US3495983A - Photosolubilization process using phenols as dmax maintainers - Google Patents
Photosolubilization process using phenols as dmax maintainers Download PDFInfo
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- US3495983A US3495983A US653590A US3495983DA US3495983A US 3495983 A US3495983 A US 3495983A US 653590 A US653590 A US 653590A US 3495983D A US3495983D A US 3495983DA US 3495983 A US3495983 A US 3495983A
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- silver halide
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/492—Photosoluble emulsions
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/38—Fixing; Developing-fixing; Hardening-fixing
Definitions
- the invention of this application is concerned with a process of forming a silver halide image by selectively exposing a photosoluble silver halide layer and dissolving the exposed photosoluble silver halide in a silver halide solvent, said process being characterized by having present, during treatment in the solvent, a D -maintaining amount of a phenolic compound devoid of ionizable iodine, or oxidizing or reducing groups which are active at the working pH, preferably a mononuclear phenol having a hydrocarbon substitutent in the o-position selected from the group consisting of o-phenylphenol and o-allylphenol.
- This invention relates to a process for forming images from photosoluble (photosolubilizable) silver halide layers.
- the present invention constitutes an improvement in a silver halide photosolubilization process by the use of a phenolic compound adjuvant which helps to prevent dissolution of silver halide in unexposed areas while allowing dissolution to proceed in the exposed areas. Because of this characteristic, the adjuvant can be characterized as a maximum density maintainer, or D maintainer.
- This invention pertains to an improvement in a photosolubilization process of forming -a direct positive silver halide image which process comprises (a) exposing, imagewise, a photosoluble layer containing silver halide made relatively less soluble in a silver halide solvent by treatment with an organic compound containing sulfur and/ or nitrogen, and capable of form- 3,495,983 Patented Feb. 17, 1970 ing a silver salt of lower solubility in Water than silver chloride, and
- the improvement being characterized by the presence while said layer is in the bath at pH 4-11, preferably 7-10, of D -maintaining amounts of an aromatic hydroxy compound having at least one benzene ring containing a phenolic hydroxyl group, including unsubstituted phenol and naphthols and said compounds substituted with alkyl, e.g., methyl, ethyl, and isopropyl; vinyl, allyl; alkoxy, e.g., methoxy; carboxy; benzoyl, or aryl, e.g., phenyl, or a hydrolyzable precursor of the compound,
- a photosoluble silver halide layer as defined in Blake US. 3,155,- 519, preferably a layer of silver chloride emulsion insolubilized with 2-mercapto-4-phenylthiazole or a related mercaptan as disclosed in said patent is prepared.
- the element may advantageously have a photographic optical sensitizing dye associated with its silver halide crystals as disclosed in assignees copending application of Blake, U.S. Ser. No. 390,460, filed Aug. 18, 1964 (US.
- the photosoluble layer is exposed, imagewise, to actinic radiation and then treated in an aqueous bath comprising from 0.1 to 2 moles per liter of a thiosulfate, e.g., sodium thiosulfate, silver halide solvent and a phenolic D maintainer as defined above.
- a particularly preferred D maintainer is o-phenylphenol in a concentration of 0.1 to 1.0 g./liter, preferably from .4 to .6 g./liter.
- the time and temperature of treatment in the aqueous bath are obviously dependent variables but at a temperature of 70 F. the time should be about 1 to 5 minutes.
- This treatment removes silver halide from the exposed areas at a much faster rate than from the unexposed areas, leaving a positive silver halide image.
- the presence of an organic compound such as o-phenylphenol further lowers the rate of dissolution of the unexposed silver halide, relative to that of the exposed silver halide, contributing to better image formation, especially to higher densities in unexposed areas.
- a useful positive image can be produced, particularly for viewing by projection, by this single treatment, although a washing step is generally used.
- it is desirable to intensify the silver halide image usually by treating with a photographic silver halide developer solution to reduce the image to one of black metallic silver.
- the silver halide image may be fogged prior to reduction by flashing to white light or, more conveniently, by use of a prefogged element such as described in assignees copending applications, Blake U.S. Ser. No. 629,426 filed Apr. 10, 1967 and Haugh U.S. Ser. No. 478,421 filed Aug. 9, 1965.
- Other methods of intensifying the silver halide image e.g., by toning, color developing, etc., are disclosed in US. 3,155,507.
- any of the various photosoluble silver halide elements described in the U.S. Patents and Blake and Haugh applications listed above can be used in the process of this invention. These, of course, may be modified as described in the patents and applications by variations in the silver halide, the binder (if present), the organic compounds for insolubilization of silver halide (whose utility can be established by the simple tests defined therein for determination of other useful compounds), the adjuvants generally employed in silver halide systems, the supports, and in the relative concentrations of the various components.
- Various auxiliary layers may be present, such as abrasion over-coatings, subbing layers, and antihalation undercoats or backing layers.
- the elements may include multilayer as well as monolayer structures.
- the various layers, including the support may include inert ingredients, e.g., pigments, organic polymer latices, and matting agents.
- inert ingredients e.g., pigments, organic polymer latices, and matting agents.
- the silver halide may be insolubilized by treatment with an appropriate organic compound either during emulsion manufacture or by treatment of the coated element with a solution of the organic compound.
