The method of claim 1 in which said penetrant as applied to said workpiece is devoid of an emulsier and the emulsier is added in said washing zone.
5. The method of claim 1 in which said electrolyte is sodium nitrite and said clay is bentonite.
l6. The method of claim 1 in which said agitation is eected by passing air through the mixture in said agitation zone.
References Cited UNITED STATES PATENTS y2,281,759 5/ 1942 Gelder 210-49 X 2,711,978 6/1955 Groom 134-10 2,806,959 9/1957 Forest et al. 73-104 X 2,953,530 9/1960 Switzer 73-104 X 3,025,190 3/1962 Groom et al. 134-10 3,252,899 5/1966 Rice 210-52 X SAMIH N. ZAHARNA, Primary Examiner U.S. Cl. X.R.
ZIO-49, 60, 83, 167
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US84673669A | 1969-08-01 | 1969-08-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3528284A true US3528284A (en) | 1970-09-15 |
Family
ID=25298797
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US846736A Expired - Lifetime US3528284A (en) | 1969-08-01 | 1969-08-01 | Method for purifying penetrant waste liquors |
Country Status (1)
Country | Link |
---|---|
US (1) | US3528284A (en) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3852163A (en) * | 1972-03-10 | 1974-12-03 | Dow Chemical Co | Spent dye liquor clean-up and vehicle recovery |
US3926044A (en) * | 1974-01-11 | 1975-12-16 | James R Alburger | Closed-loop water-washable inspection penetrant process |
US3948092A (en) * | 1974-10-08 | 1976-04-06 | Alburger James R | Method of recovering and re-cycling water-washable inspection penetrants |
US3949601A (en) * | 1974-01-11 | 1976-04-13 | Alburger James R | Open-loop water-washable inspection penetrant process |
US4600501A (en) * | 1983-11-22 | 1986-07-15 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Energy, Mines And Resources | Process for breaking emulsions produced during recovery of bitumens and heavy oils |
US4836921A (en) * | 1987-01-30 | 1989-06-06 | Magnaflux Corporation | Waste water treatment apparatus |
DE4115686A1 (en) * | 1991-05-14 | 1992-04-02 | Leuck Karl Heinz | Thermal treatment of washing water from dye-penetrant crack detection - contaminated water is heated to breakdown emulsifiers etc. and separates by gravity into clean water with floating oily phase |
US5308503A (en) * | 1988-11-21 | 1994-05-03 | Pegasus Separation Ab | Purification of industrial lubricating agents |
US5352335A (en) * | 1992-11-09 | 1994-10-04 | Albemarle Corporation | Groundwater treatment process |
US20060144994A1 (en) * | 2002-08-30 | 2006-07-06 | Peter Spirov | Homeostatic flying hovercraft |
US9004973B2 (en) | 2012-10-05 | 2015-04-14 | Qfo Labs, Inc. | Remote-control flying copter and method |
US10258888B2 (en) | 2015-11-23 | 2019-04-16 | Qfo Labs, Inc. | Method and system for integrated real and virtual game play for multiple remotely-controlled aircraft |
US11712637B1 (en) | 2018-03-23 | 2023-08-01 | Steven M. Hoffberg | Steerable disk or ball |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2281759A (en) * | 1935-10-29 | 1942-05-05 | Paul Bechtner | Sewage treatment |
US2711978A (en) * | 1951-08-08 | 1955-06-28 | Groom Reginald William | Means for cleaning surfaces of oil and oily deposits and for reclaiming the liquid used in cleaning |
US2806959A (en) * | 1954-07-26 | 1957-09-17 | Switzer Brothers Inc | Method of detecting surface discontinuities |
US2953530A (en) * | 1955-10-12 | 1960-09-20 | Switzer Brothers Inc | Method and compositions for detecting flaws |
US3025190A (en) * | 1958-02-27 | 1962-03-13 | Internat Groom Company G M B H | Method of, and compositions for use in, cleansing the interior surfaces of tanks and the like |
US3252899A (en) * | 1964-04-01 | 1966-05-24 | Gen Services Company | Treatment of water utilizing activated carbon |
-
1969
- 1969-08-01 US US846736A patent/US3528284A/en not_active Expired - Lifetime
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2281759A (en) * | 1935-10-29 | 1942-05-05 | Paul Bechtner | Sewage treatment |
US2711978A (en) * | 1951-08-08 | 1955-06-28 | Groom Reginald William | Means for cleaning surfaces of oil and oily deposits and for reclaiming the liquid used in cleaning |
US2806959A (en) * | 1954-07-26 | 1957-09-17 | Switzer Brothers Inc | Method of detecting surface discontinuities |
US2953530A (en) * | 1955-10-12 | 1960-09-20 | Switzer Brothers Inc | Method and compositions for detecting flaws |
US3025190A (en) * | 1958-02-27 | 1962-03-13 | Internat Groom Company G M B H | Method of, and compositions for use in, cleansing the interior surfaces of tanks and the like |
US3252899A (en) * | 1964-04-01 | 1966-05-24 | Gen Services Company | Treatment of water utilizing activated carbon |