- the phenolic compound should be devoid of ionizable iodine because the iodide ion readily replaces the organic compound of step (a) to form silver iodide; it should be devoid of oxidizing groups because these tend to oxidize the silver salts of organic compound of step (a) so that exposed and unexposed areas cannot be easily distinguished in terms of their rates of solution in a silver halide solvent.
- the dissolution developer i.e., the solution of silver halide solvent
- the essential components for this invention are water, silver. halide solvent and a D maintainer. Numerous useful silver halide solvents are given in US. Patent 3,155,507 but in this application the use of preferred silver halide solvents containing the thiosulfate anion will be described.
- EXAMPLE I A light-sensitive gelatino-silver chloride coagulum, made by precipitation and coagulation washing in the manner taught in Moede, U .8. Patent 2,772,165, was redispersed in an aqueous gelatin solution so as to achieve a gelatin to silver chloride weight ratio of 0.79. The resulting emulsion was digested at 170 F. for 20 minutes in the presence of 0.80 g. of Z-mercapto-4-phenylthiazole and 0.025 g. of the dye of Example I of Kendall 2,342,- 546 per mole of silver chloride.
- emulsion adjuvants were added, including gelatin hardening agents and coating aids, and the emulsion was coated on a vinylidene chloride copolymer subbed polyester base prepared as described in Example IV of Alles, US. Patent 2,779,- 684 (and to which a gelatin sub-layer had been subsequently applied).
- the coating weight was 46 mg./dn'1. calculated as metallic silver.
- a sample of the dried photosoluble film was exposed through a /2 stepwedge for 15 seconds a 24 inches distance from a high intensity, tungsten filament, incandescent lamp (General Electric Reflector Photoflood lamp, N0. PH/RFL 2).
- the exposed film serving as a control, was then processed for 3 minutes at 68 F. in a dissolution developer consisting of an aqueous solution containing 57.5 g./liter of sodium thiosulfate adjusted to a pH of 9.0 with 3 N H 80
- a second sample of the identically exposed film was treated similarly except that, per liter of dissolution developer, there was added 10 ml.
- the films were then washed in water for 3 minutes and dried in air.
- the intensified metallic silver image of the control film had a maximum transmission optical density of 2.94 while the film treated with D maintainer had a densty of over 4.0, i.e., a density greater than could be detected by the densitometer.
- the minimum densities were approximately the same (about 0.04) in both films. Also the contrasts were essentially identical in the two films.
- Example II Example I was repeated except that both the control and the experimental dissolution developers (i.e., the aqueous solutions of silver halide solvent) contained additionally 4.5 g./liter of anhydrous Na SO Both solutions were adjusted to pH 9.0 with 3 N H SO
- the film processed in the solution containing o-phenylphenol again had a D above but increased in apparent positive speed, i.e., optical densities began decreasing at steps corresponding to lower exposure, than the films in Example I.
- the D was only 0.2 but an image was visible.
- EXAMPLE III The following silver halide solvent solution was prepared for use as a dissolution developer.
- the above solution was diluted with an equal volume of water (as a control) or with an equal volume of aqueous solution containing an organic compound as a D maintainer as noted in the table above.
- a number of D maintainers were tested by using such solutions in processing exposed film samples as described in Example I.
- the samples were processed in solutions containing the Dmg,x maintainers at pH of 6.0, some at a concentration of 0.05 and others at a concentration of 0.1% by weight, processing for 2 minutes at 68 F.
- the films were then washed, intensified, washed again and dried as in Example I.
- the eifectiveness of the D maintainer is indicated by the increase in D (optical transmission density) over the control (D 1.36).
- a photosoluble element was prepared by coating an aqueous gelatin dispersion of a spectrally sensitized silver chlorobromide (70 mole percent silver chloride and 30 mole percent silver bromide) which contained 0.67 gram of the insolubilizer, 2-mercapto-4-cyclohexylthiazole, per mole of silver halide, and the merocyanine dye of Example I of Kendall U.S.P. 2,342,546 on the film base described in Example I. The dried element was then exposed behind a V2 stepwedge for 5 seconds to the light source of Example I at a distance of about 20 inches.
- a spectrally sensitized silver chlorobromide 70 mole percent silver chloride and 30 mole percent silver bromide
- the dried element was then exposed behind a V2 stepwedge for 5 seconds to the light source of Example I at a distance of about 20 inches.
- Exposed elements were immersed in a dissolution developer (compositions shown in Table II) for 30 seconds and 3 minutes, rinsed in water, reexposed, and bathed in a metol-hydroquinone intensifier (conventional photographic developer).
- a dissolution developer compositions shown in Table II
- the dissolution developers A and D serve as controls at pH l-(l-napthyl)-2-thiourea per mole of silver chloride was substituted for the benzoxazolethiol.
- EXAMPLE VII A photosoluble element, with S-nitrobenzimidazole as insolubilizer, was prepared as described in Example VI of US. Patent 3,155,507. Film samples of the element were exposed and processed as in Example IV.
- EXAMPLE VIII A photographic element was prepared by coating an aqueous gelatin dispersion of silver bromochloride (30 mole percent silver bromide and 70 mole percent silver chloride) on a film base prepared as in Example IV of Alles U.S.P. 2,779,684. After drying, the film was soaked for 30 seconds in a solution of 0.15 g. of 2,5- dimercapto-l,3,4-thiadiazole in 500 ml. ethanol-water solution (17 parts ethanol-3 parts water) to produce a photosoluble element. Exposure and processing were as The maximum transmission optical densities were then determined and are listed below.
- EXAMPLE V A photosoluble element was prepared by coating an aqueous gelatin dispersion of a spectrally sensitized silver chloride which contained 1.18 grams of benzoxazolethiol per mole of silver chloride as insolubilizer and the merocyanine dye of Example I of Kendall U.S.P. 2,342,546 on the film base of Example I. The drided element was then exposed and processed as in Example IV.
- Example V was repeated except that 2.4 grams of Dmax after described in Example IV with exposure times as indicated.
- the color coupling developer solutions contained paminodiethylaniline hydrochloride as the silver halide developing agent.
- the color coupler for the cyan developer solution was 2,4-dichloro-l-naphthol; for the yellow developer solution the color coupler was 2-methoxy-5- methacrylamido-Z-benzoylacetanilide.
- the active agents were, respectively, K Fe(CN) and Na S O In both samples a multicolor image resulted from the superimposing of a negative-positive cyan image and a positive yellow image. At the low exposure steps, the image was yellow.
- the sample processed with the D maintainer (ophenylphenol) exhibited an effective speed increase of three steps in the positive, high exposure (pure cyan) region of the image. This sample also showed better color difierentiation from step to step which is equivalent to more effective conveyance of information.
- the increased positive speed is probably attributable to the high pH of the silver halide solvent solution (the first processing solution). Processing at such a high pH (9.0) in the abesnce of the D maintainer would have resulted in very severe loss of image density.
- EXAMPLE X A silver chloride emulsion was prepared as described in Example I. Before coating, the emulsion was divided into a number of separate portions and various D maintainers were added, from siutable solvents, in the concentrations (expressed as grams of D maintainer per mole of AgCl) indicated in the table below. The portions were then coated as in Example I to give coating weights of 37 mg./dm. calculated as metallic silver. Samples of the coated films were exposed and treated for 2 minutes in the silver halide solvent solution used for the control film sample of Example IX to form positive silver chloride images.
- the present invention has the advantages of the basic process of photosolubilization, especially that of a very simple, single step process of obtaining a positive image.
- Advantages over the basic process include increased optical densities in unexposed or lightly exposed areas, both for silver halide images and for intensified images.
- processing is simpler because the D maintainers make the effects of such variables as concentration of silver halide solvent, solution pH, processing times and temperatures less critical.
- the D maintainers often increase contrast and apparent speed although decreases iri one or both of these variables sometimes occur.
- Another method is available for controlling speed and contrast. Still other advantages will be apparent from the above description of the invention.
- a photosolubilization process for forming a directpositive silver halide image which comprises:
- said process being characterized by the presence while said layer is in said bath, at a predetermined pH, of D -maintaining amounts of an aromatic hydroxy compound containing at least one phenolic hydroxy group selected from the class consisting of unsubstituted phenol and naphthols and their alkyl; vinyl; allyl; alkoxy, carboxy, benzoyl, and aryl substituted derivatives, and their hydrolyzable precursors,
- said aromatic hydroxyl compound being present in the range of 0.1 to 20 g./liter of the aqueous bath, to retard solution of the unexposed silver halide.
- a process according to claim 2 wherein said aromatic hydroxyl compound is o-phenylphenol.
- step (a) is present in such an amount, in terms of the ratio of its weight to the surface area of the silver halide crystals, that when admixed in such ratio with an aqueous silver bromochloride, 30/70 mole percent, gelatin dispersion containing 0.29 mg. of Ag in one-half ml., and said silver bromochloride dispersion is treated with 10% by weight aqueous sodium thiosulfate, so that the resulting mixture contains 0.29 mg. of Ag and 100 mg.
- a photosoluble layer containing light-sensitive silver halide made less soluble in a silver halide solvent by treatment with an organic compound containing sulfur and/or nitrogen and capable of forming a silver salt of lower solubility in water than silver chloride, said layer containing in addition a different auxiliary organic compound and which is a phenolic compound devoid of ionizable iodine, or oxidizing or reducing gI'Oups which are active at the working pH, in sufiicient quantity to further retard solution of unexposed silver halide in said layer.
- auxiliary compound is an aromatic hydroxyl compound containing at least one phenolic hydroxyl group, said compound being selected from the class consisting of unsubstituted phenol and naphthols and their alkyl, vinyl, allyl, alkoxy, carboxy, benzoyl and aryl-substituted derivatives and their hydrolyzable precursors.
- a layer according to claim 7 wherein said auxiliary compound is o-phenylphenol.
- a layer according to claim 7 wherein said auxiliary compound is o-allylphenol.
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Description
United States Patent 3,495,983 PHOTOSOLUBILIZATION PROCESS USING PHENOLS AS D MAINTAINERS Jack Freshwater Strange, Highstown, N.J., assignor to E. I. du Pont de Nemours and Company, Wilmington, Del., a corporation of Delaware No Drawing. Filed June 23, 1967, Ser. No. 653,590 Int. Cl. G03c 1/02, 5/26, 5/30 US. C]. 96-64 11 Claims ABSTRACT OF THE DISCLOSURE The invention of this application is concerned with a process of forming a silver halide image by selectively exposing a photosoluble silver halide layer and dissolving the exposed photosoluble silver halide in a silver halide solvent, said process being characterized by having present, during treatment in the solvent, a D -maintaining amount of a phenolic compound devoid of ionizable iodine, or oxidizing or reducing groups which are active at the working pH, preferably a mononuclear phenol having a hydrocarbon substitutent in the o-position selected from the group consisting of o-phenylphenol and o-allylphenol.