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3852163A (en) * | 1972-03-10 | 1974-12-03 | Dow Chemical Co | Spent dye liquor clean-up and vehicle recovery |
US3926044A (en) * | 1974-01-11 | 1975-12-16 | James R Alburger | Closed-loop water-washable inspection penetrant process |
US3949601A (en) * | 1974-01-11 | 1976-04-13 | Alburger James R | Open-loop water-washable inspection penetrant process |
US3948092A (en) * | 1974-10-08 | 1976-04-06 | Alburger James R | Method of recovering and re-cycling water-washable inspection penetrants |
US4600501A (en) * | 1983-11-22 | 1986-07-15 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Energy, Mines And Resources | Process for breaking emulsions produced during recovery of bitumens and heavy oils |
US4836921A (en) * | 1987-01-30 | 1989-06-06 | Magnaflux Corporation | Waste water treatment apparatus |
US5308503A (en) * | 1988-11-21 | 1994-05-03 | Pegasus Separation Ab | Purification of industrial lubricating agents |
US5611919A (en) * | 1988-11-21 | 1997-03-18 | Alfa Laval Separation Ab | Purification of industrial lubricating agents |
DE4115686A1 (en) * | 1991-05-14 | 1992-04-02 | Leuck Karl Heinz | Thermal treatment of washing water from dye-penetrant crack detection - contaminated water is heated to breakdown emulsifiers etc. and separates by gravity into clean water with floating oily phase |
US5352335A (en) * | 1992-11-09 | 1994-10-04 | Albemarle Corporation | Groundwater treatment process |
US20060144994A1 (en) * | 2002-08-30 | 2006-07-06 | Peter Spirov | Homeostatic flying hovercraft |
US20080223993A1 (en) * | 2002-08-30 | 2008-09-18 | Peter Spirov | Homeostatic flying hovercraft |
US7931239B2 (en) | 2002-08-30 | 2011-04-26 | Brad Pedersen | Homeostatic flying hovercraft |
US20110204187A1 (en) * | 2002-08-30 | 2011-08-25 | Peter Spirov | Homeostatic Flying Hovercraft |
US9073532B2 (en) | 2002-08-30 | 2015-07-07 | Qfo Labs, Inc. | Homeostatic flying hovercraft |
US9645580B2 (en) | 2002-08-30 | 2017-05-09 | Qfo Labs, Inc. | Radio-controlled flying craft |
US9904292B2 (en) | 2002-08-30 | 2018-02-27 | Qfo Labs, Inc. | Method for operating a radio-controlled flying hovercraft |
US9004973B2 (en) | 2012-10-05 | 2015-04-14 | Qfo Labs, Inc. | Remote-control flying copter and method |
US9011250B2 (en) | 2012-10-05 | 2015-04-21 | Qfo Labs, Inc. | Wireless communication system for game play with multiple remote-control flying craft |
US10307667B2 (en) | 2012-10-05 | 2019-06-04 | Qfo Labs, Inc. | Remote-control flying craft |
US10258888B2 (en) | 2015-11-23 | 2019-04-16 | Qfo Labs, Inc. | Method and system for integrated real and virtual game play for multiple remotely-controlled aircraft |
US11712637B1 (en) | 2018-03-23 | 2023-08-01 | Steven M. Hoffberg | Steerable disk or ball |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3528284A (en) | Method for purifying penetrant waste liquors | |
US3301779A (en) | Process for treating cold rolling mill effluent containing oil emulsified in water | |
US5199997A (en) | Treatment of hydrocarbon-contaminated particulate materials | |
US3884803A (en) | Process for separating low api gravity oil from water | |
DE3831023A1 (en) | METHOD FOR PROCESSING AND REUSING POLLUTED PLASTIC PRODUCTS | |
US3767571A (en) | Oil removal from waste waters | |
ATE241046T1 (en) | METHOD AND DEVICE FOR SKIMMING A FLOATING SURFACE LAYER OF A WATER SURFACE | |
ATE80813T1 (en) | METHOD AND DEVICE FOR SEPARATING THE COMPONENTS OF EMULSION-CONTAINING WASTEWATER BY MEANS OF AGITATED FLOTATION. | |
SU434639A3 (en) | ||
US3764265A (en) | Method for the removal of penetrants in a closed system | |
DE3328264C2 (en) | ||
DE59301241D1 (en) | Process for the treatment of oil-water emulsions, in particular from car washes | |
ATE121144T1 (en) | METHOD FOR DEOILING SMALL SOLID PARTICLES, IN PARTICULAR PRODUCTION RESIDUE CONTAINING METAL AND CONTAMINATED SOILS. | |
CN213506102U (en) | Oily sewage treatment system | |
US3949601A (en) | Open-loop water-washable inspection penetrant process | |
US1920565A (en) | Separation of mixtures of water with oil | |
DE3540256C2 (en) | ||
JPH09176659A (en) | Method for purifying oil-containing sludge | |
EP1151179B1 (en) | Removal of oil and chloride from oil contaminated material | |
RU2263900C1 (en) | Method of capillary nondestructive testing | |
CA1149305A (en) | Contactor process | |
Eliassen et al. | Grease removal by vacuum flotation | |
JP2004130292A (en) | Waste liquid treatment tank for flaw detection of metal surface and treatment method | |
RU2049871C1 (en) | Method for sand cleaning from oil and oil products | |
JP3721491B2 (en) | Method for cleaning contaminated soil with petroleum compounds |