CROSS-REFERENCE TO RELATED APPLICATION In assignees copending application of Ralph Kingsley Blake (P-DC-1034) entitled Improvement in Photosolubilization Image Formation, executed on even date with this application, there is described and claimed a similar process disclosing various other D maintainers. The phenolic D maintainers of this invention, in general, are equal to or superior to the preferred adjuvants of the Blake application.
BACKGROUND OF THE INVENTION Field of the invention This invention relates to a process for forming images from photosoluble (photosolubilizable) silver halide layers. The present invention constitutes an improvement in a silver halide photosolubilization process by the use of a phenolic compound adjuvant which helps to prevent dissolution of silver halide in unexposed areas while allowing dissolution to proceed in the exposed areas. Because of this characteristic, the adjuvant can be characterized as a maximum density maintainer, or D maintainer.
Description of the prior art Photosolubilization image-forming process and photosoluble layers and elements useful in the basic process are described in US. Patents 3,155,507 and 3,155,5149, Nov. 3, 1964, Blake application U.S. Ser. No. 629,426, filed Apr. 10, 1967, and Haugh U.S. Ser. No. 478,421, filed Aug. 9, 1965. In these patents and applications there are described simple and useful layers and processes for obtaining a positive silver halide image in a single processing step. Intensification of the image, e.g., by reduction to a black metallic silver image, constitutes an additional optional step.
SUMMARY OF THE INVENTION This invention pertains to an improvement in a photosolubilization process of forming -a direct positive silver halide image which process comprises (a) exposing, imagewise, a photosoluble layer containing silver halide made relatively less soluble in a silver halide solvent by treatment with an organic compound containing sulfur and/ or nitrogen, and capable of form- 3,495,983 Patented Feb. 17, 1970 ing a silver salt of lower solubility in Water than silver chloride, and
(b) dissolving the exposed silver halide in a silver halide solvent comprising an aqueous bath of an alkali metal or ammonium thiosulfate,
the improvement being characterized by the presence while said layer is in the bath at pH 4-11, preferably 7-10, of D -maintaining amounts of an aromatic hydroxy compound having at least one benzene ring containing a phenolic hydroxyl group, including unsubstituted phenol and naphthols and said compounds substituted with alkyl, e.g., methyl, ethyl, and isopropyl; vinyl, allyl; alkoxy, e.g., methoxy; carboxy; benzoyl, or aryl, e.g., phenyl, or a hydrolyzable precursor of the compound,
' e.g., formate or acetate, the phenolic compound being DESCRIPTION OF THE PREFERRED EMBODIMENTS In practicing the process of the invention, a photosoluble silver halide layer as defined in Blake US. 3,155,- 519, preferably a layer of silver chloride emulsion insolubilized with 2-mercapto-4-phenylthiazole or a related mercaptan as disclosed in said patent is prepared. The element may advantageously have a photographic optical sensitizing dye associated with its silver halide crystals as disclosed in assignees copending application of Blake, U.S. Ser. No. 390,460, filed Aug. 18, 1964 (US. Patent 3,384,485, May 21, 1968.) The photosoluble layer is exposed, imagewise, to actinic radiation and then treated in an aqueous bath comprising from 0.1 to 2 moles per liter of a thiosulfate, e.g., sodium thiosulfate, silver halide solvent and a phenolic D maintainer as defined above. A particularly preferred D maintainer is o-phenylphenol in a concentration of 0.1 to 1.0 g./liter, preferably from .4 to .6 g./liter. The time and temperature of treatment in the aqueous bath are obviously dependent variables but at a temperature of 70 F. the time should be about 1 to 5 minutes. This treatment removes silver halide from the exposed areas at a much faster rate than from the unexposed areas, leaving a positive silver halide image. The presence of an organic compound such as o-phenylphenol further lowers the rate of dissolution of the unexposed silver halide, relative to that of the exposed silver halide, contributing to better image formation, especially to higher densities in unexposed areas. A useful positive image can be produced, particularly for viewing by projection, by this single treatment, although a washing step is generally used. For most purposes, it is desirable to intensify the silver halide image, usually by treating with a photographic silver halide developer solution to reduce the image to one of black metallic silver. The silver halide image may be fogged prior to reduction by flashing to white light or, more conveniently, by use of a prefogged element such as described in assignees copending applications, Blake U.S. Ser. No. 629,426 filed Apr. 10, 1967 and Haugh U.S. Ser. No. 478,421 filed Aug. 9, 1965. Other methods of intensifying the silver halide image, e.g., by toning, color developing, etc., are disclosed in US. 3,155,507.
Any of the various photosoluble silver halide elements described in the U.S. Patents and Blake and Haugh applications listed above can be used in the process of this invention. These, of course, may be modified as described in the patents and applications by variations in the silver halide, the binder (if present), the organic compounds for insolubilization of silver halide (whose utility can be established by the simple tests defined therein for determination of other useful compounds), the adjuvants generally employed in silver halide systems, the supports, and in the relative concentrations of the various components. Various auxiliary layers may be present, such as abrasion over-coatings, subbing layers, and antihalation undercoats or backing layers. The elements may include multilayer as well as monolayer structures. The various layers, including the support, may include inert ingredients, e.g., pigments, organic polymer latices, and matting agents. As disclosed in US. 3,155,507, the silver halide may be insolubilized by treatment with an appropriate organic compound either during emulsion manufacture or by treatment of the coated element with a solution of the organic compound.
The phenolic compound should be devoid of ionizable iodine because the iodide ion readily replaces the organic compound of step (a) to form silver iodide; it should be devoid of oxidizing groups because these tend to oxidize the silver salts of organic compound of step (a) so that exposed and unexposed areas cannot be easily distinguished in terms of their rates of solution in a silver halide solvent.
The dissolution developer (i.e., the solution of silver halide solvent) may contain adjuvants as given in Example III. The essential components for this invention, however, are water, silver. halide solvent and a D maintainer. Numerous useful silver halide solvents are given in US. Patent 3,155,507 but in this application the use of preferred silver halide solvents containing the thiosulfate anion will be described.
The invention will be further illustrated by but is not intended to be limited to the following examples.
EXAMPLE I A light-sensitive gelatino-silver chloride coagulum, made by precipitation and coagulation washing in the manner taught in Moede, U .8. Patent 2,772,165, was redispersed in an aqueous gelatin solution so as to achieve a gelatin to silver chloride weight ratio of 0.79. The resulting emulsion was digested at 170 F. for 20 minutes in the presence of 0.80 g. of Z-mercapto-4-phenylthiazole and 0.025 g. of the dye of Example I of Kendall 2,342,- 546 per mole of silver chloride. Normal emulsion adjuvants were added, including gelatin hardening agents and coating aids, and the emulsion was coated on a vinylidene chloride copolymer subbed polyester base prepared as described in Example IV of Alles, US. Patent 2,779,- 684 (and to which a gelatin sub-layer had been subsequently applied). The coating weight was 46 mg./dn'1. calculated as metallic silver.
A sample of the dried photosoluble film was exposed through a /2 stepwedge for 15 seconds a 24 inches distance from a high intensity, tungsten filament, incandescent lamp (General Electric Reflector Photoflood lamp, N0. PH/RFL 2). The exposed film, serving as a control, was then processed for 3 minutes at 68 F. in a dissolution developer consisting of an aqueous solution containing 57.5 g./liter of sodium thiosulfate adjusted to a pH of 9.0 with 3 N H 80 A second sample of the identically exposed film was treated similarly except that, per liter of dissolution developer, there was added 10 ml. of a 1 N NaOH solution containing 5% by weight of o-phenylphenol; the solution pH again was adjusted to 9.0 Positive, AgCl images were obtained in both films but the D was greater in the film treated in the o-phenylphenol solution. Both films were given an overall exposure to white light from a suitable lamp after washing in water for 2 minutes and then the images were intensified by treatment for 1 minute in a photographic silver halide developer of the following composition, which had been diluted 1:1 with water before use:
Water ml 750 p-Methylaminophenol sulfate g 3 Na SO (anhyd) g 45 Hydroquinone g 12 Na CO -lH O g 79 KBr g 1.9 Water to make 1 liter.
The films were then washed in water for 3 minutes and dried in air. The intensified metallic silver image of the control film had a maximum transmission optical density of 2.94 while the film treated with D maintainer had a densty of over 4.0, i.e., a density greater than could be detected by the densitometer. The minimum densities were approximately the same (about 0.04) in both films. Also the contrasts were essentially identical in the two films.
EXAMPLE II Example I was repeated except that both the control and the experimental dissolution developers (i.e., the aqueous solutions of silver halide solvent) contained additionally 4.5 g./liter of anhydrous Na SO Both solutions were adjusted to pH 9.0 with 3 N H SO The film processed in the solution containing o-phenylphenol again had a D above but increased in apparent positive speed, i.e., optical densities began decreasing at steps corresponding to lower exposure, than the films in Example I. For the control film, the D was only 0.2 but an image was visible.
EXAMPLE III The following silver halide solvent solution was prepared for use as a dissolution developer.
Water ml-.. 800 N32820:; g Na SO (anhyd) g 15 Na2B407' g 18 Glacial acetic acid ml 12 KAl(SO -12H O g 20 Water to 1 liter. pH adjusted with 3 N NaOH to 6.0.
Prior to use, the above solution was diluted with an equal volume of water (as a control) or with an equal volume of aqueous solution containing an organic compound as a D maintainer as noted in the table above. A number of D maintainers were tested by using such solutions in processing exposed film samples as described in Example I. The samples were processed in solutions containing the Dmg,x maintainers at pH of 6.0, some at a concentration of 0.05 and others at a concentration of 0.1% by weight, processing for 2 minutes at 68 F. The films were then washed, intensified, washed again and dried as in Example I. In the table below, the eifectiveness of the D maintainer is indicated by the increase in D (optical transmission density) over the control (D 1.36).
TABLE I Organic compounds D maintainer: D Control 1.36
Phenol n. 3.0
o-Nitrophenol 3.4 p-Nitrophenol 3.1 3,4-dimethylphenol 4+ l-naphtliol 4+ 2-naphthol 3.8 3,5dinitrosalicylic acid 3.0 Salicylic acid 2.8 m-Hydroxybenzoic acid 2.6
p-Hydroxybenzoic acid 2.5
TABLE IContinued D maintainer: D B-phenylsalicylic acid 2.8 5-phenylsalicylic acid 2.5 p-Phenylphenol 3.0 o-Phenylphenol 4+ Eugenol 3.8 l-naphthyl acetate 3.5 2-naphthyl acetate 3.3
Tetrahydrofurfuryl alcohol+p-phenylphenol 3. 2-allylphenol 3.6
EXAMPLE IV A photosoluble element was prepared by coating an aqueous gelatin dispersion of a spectrally sensitized silver chlorobromide (70 mole percent silver chloride and 30 mole percent silver bromide) which contained 0.67 gram of the insolubilizer, 2-mercapto-4-cyclohexylthiazole, per mole of silver halide, and the merocyanine dye of Example I of Kendall U.S.P. 2,342,546 on the film base described in Example I. The dried element was then exposed behind a V2 stepwedge for 5 seconds to the light source of Example I at a distance of about 20 inches. Exposed elements were immersed in a dissolution developer (compositions shown in Table II) for 30 seconds and 3 minutes, rinsed in water, reexposed, and bathed in a metol-hydroquinone intensifier (conventional photographic developer). As can be seen in Table II, the dissolution developers A and D serve as controls at pH l-(l-napthyl)-2-thiourea per mole of silver chloride was substituted for the benzoxazolethiol.
Dmnx after Dmax after seconds 3 minutes Dissolution developer:
A (control) 0. 4 0.05
1. 39 1.3 D (control) 0.75 0. 13 2. 75 2.
EXAMPLE VII A photosoluble element, with S-nitrobenzimidazole as insolubilizer, was prepared as described in Example VI of US. Patent 3,155,507. Film samples of the element were exposed and processed as in Example IV.
D after Dissolution developer: 30 seconds D (control) 3.1
EXAMPLE VIII A photographic element was prepared by coating an aqueous gelatin dispersion of silver bromochloride (30 mole percent silver bromide and 70 mole percent silver chloride) on a film base prepared as in Example IV of Alles U.S.P. 2,779,684. After drying, the film was soaked for 30 seconds in a solution of 0.15 g. of 2,5- dimercapto-l,3,4-thiadiazole in 500 ml. ethanol-water solution (17 parts ethanol-3 parts water) to produce a photosoluble element. Exposure and processing were as The maximum transmission optical densities were then determined and are listed below.
D m .1. after 30 seconds 3 minutes Dissolution developer:
3% (control) D (control) E When the insolubilizer, Z-mercapto 4-cyclohexylthiazole, was replaced with dodecanethiol or p-bromothiophenol, after 3 minutes of processing increases of D were also observed.
EXAMPLE V A photosoluble element was prepared by coating an aqueous gelatin dispersion of a spectrally sensitized silver chloride which contained 1.18 grams of benzoxazolethiol per mole of silver chloride as insolubilizer and the merocyanine dye of Example I of Kendall U.S.P. 2,342,546 on the film base of Example I. The drided element was then exposed and processed as in Example IV.
D... after Dm after 30 seconds 3 minutes Dissolution developer:
(control 1. 0 0. 29
D (control) 1. 0 0. 08
EXAMPLE VI Example V was repeated except that 2.4 grams of Dmax after described in Example IV with exposure times as indicated.
Exposure Dmux alter (seconds) 40 seconds Dissolution developer:
A (control 5 1. 5 1. 98 D (control) 2 2. 16 2 3. 60
EXAMPLE IX In assignees copending application of Haugh, Ser. No. 546,202, filed Apr. 29, 1966 a process was disclosed whereby a single exposure of a photosoluble element could be followed by the development of superimposed positive and negative images. With one or more color coupling development steps it is possible to obtain various types of unusual images, some of which may have considerably utility. Processing in the presence of the D maintainers of the present invention can provide improvements in the above Haugh process as demonstrated in the following working example:
Samples of the photosoluble film of Example I were exposed through a /2 step wedge as described in that example. A control sample was processed for 2 minutes in the following silver halide solvent solution:
H O ml 800 N32820:; anhyd. g.. Na SO g 7.5 Na B O- g 9 Glacial acetic acid ml 6 g CH COOK g 5 H O t0 1000 ml.
A second sample of the exposed film was processed for 2 minutes in the following silver halide solvent solution:
B to 1000 rnl. 3 N H 80 added to reduce pH to 9.0.
After these treatments in the silver halide solvents, the two film samples were processed identically as follows (all processing steps being carried out at 68 F.):
Minutes Washed in water for 2 Color development in cyan color coupler solution 4 Washed in water for 5 Uniform (excess) exposure to lamp used for imagewise exposureto expose all of the remaining silver halide.
Minutes Color development in yellow color coupler solution 5 Washed in water for 5 Bleach 2 Fix 2 Washed in water for 2 Dry in air.
The color coupling developer solutions contained paminodiethylaniline hydrochloride as the silver halide developing agent. The color coupler for the cyan developer solution was 2,4-dichloro-l-naphthol; for the yellow developer solution the color coupler was 2-methoxy-5- methacrylamido-Z-benzoylacetanilide. In the conventional bleaching and fixing solutions the active agents were, respectively, K Fe(CN) and Na S O In both samples a multicolor image resulted from the superimposing of a negative-positive cyan image and a positive yellow image. At the low exposure steps, the image was yellow. There was a gradual increase of cyan density with increasing exposure so that the image gradually changed from yellow-green to green as the positive yellow component of the image decreased in density. The cyan component of the image reached a peak density at intermediate exposure levels, changing from a negative to a positive image. At higher exposure levels there was a pure cyan positive image, while at the very highest exposure level all of the silver halide had been removed by dissolution development and there was no image present.
The sample processed with the D maintainer (ophenylphenol) exhibited an effective speed increase of three steps in the positive, high exposure (pure cyan) region of the image. This sample also showed better color difierentiation from step to step which is equivalent to more effective conveyance of information. The increased positive speed is probably attributable to the high pH of the silver halide solvent solution (the first processing solution). Processing at such a high pH (9.0) in the abesnce of the D maintainer would have resulted in very severe loss of image density.
EXAMPLE X A silver chloride emulsion was prepared as described in Example I. Before coating, the emulsion was divided into a number of separate portions and various D maintainers were added, from siutable solvents, in the concentrations (expressed as grams of D maintainer per mole of AgCl) indicated in the table below. The portions were then coated as in Example I to give coating weights of 37 mg./dm. calculated as metallic silver. Samples of the coated films were exposed and treated for 2 minutes in the silver halide solvent solution used for the control film sample of Example IX to form positive silver chloride images. These images were intensified by flashing to white light, developing, washing, and drying as described in Example I (using the same p-methylaminophenol sulfate/hydroquinone developer de scribed there- 8 in). From the results given below it is obvious that D maintainers are elfective in the emulsions as well as in the processing solutions and the amounts used are in excess of that used for the photosolubilization effect.
TABLE 3 DE maintainer in emulsion Concentration Dmnx None 3. 36 Catechol 6 4. 0+ 2,4-dihydroxybenzophenon 1. 6 3. 83 Do 3. 1 4. 0+ .3. 2 3. 79 6. 1 3. 99 2 4. 0+ 4 4. 0+
The present invention has the advantages of the basic process of photosolubilization, especially that of a very simple, single step process of obtaining a positive image. Advantages over the basic process include increased optical densities in unexposed or lightly exposed areas, both for silver halide images and for intensified images. Also, processing is simpler because the D maintainers make the effects of such variables as concentration of silver halide solvent, solution pH, processing times and temperatures less critical. The D maintainers often increase contrast and apparent speed although decreases iri one or both of these variables sometimes occur. Thus, by proper selection of the D; maintainer and its concentration, another method is available for controlling speed and contrast. Still other advantages will be apparent from the above description of the invention.
The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. A photosolubilization process for forming a directpositive silver halide image which comprises:
(a) exposing, imagewise, a photosoluble layer containing silver halide made relatively less soluble in a silver halide solvent by treatment with an organic compound containing sulfur and/or nitrogen and capable of forming a silver salt of lower solubility in water than silver chloride, and
(b) dissolving the exposed silver halide in a silver halide solvent comprising an aqueous bath of an alkali metal or ammonium thiosulfate,
said process being characterized by the presence while said layer is in said bath, at a predetermined pH, of D -maintaining amounts of an aromatic hydroxy compound containing at least one phenolic hydroxy group selected from the class consisting of unsubstituted phenol and naphthols and their alkyl; vinyl; allyl; alkoxy, carboxy, benzoyl, and aryl substituted derivatives, and their hydrolyzable precursors,
said aromatic hydroxyl compound being present in the range of 0.1 to 20 g./liter of the aqueous bath, to retard solution of the unexposed silver halide.
2. A process according to claim 1 wherein said aromatic hydroxyl compound is present in said bath initially in the specified quantities.
3. A process according to claim 2 wherein said aromatic hydroxyl compound is o-phenylphenol.
4. A process according to claim 2 wherein said aromatic hydroxyl compound is o-allylphenol.
5. A process according to claim 2 wherein the organic compound of step (a) is present in such an amount, in terms of the ratio of its weight to the surface area of the silver halide crystals, that when admixed in such ratio with an aqueous silver bromochloride, 30/70 mole percent, gelatin dispersion containing 0.29 mg. of Ag in one-half ml., and said silver bromochloride dispersion is treated with 10% by weight aqueous sodium thiosulfate, so that the resulting mixture contains 0.29 mg. of Ag and 100 mg. of sodium thiosulfate, at least three times the amount of silver bromochloride remains undissolved as compared with a similar dispersion successively treated with by weight aqueous sodium hypochlorite and by weight aqueous sodium thiosulfate, so that the result ing mixture contains 0.29 mg. of Ag, 25 mg. of sodium hypochlorite and 100 mg. of sodium thiosulfate, after vigorous agitation of both dispersions for 30 seconds at 25 C.
6. A process according to claim 2 wherein said aromatic hydroxyl compound is l-naphthol.
7. A photosoluble layer containing light-sensitive silver halide made less soluble in a silver halide solvent by treatment with an organic compound containing sulfur and/or nitrogen and capable of forming a silver salt of lower solubility in water than silver chloride, said layer containing in addition a different auxiliary organic compound and which is a phenolic compound devoid of ionizable iodine, or oxidizing or reducing gI'Oups which are active at the working pH, in sufiicient quantity to further retard solution of unexposed silver halide in said layer.
8. A layer according to claim 7 wherein said organic compound is present in such an amount, in terms of the ratio of its weight to the surface area of the silver halide crystals, that when admixed in such ratio with an aqueous silver bromochloride dispersion, 30/70 mole percent, gelatin emulsion containing 0.29 mg. ofAg in one-half ml., and said silver bromochloride dispersion is treated with 10% by weight aqueous sodium thiosulfate, so that the resulting mixture contains 0.29 mg. of Ag and 100 mg. of sodium thiosulfate, at least three times the amount of silver bromochloride remains undissolved as compared with a similar dispersion successively treated with 5% by weight aqueous sodium hypochlorite and 10% by weight aqueous sodium thiosulfate, so that the resulting mixture contains 0.29 mg. of Ag, 25 mg. of sodium hypochlorite and mg. of sodium thiosulfate, after vigorous agitation of both dispersions for 30 seconds at 25 C.
9. A layer according to claim 7 wherein said auxiliary compound is an aromatic hydroxyl compound containing at least one phenolic hydroxyl group, said compound being selected from the class consisting of unsubstituted phenol and naphthols and their alkyl, vinyl, allyl, alkoxy, carboxy, benzoyl and aryl-substituted derivatives and their hydrolyzable precursors.
10. A layer according to claim 7 wherein said auxiliary compound is o-phenylphenol.
11. A layer according to claim 7 wherein said auxiliary compound is o-allylphenol.
References Cited UNITED STATES PATENTS 2,230,977 2/1941 Ham 9666.4 X 3,155,507 11/1964 Blake 9664 NORMAN G. TORCHIN, Primary Examiner R. E. FIGHTER, Assistant Examiner US. Cl. X.R. 96-94
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US64825067A | 1967-06-23 | 1967-06-23 | |
US65359067A | 1967-06-23 | 1967-06-23 | |
US64822967A | 1967-06-23 | 1967-06-23 |
Publications (1)
Publication Number | Publication Date |
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US3495983A true US3495983A (en) | 1970-02-17 |
Family
ID=27417807
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US653590A Expired - Lifetime US3495983A (en) | 1967-06-23 | 1967-06-23 | Photosolubilization process using phenols as dmax maintainers |
US648250A Expired - Lifetime US3495982A (en) | 1967-06-23 | 1967-06-23 | Process for dissolution development using thiourea compounds as dmax maintainers |
US648229A Expired - Lifetime US3493373A (en) | 1967-06-23 | 1967-06-23 | Photosolubilization image formation process with organic dmax. maintainers |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US648250A Expired - Lifetime US3495982A (en) | 1967-06-23 | 1967-06-23 | Process for dissolution development using thiourea compounds as dmax maintainers |
US648229A Expired - Lifetime US3493373A (en) | 1967-06-23 | 1967-06-23 | Photosolubilization image formation process with organic dmax. maintainers |
Country Status (4)
Country | Link |
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US (3) | US3495983A (en) |
BE (1) | BE716966A (en) |
DE (1) | DE1772705A1 (en) |
GB (1) | GB1234993A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3849133A (en) * | 1970-04-20 | 1974-11-19 | Fuji Photo Film Co Ltd | Process for forming photographic images by high speed diffusion transfer process |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3628956A (en) * | 1967-12-08 | 1971-12-21 | Du Pont | Process for preparing direct positive images by photosolubilization |
US3652279A (en) * | 1969-07-18 | 1972-03-28 | Du Pont | Nitrogen-containing dmax maintainers for use in photosoluble emulsions |
US4031127A (en) * | 1975-08-06 | 1977-06-21 | Eastman Kodak Company | Acyl hydrazino thiourea derivatives as photographic nucleating agents |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2230977A (en) * | 1940-04-04 | 1941-02-04 | American Cyanamid Co | Single solution photographic developing and fixing bath |
US3155507A (en) * | 1961-12-08 | 1964-11-03 | Du Pont | Photographic processes |
-
1967
- 1967-06-23 US US653590A patent/US3495983A/en not_active Expired - Lifetime
- 1967-06-23 US US648250A patent/US3495982A/en not_active Expired - Lifetime
- 1967-06-23 US US648229A patent/US3493373A/en not_active Expired - Lifetime
-
1968
- 1968-06-21 GB GB29787/68A patent/GB1234993A/en not_active Expired
- 1968-06-21 BE BE716966D patent/BE716966A/xx unknown
- 1968-06-22 DE DE19681772705 patent/DE1772705A1/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2230977A (en) * | 1940-04-04 | 1941-02-04 | American Cyanamid Co | Single solution photographic developing and fixing bath |
US3155507A (en) * | 1961-12-08 | 1964-11-03 | Du Pont | Photographic processes |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3849133A (en) * | 1970-04-20 | 1974-11-19 | Fuji Photo Film Co Ltd | Process for forming photographic images by high speed diffusion transfer process |
Also Published As
Publication number | Publication date |
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DE1772705A1 (en) | 1970-08-27 |
US3495982A (en) | 1970-02-17 |
GB1234993A (en) | 1971-06-09 |
US3493373A (en) | 1970-02-03 |
BE716966A (en) | 1968-12-23 |
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